JP2022017378A - 洗剤組成物 - Google Patents
洗剤組成物 Download PDFInfo
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- JP2022017378A JP2022017378A JP2021173515A JP2021173515A JP2022017378A JP 2022017378 A JP2022017378 A JP 2022017378A JP 2021173515 A JP2021173515 A JP 2021173515A JP 2021173515 A JP2021173515 A JP 2021173515A JP 2022017378 A JP2022017378 A JP 2022017378A
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- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/166—Organic compounds containing borium
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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Abstract
Description
本明細書で使用するとき、用語「アルコキシ」は、C1~C8アルコキシ、及びブチレンオキシド、グリシドールオキシド、エチレンオキシド又はプロピレンオキシドなどの繰り返し単位を有するポリオールのC1~C8アルコキシ誘導体を含むことを意図する。
ヌクレアーゼ酵素は、核酸のヌクレオチドサブユニット間のホスホジエステル結合を切断することができる酵素である。本明細書におけるヌクレアーゼ酵素は、好ましくは、デオキシリボヌクレアーゼ若しくはリボヌクレアーゼ酵素、又はこれらの機能的断片である。機能的断片又は部分とは、DNA骨格鎖におけるホスホジエステル結合の切断を触媒するヌクレアーゼ酵素の部分を意味し、したがって、触媒活性を保持する上記のヌクレアーゼタンパク質の領域である。したがって、それは、その機能が維持されている酵素及び/又は変異体及び/又は誘導体及び/又はホモログの、切頭されているが機能的なバージョンを含む。
界面活性剤系は、アニオン性界面活性剤及び非イオン性界面活性剤を含み、アニオン性界面活性剤の非イオン性界面活性剤に対する重量比は、1.5:1~1:10、好ましくは1.2:1~1:5、より好ましくは1:1~1:4である。
アニオン性界面活性剤は、1つの界面活性剤、又は典型的には、1つを超える界面活性剤の混合物を含み得る。好ましいアニオン性洗浄性界面活性剤は、アルキルベンゼンスルホネート、アルコキシル化アニオン性界面活性剤、又はこれらの組み合わせである。好適なアニオン性洗浄性界面活性剤としては、サルフェート洗浄性界面活性剤及びスルホネート洗浄性界面活性剤が挙げられる。
好適な非イオン性界面活性剤の例は、C8~C18アルキルエトキシレート(例えば、Shell製のNEODOL(登録商標)非イオン性界面活性剤);C6~C12アルキルフェノールアルコキシレート(アルコキシレート単位は、エチレンオキシ単位、プロピレンオキシ単位、又はこれらの混合物であってよい);エチレンオキシド/プロピレンオキシドブロックポリマーとのC12~C18アルコール及びC6~C12アルキルフェノール縮合物(例えば、BASF製のPluronic(登録商標));C14~C22中鎖分枝状アルコール;C14~C22中鎖分枝状アルキルアルコキシレート(典型的には1~30の平均アルコキシル化度を有する);アルキル多糖類(一態様では、アルキルポリグリコシド);ポリヒドロキシ脂肪酸アミド、エーテル末端保護ポリ(オキシアルキル化)アルコール界面活性剤、並びにこれらの混合物からなる群から選択される。
本発明の洗浄組成物は、ヌクレアーゼ酵素及び界面活性剤系に加えて、任意の洗浄及び/又は処理補助物質を含む。好ましくは、本組成物は、E.C.3.2.1.52のβ-N-アセチルグルコサミニダーゼ酵素、好ましくは、配列番号4に対して少なくとも70%又は少なくとも75%又は少なくとも80%又は少なくとも85%又は少なくとも90%又は少なくとも95%又は少なくとも96%又は少なくとも97%又は少なくとも98%又は少なくとも99%又は少なくとも100%の同一性を有する酵素を更に含む。存在するとき、β-N-アセチルグルコサミニダーゼ酵素は、典型的には、組成物の約0.00001重量%~約2重量%、約0.0001重量%~約1重量%、又は更には約0.001重量%~約0.5重量%の酵素タンパク質の量で存在する。
