JP5166774B2 - 複合物 - Google Patents
複合物 Download PDFInfo
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- JP5166774B2 JP5166774B2 JP2007142985A JP2007142985A JP5166774B2 JP 5166774 B2 JP5166774 B2 JP 5166774B2 JP 2007142985 A JP2007142985 A JP 2007142985A JP 2007142985 A JP2007142985 A JP 2007142985A JP 5166774 B2 JP5166774 B2 JP 5166774B2
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Composite Materials (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Mold Materials And Core Materials (AREA)
- Laminated Bodies (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Glass Melting And Manufacturing (AREA)
- Surface Treatment Of Glass (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Storage Of Fruits Or Vegetables (AREA)
- Cereal-Derived Products (AREA)
- Braking Arrangements (AREA)
- Audible-Bandwidth Dynamoelectric Transducers Other Than Pickups (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Glass Compositions (AREA)
Description
a)コロイド状無機粒子と、
b)1種もしくはそれ以上の一般式(I)
Rx−Si−A4−x (I)
[式中、
基Aは同一または異なりそしてメトキシ以外の加水分解的に除去することができる1個もしくは複数のヒドロキシル基であり、基Rは同一または異なりそして加水分解的に除去することができない基であり、そしてxは0,1,2または3であり、ここでシランの少なくとも50モル%ではx>1である]
のシランを、存在する加水分解可能な基1モル当り0.1〜0.45モル%の水を用いるゾル−ゲル法にて微小複合ゾルの生成、微小複合ゾルのさらなる加水分解と縮合、更に水を追加しての微小複合ゾルの活性化、およびその後の硬化により表面改質された複合材料に関する。
Si(OC2H5)4, Si(O-n-またはイソ-C3H7)4, Si(OC4H9)4, SiCl4, Si(OOCCH3)4,
CH3-SiCl3, CH3-Si(OC2H5)3, C2H5-SiCl3, C2H5-Si(OC2H5)3, C3H7-Si(OC2H5)3, C6H5-Si-(OC2H5)3, C6H5-Si(OC2H5)3, (C2H5O)3-Si-C3H6-Cl, (CH3)2SiCl2, (CH3)2Si(OC2H5)2, (CH3)2Si(OH)2, (C6H5)2SiCl2, (C6H5)2Si(OC2H5)2, (C6H5)2Si(OC2H5)2, (イソ-C3H7)3SiOH, CH2=CH-Si(OOCCH3)3, CH2=CH-SiCl3, CH2=CH-Si(OC2H5)3, HSiCl3, CH2=CH-Si(OC2H4OCH3)3,
CH2=CH-CH2-Si(OC2H5)3, CH2=CH-CH2-Si(OOCCH3)3,
CH2=C(CH3)COO-C3H7-Si-(OC2H5)3, CH2=C(CH3)-COO-C3H7-Si(OC2H5)3,
n-C6H13-CH2-CH2-Si(OC2H5)3, n-C8H17-CH2-CH2-Si(OC2H5)3,
RxSiO(2−0.5x)のポリシロキサンとして表される成分(b)の割合は一般的には20〜95重量%、好ましくは40〜90重量%、そして特に好ましくは70〜90重量%である。
MTEOS = メチルトリエトキシシラン
TEOS = テトラエトキシシラン
PTEOS = フェニルトリエトキシシラン
ETEOS = エチルトリエトキシシラン
803mlのMTEOSおよび223mlのTEOSを混合しそして比1:1で分ける。シラン混合物の半分を165gのZrO2ゾル(日産化学からのSNZS−30A)と共に強く攪拌しそして4.4gの濃塩酸と混合、そして5分後に、シラン混合物のもう一方の半分と混合する。
1.ゾルの製造
16.7mlのシリカゾルおよび0.49mlの濃塩酸を65.4mlのMTEOSおよび18.3mlのTEOSの混合物に激しく攪拌しながら加える。シラン類の反応後に、ゾルを氷浴中で冷却しそしてガラス繊維フィルター(シュライヘル・アンド・シュール(Schleicher and Schull)、レジスト(Rezist)40GF)を用いて濾過する。
100gのガラスゴール小球を20mlの上記ゾルと混合しそして12cm直径のプレス型の中で5分間にわたり4.4MPaの圧力で加圧する。成形品を次に80℃で循環空気乾燥室中で8時間にわたり加熱する。これにより、原料の融点より低い温度においても寸法安定性のままである成形品を与える(成形品中のガラス小球の割合は6重量%である)。
1.標準結合剤Aの製造
フラスコに655gのMTEOSおよび191gのTEOSを、そして次に142gの水性シリカゾルを充填し、そして直後に9mlのH2SO4(40重量%)を生じた混合物に強く攪拌しながら加える。約1分間の強い攪拌後に、発熱反応が始まる(温度は約60℃に上昇する)。熟成のために、それのその後の使用のために分散液を室温で一夜保つかまたは1時間還流させる。
