JP2017530852A - 撥性表面を含むスプレー塗布システム構成要素及び方法 - Google Patents
撥性表面を含むスプレー塗布システム構成要素及び方法 Download PDFInfo
- Publication number
- JP2017530852A JP2017530852A JP2017502797A JP2017502797A JP2017530852A JP 2017530852 A JP2017530852 A JP 2017530852A JP 2017502797 A JP2017502797 A JP 2017502797A JP 2017502797 A JP2017502797 A JP 2017502797A JP 2017530852 A JP2017530852 A JP 2017530852A
- Authority
- JP
- Japan
- Prior art keywords
- component
- liquid
- paint
- carbon atoms
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005871 repellent Substances 0.000 title claims abstract description 126
- 230000002940 repellent Effects 0.000 title claims abstract description 122
- 238000005507 spraying Methods 0.000 title claims description 21
- 238000000034 method Methods 0.000 title abstract description 52
- 239000007788 liquid Substances 0.000 claims abstract description 264
- 239000010410 layer Substances 0.000 claims abstract description 202
- 239000000463 material Substances 0.000 claims abstract description 132
- 239000000314 lubricant Substances 0.000 claims abstract description 107
- 239000007921 spray Substances 0.000 claims abstract description 86
- 229920002313 fluoropolymer Polymers 0.000 claims abstract description 58
- 239000004811 fluoropolymer Substances 0.000 claims abstract description 56
- 239000002491 polymer binding agent Substances 0.000 claims abstract description 53
- 239000002344 surface layer Substances 0.000 claims abstract description 37
- 229920000620 organic polymer Polymers 0.000 claims abstract description 35
- 239000011148 porous material Substances 0.000 claims abstract description 19
- 239000000654 additive Substances 0.000 claims abstract description 16
- 230000000996 additive effect Effects 0.000 claims abstract description 14
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 14
- 239000002861 polymer material Substances 0.000 claims abstract description 11
- 238000002844 melting Methods 0.000 claims abstract description 10
- 230000008018 melting Effects 0.000 claims abstract description 10
- 230000005484 gravity Effects 0.000 claims abstract description 8
- 239000003973 paint Substances 0.000 claims description 230
- 125000004432 carbon atom Chemical group C* 0.000 claims description 197
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 89
- -1 alkylene glycol alkyl ether Chemical class 0.000 claims description 75
- 239000000203 mixture Substances 0.000 claims description 57
- 150000001875 compounds Chemical class 0.000 claims description 55
- 239000003960 organic solvent Substances 0.000 claims description 43
- 229920000642 polymer Polymers 0.000 claims description 33
- 229920001577 copolymer Polymers 0.000 claims description 28
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 26
- 125000002947 alkylene group Chemical group 0.000 claims description 25
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 18
- 229920006120 non-fluorinated polymer Polymers 0.000 claims description 17
- 229920000728 polyester Polymers 0.000 claims description 16
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 15
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- 229920000098 polyolefin Polymers 0.000 claims description 14
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 13
- 239000011737 fluorine Substances 0.000 claims description 13
- 125000005647 linker group Chemical group 0.000 claims description 13
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical group FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 9
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 125000000623 heterocyclic group Chemical group 0.000 claims description 8
- 239000004793 Polystyrene Substances 0.000 claims description 7
- 125000005515 organic divalent group Chemical group 0.000 claims description 7
- 229920002223 polystyrene Polymers 0.000 claims description 7
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 6
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 130
- 239000002245 particle Substances 0.000 description 102
- 238000000576 coating method Methods 0.000 description 75
- 230000002209 hydrophobic effect Effects 0.000 description 73
- 239000008199 coating composition Substances 0.000 description 72
- 239000011248 coating agent Substances 0.000 description 62
- 239000002105 nanoparticle Substances 0.000 description 57
- 239000000377 silicon dioxide Substances 0.000 description 52
- 239000000758 substrate Substances 0.000 description 41
- 239000000243 solution Substances 0.000 description 39
- 239000007787 solid Substances 0.000 description 34
- 229910052809 inorganic oxide Inorganic materials 0.000 description 33
- 229910000077 silane Inorganic materials 0.000 description 31
- 125000000217 alkyl group Chemical group 0.000 description 27
- 125000003118 aryl group Chemical group 0.000 description 27
- 239000002253 acid Substances 0.000 description 22
- 150000003254 radicals Chemical class 0.000 description 22
- 239000002904 solvent Substances 0.000 description 22
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 21
- 239000010702 perfluoropolyether Substances 0.000 description 21
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 20
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 19
- 238000010998 test method Methods 0.000 description 17
- 229930195733 hydrocarbon Natural products 0.000 description 16
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 description 15
- 150000002430 hydrocarbons Chemical class 0.000 description 15
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 15
- 239000011521 glass Substances 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 13
- 229920001774 Perfluoroether Polymers 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 12
- 229920001451 polypropylene glycol Polymers 0.000 description 12
- 150000004756 silanes Chemical class 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 11
- 239000012530 fluid Substances 0.000 description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 10
- 125000003710 aryl alkyl group Chemical group 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 10
- 239000000049 pigment Substances 0.000 description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 description 10
- 238000005245 sintering Methods 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 125000003545 alkoxy group Chemical group 0.000 description 9