(a)米国特許第6,312,936(B1)号、同第5,679,630号、同第4,760,025号、同第7,262,042号、及び国際公開第WO09/021867号に記載されている、バチルス・レンタス(Bacillus lentus)、バチルス・アルカロフィラス(B. alkalophilus)、バチルス・ズブチルス(B. subtilis)、バチルス・アミロリケファシエンス(B. amyloliquefaciens)、バチルス・プミルス(Bacillus pumilus)、及びバチルス・ギブソニイ(Bacillus gibsonii)などのバチルス属由来のものを含むサブチリシン(EC 3.4.21.62)。
(b)国際公開第89/06270号に記載されているフサリウム属プロテアーゼ、並びに同第05/052161号及び同第05/052146号に記載されているセルロモナス属に由来するキモトリプシンプロテアーゼを含むトリプシン(例えば、ブタ又はウシ起源)などのトリプシン型又はキモトリプシン型プロテアーゼ。
(c)国際公開第07/044993(A2)号に記載されているバチルス・アミロリケファシエンスに由来するものを含むメタロプロテアーゼ。
(a)国際公開第94/02597号、同第94/18314号、同第96/23874号及び同第97/43424号に記載されている変異体、特に国際公開第96/23874号に配列番号2として列挙されている酵素に対して、以下の位置:15、23、105、106、124、128、133、154、156、181、188、190、197、202、208、209、243、264、304、305、391、408及び444のうちの1つ以上が置換されている変異体。
(b)米国特許第5,856,164号、並びに国際公開第99/23211号、同第96/23873号、同第00/60060号及び同第06/002643号に記載されている変異体、特に国際公開第06/002643号に配列番号12として列挙されているAA560酵素に対して、以下の位置:
26、30、33、82、37、106、118、128、133、149、150、160、178、182、186、193、203、214、231、256、257、258、269、270、272、283、295、296、298、299、303、304、305、311、314、315、318、319、339、345、361、378、383、419、421、437、441、444、445、446、447、450、461、471、482、484のうちの1つ以上が置換されている変異体、好ましくはD183*及びG184*の欠失も含有する変異体。
(c)国際公開第06/002643号における配列番号4、バチルス属SP722由来の野生型酵素と少なくとも90%の同一性を示す変異体、特に183及び184位に欠失を有する変異体、並びに参照によって本明細書に組み込まれる国際公開第00/60060号に記載されている変異体。
(d)バチルス属の種707(米国特許第6,093,562号の配列番号7)由来の野生型酵素と少なくとも95%の同一性を示す変異体、特に以下の変異:M202、M208、S255、R172及び/又はM261のうちの1つ以上含をむもの。好ましくは、上記のアミラーゼは、M202L、M202V、M202S、M202T、M202I、M202Q、M202W、S255N及び/又はR172Qのうちの1つ以上を含む。特に好ましいのは、M202L又はM202T突然変異を含むものである。
(e)国際公開第09/149130号に記載されている変異体、好ましくは国際公開第09/149130号の配列番号1又は配列番号2と少なくとも90%の同一性を示す変異体、ゲオバチルス・ステアロフェルモフィルス(Geobacillus Stearophermophiluss)に由来する野生型酵素又はその切頭バージョン。
(f)欧州特許第2540825号及び同第2357220号、同第2534233号に記載されている変異体。(g)国際公開第2009100102号及び同第2010115028号に記載されている変異体。
(VI)-[(OCHR1-CHR2)a-O-OC-Ar-CO-]d
(VII)-[(OCHR3-CHR4)b-O-OC-sAr-CO-]e
(VIII)-[(OCHR5-CHR6)c-OR7]f
(式中、
a、b及びcは、1~200であり、
d、e及びfは、1~50であり、
Arは、1,4-置換フェニレンであり、
sArは、5位がSO3Meで置換されている1,3-置換フェニレンであり、
Meは、Li、K、Mg/2、Ca/2、Al/3、アンモニウム、モノ-、ジ-、トリ-若しくはテトラアルキルアンモニウム(アルキル基は、C1~C18アルキル又はC2~C10ヒドロキシアルキルである)、又はこれらの混合物であり;
