JP4955759B2 - 強化された接着性を有するポリオレフィン層を含んでなる構造部材 - Google Patents
強化された接着性を有するポリオレフィン層を含んでなる構造部材 Download PDFInfo
- Publication number
- JP4955759B2 JP4955759B2 JP2009512467A JP2009512467A JP4955759B2 JP 4955759 B2 JP4955759 B2 JP 4955759B2 JP 2009512467 A JP2009512467 A JP 2009512467A JP 2009512467 A JP2009512467 A JP 2009512467A JP 4955759 B2 JP4955759 B2 JP 4955759B2
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- Prior art keywords
- layer
- profile
- polyolefin
- composition
- cladding tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 83
- 239000000203 mixture Substances 0.000 claims abstract description 70
- 150000003961 organosilicon compounds Chemical class 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims description 31
- 239000002184 metal Substances 0.000 claims description 31
- 229910000831 Steel Inorganic materials 0.000 claims description 23
- 238000005253 cladding Methods 0.000 claims description 23
- 239000010959 steel Substances 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 16
- 230000001737 promoting effect Effects 0.000 claims description 13
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 229920001384 propylene homopolymer Polymers 0.000 claims description 3
- 125000005372 silanol group Chemical group 0.000 claims description 3
- 238000004381 surface treatment Methods 0.000 claims description 2
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 109
- 239000004593 Epoxy Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- -1 polypropylene Polymers 0.000 description 13
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 12
- 239000012790 adhesive layer Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Chemical class OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Chemical class OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical class OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
- 239000011976 maleic acid Chemical class 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 150000001282 organosilanes Chemical class 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910020175 SiOH Inorganic materials 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 238000007719 peel strength test Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical class FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229920003182 Surlyn® Polymers 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002998 adhesive polymer Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- NIDNOXCRFUCAKQ-UHFFFAOYSA-N bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical class C1C2C=CC1C(C(=O)O)C2C(O)=O NIDNOXCRFUCAKQ-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical class OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical class C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- RTFMGYRAUWLAJG-UHFFFAOYSA-N dimethoxy-methyl-prop-2-enoxysilane Chemical compound CO[Si](C)(OC)OCC=C RTFMGYRAUWLAJG-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- NNBRCHPBPDRPIT-UHFFFAOYSA-N ethenyl(tripropoxy)silane Chemical compound CCCO[Si](OCCC)(OCCC)C=C NNBRCHPBPDRPIT-UHFFFAOYSA-N 0.000 description 1
- MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 description 1
- 229920006245 ethylene-butyl acrylate Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000005002 finish coating Substances 0.000 description 1