- 150000002009 diols Chemical class 0.000 description 9
- 229910021485 fumed silica Inorganic materials 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 8
- 125000000732 arylene group Chemical group 0.000 description 8
- 125000004122 cyclic group Chemical group 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920006395 saturated elastomer Polymers 0.000 description 8
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 7
- 230000001965 increasing effect Effects 0.000 description 7
- 229920001684 low density polyethylene Polymers 0.000 description 7
- 239000004702 low-density polyethylene Substances 0.000 description 7
- 239000010687 lubricating oil Substances 0.000 description 7
- 239000000155 melt Substances 0.000 description 7
- 229920009441 perflouroethylene propylene Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000004809 Teflon Substances 0.000 description 6
- 229920006362 Teflon® Polymers 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 229920000180 alkyd Polymers 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 125000005843 halogen group Chemical group 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 150000001409 amidines Chemical class 0.000 description 5
- 125000002102 aryl alkyloxo group Chemical group 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- 125000001309 chloro group Chemical group Cl* 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 238000001723 curing Methods 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 125000006551 perfluoro alkylene group Chemical group 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 238000004381 surface treatment Methods 0.000 description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 125000004423 acyloxy group Chemical group 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 238000000137 annealing Methods 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 125000004104 aryloxy group Chemical group 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 125000002837 carbocyclic group Chemical group 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 125000003709 fluoroalkyl group Chemical group 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- BNJOQKFENDDGSC-UHFFFAOYSA-N octadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCC(O)=O BNJOQKFENDDGSC-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000011164 primary particle Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 238000000527 sonication Methods 0.000 description 4
- 239000012855 volatile organic compound Substances 0.000 description 4
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910018540 Si C Inorganic materials 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- 238000003917 TEM image Methods 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 3
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 125000001165 hydrophobic group Chemical group 0.000 description 3
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 238000003760 magnetic stirring Methods 0.000 description 3
- 238000010128 melt processing Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 210000003739 neck Anatomy 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 150000007530 organic bases Chemical class 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920005596 polymer binder Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 238000010345 tape casting Methods 0.000 description 3
- ROGGTOFSFBCHBF-UHFFFAOYSA-N (1-chloro-2-dodecylhexadecyl)-dimethylsilane Chemical compound CCCCCCCCCCCCCCC(C(Cl)[SiH](C)C)CCCCCCCCCCCC ROGGTOFSFBCHBF-UHFFFAOYSA-N 0.000 description 2
- ZFDWWDZLRKHULH-UHFFFAOYSA-N 1,2-dimethyl-5,6-dihydro-4h-pyrimidine Chemical compound CN1CCCN=C1C ZFDWWDZLRKHULH-UHFFFAOYSA-N 0.000 description 2
- SGUVLZREKBPKCE-UHFFFAOYSA-N 1,5-diazabicyclo[4.3.0]-non-5-ene Chemical compound C1CCN=C2CCCN21 SGUVLZREKBPKCE-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- KJJPLEZQSCZCKE-UHFFFAOYSA-N 2-aminopropane-1,3-diol Chemical compound OCC(N)CO KJJPLEZQSCZCKE-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 125000002619 bicyclic group Chemical group 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- QAADEYIJKBTPIG-UHFFFAOYSA-N chloro-dimethyl-triacontylsilane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC[Si](C)(C)Cl QAADEYIJKBTPIG-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 150000002357 guanidines Chemical class 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000005661 hydrophobic surface Effects 0.000 description 2
- JJOJFIHJIRWASH-UHFFFAOYSA-N icosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCC(O)=O JJOJFIHJIRWASH-UHFFFAOYSA-N 0.000 description 2
- 230000033001 locomotion Effects 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 238000013008 moisture curing Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N octan-3-ol Chemical compound CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 2
- 238000006384 oligomerization reaction Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- LUYQYZLEHLTPBH-UHFFFAOYSA-N perfluorobutanesulfonyl fluoride Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)S(F)(=O)=O LUYQYZLEHLTPBH-UHFFFAOYSA-N 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- WMOVHXAZOJBABW-UHFFFAOYSA-N tert-butyl acetate Chemical compound CC(=O)OC(C)(C)C WMOVHXAZOJBABW-UHFFFAOYSA-N 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WSXNCJNDCDTRSA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,20-dotetracontafluoroicosane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F WSXNCJNDCDTRSA-UHFFFAOYSA-N 0.000 description 1
- AXFFGMPNSZVEDX-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,21,21,22,22,23,23,24,24,24-pentacontafluorotetracosane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F AXFFGMPNSZVEDX-UHFFFAOYSA-N 0.000 description 1
- OKIYQFLILPKULA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F OKIYQFLILPKULA-UHFFFAOYSA-N 0.000 description 1
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical compound CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 1
- XKBWVLHEBFSMMG-UHFFFAOYSA-N 1,2-diethyl-5,6-dihydro-4h-pyrimidine Chemical compound CCN1CCCN=C1CC XKBWVLHEBFSMMG-UHFFFAOYSA-N 0.000 description 1
- WGYZMNBUZFHYRX-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-ol Chemical compound COCC(C)OCC(C)O WGYZMNBUZFHYRX-UHFFFAOYSA-N 0.000 description 1
