JP5161988B2 - 手袋に対するテクスチャード加工表面被覆および製造方法 - Google Patents
手袋に対するテクスチャード加工表面被覆および製造方法 Download PDFInfo
- Publication number
- JP5161988B2 JP5161988B2 JP2011043970A JP2011043970A JP5161988B2 JP 5161988 B2 JP5161988 B2 JP 5161988B2 JP 2011043970 A JP2011043970 A JP 2011043970A JP 2011043970 A JP2011043970 A JP 2011043970A JP 5161988 B2 JP5161988 B2 JP 5161988B2
- Authority
- JP
- Japan
- Prior art keywords
- latex
- glove
- layer
- nitrile
- textured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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Images
Classifications
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Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Gloves (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は、テクスチャード加工表面を伴う手袋および該手袋を製造する方法に関する。
無保護(Unsupported)手袋は、手のような形状の手袋の型を液体ラテックスおよび混合化学薬品のタンクの中に浸漬することにより製造される。ラテックスはゴムを硬化するのに用いられる硫化剤を含んでいてもよく、そして乾燥ゴムフィルムが製造される。型は、最初に、ラテックスをゲル化し次に手袋を型から取り除くのを容易にする凝固剤で予め被覆される。予め被覆された型は、その後手袋を製造するのに必要な化学薬品のタンクに浸漬される。まだ型上にある間に、ラテックス手袋はまたタンパク質および残余化学薬品を浸出させるために1またはそれ以上の洗浄処理をうける。湿ったゲルは、加熱した炉内で乾燥および硬化され、ラテックス手袋は、型から裏返しに剥ぎ取られ、パッケージ化され、および/または滅菌される前に型上で硬化する。剥ぎ取られた手袋の内側表面は滑らかであると同時に手袋の外側表面は手袋の型由来のテクスチャーの痕(impression)を採る。
本発明の原理に基づいて、一般的な塩のような離散粒子の層を被覆したラテックスフィルムの液体表面に包埋し、浸漬したラテックス層をゲル化または乾燥し、テクスチャード加工表面を残すように離散粒子を溶解し、それから浸出、乾燥および硬化しそして最後に型から手袋を取り除くことにより製造したテクスチャード加工表面被覆を有する手袋が提供される。一実施態様において、本発明は、湿潤グリップを改良するために手袋外側の、快適性を改良するために手袋内側の、または両方のテクスチャード加工表面被覆を提供し得る。他の実施態様において、本発明はまた、発泡材料を織布、メリヤス生地または他の下地層に塗布し、液体発泡材料層の中に離散粒子の層を包埋し、発泡層を加工しそして包埋した離散粒子を溶解することにより製造されたテクスチャード加工表面を提供し得る。別の実施態様において、本発明はさらにそれによりテクスチャード加工表面被覆または開細胞型発泡表面被覆を伴う手袋を製造することができる方法を提供する。
本発明は、非ゲル化ラテックスの層に離散粒子を包埋することにより製造した無発泡ラテックスまたは発泡ラテックスのいずれかにより製造されたテクスチャード加工表面被覆を伴う手袋に関する。ラテックス層は、理想的には離散粒子に接触することでゲル化している。プロセスは手袋を乾燥および硬化することにより完了する。離散粒子は、粒子を適当な溶媒中に溶解させることにより、ゲル化または硬化後のいずれかに層から除去され得る。このプロセスは、離散粒子が包埋していた箇所に痕(impression)を残し、グリップ、より少ない直の皮膚の接触を伴う手袋内の空気循環および吸汗性の程度を改良し得るテクスチャード加工表面被覆となる。例えば、湿潤/油グリップは、本発明のテクスチャード加工手袋において改良される。発泡材料は、テクスチャード加工表面層を製造するために無発泡ラテックスの代わりに使用されてもよく、優れたグリップ、より高い吸汗性および絶縁体(insulation)の柔軟な層を提供する。