- 239000001530 fumaric acid Chemical class 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- RSKGMYDENCAJEN-UHFFFAOYSA-N hexadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OC)(OC)OC RSKGMYDENCAJEN-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
- ICRFXIKCXYDMJD-UHFFFAOYSA-N n'-benzyl-n'-ethenyl-n-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN(C=C)CC1=CC=CC=C1 ICRFXIKCXYDMJD-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Chemical class CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- SGCFZHOZKKQIBU-UHFFFAOYSA-N tributoxy(ethenyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=C SGCFZHOZKKQIBU-UHFFFAOYSA-N 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- OYGYKEULCAINCL-UHFFFAOYSA-N triethoxy(hexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC OYGYKEULCAINCL-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
- SYYDEXILBJXXIA-UHFFFAOYSA-N trimethoxy(pent-4-enyl)silane Chemical compound CO[Si](OC)(OC)CCCC=C SYYDEXILBJXXIA-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
- F16L58/04—Coatings characterised by the materials used
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L58/00—Protection of pipes or pipe fittings against corrosion or incrustation
- F16L58/02—Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
- F16L58/04—Coatings characterised by the materials used
- F16L58/10—Coatings characterised by the materials used by rubber or plastics
- F16L58/1054—Coatings characterised by the materials used by rubber or plastics the coating being placed outside the pipe
- F16L58/109—Coatings characterised by the materials used by rubber or plastics the coating being placed outside the pipe the coating being an extruded layer
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/14—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
- F16L9/147—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups comprising only layers of metal and plastics with or without reinforcement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/06—Coating on the layer surface on metal layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/24—Organic non-macromolecular coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
- Y10T428/1359—Three or more layers [continuous layer]
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Description
(i)第一材料から構成される層または異形材(A)と、
(ii)層または異形材(A)に隣接し、ポリオレフィンを含むベース樹脂を含んでなる組成物から構成されるポリオレフィン層または異形材(B)、
を含んでなる構造部材であって、層または異形材(A)と層または異形材(B)のいずれかまたは両方の表面は、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む組成物で処理されていることを特徴とする構造部材を提供する。
好ましくは、有機ケイ素化合物は非ポリマー化合物である。
を一末端に有しビニル基を反対の末端に有する加水分解されたビニルシランである。
からなる群から選択される。
好ましくは、該接着促進性基は極性基である。
第一の実施形態では、内側金属壁の外側表面上に、中間のポリオレフィン接着層を形成し、その上に、順に外側のポリオレフィン保護層を形成する。
1.定義および測定法
a)メルトフローレート
メルトフローレート(MFR)は、ISO 1133に準じて決定され、「g/10分」で表示する。MFRは、ポリマーの流動性、したがって加工性を表示するものである。メルトフローレートが高ければ高いほど、ポリマーの粘度は低い。MFRは、ポリエチレンについては190℃、ポリプロピレンについては230℃で決定される。MFRは、2.16kg(MFR2)、5kg(MFR5)または21.6kg(MFR21)などの異なる荷重で決定してよい。
スチール上のポリマーの接着性は、Instron 1122剥離強度試験装置によってDIN 30670に準じて試験した。3cm幅のストリップをコーティング層から切り取る。ストリップの他端を引張装置に固定し、スチールから10mm/分の引張速度でストリップを引っ張る間、引張強さを測定する。結果はN/cmで表す。
以下の手順に従って、異なった被覆スチール管構造部材を製造した。
パイプ輸送システム、誘導オーブン、エポキシ噴霧ユニット、接着剤ポリマー用押出機、最上層用押出機および冷却槽からなる連続式クロスヘッド押出ライン(side extrusion line)であるスチール管被覆パイロットラインで、コーティングを行った。
スチール管コーティングラインに用いたスチール管は、長さ1mおよび直径100mmである。