- 239000005968 1-Decanol Substances 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 description 1
- SCBRJAHMOLUGRP-UHFFFAOYSA-N 1-ethyl-2-methyl-5,6-dihydro-4h-pyrimidine Chemical compound CCN1CCCN=C1C SCBRJAHMOLUGRP-UHFFFAOYSA-N 0.000 description 1
- PCBKFYSULGJBGS-UHFFFAOYSA-N 1-ethyl-2-propan-2-yl-5,6-dihydro-4h-pyrimidine Chemical compound CCN1CCCN=C1C(C)C PCBKFYSULGJBGS-UHFFFAOYSA-N 0.000 description 1
- NTCVBYCDNOJYGK-UHFFFAOYSA-N 1-ethyl-2-propyl-5,6-dihydro-4h-pyrimidine Chemical compound CCCC1=NCCCN1CC NTCVBYCDNOJYGK-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- WGGNJZRNHUJNEM-UHFFFAOYSA-N 2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-triazatrisilinane Chemical compound C[Si]1(C)N[Si](C)(C)N[Si](C)(C)N1 WGGNJZRNHUJNEM-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- OHJYHAOODFPJOD-UHFFFAOYSA-N 2-(2-ethylhexoxy)ethanol Chemical compound CCCCC(CC)COCCO OHJYHAOODFPJOD-UHFFFAOYSA-N 0.000 description 1
- ACUZDYFTRHEKOS-SNVBAGLBSA-N 2-Decanol Natural products CCCCCCCC[C@@H](C)O ACUZDYFTRHEKOS-SNVBAGLBSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- GYHPTPQZVBYHLC-UHFFFAOYSA-N 2-[2-[2-[2-(2-ethylhexanoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOCCOC(=O)C(CC)CCCC GYHPTPQZVBYHLC-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- UADWUILHKRXHMM-UHFFFAOYSA-N 2-ethylhexyl benzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1 UADWUILHKRXHMM-UHFFFAOYSA-N 0.000 description 1
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 description 1
- LJOIJIAJSKVDSN-UHFFFAOYSA-N 2-methyl-1-propan-2-yl-5,6-dihydro-4h-pyrimidine Chemical compound CC(C)N1CCCN=C1C LJOIJIAJSKVDSN-UHFFFAOYSA-N 0.000 description 1
- YMECANGUBVFOOC-UHFFFAOYSA-N 2-methyl-1-propyl-5,6-dihydro-4h-pyrimidine Chemical compound CCCN1CCCN=C1C YMECANGUBVFOOC-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- NMRPBPVERJPACX-QMMMGPOBSA-N 3-Octanol Natural products CCCCC[C@@H](O)CC NMRPBPVERJPACX-QMMMGPOBSA-N 0.000 description 1
- JDFDHBSESGTDAL-UHFFFAOYSA-N 3-methoxypropan-1-ol Chemical compound COCCCO JDFDHBSESGTDAL-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 description 1
- TVGGZQXYTIPHSN-UHFFFAOYSA-N 4,5-dimethyl-1,3-dioxole Chemical compound CC1=C(C)OCO1 TVGGZQXYTIPHSN-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- 101100136062 Mycobacterium tuberculosis (strain ATCC 25618 / H37Rv) PE10 gene Proteins 0.000 description 1
- 101100136063 Mycobacterium tuberculosis (strain ATCC 25618 / H37Rv) PE11 gene Proteins 0.000 description 1
- 101100136064 Mycobacterium tuberculosis (strain ATCC 25618 / H37Rv) PE13 gene Proteins 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229920006367 Neoflon Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 101150087801 PE23 gene Proteins 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- GJWAPAVRQYYSTK-UHFFFAOYSA-N [(dimethyl-$l^{3}-silanyl)amino]-dimethylsilicon Chemical compound C[Si](C)N[Si](C)C GJWAPAVRQYYSTK-UHFFFAOYSA-N 0.000 description 1
- HIMXYMYMHUAZLW-UHFFFAOYSA-N [[[dimethyl(phenyl)silyl]amino]-dimethylsilyl]benzene Chemical compound C=1C=CC=CC=1[Si](C)(C)N[Si](C)(C)C1=CC=CC=C1 HIMXYMYMHUAZLW-UHFFFAOYSA-N 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- YCLAMANSVUJYPT-UHFFFAOYSA-L aluminum chloride hydroxide hydrate Chemical compound O.[OH-].[Al+3].[Cl-] YCLAMANSVUJYPT-UHFFFAOYSA-L 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 238000005815 base catalysis Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 150000004283 biguanides Chemical class 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Substances OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 1
- ACUZDYFTRHEKOS-UHFFFAOYSA-N decan-2-ol Chemical compound CCCCCCCCC(C)O ACUZDYFTRHEKOS-UHFFFAOYSA-N 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- LQJBNNIYVWPHFW-QXMHVHEDSA-N gadoleic acid Chemical compound CCCCCCCCCC\C=C/CCCCCCCC(O)=O LQJBNNIYVWPHFW-QXMHVHEDSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000013038 hand mixing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical compound BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 125000001905 inorganic group Chemical group 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 229940104873 methyl perfluorobutyl ether Drugs 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- SLYCYWCVSGPDFR-UHFFFAOYSA-N octadecyltrimethoxysilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SLYCYWCVSGPDFR-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229960004624 perflexane Drugs 0.000 description 1
- 229950011087 perflunafene Drugs 0.000 description 1
- UWEYRJFJVCLAGH-IJWZVTFUSA-N perfluorodecalin Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)[C@@]2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)[C@@]21F UWEYRJFJVCLAGH-IJWZVTFUSA-N 0.000 description 1
- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 description 1
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- HTYPUNPKBFMFFO-UHFFFAOYSA-N platinum silver Chemical compound [Ag][Pt][Pt] HTYPUNPKBFMFFO-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001843 polymethylhydrosiloxane Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052990 silicon hydride Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 238000001915 surface Penning-ionisation electron spectroscopy Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- QZZGJDVWLFXDLK-UHFFFAOYSA-N tetracosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(O)=O QZZGJDVWLFXDLK-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
- B05B7/2478—Gun with a container which, in normal use, is located above the gun
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
- B05B7/2405—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle
- B05B7/2424—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle the carried liquid and the main stream of atomising fluid being brought together downstream of the container before discharge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
- B05B7/2481—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device with a flexible container for liquid or other fluent material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
- C08K5/435—Sulfonamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
- Nozzles (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
Abstract