R1、R2、R3、R4、R5及びR6は、独立して、H又はC1~C18n-若しくはイソ-アルキルであり、
R7は、直鎖若しくは分枝鎖C1~C18アルキル、又は直鎖若しくは分枝鎖C2~C30アルケニル、又は5~9個の炭素原子を有するシクロアルキル基、又はC8~C30アリール基又はC6~C30アリールアルキル基である)。
(R)(R1)(R2)(R3)N+X-
(式中、Rは、直鎖又は分枝鎖、置換又は非置換のC6~18アルキル又はアルケニル部分であり、R1及びR2は、独立して、メチル又はエチル部分から選択され、R3は、ヒドロキシル、ヒドロキシメチル又はヒドロキシエチル部分であり、Xは、電気的中性を提供するアニオンであり、好適なアニオンとしては、例えば塩化物などのハロゲン化物、硫酸及びスルホン酸が挙げられる。好適なカチオン性洗浄界面活性剤は、モノ-C6~18アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロライドである。非常に好適なカチオン性洗浄界面活性剤は、モノ-C8~10アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロライド、モノ-C10~12アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロライド、及びモノ-C10アルキルモノヒドロキシエチルジメチル第四級アンモニウムクロライドである。
本組成物は、布地濃淡染料を含んでいてよい。好適な布地濃淡染料(時に、色調剤、青味剤又は白色剤と呼ばれることもある)は、典型的には、青又は紫の濃淡を布地にもたらす。布地濃淡染料は、単独又は組み合わせて使用して、特定の色調の濃淡を作り出すことができ、及び/又は異なる種類の布地に濃淡を付けることができる。これは、例えば、赤と緑-青の染料とを混合して青又は紫の濃淡を生じさせることによって提供され得る。布地濃淡染料は、アクリジン、アントラキノン(多環式キノンを含む)、アジン、予め金属化(premetallized)されたアゾを含むアゾ(例えば、モノアゾ、ジアゾ、トリスアゾ、テトラキスアゾ、ポリアゾ)、ベンゾジフラン及びベンゾジフラノン、カロテノイド、クマリン、シアニン、ジアザヘミシアニン、ジフェニルメタン、ホルマザン、ヘミシアニン、インジゴイド、メタン、ナフタルイミド、ナフトキノン、ニトロ及びニトロソ、オキサジン、フタロシアニン、ピラゾール、スチルベン、スチリル、トリアリールメタン、トリフェニルメタン、キサンテン、並びにこれらの混合物が挙げられるが、これらに限定されない任意の公知の化学分類の染料から選択してよい。
R1及びR2は、独立して、H、アルキル、アルコキシ、アルキレンオキシ、アルキル末端保護されたアルキレンオキシ、尿素、及びアミドからなる群から選択され、
R3は、置換アリール基であり、
Xは、スルホンアミド部分と、任意にアルキル及び/又はアリール部分とを含む置換基であり、当該置換基は、少なくとも1本のアルキレンオキシ鎖を含む)。色調染料は、好ましくはアルコキシル化されている、チオフェンアゾ染料などのチオフェン染料であってよい。任意に、染料は、スルホン酸基、カルボン酸基、又は第四級アンモニウム基から選択される少なくとも1つの可溶化基で置換されていてもよい。特に好ましい染料は、Milliken Company製のLiquitint染料、特に、バイオレットDDである。
本発明の組成物は、固体(例えば、顆粒又は錠剤)であっても、又は液体形態であってもよい。好ましくは、本組成物は、液体形態である。本組成物は、配合者によって選択される任意の方法によって作製してよく、その非限定的な例は、実施例及び米国特許第4,990,280号、米国特許出願公開第20030087791(A1)号、同第20030087790(A1)号、同第20050003983(A1)号、同第20040048764(A1)号、米国特許第4,762,636号、同第6,291,412号、米国特許出願公開第20050227891(A1)号、欧州特許第1070115(A2)号、米国特許第5,879,584号、同第5,691,297号、同第5,574,005号、同第5,569,645号、同第5,565,422号、同第5,516,448号、同第5,489,392号、同第5,486号に記載されている。
これら実施例は、単位用量洗濯洗剤用の様々な処方を提供する。組成物8~12は、1つの単位容量区画を含む。組成物を封入するために使用されるフィルムはPVAである。
典型的にはフロントローディング式自動洗濯機用の顆粒状洗濯洗剤組成物
Claims (14)