清浄なスチールグリットブラスト仕上スチール管をローリング輸送バンド上にセットした。誘導オーブン中、数秒の滞留時間で管表面を180〜220℃まで加熱した。
清浄なスチールグリットブラスト仕上スチール管(比較例1と同じもの)を、ローリング輸送バンド上にセットした。外側の管表面を噴霧によって10%有機シラン−水溶液(Oxsilan MM−0705、Chemetallから入手可能)で湿潤させた。次いで、スチール表面を160℃まで加熱し、接着層を押し出す前に表面を乾燥させた。こうして得られた層の厚みは10マイクロメーターであった。
接着層と仕上塗層の押出は、比較例1と同様にして行った。
接着層と仕上塗層の押出はこれまでの実施例と同様にして行ったが、有機シランもエポキシ層も管表面上に加えない前に行った。
清浄なスチールグリットブラスト仕上スチール管を、ローリング輸送バンド上にセットした。管表面を噴霧によって10%有機シラン−水溶液(Oxsilan MM−0705、Chemetallから入手可能)で湿潤させた。次いで、スチール表面を160℃まで加熱し、表面を乾燥させた。こうして得られた層の厚みは10マイクロメーターであった。
有機シラン溶液によるスチール表面の処理を適用しなかったこと以外は実施例4と同様にして、コーティングを行った。
実施例1〜5の被覆管に対する剥離強度試験の結果を下記の表1に示す。
本明細書の当初の開示は、少なくとも下記の態様を包含する。
〔1〕 (i)第一材料から構成される層または異形材(A)と、
(ii)層または異形材(A)に隣接し、ポリオレフィンを含むベース樹脂を含んでなる組成物から構成されるポリオレフィン層または異形材(B)、
を含んでなる構造部材であって、層または異形材(A)と層または異形材(B)のいずれかまたは両方の表面は、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む組成物で処理されていることを特徴とする構造部材。
〔2〕 層または異形材(A)はポリマー組成物、ガラス、金属または金属合金から構成される、〔1〕に記載の構造部材。
〔3〕 層または異形材(A)は金属または金属合金から構成される、〔2〕に記載の構造部材。
〔4〕 層または異形材(A)の表面は、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む前記組成物で処理されている、〔1〕〜〔3〕のいずれかに記載の構造部材。
〔5〕 有機ケイ素化合物は、加水分解後にシラノール基を生じる一以上の加水分解性基を含んでなる、〔1〕〜〔4〕のいずれかに記載の構造部材。
〔6〕 有機ケイ素化合物は構造要素:
を含んでなる、〔1〕〜〔5〕のいずれかに記載の構造部材。
〔7〕 層または異形材(A)および/または層または異形材(B)の表面処理は、有機ケイ素化合物の溶液を表面に適用することを含む、〔1〕〜〔6〕のいずれかに記載の構造部材。
〔8〕 層または異形材(B)を構成する組成物のポリオレフィンは接着促進性基を含んでなる、〔1〕〜〔7〕のいずれかに記載の構造部材。
〔9〕 接着促進性基は極性基である、〔8〕に記載の構造部材。
〔10〕 ポリオレフィン中の極性基はアクリレート、カルボン酸およびアミンから選択される、〔9〕に記載の構造部材。
〔11〕 ポリオレフィン中の接着促進性基の量は0.01〜5.0モル%である、〔8〕〜〔10〕のいずれかに記載の構造部材。
〔12〕 層または異形材(B)を構成する組成物のベース樹脂のポリオレフィンは、エチレンホモポリマーまたはコポリマーもしくはプロピレンホモポリマーまたはコポリマーである、〔1〕〜〔11〕のいずれかに記載の構造部材。
〔13〕 第一材料から構成される層または異形材(A)の表面および/またはポリオレフィンを含む組成物から構成されるポリオレフィン層または異形材(B)の表面を、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む組成物で処理することを特徴とする、構造部材の製造方法。
〔14〕 〔1〕〜〔12〕に記載の構造部材を含むことを特徴とする物品。
〔15〕 被覆管である、〔14〕に記載の物品。
〔16〕 多層構造部材の層/異形材(A)はスチールから構成され、その外表面は、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む組成物で処理されている、〔15〕に記載の被覆管。
〔17〕 ポリオレフィンを含む組成物から構成される層/異形材(B)を含んでなる構造部材における接着促進剤としての、有機ケイ素化合物を含む組成物の使用。
Claims (12)
- 構造部材を含んでなる被覆管であって、該構造部材は、
(i)金属または金属合金から構成される層または異形材(A)と、
(ii)層または異形材(A)に隣接し、ポリオレフィンを含むベース樹脂を含んでなる組成物から構成されるポリオレフィン層または異形材(B)、
を含んでなる構造部材であって、層または異形材(A)の表面は、クロム酸塩で処理することなく、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む組成物で処理されていることを特徴とする、被覆管。 - 有機ケイ素化合物は、加水分解後にシラノール基を生じる一以上の加水分解性基を含んでなる、請求項1に記載の被覆管。
- 層または異形材(A)の表面処理は、有機ケイ素化合物の溶液を表面に適用することを含む、請求項1〜3のいずれかに記載の被覆管。
- 層または異形材(B)を構成する組成物のポリオレフィンは接着促進性基を含んでなる、請求項1〜4のいずれかに記載の被覆管。
- 接着促進性基は極性基である、請求項5に記載の被覆管。
- ポリオレフィン中の極性基はアクリレート、カルボン酸およびアミンから選択される、請求項6に記載の被覆管。
- ポリオレフィン中の接着促進性基の量は0.01〜5.0モル%である、請求項5〜7のいずれかに記載の被覆管。
- 層または異形材(B)を構成する組成物のベース樹脂のポリオレフィンは、エチレンホモポリマーまたはコポリマーもしくはプロピレンホモポリマーまたはコポリマーである、請求項1〜8のいずれかに記載の被覆管。
- 請求項1〜9のいずれかに記載の被覆管の製造方法であって、被覆管に含まれる構造部材は、金属または金属合金から構成される層または異形材(A)の表面を、(A)とポリオレフィンを含む組成物から構成されるポリオレフィン層または異形材(B)を互いに隣接させる前に有機ケイ素化合物を含む組成物で処理することにより製造される、方法。
- 多層構造部材の層/異形材(A)はスチールから構成され、その外表面は、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む組成物で処理されている、請求項1〜9のいずれかに記載の被覆管。
- 請求項1〜9および11のいずれかに記載の被覆管における接着促進剤としての、有機ケイ素化合物を含む組成物の使用であって、層または異形材(A)の表面は、クロム酸塩で処理することなく、(A)と(B)を互いに隣接させる前に有機ケイ素化合物を含む該組成物で処理されていることを特徴とする使用。
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EP06010822.2 | 2006-05-26 | ||
EP06010822A EP1859926B1 (en) | 2006-05-26 | 2006-05-26 | Coated pipe comprising polyolefin layer with enhanced adhesion |