Description
Rf−[Q−[C(R1)2−Si(R2)3−x(R3)x]y]z
(I)
Rf−Q−[C(R1)2−Si(R2)3−x(R3)x]y
(Ia)
Rf−[Q−[C(R1)2−Si(R2)3−x(R3)x]y]2
(Ib)
[(R3)x(R2)3−xSi−C(R1)2]y−Q−Rf−Q−[C(R1)2−Si(R2)3−x(R3)x]y
Rf−C(R1)2−Si(R2)3−x(R3)x
(Ia−1)
Rf−[C(R1)2−Si(R2)3−x(R3)x]2
(Ib−1)
Rf−Q−C(R1)2−Si(R2)3−x(R3)x
(Ia−2)
Rf−[Q−C(R1)2−Si(R2)3−x(R3)x]2
(Ib−2)
−C(R1)2−Si(R2)3−x(R3)x
Rf−Q−[C(R1)2−Si(R2)3−x(R3)x]2
(Ia−3)
Rf−[Q−[C(R1)2−Si(R2)3−x(R3)x]2]2
(Ib−3)
R1L[Si(R2)3−x(R3)x]y
(II)
R1LSi(R2)3−x(R3)x
(IIa)
(R3)x(R2)3−xSiLR1LSi(R2)3−x(R3)x
(IIb)
R1[Si(R2)3−x(R3)x]y
(III)
式中、R1及びR3は、独立して、非加水分解性基であり、R2はヒドロキシルであり、xは2であり、yは1である。典型的な実施形態では、R1及びR3は、独立して、水素、C1〜C4アルキル(例えば、メチル、エチル)又はフェニルである。
(Rf−L−P)nA
Rfは、フッ素化基であり、
Lは、独立して、有機二価結合基であり、
Pは、独立して、カテナリーの二価ヘテロ原子含有カルボニル部分であり、
Aは、炭化水素部分であり、
nは、典型的には、1〜3の範囲である。
−SO2N(R’)(CH2)k−
−CON(R’)(CH2)k−
−(CH2)k−
−(CH2)kO(CH2)k−
−(CH2)kS(CH2)k−
−(CH2)kSO2(CH2)k−
C4F9SO2N(CH3)(CH2)kOC(O)−A−C(O)O(CH2)kN(CH3)SO2C4F9
又は
C4F9SO2N(CH3)(CH2)kOC(O)−A
のうちの1つを有し、式中、k及びAは、既に記載したとおりである。
実施形態1は、水との前進接触角と後退接触角との差が10未満であるような撥液性表面を備える、スプレー塗布システムの構成要素である。
(Rf−L−P)nA
Rfは、フッ素化基であり、
Lは、独立して有機二価結合基であり、
Pは、カテナリーの二価ヘテロ原子含有カルボニル部分、例えば、−C(O)O−であり、
Aは、炭化水素部分であり、
nは、典型的には、1〜3の範囲である、実施形態3に記載の構成要素である。
液体貯蔵器及び/又はライナー用の蓋と、を備え、少なくとも上記液体貯蔵器及び/又はライナーは、多孔質層及びその多孔質層の孔に浸透した潤滑剤を含む撥液性表面層又は実施形態1〜24による撥液性表面を備える、スプレー塗布システムである。
実施形態50〜51のスプレー塗布システムを提供する工程と、上記スプレー塗布システムを利用して水性液体を塗布する工程と、を含む、スプレー塗布システムの使用方法である。
(a)構成要素を提供する工程と、(b)表面処理された多孔質層を構成要素の表面上に形成する工程であって、多孔質層が焼結無機酸化物粒子を含み、多孔質層の表面が疎水性層を含む、工程と、(c)潤滑剤を、表面処理された多孔質層の孔に浸透させる工程と、を含む、実施形態57の方法である。
IRデータは、Nicolet 6700シリーズFT−IR分光計(Thermo Scientific,Waltham,MA)を使用して得た。
水接触角は、Rame−Hartゴニオメータ−(Rame−Hart Instrument Co.,Succasunna,NJ)を使用して測定した。前進角(θadv)及び後退角(θrec)は、水が注射器を介して静止液滴の内外へ供給されたときに測定した(液滴体積約5μL)。測定は、各表面上の2つの異なる点で行い、報告する測定値は、各試料について4つの値の平均である(各液滴について、左側及び右側の測定値)。
試験表面をPPG Envirobase塗料に浸漬し、一晩静置した。次いで、試験基材を塗料から取り出し、5分間垂直に保持して、コーティングから塗料が潜在的に流れ落ちるようにする。その後も塗料によって被覆されている表面の割合(百分率で表示)を、目視検査によって推測した。
HFPOシランは、式F(CF(CF3)CF2O)aCF(CF3)−CONH(CH2)3Si(OCH3)3の化合物で、式中、変数aは4〜20の範囲である。この材料は、HFPO−COOCH3(20g、0.01579モル)及びNH2CH2CH2CH2−Si(OCH3)3(2.82g、0.01579モル)を、N2雰囲気下で、電磁攪拌棒、窒素(N2)入口、及び還流冷却器を備えた100mL 3つ口丸底フラスコに仕込むことによって調製した。反応混合物を75℃で12時間加熱した。反応は、赤外(IR)分光法によって監視し、エステルピークが消失した後、得られた透明で粘稠な油を更に8時間真空下で保持し、そのまま使用した。
α,ω HFPOジメチルエステルCH3OC(O)−HFPO−C(O)OCH3は、米国特許第7,718,264号の調製第26番に類似した方法によって調製した。
出発ジオールHFPO−CONHCH[CH2OH]2は、撹拌棒を備えた500mLの丸底に、100g(0.0704モル、1420MW)のHFPO−C(O)OCH3及び8.34g(0.0915モル)の2−アミノ−1,3−プロパンジオールを仕込み、75℃で2時間加熱することによって調製した。この反応に200gのメチル−t−ブチルエーテルを加え、黄色の油(おそらく未反応の2−アミノ−1,3−プロパンジオール)が反応から分離された。次いで、黄色の油は加えずに、反応を分液漏斗に注いだ。反応を20mLの2N HCl水溶液で洗浄し、一晩放置して分離させた。有機層を20mLの1N水酸化アンモニウムで洗浄し、30分放置して分離させ、20mLの水で洗浄し、30分放置して分離させ、無水硫酸マグネシウムで乾燥し、濾過し、最大95℃で約1.5時間濃縮して、ジオールHFPO−CONHCH[CH2OH]2を得た。
撹拌棒を備えた25mLジャーに、10g(570MW、285MW、0.0351当量)のPripol 2033、7.20g(205.29MW、0.0351モル)のGeniosil GF−40、及びDBTDLの10% MEK溶液100マイクロリットルを仕込んだ。このジャーをシールし、75℃の浴中に置き、磁気撹拌しながら2時間加熱した。2時間の終了時点で、反応のFTIR分析は、約2265cm−1に残留−NCOのピークを示さなかった。
PE1コーティング配合物の調製は、最初にNALCO 1115の分散体を、適量の蒸留(DI)水を添加することによって固形分5重量%まで希釈した。次いで、1M HNO3触媒を上記の希釈分散体に添加し、分散体のpHを2に調節した。
EX24〜EX66の試料は、種々の潤滑剤を、上記の表面処理された多孔質PE1〜PE23試料に浸透させることによって調製した。これは、潤滑剤が広がって表面処理された多孔質層の全体が覆われるまで、所望の潤滑剤をPE1〜PE23試料上に滴下し、その後、試料を垂直に一晩保持して、余分な潤滑剤が流れ去るようにすることで実施した。
熱成形低密度ポリエチレン(LDPE)PPS(商標)ライナー(400mL)は、3M製であった。
上記の撥性内表面を有するライナー及び撥性内表面のない同じライナーである比較ライナー(CE.F)をそれぞれ秤量した。70gのPPG Environbase自動車用塗料を、撥性内表面を有するライナー及び撥性内表面のない同じライナーである比較ライナー(CE.F)内に注いだ。ライナーを手で振盪及び回転し、塗料が容器の側壁の全てに確実に触れるようにした。次いで、塗料をライナーから注ぎ出し、ライナーを逆さまにして5分間(撥性内面を有するライナー)又は約3時間(CE.F)置き、更に多くの塗料を排出させた。ライナーをそれぞれ再秤量し、残留塗料の質量を計算した。試験結果は以下のとおりであった。
材料
下記の実施例で使用した全てのフルオロケミカル化合物、非フッ素化バインダー及びフルオロポリマーは、25℃及び40°F(4.44℃)〜130°F(54.4℃)の範囲の温度で固体である。
MEFBSE(C4F9SO2N(CH3)C2H4OH)(357当量を有するフルオロケミカルアルコール)は、本質的に米国特許第2,803,656号(Ahlbrecht,et al.)の実施例1に記載の手順を用いて、ペルフルオロブタンスルホニルフルオリド(PBSF)をメチルアミンと反応させてMEFBSA(C4F9SO2N(CH3)H)を生成した後、エチレンクロロヒドリンと反応させることによって2段階で生成した。
フルオロケミカル2は、長鎖炭化水素酸(Unicide 350、C25平均)、及びMEFBSE(C4F9SO2N(CH3)C2H4OH)をフルオロケミカル1の合成と同じ方法でエステル化することによって生成した。
1滴の(例えば、PPG Envirobase)塗料(約0.2mL)を、試料(7.5cm×5.0cmのコーティングされたスライドガラス)の(例えば、撥性表面の)中央部分に21℃で塗布した。試料(例えば、スライドガラス)を直ちに垂直に配向した。塗料の液滴がスライドガラスを滑り落ちた場合は「合格」、そうでない場合は「不合格」と表記した。
試料の非撥性表面全体(すなわち、7.5cm×5.0cmのスライドガラスのコーティングされていない側)を、3M Companyから商品名「SCOTCH−BLUE PAINTERS TAPE」で入手したテープでマスキングした。次いで、試料(スライドガラス)を、21℃にて、(例えば、PPG Envirobase)塗料に3.5cmの深さまで10分間浸漬した(換言すれば、コーティングした表面の約半分を浸漬した)。試料(スライドガラス)を希釈塗料から取り出し、30秒間垂直に配向し、マスキングテープを外した。次いで、浸漬したコーティングされた表面に残った塗料を目視で推測し、残留塗料被覆率の百分率で表した。
十分なサイズ(2.8×3.2cm)の試料を秤量した。試料の非撥性表面(すなわち、コーティングされていない側)全体を、テープ「SCOTCH−BLUE PAINTERS TAPE」でマスキングした。試料の撥性表面を、(例えば、PPG Envirobase)塗料に21℃にて10分間完全に浸漬した(例えば、30g)。次いで、試料を塗料から取り出し、マスキングテープを外し、試料をバインダークリップを用いて1分間垂直に配向した。試料の底縁をペーパータオルに接触させ、材料の底縁沿いに溜まっている可能性のある塗料を吸い取った。各試料の重量を再度測定し、面積当たりの残留塗料の量を計算した。コーティングされた表面に残った塗料を目視で推測し、残留塗料被覆率の百分率で表した。
ポリマーバインダー及びフッ素化添加剤を含有するPE32〜PE56コーティング溶液を調製し、下記の実施例(EX)及び比較例(CE)で使用した。
スライドガラス(7.5×5.0cm、厚さ0.1cm、Fisherより入手)をアセトンで洗浄し、WYPALLペーパータオルで拭いて乾燥させた。洗浄したスライドガラスを平坦な表面上に置き、約0.5mLの各コーティング組成物を、洗浄したスライドガラス上に、52番マイヤーロッドを用いて均一にコーティングし、21℃で約2時間乾燥した。これにより、最初は約133マイクロメートルで、溶媒蒸発後は5マイクロメートルのコーティングが得られる。
CE83は、その内壁にいかなるコーティング溶液も塗布せずに「そのまま」使用したLDPE PPSの400mL容器であった。
CE87は、「Earlex L0190”1 quart(946mL)PTFE Coated Metal Paint Container」(Home Depot USA Inc.(Atlanta,GA)から入手)の底から切り取った試料であった。この切り取り試料は、2.8cm×3.2cmの寸法の矩形であった。塗料撥性及び水接触角は、次のように評価された:
Norton(商標)FEPビーカーライナーは、Welch Fluorocarbon,Inc.(Dover NH)から入手した。塗料撥性及び水接触角は、次のように評価された:
EX91は、ピペットでPE41溶液をライナー内に移し、溶液が容器の内部全体を濡らすまでライナーを回転することによって表面のPPSライナーをコーティングして調製した。次いで、コーティングした容器を回転して逆さまにし、余分なコーティング溶液を排出し、この逆さまの位置で室温にて2時間乾燥した。次いで、コーティングしたライナーの一部を側面から切り取り、塗料撥性試験に使用した。塗料撥性は、4種類の塗料で、試験方法6に従って評価した。
Spies Hecker:70体積%のWT389 Platinum Silver Permahyd Hi−TEC Base Coat 480と30体積%のHi−TEC WT 6050
Glasurit:50体積%のJet Black 90−1250 Base Coatと50体積%の90 Adjusting Base 93−E3
Sikkens:70体積%のJet Black Autowave 391096と30体積%のAutowave WB 391196
CE92は、いかなる処理も行っていないPPSライナーの側面からの切断片であった。切断試料の寸法は、5cm×5cmであった。
[項目1]
水との後退接触角が90°〜135°の範囲であるような撥液性表面を備える、スプレー塗布システムの構成要素。
[項目2]
前記撥液性表面がフルオロケミカル材料の表面層を含む、項目1に記載の構成要素。
[項目3]
前記撥液性表面層が非フッ素化有機ポリマーバインダーを更に含む、項目1又は2に記載の構成要素。
[項目4]
前記フルオロケミカル材料が次式を有する化合物であり、
(R f −L−P) n A
R f は、フッ素化基であり、
Lは、独立して有機二価結合基であり、
Pは、カテナリーの二価ヘテロ原子含有カルボニル部分、例えば、−C(O)O−であり、
Aは、炭化水素部分であり、
nは、典型的には、1〜3の範囲である、項目2又は3に記載の構成要素。
[項目5]
Lが4〜40個の炭素原子を含む炭化水素部分である、項目4に記載の構成要素。
[項目6]
Lが−SO 2 N(CH 3 )(CH 2 ) n −であり、式中、nは1〜4の範囲である、項目4又は5に記載の構成要素。
[項目7]