- ヌクレアーゼ酵素、好ましくはデオキシリボヌクレアーゼ及び/又はリボヌクレアーゼ酵素と、アニオン性界面活性剤及び非イオン性界面活性剤を含む界面活性剤系と、を含み、アニオン性界面活性剤の非イオン性界面活性剤に対する重量比が1.5:1~1:10である、洗浄組成物。
- 5~80重量%又は10~50重量%、より好ましくは15~45重量%の総界面活性剤レベルを含む、請求項1に記載の洗浄組成物。
- 前記アニオン性界面活性剤の非イオン性界面活性剤に対する重量比が、1.2:1~1:4、又は更には1:1~1:2である、請求項1又は2に記載の洗浄組成物。
- 前記アニオン性界面活性剤が、アルキルアルコキシル化サルフェート界面活性剤を含み、好ましくはエトキシル化されており、好ましくは0.5~2.5の平均アルコキシル化度を有する、請求項1~3のいずれか一項に記載の洗浄組成物。
- 前記界面活性剤系が、カチオン性、双極性及び両性の界面活性剤から選択される追加の界面活性剤を含み、好ましくは、前記追加の界面活性剤が、総界面活性剤系の20重量%未満で含まれる、請求項1~4のいずれか一項に記載の洗浄組成物。
- 前記ヌクレアーゼ酵素が、E.C.クラスE.C.3.1.21.x(式中、x=1、2、3、4、5、6、7、8、9)、3.1.22.y(式中、y=1、2、4、5)、E.C.3.1.30.z(式中、z=1、2)若しくはE.C.3.1.31.1のいずれか、又はこれらの混合物から選択され、好ましくは、E.C.3.1.21、好ましくは、E.C.3.1.21.1である、請求項1~5のいずれか一項に記載の洗浄組成物。
- 前記ヌクレアーゼ酵素が、デオキシリボヌクレアーゼを含む、請求項1~6のいずれか一項に記載の洗浄組成物。
- 前記酵素が、RNase活性及びDNase活性の両方を有する酵素、好ましくはE.C.3.1.30.2の酵素を含む、請求項6に記載の洗浄組成物。
- 前記酵素が、微生物の酵素、好ましくは細菌の酵素である、請求項1~8のいずれか一項に記載の洗浄組成物。
- 前記酵素が、配列番号1、配列番号2又は配列番号3に示すアミノ酸配列と少なくとも85%、又は少なくとも90、又は少なくとも95%、又は更には100%の同一性を有するアミノ酸配列を有する、請求項1~9のいずれか一項に記載の洗浄組成物。
- E.C.3.2.1.52のβ-N-アセチルグルコサミニダーゼ酵素、好ましくは、配列番号4と少なくとも70%の同一性を有する酵素を含む、請求項1~10のいずれか一項に記載の洗浄組成物。
- 前記組成物が、布地濃淡染料、並びに/又は、第1の洗浄リパーゼ等のリパーゼ、アミラーゼ、プロテアーゼ、マンナナーゼ、ペクチン酸リアーゼ、セルラーゼ及びクチナーゼから選択される追加の酵素を更に含む、請求項1~11のいずれか一項に記載の洗浄組成物。
- 布地を洗浄する方法であって、請求項1~12のいずれか一項に記載の洗浄組成物を水と混合して水性液を形成する工程と、洗濯工程において生地を前記水性液と接触させる工程と、を含む、方法。
- アニオン性界面活性剤及び非イオン性界面活性剤を含む界面活性剤系の使用であって、アニオン性界面活性剤の非イオン性界面活性剤に対する重量比が1.5:1~1:10であり、ヌクレアーゼ酵素による生地の洗浄を促進するための使用。
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- 2016-04-27 WO PCT/US2016/029427 patent/WO2016176241A1/en active Application Filing
- 2016-04-27 HU HUE16167262A patent/HUE039245T2/hu unknown
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ZA201706666B (en) | 2019-05-29 |
CN117736810A (zh) | 2024-03-22 |
EP3088506B1 (en) | 2018-05-23 |
CN107820515A (zh) | 2018-03-20 |
JP2020023704A (ja) | 2020-02-13 |
ES2682178T3 (es) | 2018-09-19 |
US20160319228A1 (en) | 2016-11-03 |
JP2018521149A (ja) | 2018-08-02 |
DK3088506T3 (en) | 2018-08-13 |
WO2016176241A1 (en) | 2016-11-03 |
EP3088506A1 (en) | 2016-11-02 |
HUE039245T2 (hu) | 2018-12-28 |
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