PCT/EP2007/004633 WO2007137764A1 (en) | 2006-05-26 | 2007-05-24 | Coated pipe comprising polyolefin layer with enhanced adhesion |
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EP (1) | EP1859926B1 (ja) |
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Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL1985909T3 (pl) | 2007-04-25 | 2011-08-31 | Oy Kwh Pipe Ab | Sposób i urządzenie do powlekania rur |
PL2072587T3 (pl) | 2007-12-20 | 2020-11-02 | Borealis Technology Oy | Powlekane rury o ulepszonych właściwościach mechanicznych w wysokich temperaturach i sposób ich wytwarzania |
PL2072586T3 (pl) | 2007-12-20 | 2021-05-31 | Borealis Technology Oy | Powlekane rury o ulepszonych właściwościach mechanicznych i sposób ich wytwarzania |
EP2072588B1 (en) | 2007-12-20 | 2012-10-10 | Borealis Technology Oy | Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof |
EP2072589A1 (en) | 2007-12-20 | 2009-06-24 | Borealis Technology Oy | Process for coating a pipe with high throughput using multimodal ethylene copolymer, and coated pipes obtained thereof |
EP2298531A1 (en) | 2009-09-17 | 2011-03-23 | Oy KWH Pipe AB | Apparatus and method for coating pipes or pipe sections |
EP2298455A1 (en) | 2009-09-17 | 2011-03-23 | Borealis AG | Method of coating pipes or pipe sections |
EP2520625A1 (en) | 2011-05-06 | 2012-11-07 | Borealis AG | Coating composition |
EP2532769A1 (en) * | 2011-06-10 | 2012-12-12 | Amcor Flexibles Kreuzlingen Ltd. | Method of producing a chromium-free conversion coating on a surface of an aluminium or aluminium alloy strip |
KR101166886B1 (ko) | 2012-04-23 | 2012-07-18 | (주)금강 | 환형으로 권취가 용이한 금속 수지 복합관 및, 그 제조방법 |
FR2994243B1 (fr) * | 2012-08-06 | 2016-06-10 | Saint-Gobain Pam | Element de tuyauterie a base de fer pour canalisation enterree, comprenant un revetement exterieur |
ITMI20121679A1 (it) * | 2012-10-08 | 2014-04-09 | Saipem Spa | Metodo, apparecchiatura e stazione di lavoro per applicare un foglio protettivo di materiale polimerico a una tubazione e programma per elaboratore per attuare il metodo |
EP2860200B1 (en) | 2013-10-10 | 2017-08-02 | Borealis AG | Polyethylene composition for pipe and pipe coating applications |
KR101567916B1 (ko) | 2014-01-27 | 2015-11-10 | 임흥순 | 파이프 코팅 조성물 |
ES2709352T3 (es) * | 2014-12-30 | 2019-04-16 | Dow Global Technologies Llc | Derivado de sulfonil-azida para una capa de enlace |
EP3053976A1 (en) | 2015-02-09 | 2016-08-10 | Borealis AG | Adhesive composition |
US20220154870A1 (en) * | 2015-02-17 | 2022-05-19 | Winn & Coales International Limited | Metal pipes with anticorrosive polyolefin covering layer |
CN109563321B (zh) | 2016-06-03 | 2022-09-20 | Msi科技有限责任公司 | 粘合剂组合物、含所述粘合剂组合物的制品及其方法 |
CN109803986B (zh) | 2016-09-28 | 2020-04-14 | 博里利斯股份公司 | 用于制备涂覆管道的方法 |
US20220089802A1 (en) | 2019-01-28 | 2022-03-24 | Borealis Ag | Process for producing a polymer composition |
WO2021011576A1 (en) * | 2019-07-17 | 2021-01-21 | Jindal Films Americas Llc | Heat-stable biaxially oriented polypropylene films |
CN115803391A (zh) | 2020-07-13 | 2023-03-14 | 博里利斯股份公司 | 粘合剂聚乙烯组合物 |
KR20230038238A (ko) | 2020-07-13 | 2023-03-17 | 보레알리스 아게 | 접착성 폴리에틸렌 조성물 |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5274611A (en) * | 1975-11-05 | 1977-06-22 | Dynamit Nobel Ag | Production of laminated safety glass |