前記フルオロケミカル材料の少なくとも50重量%について、R f がCF 3 [CF 2 ] 3 −である、項目4〜6のいずれか一項に記載の構成要素。
[項目8]
前記炭化水素部分が飽和アルキレン部分である、項目4〜7のいずれか一項に記載の構成要素。
[項目9]
前記フルオロケミカル材料が少なくとも25重量%のフッ素含有量を有する、項目4〜8のいずれか一項に記載の構成要素。
[項目10]
nが平均で少なくとも2である、項目4〜9のいずれか一項に記載の構成要素。
[項目11]
前記炭化水素部分が平均で25個以下の炭素原子を有する、項目4〜10のいずれか一項に記載の構成要素。
[項目12]
前記非フッ素化有機ポリマーバインダーが、ポリスチレン、アクリル、ポリエステル、ポリウレタン、ポリオレフィン、及びポリ塩化ビニルから選択される、項目1〜11のいずれか一項に記載の構成要素。
[項目13]
前記フルオロケミカル材料が、前記非フッ素化ポリマーバインダーとの共有結合を形成しない、項目1〜12のいずれか一項に記載の構成要素。
[項目14]
前記撥液性表面がフルオロポリマーを含む、項目1又は2に記載の構成要素。
[項目15]
前記フルオロポリマーが、テトラフルオロエチレン(TFE)のコポリマーである、項目14に記載の構成要素。
[項目16]
前記コポリマーが、2.18g/cm 3 未満の密度を有する、項目15に記載の構成要素。
[項目17]
前記フルオロポリマーが、複素環式フッ化炭素基の重合単位を含む、項目15又は16に記載の構成要素。
[項目18]
前記複素環式フッ化炭素基が酸素原子を含む、項目17に記載の構成要素。
[項目19]
前記フルオロポリマーが、テトラフルオロエチレンとペルフルオロアルキルジオキソールとのコポリマーである、項目15〜18のいずれか一項に記載の構成要素。
[項目20]
前記フルオロポリマーが、テトラフルオロエチレンとヘキサフルオロプロピレンとのコポリマーである、項目15〜19のいずれか一項に記載の構成要素。
[項目21]
前記フルオロポリマーが、19モル%未満のフッ化ビニリデンの重合単位を含む、項目15〜16及び20のいずれか一項に記載の構成要素。
[項目22]
前記構成要素の少なくとも前記撥液性表面が、熱加工可能なポリマーとフルオロケミカル材料溶融添加剤とを含む、項目1又は2に記載の構成要素。
[項目23]
前記フルオロケミカル材料溶融添加剤が、項目4〜11のいずれか一項又は組み合わせに従うことを特徴とする、項目22に記載の構成要素。
[項目24]
スプレー塗布システムの構成要素であって、前記構成要素は撥液性表面層を含み、前記撥液性表面層が多孔質層と前記多孔質層の孔に浸透した潤滑剤とを含む、構成要素。
[項目25]
前記構成要素が、液体貯蔵器、液体貯蔵器ライナー、液体貯蔵器若しくはライナー用の蓋、又はこれらの組み合わせである、項目1〜24のいずれか一項に記載の構成要素。
[項目26]
前記構成要素が熱可塑性ポリマー材料を含む、項目25に記載の構成要素。
[項目27]
前記構成要素が取り外し可能な液体貯蔵器ライナーである、項目25又は26に記載の構成要素。
[項目28]
前記構成要素が、圧潰可能な液体貯蔵器又はライナーである、項目25〜27のいずれか一項に記載の構成要素。
[項目29]
前記スプレー塗布システムが、重力供給式スプレーガンを更に含む、項目25〜28のいずれか一項に記載の構成要素。
[項目30]
前記撥液性表面層が、少なくとも5、10、15、20、又は25g/リットルの揮発性有機溶媒を有する水性塗料を撥く、項目1〜29のいずれか一項に記載の構成要素。
[項目31]
前記揮発性有機溶媒が水溶性である、項目30に記載の構成要素。
[項目32]
前記有機溶媒が1種類以上のアルコールを含む、項目30又は31に記載の構成要素。
[項目33]
前記有機溶媒がアルキレングリコールアルキルエーテルを含む、項目30〜32のいずれか一項に記載の構成要素。
[項目34]
前記有機溶媒が2−ブトキシエタノール、ブトキシプロパン−2−オール、2−(2−ブトキシエトキシ)エタノール、及びこれらの混合物を含む、項目33〜33に記載の構成要素。
[項目35]
残留塗料の質量が0.01g/cm 2 以下であるような撥液性表面を備える、スプレー塗布システムの構成要素。
[項目36]
前記撥液性表面の水との前進接触角と後退接触角と間の差が15又は10未満であるような撥液性を備える、スプレー塗布システムの構成要素。
[項目37]
10重量%の2−n−ブトキシエタノールと90重量%の脱イオン水を含有する溶液との後退接触角が少なくとも40°であるような撥液性表面を備える、スプレー塗布システムの構成要素。
[項目38]
垂直に配向したときに塗料の液滴が表面から滑り落ちるような撥液性表面を備える、スプレー塗布システムの構成要素。
[項目39]
前記構成要素が、項目1〜37のいずれか一項又は組み合わせを更なる特徴とする、項目35〜38のいずれか一項に記載の構成要素。
[項目40]
スプレーガンと、
前記スプレーガンに取り付けられた液体貯蔵器と、
任意に、前記液体貯蔵器用のライナーと、
前記液体貯蔵器及び/又はライナー用の蓋と、を備え、
少なくとも前記液体貯蔵器及び/又はライナーは、多孔質層及び該多孔質層の孔に浸透した潤滑剤を含む撥液性表面層又は項目1〜37に従う撥液性表面を備える、スプレー塗布システム。
Claims (40)
- 水との後退接触角が90°〜135°の範囲であるような撥液性表面を備える、スプレー塗布システムの構成要素。
- 前記撥液性表面がフルオロケミカル材料の表面層を含む、請求項1に記載の構成要素。
- 前記撥液性表面層が非フッ素化有機ポリマーバインダーを更に含む、請求項1又は2に記載の構成要素。
- 前記フルオロケミカル材料が次式を有する化合物であり、
(Rf−L−P)nA
Rfは、フッ素化基であり、
Lは、独立して有機二価結合基であり、
Pは、カテナリーの二価ヘテロ原子含有カルボニル部分、例えば、−C(O)O−であり、
Aは、炭化水素部分であり、
nは、典型的には、1〜3の範囲である、請求項2又は3に記載の構成要素。 - Lが4〜40個の炭素原子を含む炭化水素部分である、請求項4に記載の構成要素。
- Lが−SO2N(CH3)(CH2)n−であり、式中、nは1〜4の範囲である、請求項4又は5に記載の構成要素。
- 前記フルオロケミカル材料の少なくとも50重量%について、RfがCF3[CF2]3−である、請求項4〜6のいずれか一項に記載の構成要素。
- 前記炭化水素部分が飽和アルキレン部分である、請求項4〜7のいずれか一項に記載の構成要素。
- 前記フルオロケミカル材料が少なくとも25重量%のフッ素含有量を有する、請求項4〜8のいずれか一項に記載の構成要素。
- nが平均で少なくとも2である、請求項4〜9のいずれか一項に記載の構成要素。
- 前記炭化水素部分が平均で25個以下の炭素原子を有する、請求項4〜10のいずれか一項に記載の構成要素。
- 前記非フッ素化有機ポリマーバインダーが、ポリスチレン、アクリル、ポリエステル、ポリウレタン、ポリオレフィン、及びポリ塩化ビニルから選択される、請求項1〜11のいずれか一項に記載の構成要素。
- 前記フルオロケミカル材料が、前記非フッ素化ポリマーバインダーとの共有結合を形成しない、請求項1〜12のいずれか一項に記載の構成要素。
- 前記撥液性表面がフルオロポリマーを含む、請求項1又は2に記載の構成要素。
- 前記フルオロポリマーが、テトラフルオロエチレン(TFE)のコポリマーである、請求項14に記載の構成要素。
- 前記コポリマーが、2.18g/cm3未満の密度を有する、請求項15に記載の構成要素。
- 前記フルオロポリマーが、複素環式フッ化炭素基の重合単位を含む、請求項15又は16に記載の構成要素。
- 前記複素環式フッ化炭素基が酸素原子を含む、請求項17に記載の構成要素。
- 前記フルオロポリマーが、テトラフルオロエチレンとペルフルオロアルキルジオキソールとのコポリマーである、請求項15〜18のいずれか一項に記載の構成要素。
- 前記フルオロポリマーが、テトラフルオロエチレンとヘキサフルオロプロピレンとのコポリマーである、請求項15〜19のいずれか一項に記載の構成要素。
- 前記フルオロポリマーが、19モル%未満のフッ化ビニリデンの重合単位を含む、請求項15〜16及び20のいずれか一項に記載の構成要素。
- 前記構成要素の少なくとも前記撥液性表面が、熱加工可能なポリマーとフルオロケミカル材料溶融添加剤とを含む、請求項1又は2に記載の構成要素。
- 前記フルオロケミカル材料溶融添加剤が、請求項4〜11のいずれか一項又は組み合わせに従うことを特徴とする、請求項22に記載の構成要素。
- スプレー塗布システムの構成要素であって、前記構成要素は撥液性表面層を含み、前記撥液性表面層が多孔質層と前記多孔質層の孔に浸透した潤滑剤とを含む、構成要素。
- 前記構成要素が、液体貯蔵器、液体貯蔵器ライナー、液体貯蔵器若しくはライナー用の蓋、又はこれらの組み合わせである、請求項1〜24のいずれか一項に記載の構成要素。
- 前記構成要素が熱可塑性ポリマー材料を含む、請求項25に記載の構成要素。
- 前記構成要素が取り外し可能な液体貯蔵器ライナーである、請求項25又は26に記載の構成要素。
- 前記構成要素が、圧潰可能な液体貯蔵器又はライナーである、請求項25〜27のいずれか一項に記載の構成要素。
- 前記スプレー塗布システムが、重力供給式スプレーガンを更に含む、請求項25〜28のいずれか一項に記載の構成要素。
- 前記撥液性表面層が、少なくとも5、10、15、20、又は25g/リットルの揮発性有機溶媒を有する水性塗料を撥く、請求項1〜29のいずれか一項に記載の構成要素。
- 前記揮発性有機溶媒が水溶性である、請求項30に記載の構成要素。
- 前記有機溶媒が1種類以上のアルコールを含む、請求項30又は31に記載の構成要素。
- 前記有機溶媒がアルキレングリコールアルキルエーテルを含む、請求項30〜32のいずれか一項に記載の構成要素。
- 前記有機溶媒が2−ブトキシエタノール、ブトキシプロパン−2−オール、2−(2−ブトキシエトキシ)エタノール、及びこれらの混合物を含む、請求項33〜33に記載の構成要素。
- 残留塗料の質量が0.01g/cm2以下であるような撥液性表面を備える、スプレー塗布システムの構成要素。
- 前記撥液性表面の水との前進接触角と後退接触角と間の差が15又は10未満であるような撥液性を備える、スプレー塗布システムの構成要素。
- 10重量%の2−n−ブトキシエタノールと90重量%の脱イオン水を含有する溶液との後退接触角が少なくとも40°であるような撥液性表面を備える、スプレー塗布システムの構成要素。
- 垂直に配向したときに塗料の液滴が表面から滑り落ちるような撥液性表面を備える、スプレー塗布システムの構成要素。
- 前記構成要素が、請求項1〜37のいずれか一項又は組み合わせを更なる特徴とする、請求項35〜38のいずれか一項に記載の構成要素。
- スプレーガンと、
前記スプレーガンに取り付けられた液体貯蔵器と、
任意に、前記液体貯蔵器用のライナーと、
前記液体貯蔵器及び/又はライナー用の蓋と、を備え、
少なくとも前記液体貯蔵器及び/又はライナーは、多孔質層及び該多孔質層の孔に浸透した潤滑剤を含む撥液性表面層又は請求項1〜37に従う撥液性表面を備える、スプレー塗布システム。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462069512P | 2014-10-28 | 2014-10-28 | |
US62/069,512 | 2014-10-28 | ||
PCT/US2015/057686 WO2016069674A1 (en) | 2014-10-28 | 2015-10-28 | Spray application system components comprising a repellent surface & methods |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017530852A true JP2017530852A (ja) | 2017-10-19 |
JP6616395B2 JP6616395B2 (ja) | 2019-12-04 |
Family
ID=54540203
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017502797A Active JP6616395B2 (ja) | 2014-10-28 | 2015-10-28 | 撥性表面を含むスプレー塗布システム構成要素及び方法 |
Country Status (12)
Country | Link |
---|---|
US (4) | US10391506B2 (ja) |
EP (1) | EP3122470A1 (ja) |
JP (1) | JP6616395B2 (ja) |
KR (1) | KR20170077162A (ja) |
CN (1) | CN107073494B (ja) |
AU (1) | AU2015339342B2 (ja) |
BR (1) | BR112017008787A2 (ja) |
CA (1) | CA2966343A1 (ja) |
MX (1) | MX2017005336A (ja) |
RU (1) | RU2687436C2 (ja) |
SG (1) | SG11201703320QA (ja) |
WO (1) | WO2016069674A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020080167A1 (ja) * | 2018-10-16 | 2020-04-23 | Agc株式会社 | 含フッ素エーテル化合物および物品 |
WO2021100827A1 (ja) * | 2019-11-22 | 2021-05-27 | ダイキン工業株式会社 | フルオロポリエーテル基シラン含有化合物 |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112017008787A2 (pt) | 2014-10-28 | 2017-12-26 | 3M Innovative Properties Co | componentes de um sistema de aplicação de aspersões que compreende uma superfície repelente & métodos |