フラスコに621gのMTEOSおよび181gのTEOSを、そして次に185gの水性シリカゾル(「レバシル(Levasil)50/50」、SiO2固体含有量50重量%、バイエル(BAYER)製)を充填し、そして直後に10.3mlのH2SO4(40重量%)を生じた混合物に強く攪拌しながら加える。約1分間の強い攪拌後に、発熱反応が始まる(温度は約60℃に上昇する)。熟成のために、分散液を室温で一夜保つかまたは1時間還流させて、次工程に供する。
フラスコに463gのMTEOS、180gのTEOSおよび128gのジメチルジエトキシシランを充填し、その後に267gの水性シリカゾルおよび直後に6.06mlのHCl(37重量%)を生じた混合物に強く攪拌しながら加える。約1分間の強い攪拌後に、発熱反応が始まる(温度は約60℃に上昇する)。分散液を室温へのそれの冷却後に直接使用することができる。
Claims (14)
- 粉末状、薄片、シートまたは成形品の形状のガラスからなる基質および前記基質と接触する微小複合物により特徴づけられ、そして
a)コロイド状無機粒子と、
b)1種もしくはそれ以上の一般式(I)
Rx−Si−A4−x (I)
[式中、
基Aは同一または異なりそしてメトキシ以外の加水分解的に除去することができる1個もしくは複数のヒドロキシル基であり、基Rは同一または異なりそして加水分解的に除去することができない基であり、そしてxは0,1,2または3であり、ここでシランの少なくとも50モル%ではx>1である]
のシランを、存在する加水分解可能な基1モル当り0.1〜0.45モル%の水を用いるゾル−ゲル法にて微小複合ゾルの生成、微小複合ゾルのさらなる加水分解と縮合、更に水を追加しての微小複合ゾルの活性化、およびその後の硬化により表面改質された複合材料。 - 表面改質が酸縮合触媒の存在下で1〜2のpHにおいて行われることを特徴とする、請求項1記載の複合材料。
- 微小複合ゾルを室温〜120℃の温度における後反応にかけることを特徴とする、請求項1または2記載の複合材料。
- コロイド状無機粒子がゾルおよび微小のSiO2、TiO2、ZrO2、Al2O3、Y2O3、CeO2、SnO2、ZnO、酸化鉄または炭素のゾルまたは分散性粉末よりなる群から選択されることを特徴とする、請求項1〜3のいずれか1項に記載の複合材料。
- 微小複合ゾルを製造するために、硬化触媒、有機結合剤、顔料、染料、難燃剤、ガラス形成要素の化合物、腐食防止剤およびコーティング助剤からなる群から選ばれる他の添加剤(c)を使用することを特徴とする、請求項1〜4のいずれか1項に記載の複合材料。
- 微小複合物を製造するために5〜60重量%のコロイド状無機粒子を使用することを特徴とする、請求の範囲第1項〜第5項のいずれか1項に記載の複合材料。
- 微小複合物を製造するために20〜95重量%の式RxSiO(2−0.5x)で表されるポリシロキサンを使用することを特徴とする、請求項1〜6のいずれか1項に記載の複合材料。
- 微小複合物を製造するために20重量%より多くない他の添加剤(c)を使用することを特徴とする、請求項5〜7のいずれか1項に記載の複合材料。
- 存在する加水分解可能な基1モル当り0.25〜0.45モル%の水を使用して表面改質を行うことを特徴とする、請求項1〜8のいずれか1項に記載の複合材料。
- 微小複合物の重量割合が0.1〜80%であることを特徴とする、請求項1〜8のいずれか1項に記載の複合材料。
- .硬化を熱的に行うことを特徴とする、請求項1〜10のいずれか1項に記載の複合材料。
- 微小複合物でコーティングされた基質または微小複合物で統合された基質材料を含む成形品の形態での請求項1〜11のいずれか1項に記載の複合材料。
- 前記基質を、微小複合物がコーティングおよび/または統合している、請求項1〜12のいずれか1項に記載の複合材料。
- 前記基質がガラスの成形品であることを特徴とする請求項1〜13の何れか1項に記載の複合材料。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1996147368 DE19647368A1 (de) | 1996-11-15 | 1996-11-15 | Verbundwerkstoffe |
DE19647368.3 | 1996-11-15 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52318798A Division JP4003810B2 (ja) | 1996-11-15 | 1997-11-14 | 複合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007314416A JP2007314416A (ja) | 2007-12-06 |
JP5166774B2 true JP5166774B2 (ja) | 2013-03-21 |
Family
ID=7811826
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52318998A Pending JP2001508361A (ja) | 1996-11-15 | 1997-11-14 | 鋳物結合剤 |
JP52318898A Pending JP2001507085A (ja) | 1996-11-15 | 1997-11-14 | 植物原料を基にした複合材料 |
JP52318798A Expired - Lifetime JP4003810B2 (ja) | 1996-11-15 | 1997-11-14 | 複合物 |