JPS5292918A (en) * | 1975-12-06 | 1977-08-04 | Kabel Metallwerke Ghh | Pipe for conveying liquid or gaseous medium * especially under high temperature and high pressure |
JPS5335780A (en) * | 1976-09-13 | 1978-04-03 | Philips Nv | Method of producing compound |
JPS5693542A (en) * | 1979-12-27 | 1981-07-29 | Mitsubishi Petrochemical Co | Bridged polyethylene resin laminated film or sheet |
JPS6244439A (ja) * | 1985-08-22 | 1987-02-26 | 新日本製鐵株式会社 | ポリオレフイン被覆金属管 |
JPS62230655A (ja) * | 1976-10-30 | 1987-10-09 | デイナミ−ト・ノ−ベル・アクチエンゲゼルシヤフト | 積層安全ガラスの製法 |
JPS63196631A (ja) * | 1985-04-10 | 1988-08-15 | アイ テイ テイ インダストリ−ズ インコ−ポレ−テツド | 複合構造体およびその製造方法 |
JPH0780991A (ja) * | 1993-09-16 | 1995-03-28 | Sekisui Chem Co Ltd | 積層体の製造方法 |
US5759629A (en) * | 1996-11-05 | 1998-06-02 | University Of Cincinnati | Method of preventing corrosion of metal sheet using vinyl silanes |
JPH10315390A (ja) * | 1997-05-21 | 1998-12-02 | Nkk Corp | 耐食性、アルカリ脱脂後の耐食性、塗装性に優れた有機被覆鋼板 |
GB2341434A (en) * | 1998-09-11 | 2000-03-15 | Burley Colin G | Method of lining pipes |
WO2001053367A1 (fr) * | 2000-01-21 | 2001-07-26 | Solvay Polyolefins Europe-Belgium (Societe Anonyme) | Composition a base de polyethylene reticulable |
DE10062272A1 (de) * | 2000-12-14 | 2002-06-20 | Solvay | Verfahren zur Herstellung von Rohren oder Formteilen" |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE265018C (ja) | ||||
LU35689A1 (ja) * | 1957-01-09 | 1900-01-01 | ||
US4077098A (en) * | 1975-04-07 | 1978-03-07 | Nippon Steel Corporation | Apparatus for manufacturing a metallic tube coated with a thermoplastic resin film having little residual strain |
CA1111750A (en) * | 1976-10-30 | 1981-11-03 | Rolf Beckmann | Laminated safety glass and a process for the production thereof |
US4639495A (en) * | 1981-12-21 | 1987-01-27 | E. I. Du Pont De Nemours And Company | Extruding process for preparing functionalized polyolefin polymers |
JPS58198530A (ja) * | 1982-05-17 | 1983-11-18 | Toa Nenryo Kogyo Kk | ポリオレフイン系共重合体の製造方法 |
US4950541A (en) * | 1984-08-15 | 1990-08-21 | The Dow Chemical Company | Maleic anhydride grafts of olefin polymers |
US4654262A (en) * | 1985-04-10 | 1987-03-31 | Itt Corporation | Polyolefin resin surface preparation |
US5194509A (en) * | 1986-11-20 | 1993-03-16 | Basf Aktiengesellschaft | Peroxide-free grafting of homopolymers and copolymers of ethylene having densities equal to or greater than 0.930 g/cm3, and use of the graft copolymers for the preparation of ionomers of adhesion promoters |
FI870161A (fi) * | 1987-01-15 | 1988-07-16 | Neste Oy | Modifierad polyolefin. |
CN1044128C (zh) | 1993-11-17 | 1999-07-14 | 上海橡胶制品研究所 | 有机硅胶粘剂用表面增粘处理剂 |
US5932306A (en) * | 1995-04-24 | 1999-08-03 | Usui Kokusai Sangyo Kaisha Limited | Corrosion-and-chipping-resistant resin coating structure for stainless steel pipes |
US6166142A (en) | 1998-01-27 | 2000-12-26 | E. I. Du Pont De Nemours And Company | Adhesive compositions based on blends of grafted metallocene catalyzed and polar ethylene copolymers |
BE1012796A3 (fr) * | 1999-07-26 | 2001-03-06 | Solvay | Article imprimable a base de polyolefine. |
EP1260547A1 (en) * | 2001-05-21 | 2002-11-27 | Borealis Technology OY | Polyolefin coated steel pipes |
ES2341605T3 (es) | 2001-11-29 | 2010-06-23 | Borealis Technology Oy | Composicion polimerica adhesiva. |