WO2017031074A1 (en) | 2015-08-17 | 2017-02-23 | 3M Innovative Properties Company | Nanoclay filled barrier adhesive compositons |
CN108350289B (zh) | 2015-10-28 | 2021-10-12 | 3M创新有限公司 | 基于溶剂的拒斥性涂料组合物和经涂覆的基材 |
CN108350290B (zh) | 2015-10-28 | 2021-10-15 | 3M创新有限公司 | 包括拒斥性表面的经历冰形成的制品 |
JP6873122B2 (ja) * | 2015-10-28 | 2021-05-19 | スリーエム イノベイティブ プロパティズ カンパニー | 撥性表面を含むスプレー塗布システム構成要素及び方法 |
USD800868S1 (en) * | 2016-03-18 | 2017-10-24 | Kenneth D. Crenshaw | Dual nozzle sprayer |
WO2017189475A1 (en) | 2016-04-26 | 2017-11-02 | 3M Innovative Properties Company | Articles subject to ice formation comprising a repellent surface comprising a siloxane material |
CN109311834A (zh) | 2016-05-31 | 2019-02-05 | 3M创新有限公司 | 含氟哌嗪酰胺 |
US20190177576A1 (en) * | 2016-08-18 | 2019-06-13 | Saint-Gobain Performance Plastics Corporation | Adhesive film |
EP3510017B1 (en) | 2016-09-09 | 2021-05-05 | 3M Innovative Properties Company | Partially fluorinated aromatic esters |
ES2594332A1 (es) * | 2016-09-23 | 2016-12-19 | Salinas E Hijos, S.L. | Depósito para pistola pulverizadora de pintura. |
WO2018229596A1 (en) | 2017-06-13 | 2018-12-20 | 3M Innovative Properties Company | Melt additive compounds, methods of using the same, and articles and compositions including the same |
CN110891693B (zh) | 2017-07-14 | 2022-07-01 | 3M创新有限公司 | 用于喷枪的流体递送组件 |
JP6965930B2 (ja) * | 2017-08-17 | 2021-11-10 | 信越化学工業株式会社 | 撥水部材及び撥水部材の製造方法 |
US10865317B2 (en) | 2017-08-31 | 2020-12-15 | Kimberly-Clark Worldwide, Inc. | Low-fluorine compositions with cellulose for generating superhydrophobic surfaces |
CN111433301B (zh) * | 2017-11-30 | 2022-06-14 | 艾仕得涂料***有限责任公司 | 利用高转移效率施涂器施加的涂料组合物及其方法和*** |
EP3539887B1 (en) * | 2018-03-16 | 2021-05-26 | Schott AG | Hollow body, in particular for packaging a pharmaceutical composition, having a layer of glass and a surface region with a contact angle for wetting with water |
EP3762151A4 (en) * | 2018-03-19 | 2021-10-20 | Wagner Spray Tech Corporation | HAND SPRAYER FOR LIQUID |
US11866602B2 (en) | 2018-06-12 | 2024-01-09 | 3M Innovative Properties Company | Fluoropolymer compositions comprising fluorinated additives, coated substrates and methods |
CN112262172B (zh) | 2018-06-12 | 2023-08-01 | 3M创新有限公司 | 包含胺固化剂的含氟聚合物涂料组合物、经涂覆的基底以及相关方法 |
US11441830B2 (en) * | 2018-12-26 | 2022-09-13 | Rebound Technologies, Inc. | Solid production systems, devices, and methods utilizing oleophilic surfaces |
JP7066066B2 (ja) | 2018-12-27 | 2022-05-12 | スリーエム イノベイティブ プロパティズ カンパニー | スプレー装置用の流体送達アセンブリ |
DE102019121952A1 (de) * | 2019-08-14 | 2021-02-18 | Sata Gmbh & Co. Kg | Fließbecher für eine Farbspritzpistole |
WO2021088198A1 (en) | 2019-11-04 | 2021-05-14 | 3M Innovative Properties Company | Electronic telecommunications articles comprising crosslinked fluoropolymers and methods |
CN111173236B (zh) * | 2020-01-13 | 2021-04-02 | 上海家倍得装饰工程有限公司 | 一种家装用便携式喷涂装置 |
CN112064993A (zh) * | 2020-09-09 | 2020-12-11 | 湖州拓高机械有限公司 | 一种方便调节涂量的手持式墙体喷漆装置 |
WO2024092328A1 (pt) * | 2022-10-31 | 2024-05-10 | Cia. Industrial H. Carlos Schneider | Composição de um revestimento e respectivo processo de aplicação em substratos metálicos |
Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56154860U (ja) * | 1980-04-20 | 1981-11-19 | ||
JPH04270649A (ja) * | 1991-02-26 | 1992-09-28 | Toray Ind Inc | 離型フイルム |
WO1996001152A1 (en) * | 1994-07-01 | 1996-01-18 | The Procter & Gamble Company | Improved anti-clogging atomizer nozzle |
JP2001508698A (ja) * | 1997-01-24 | 2001-07-03 | ミネソタ・マイニング・アンド・マニュファクチャリング・カンパニー | 液体噴霧装置、並びに該装置とともに使用するのに適する使い捨て収納容器およびライナー |
JP2001511477A (ja) * | 1997-07-28 | 2001-08-14 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 合成有機ポリマーに対する疎水性で疎油性の添加剤としての高温安定フルオロケミカル |
JP2004531598A (ja) * | 2001-03-09 | 2004-10-14 | スリーエム イノベイティブ プロパティズ カンパニー | パーフルオロアルキル部分を含む撥水撥油性付与エステルオリゴマー |
JP2007515498A (ja) * | 2003-07-22 | 2007-06-14 | ライプニッツ−インスティトゥート フィア ノイエ マテリアーリエン ゲマインニュッツィゲ ゲゼルシャフト ミット ベシュレンクタ ハフトゥンク | 撥液性コーティング組成物及び高アルカリ耐性を有するコーティング |
JP2007523971A (ja) * | 2003-12-31 | 2007-08-23 | スリーエム イノベイティブ プロパティズ カンパニー | 撥水撥油性フルオロアクリレート |
JP2007297543A (ja) * | 2006-05-01 | 2007-11-15 | Shin Etsu Chem Co Ltd | 防汚コーティング剤がハードコート層に固着された複合ハードコート層を有する基材及びその形成方法 |
JP2008524376A (ja) * | 2004-12-15 | 2008-07-10 | スリーエム イノベイティブ プロパティズ カンパニー | ポリマー溶融体の忌避性添加剤としてのフルオロケミカルジエステル |
JP2011067710A (ja) * | 2009-09-23 | 2011-04-07 | Ransburg Industry Kk | 静電塗装機用の塗料カートリッジの洗浄方法及び塗料バッグ |
WO2012121858A1 (en) * | 2011-03-09 | 2012-09-13 | 3M Innovative Properties Company | Antireflective film comprising large particle size fumed silica |
JP2014509959A (ja) * | 2011-01-19 | 2014-04-24 | プレジデント アンド フェローズ オブ ハーバード カレッジ | 高圧力安定性、光透過性、および自己修復特性を伴う易滑性表面 |
US20140287243A1 (en) * | 2013-03-06 | 2014-09-25 | University Of Pittsburgh - Of The Commonwealth System Of Higher Education | Superhydrophobic coatings |
Family Cites Families (190)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2504482A (en) | 1949-06-17 | 1950-04-18 | Premo Pharmaceutical Lab Inc | Drain-clear container for aqueous-vehicle liquid pharmaceutical preparations |
US2688568A (en) | 1950-10-02 | 1954-09-07 | Pfizer & Co C | Process of producing drain-clear containers |
US2622598A (en) | 1951-03-08 | 1952-12-23 | Premo Pharmaceutical Lab Inc | Drain-clear container for aqueous liquid pharmaceutical preparations |
US2803656A (en) | 1956-01-23 | 1957-08-20 | Minnesota Mining & Mfg | Fluorocarbonsulfonamidoalkanols and sulfates thereof |
US2898317A (en) | 1957-07-01 | 1959-08-04 | Dow Chemical Co | Film forming aqueous colloidal dispersions containing aromatic nitroalkanols and method for preparing same |
US3372125A (en) | 1965-11-15 | 1968-03-05 | Peter Strong & Company Inc | Denture cleanser |
US3746196A (en) | 1971-01-29 | 1973-07-17 | Green Cross Corp | Coated plastic container for liquid medicine |
US3759874A (en) | 1971-08-30 | 1973-09-18 | Fmc Corp | Fluorinated polyurethanes as soil release agents |
US3787351A (en) | 1972-02-28 | 1974-01-22 | Minnesota Mining & Mfg | Use of soluble fluoroaliphatic oligomers in resin composite articles |
AR206790A1 (es) | 1973-11-23 | 1976-08-23 | Goodyear Tire & Rubber | Estructura metalica provista de superficies preparadas para entrar en contacto con el agua a su temperatura de congelacion o por debajo de la misma |
JPS5338087B2 (ja) | 1975-01-13 | 1978-10-13 | ||