JP2007142985A Expired - Lifetime JP5166774B2 (ja) | 1996-11-15 | 2007-05-30 | 複合物 |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52318998A Pending JP2001508361A (ja) | 1996-11-15 | 1997-11-14 | 鋳物結合剤 |
JP52318898A Pending JP2001507085A (ja) | 1996-11-15 | 1997-11-14 | 植物原料を基にした複合材料 |
JP52318798A Expired - Lifetime JP4003810B2 (ja) | 1996-11-15 | 1997-11-14 | 複合物 |
Country Status (14)
Country | Link |
---|---|
US (3) | US6287639B1 (ja) |
EP (3) | EP0938405B1 (ja) |
JP (4) | JP2001508361A (ja) |
CN (1) | CN1236339A (ja) |
AT (3) | ATE504553T1 (ja) |
AU (3) | AU5482598A (ja) |
BR (2) | BR9713084A (ja) |
CA (1) | CA2271310A1 (ja) |
DE (4) | DE19647368A1 (ja) |
ES (3) | ES2155707T3 (ja) |
ID (1) | ID18721A (ja) |
PL (1) | PL333455A1 (ja) |
PT (2) | PT946313E (ja) |
WO (3) | WO1998022536A2 (ja) |
Families Citing this family (138)
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DE19647368A1 (de) * | 1996-11-15 | 1998-05-20 | Inst Neue Mat Gemein Gmbh | Verbundwerkstoffe |
DE19963069A1 (de) * | 1999-12-24 | 2001-06-28 | Iwt Stiftung Inst Fuer Werksto | Schutzbeschichtung für Werkstück |
DE10021726A1 (de) * | 2000-05-04 | 2001-11-15 | Henkel Kgaa | Verwendung von nanoskaligen Teilchen zur Verbesserung der Schmutzablösung |
US6447860B1 (en) * | 2000-05-12 | 2002-09-10 | Pechiney Emballage Flexible Europe | Squeezable containers for flowable products having improved barrier and mechanical properties |
EP1156024A1 (en) * | 2000-05-19 | 2001-11-21 | "VLAAMSE INSTELLING VOOR TECHNOLOGISCH ONDERZOEK", afgekort "V.I.T.O." | Composite ceramic precursors and layers |
DE10036434A1 (de) * | 2000-07-26 | 2002-04-18 | Graf Papiere Gmbh I K | Verfahren zur Herstellung einer Barriereschicht auf einer Oberfläche und damit hergestellter Gegenstand |
DE10063090A1 (de) * | 2000-12-18 | 2002-06-20 | Henkel Kgaa | Nanoskaliges ZnO in Hygiene-Produkten |
DE10063519A1 (de) * | 2000-12-20 | 2002-07-04 | Nano X Gmbh | Lösungsmittelarme Sol-Gel-Systeme |
DE10063739B4 (de) * | 2000-12-21 | 2009-04-02 | Ferro Gmbh | Substrate mit selbstreinigender Oberfläche, Verfahren zu deren Herstellung und deren Verwendung |
US6447577B1 (en) | 2001-02-23 | 2002-09-10 | Intevep, S. A. | Method for removing H2S and CO2 from crude and gas streams |
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US6607036B2 (en) | 2001-03-01 | 2003-08-19 | Intevep, S.A. | Method for heating subterranean formation, particularly for heating reservoir fluids in near well bore zone |
US6579832B2 (en) | 2001-03-02 | 2003-06-17 | Intevep S.A. | Method for treating drilling fluid using nanoparticles |