硝酸カルシウム、 水溶液濃度35容量%
TRITON X 100 約0.1容量%
DEFOAMER 1512M 約0.5容量%
凝固剤溶液を30から40℃に加熱する。清浄な陶材の手袋の型は、凝固剤溶液中に浸漬することによりその表面を均一に被覆する。浸漬速度はおよそ1.5cm/秒、滞留時間は5から10秒、そして抽出速度はおよそ0.75cm/秒である。
REVENEX 99G43 100phr
硫黄 0.5phr
酸化亜鉛 3.0phr
ZMBT 0.7phr
pHを9.0に調節する(アンモニアまたは水酸化カリウムを用いて)。ラテックスの粘度は通常20から40cps(ブルックフィールド粘度計モデルDV1+、スピンドル# 2 @ 30 rpm)である。ラテックスは20から25℃に保持する。浸漬速度はおよそ1.5cm/秒、ラテックス中の滞留時間は所望の壁厚に依存し30から90秒、そして抽出速度はおよそ1.2cm/秒である。
REVENEX 99G43 100phr
硫黄 0.5phr
酸化亜鉛 3.0phr
ZMBT 0.7phr
このラテックスのpHは9.0に調節されており(アンモニアまたは水酸化カリウムを用いて)、ラテックスの粘度はポリアクリル酸アンモニウムを用いて500cps(ブルックフィールド粘度計モデル DV1+、スピンドル# 2 @ 30 rpm)に調節されている。ラテックスは20から25℃に保持する。浸漬速度はおよそ1から3cm/秒、ラテックス中の滞留時間はおよそ10から30秒、そして抽出速度はおよそ2cm/秒である。
1.ボランティアの試験者が試験手袋を着用する。
2.試験者は、親指および第一指(または第二指)のみを用いて、各向かい合った表面上の1本の指は床に向かって表面に沿っておよそ4cmの点で、接触点として指および親指の指腹の先のみを用いて、表面に対して直角に装置をグリップする。
3.試験者は、装置を強く握り持ち上げようと試み、それから滑らずに静止して保持するのに十分な力で装置を保持する。
4.即時グリップ力が、質量秤を読み取った質量単位で記録される。
5.最初のグリップおよび持ち上げの後、定常グリップ力がおよそ5から10秒後に記録される。
6.グリップは、装置がグリップからすべるように徐々に緩められる。
7.最小グリップ力がすべりの時点で記録される。
8.さらなる重量が続いて装置に加えられ、そしてステップ1−7が繰り返される。
Claims (8)
- 湿潤グリップを備え付けるのに適した手袋であって、該手袋が、ラテックス材料の保護、又は非ラテックス材料の保護、及びラテックスを含む外側の層を含み、ここで該外側の層がラテックス上に位置する多面的な痕を有するテクスチャード加工表面であり、該テクスチャード加工表面が、
(i)非硬化ラテックスを多面的な塩の粒子に曝して効果的にラテックスを不安定化して、多面的な痕を形成し、
(ii)ラテックス表面から該塩を洗浄除去し、且つ
(iii)その後にのみラテックス表面を熱硬化する、
ことにより形成され得る構成を有する、手袋。 - 痕が外側の層に沿って、50〜6000ミクロンの大きさの範囲で存在する、請求項1記載の手袋。
- ラテックスが、天然ゴムラテックス、またはポリウレタン、ニトリル、ポリクロロプレン、もしくはそれらの組み合わせを含む合成ゴムラテックスを含む、請求項1記載の手袋。
- 外側の層が、液体不浸透性ニトリルラテックスを含む、請求項1記載の手袋。
- ニトリルラテックス層の第一の側が複数の多面的な痕を含み、ニトリルラテックス層の第二の側は痕が実質的にない、請求項4記載の手袋。
- 着用された場合、潤滑油および油圧オイルで覆われたステンレス鋼の細長い部分を有する1.9kgの重荷を垂直に持ち上げるために約3.2kg以下の即時グリップ力を要する、請求項1記載の手袋。
- 着用された場合、潤滑油および油圧オイルで覆われたステンレス鋼の細長い部分を有する2.7kgの重荷を垂直に持ち上げるために約4.5kg以下の即時グリップ力を要する、請求項1記載の手袋。
- 着用された場合、潤滑油および油圧オイルで覆われたステンレス鋼の細長い部分を有する3.5kgの重荷を垂直に持ち上げるために約6.8kg以下の即時グリップ力を要する、請求項1記載の手袋。
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US10/882,016 US7771644B2 (en) | 2003-07-02 | 2004-06-30 | Textured surface coating for gloves and method of making |
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