US4209610A (en) | 1975-06-30 | 1980-06-24 | Frank Mares | Partially fluorinated esters or amide/esters of benzene polycarboxylic acids, and dyeable pet and nylon fibers incorporating the same and process of making such fibers |
US4508916A (en) | 1979-04-11 | 1985-04-02 | Minnesota Mining And Manufacturing Company | Curable substituted urethane acrylates |
JPS56154860A (en) | 1980-04-30 | 1981-11-30 | Fujitsu Ltd | Detection system for frequency difference signal |
US4301208A (en) | 1980-09-04 | 1981-11-17 | The United States Of America As Represented By The Secretary Of The Army | Method for reducing the adhesion of ice to the walls of navigation locks |
US4472466A (en) | 1982-03-08 | 1984-09-18 | American Hoechst Corporation | Soil repellent fluorinated esters of multi-ring anhydride systems |
JPS6123656A (ja) | 1984-07-11 | 1986-02-01 | Kansai Paint Co Ltd | 着氷防止有機塗料組成物 |
US5213743A (en) | 1986-06-24 | 1993-05-25 | Goyo Paper Working Co., Ltd. | Method of manufacturing release paper |
US5221497A (en) | 1988-03-16 | 1993-06-22 | Nissan Chemical Industries, Ltd. | Elongated-shaped silica sol and method for preparing the same |
US4791166A (en) | 1988-03-23 | 1988-12-13 | Hoechst Celanese Corporation | Fluorocarbon polymer compositions and methods |
JP2631224B2 (ja) | 1988-04-27 | 1997-07-16 | 関西ペイント株式会社 | 着氷防止塗料組成物 |
JP2505536B2 (ja) | 1988-06-10 | 1996-06-12 | 積水化学工業株式会社 | 撥水・撥油剤および撥水・撥油性組成物 |
US5169900A (en) | 1988-08-05 | 1992-12-08 | Du Pont Canada Inc. | Polyolefin coatings and films having release characteristics |
US5187015A (en) | 1989-02-17 | 1993-02-16 | Minnesota Mining And Manufacturing Company | Ice release composition, article and method |
JPH0341160A (ja) | 1989-07-07 | 1991-02-21 | Kao Corp | 撥液性のすぐれた熱可塑性樹脂組成物 |
JP2770547B2 (ja) | 1990-04-23 | 1998-07-02 | 三菱マテリアル株式会社 | 含フッ素ジエステル型化合物およびその製造方法 |
JPH07119403B2 (ja) | 1990-10-15 | 1995-12-20 | 日東化学株式会社 | 自動車の塗膜用保護撥水剤 |
FI93649C (fi) | 1990-10-29 | 1995-05-10 | Neste Oy | Polymeerituote, joka toimii irrokekalvona sen päälle kiinnitettäviä paineherkkiä liimoja sisältäviä pintoja varten |
US5459188A (en) | 1991-04-11 | 1995-10-17 | Peach State Labs, Inc. | Soil resistant fibers |
US5350795A (en) | 1991-07-10 | 1994-09-27 | Minnesota Mining And Manufacturing Company | Aqueous oil and water repellent compositions which cure at ambient temperature |
US5157139A (en) | 1991-10-03 | 1992-10-20 | Dow Corning Corporation | Inorganic acid catalysed silylation reactions |
JP3306454B2 (ja) | 1991-10-14 | 2002-07-24 | 大阪瓦斯株式会社 | 着雪着氷防止塗料組成物 |
EP0613462B1 (en) | 1991-11-12 | 1996-01-17 | Minnesota Mining And Manufacturing Company | Fluoroaliphatic dimer acid derivatives and use thereof |
US5267693A (en) | 1992-02-12 | 1993-12-07 | Dickey Barry A | Spray gun non-stick paint connector block |
JPH05331407A (ja) | 1992-06-03 | 1993-12-14 | Kanto Auto Works Ltd | 除氷及び着氷防止に優れた耐チッピング塗料組成物 |
JPH05338087A (ja) | 1992-06-08 | 1993-12-21 | Dainippon Printing Co Ltd | 離型シート及びその製造方法 |
JPH06316548A (ja) | 1993-03-12 | 1994-11-15 | Idemitsu Petrochem Co Ltd | ペルフルオロカルボン酸エステル,該エステルを含有する撥水剤及び該エステルの製造方法 |
EP0702709B1 (en) | 1993-05-14 | 1998-01-28 | E.I. Du Pont De Nemours And Company | Anhydride-epoxy coating composition modified with a fluoropolymer |
US5476901A (en) | 1993-06-24 | 1995-12-19 | The Procter & Gamble Company | Siloxane modified polyolefin copolymers |
US6150020A (en) | 1993-09-23 | 2000-11-21 | Bba Nonwovens Simpsonville, Inc. | Articles exhibiting improved hydrophobicity |
CA2143277C (en) | 1994-04-19 | 2000-05-16 | Michael J. Kosmyna | Hand held paint spray gun with top mounted paint cup |
US5708068A (en) | 1995-01-16 | 1998-01-13 | Union Carbide Chemicals & Plastics Technology Corporation | Aircraft deicing/anti-icing fluids thickened by associative polymers |
US5674592A (en) * | 1995-05-04 | 1997-10-07 | Minnesota Mining And Manufacturing Company | Functionalized nanostructured films |
US5728469A (en) | 1995-06-06 | 1998-03-17 | Avery Dennison Corporation | Block copolymer release surface for pressure sensitive adhesives |
US5618903A (en) | 1995-06-06 | 1997-04-08 | Shell Oil Company | Anionically polymerized block copolymers of ethylene and cyclic siloxane monomers |
DE69624923T2 (de) | 1995-08-11 | 2003-08-21 | Daikin Industries, Ltd. | Silizium enthaltende organische fluorpolymere und ihre verwendung |
US5859126A (en) | 1995-09-18 | 1999-01-12 | E. I. Du Pont De Nemours And Company | Coatings containing fluorinated esters |
US5637657A (en) | 1995-09-18 | 1997-06-10 | E. I. Du Pont De Nemours And Company | Surface coating compositions containing fluoroalkyl esters of unsaturated fatty acids |
US5798402A (en) | 1995-12-21 | 1998-08-25 | E. I. Du Pont De Nemours And Company | Fluorinated sulfone melt additives for thermoplastic polymers |
US5681963A (en) | 1995-12-21 | 1997-10-28 | E. I. Du Pont De Nemours And Company | Fluorinated melt additives for thermoplastic polymers |
TW376397B (en) | 1995-12-21 | 1999-12-11 | Du Pont | Fluorinated ester melt additives for thermoplastic fibers |
TW426712B (en) | 1995-12-21 | 2001-03-21 | Du Pont | Fluorinated diester melt additives for thermoplastic polymers and their uses |
US6258758B1 (en) | 1996-04-26 | 2001-07-10 | Platinum Research Organization Llc | Catalyzed surface composition altering and surface coating formulations and methods |
US5670573A (en) | 1996-08-07 | 1997-09-23 | E. I. Du Pont De Nemours And Company | Coatings containing fluorinated esters |
EP0825241B1 (en) | 1996-08-16 | 2003-03-26 | Nippon Telegraph And Telephone Corporation | Water repellent coating composition, method for preparing the same, and coating films and coated articles using the same |
US6465107B1 (en) | 1996-09-13 | 2002-10-15 | Dupont Canada Inc. | Silicone-containing polyolefin film |
US5747392A (en) | 1996-11-19 | 1998-05-05 | Hi-Tex, Inc. | Stain resistant, water repellant, interpenetrating polymer network coating-treated textile fabric |
AU2425597A (en) | 1997-03-31 | 1998-10-22 | Procter & Gamble Company, The | Package providing good drainage to viscous contents |
AU4106897A (en) | 1997-04-01 | 1998-10-22 | Soudal | Coupling |
US6013715A (en) | 1997-04-22 | 2000-01-11 | Dow Corning Corporation | Thermoplastic silicone elastomers |
DE19730245B4 (de) | 1997-07-15 | 2007-08-30 | W.L. Gore & Associates Gmbh | Beschichtungsmaterial, beschichtetes Material und Verfahren zu deren Herstellung |