US6554070B2 (en) | 2001-03-16 | 2003-04-29 | Intevep, S.A. | Composition and method for sealing an annular space between a well bore and a casing |
US20040247897A1 (en) * | 2001-07-18 | 2004-12-09 | Hans-Joachim Quenzer | Sol solution for producing glass coatings for electrically conductive materials that can be used in anodic bonding |
TW523532B (en) * | 2001-08-09 | 2003-03-11 | Ind Tech Res Inst | Epoxy/clay nanocomposite for copper clad laminate applications |
US6579572B2 (en) | 2001-08-13 | 2003-06-17 | Intevep, S.A. | Water-based system for altering wettability of porous media |
DE10141687A1 (de) * | 2001-08-25 | 2003-03-06 | Degussa | Siliciumverbindungen enthaltendes Mittel zur Beschichtung von Oberflächen |
US6723378B2 (en) * | 2001-10-25 | 2004-04-20 | The Regents Of The University Of California | Fibers and fabrics with insulating, water-proofing, and flame-resistant properties |
DE10201747C1 (de) * | 2002-01-18 | 2003-08-14 | Schott Glas | Glas-Keramik-Komposit, Verfahren zu seiner Herstellung und Verwendungen |
TR200401615T4 (tr) † | 2002-07-31 | 2004-09-21 | Itn Nanovation Gmbh | Yakma kazanları |
US6793592B2 (en) * | 2002-08-27 | 2004-09-21 | Acushnet Company | Golf balls comprising glass ionomers, or other hybrid organic/inorganic compositions |
US7238122B2 (en) * | 2002-08-27 | 2007-07-03 | Acushnet Company | Ormocer composites for golf ball components |
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WO2004044486A2 (en) * | 2002-11-14 | 2004-05-27 | Koninklijke Philips Electronics N.V. | Light-transmitting substrate provided with a light-absorbing coating |
DE10303650A1 (de) * | 2003-01-27 | 2004-07-29 | Hansgrohe Ag | Beschichtungsverfahren |
DE10303649A1 (de) * | 2003-01-27 | 2004-07-29 | Hansgrohe Ag | Beschichtungsverfahren |
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DE10308949B4 (de) * | 2003-02-28 | 2008-12-11 | BAM Bundesanstalt für Materialforschung und -prüfung | Verfahren zur Herstellung von anorganisch modifizierten cellulosehaltigen Werkstoffen sowie anorganisch modifizierter Werkstoff |
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ES2292879T3 (es) * | 2003-06-13 | 2008-03-16 | ESK CERAMICS GMBH & CO.KG | Capa desmoldeante duradera de nitruro de boro para el moldeo por inyeccion de metales no ferricos. |
DE10326769B3 (de) * | 2003-06-13 | 2004-11-11 | Esk Ceramics Gmbh & Co. Kg | Dauerhafte BN-Formtrennschichten für das Druckgießen von Nichteisenmetallen |
DE10334856B4 (de) * | 2003-07-29 | 2007-06-06 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Verbundformteil und Verfahren zu seiner Herstellung |
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