US7064163B2 (en) * | 2002-09-04 | 2006-06-20 | Msi Technology Llc | Polyolefin-based adhesive resins and method of making adhesive resins |
US6894115B2 (en) * | 2002-12-17 | 2005-05-17 | Equistar Chemicals, Lp | Dual-functionalized adhesive compositions |
-
2006
- 2006-05-26 AT AT06010822T patent/ATE554917T1/de active
- 2006-05-26 EP EP06010822A patent/EP1859926B1/en not_active Not-in-force
-
2007
- 2007-05-24 KR KR1020087030446A patent/KR20090020613A/ko active Search and Examination
- 2007-05-24 CN CN2007800191613A patent/CN101454149B/zh not_active Expired - Fee Related
- 2007-05-24 CA CA2653749A patent/CA2653749C/en not_active Expired - Fee Related
- 2007-05-24 WO PCT/EP2007/004633 patent/WO2007137764A1/en active Application Filing
- 2007-05-24 US US12/301,826 patent/US9453598B2/en active Active
- 2007-05-24 AU AU2007267421A patent/AU2007267421B2/en not_active Ceased
- 2007-05-24 JP JP2009512467A patent/JP4955759B2/ja not_active Expired - Fee Related
- 2007-05-24 BR BRPI0712922-0A patent/BRPI0712922A2/pt active Search and Examination
- 2007-05-24 EA EA200802374A patent/EA014517B1/ru not_active IP Right Cessation
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5274611A (en) * | 1975-11-05 | 1977-06-22 | Dynamit Nobel Ag | Production of laminated safety glass |
JPS5292918A (en) * | 1975-12-06 | 1977-08-04 | Kabel Metallwerke Ghh | Pipe for conveying liquid or gaseous medium * especially under high temperature and high pressure |
JPS5335780A (en) * | 1976-09-13 | 1978-04-03 | Philips Nv | Method of producing compound |
JPS62230655A (ja) * | 1976-10-30 | 1987-10-09 | デイナミ−ト・ノ−ベル・アクチエンゲゼルシヤフト | 積層安全ガラスの製法 |
JPS5693542A (en) * | 1979-12-27 | 1981-07-29 | Mitsubishi Petrochemical Co | Bridged polyethylene resin laminated film or sheet |
JPS63196631A (ja) * | 1985-04-10 | 1988-08-15 | アイ テイ テイ インダストリ−ズ インコ−ポレ−テツド | 複合構造体およびその製造方法 |
JPS6244439A (ja) * | 1985-08-22 | 1987-02-26 | 新日本製鐵株式会社 | ポリオレフイン被覆金属管 |
JPH0780991A (ja) * | 1993-09-16 | 1995-03-28 | Sekisui Chem Co Ltd | 積層体の製造方法 |
US5759629A (en) * | 1996-11-05 | 1998-06-02 | University Of Cincinnati | Method of preventing corrosion of metal sheet using vinyl silanes |
JP2001504146A (ja) * | 1996-11-05 | 2001-03-27 | ザ ユニバーシティ オブ シンシナティ | ビニルシランを用いた金属シートの腐蝕の防止法 |
JPH10315390A (ja) * | 1997-05-21 | 1998-12-02 | Nkk Corp | 耐食性、アルカリ脱脂後の耐食性、塗装性に優れた有機被覆鋼板 |
GB2341434A (en) * | 1998-09-11 | 2000-03-15 | Burley Colin G | Method of lining pipes |
WO2001053367A1 (fr) * | 2000-01-21 | 2001-07-26 | Solvay Polyolefins Europe-Belgium (Societe Anonyme) | Composition a base de polyethylene reticulable |
DE10062272A1 (de) * | 2000-12-14 | 2002-06-20 | Solvay | Verfahren zur Herstellung von Rohren oder Formteilen" |
Also Published As
Publication number | Publication date |
---|---|
EP1859926A1 (en) | 2007-11-28 |
CN101454149A (zh) | 2009-06-10 |
BRPI0712922A2 (pt) | 2012-10-02 |
CA2653749C (en) | 2011-11-29 |
EP1859926B1 (en) | 2012-04-25 |
CA2653749A1 (en) | 2007-12-06 |
US20110217497A1 (en) | 2011-09-08 |
EA200802374A1 (ru) | 2009-06-30 |
AU2007267421B2 (en) | 2010-08-19 |
WO2007137764A1 (en) | 2007-12-06 |
JP2009538246A (ja) | 2009-11-05 |
CN101454149B (zh) | 2012-06-20 |
EA014517B1 (ru) | 2010-12-30 |
ATE554917T1 (de) | 2012-05-15 |
AU2007267421A1 (en) | 2007-12-06 |
US9453598B2 (en) | 2016-09-27 |
KR20090020613A (ko) | 2009-02-26 |
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