JP3384715B2 (ja) | 1997-07-22 | 2003-03-10 | 松下電器産業株式会社 | 保護膜の製造方法及び保護膜製造装置 |
KR100588281B1 (ko) | 1997-09-24 | 2006-09-22 | 아사히 가라스 가부시키가이샤 | 불소-함유수지조성물 |
US5914384A (en) | 1997-11-21 | 1999-06-22 | E. I. Du Pont De Nemours And Company | Coating compositions containing a highly fluorinated hydroxyl containing additive |
AU4059399A (en) | 1998-06-04 | 1999-12-20 | Nippon Sheet Glass Co. Ltd. | Process for producing article coated with water-repellent film, article coated with water-repellent film, and liquid composition for water-repellent film coating |
JP2000087014A (ja) | 1998-09-11 | 2000-03-28 | Asahi Glass Co Ltd | 撥水撥油剤組成物 |
EP1088867A1 (de) | 1999-09-30 | 2001-04-04 | Ciba Spezialitätenchemie Pfersee GmbH | Zusammensetzungen für die öl- und wasserabweisende Ausrüstung von Fasermaterialien |
US6664318B1 (en) | 1999-12-20 | 2003-12-16 | 3M Innovative Properties Company | Encapsulant compositions with thermal shock resistance |
DE10004132B4 (de) | 2000-01-31 | 2007-02-01 | Few Chemicals Gmbh | Beschichtungszusammensetzung zur Herstellung schmutzabweisender Schichten und Zweikomponentensystem sowie deren Verwendung |
KR100679898B1 (ko) | 2000-02-29 | 2007-02-07 | 아사히 가라스 가부시키가이샤 | 불소함유 화합물 및 발수발유제 조성물 |
JP2001288788A (ja) * | 2000-04-04 | 2001-10-19 | Toto Ltd | 放水機器の残水垂れ防止方法、残水垂れ防止性放水機器、並びに残水垂れ防止性放水機器用コーティング組成物 |
US6586522B1 (en) | 2000-06-12 | 2003-07-01 | 3M Innovative Properties Company | Water- and oil-repellent composition |
JP2002053792A (ja) | 2000-08-08 | 2002-02-19 | Toto Ltd | 吸水性コーティング組成物 |
US6485709B2 (en) | 2001-01-23 | 2002-11-26 | Addent Inc. | Dental bleaching gel composition, activator system and method for activating a dental bleaching gel |
US6803109B2 (en) | 2001-03-09 | 2004-10-12 | 3M Innovative Properties Company | Water-and oil-repellency imparting urethane oligomers comprising perfluoroalkyl moieties |
US6649272B2 (en) | 2001-11-08 | 2003-11-18 | 3M Innovative Properties Company | Coating composition comprising fluorochemical polyether silane polycondensate and use thereof |
US6797795B2 (en) | 2002-06-07 | 2004-09-28 | The Boeing Company | Polysiloxane(amide-ureide) anti-ice coating |
US7041727B2 (en) | 2002-06-25 | 2006-05-09 | 3M Innovative Properties Company | Latex paint compositions and coatings |
DE10239071A1 (de) | 2002-08-26 | 2004-03-11 | Basf Ag | Verfahren zur Herstellung von Oberflächen, auf denen Flüssigkeiten nicht haften |
AU2003901735A0 (en) | 2003-04-11 | 2003-05-01 | Unisearch Limited | Durable superhydrophobic coating |
EP1475426B1 (de) | 2003-04-24 | 2006-10-11 | Goldschmidt GmbH | Verfahren zur Herstellung von ablösbaren schmutz- und wasserabweisenden flächigen Beschichtungen |
EP1493761A1 (en) | 2003-07-02 | 2005-01-05 | 3M Innovative Properties Company | Fluoropolymer of fluorinated short chain acrylates or methacrylates and oil- and water repellent compositions based thereon |
US20050016489A1 (en) | 2003-07-23 | 2005-01-27 | Endicott Mark Thomas | Method of producing coated engine components |
DE10335761A1 (de) | 2003-08-05 | 2005-03-03 | Goldschmidt Ag | Verwendung organomodifizierter Siloxane zur Oberflächenmodifizierung von Polyolefinen |
US7652115B2 (en) | 2003-09-08 | 2010-01-26 | 3M Innovative Properties Company | Fluorinated polyether isocyanate derived silane compositions |
US7803894B2 (en) | 2003-12-05 | 2010-09-28 | 3M Innovatie Properties Company | Coating compositions with perfluoropolyetherisocyanate derived silane and alkoxysilanes |
US7828889B2 (en) | 2003-12-18 | 2010-11-09 | The Clorox Company | Treatments and kits for creating transparent renewable surface protective coatings |
US20050145134A1 (en) | 2003-12-30 | 2005-07-07 | Petrin Jason T. | Latex paint compositions and coatings |
ITMI20040106A1 (it) | 2004-01-27 | 2004-04-27 | Solvay Solexis Spa | Poliuretani |
JP3848334B2 (ja) | 2004-04-14 | 2006-11-22 | 富士重工業株式会社 | 混合塗料及びその製造方法 |
US7101618B2 (en) | 2004-05-07 | 2006-09-05 | 3M Innovative Properties Company | Article comprising fluorochemical surface layer |
EP1749037A1 (en) | 2004-05-25 | 2007-02-07 | Ciba SC Holding AG | Perfluorinated esters, polyester, ethers and carbonates |
US7399807B2 (en) | 2004-07-09 | 2008-07-15 | Unitex Chemical Corporation | Hydrophobic, oleophobic and alcohol-resistant fluorochemical additive |
DE102004053384A1 (de) | 2004-11-02 | 2006-05-04 | Degussa Ag | Flüssiges, viskoses Mittel auf Basis eines organofunktionellen Silansystems zur Herstellung witterungsstabiler Schutzbeschichtungen zur Verhinderung von Verschmutzungen von Oberflächen |
US20060142530A1 (en) | 2004-12-28 | 2006-06-29 | Moore George G | Water- and oil-repellent fluorourethanes and fluoroureas |
JP2006256282A (ja) | 2005-03-18 | 2006-09-28 | Fuji Xerox Co Ltd | 液滴吐出ヘッド及びその製造方法、並びに、液滴吐出装置 |
US20060216524A1 (en) | 2005-03-23 | 2006-09-28 | 3M Innovative Properties Company | Perfluoropolyether urethane additives having (meth)acryl groups and hard coats |
US20060248656A1 (en) | 2005-05-06 | 2006-11-09 | Invista North America S.A.R.L. | New process of making permanent acid stain resistance for a lightly dyed polyamide carpet |
US20060281861A1 (en) | 2005-06-13 | 2006-12-14 | Putnam John W | Erosion resistant anti-icing coatings |
FR2887891B1 (fr) | 2005-07-01 | 2007-09-21 | Commissariat Energie Atomique | Materiau a base de polysiloxane et a faible hysteresis de mouillage et procede de depot d'un tel materiau. |
US7375698B2 (en) | 2005-12-02 | 2008-05-20 | Andrew Corporation | Hydrophobic feed window |
US20070212491A1 (en) | 2006-03-08 | 2007-09-13 | Yen Jessica C | Fluorochemical and lecithin additive for coatings |
US7553514B2 (en) | 2006-08-28 | 2009-06-30 | 3M Innovative Properties Company | Antireflective article |
JP5226952B2 (ja) | 2007-01-26 | 2013-07-03 | パナソニック株式会社 | 浴室の内面部材 |
US9062283B2 (en) | 2007-02-26 | 2015-06-23 | Stemcell Technologies Inc. | Method of reducing curvature in a meniscus of liquid medium |
US7857905B2 (en) | 2007-03-05 | 2010-12-28 | Momentive Performance Materials Inc. | Flexible thermal cure silicone hardcoats |
JP4218729B2 (ja) | 2007-03-15 | 2009-02-04 | 東洋製罐株式会社 | 非油性内容物用ポリエチレン製容器 |
JP4803827B2 (ja) | 2007-06-04 | 2011-10-26 | 日東電工株式会社 | 剥離ライナーおよび該ライナーを備える感圧接着シート |
JP2010529263A (ja) | 2007-06-08 | 2010-08-26 | スリーエム イノベイティブ プロパティズ カンパニー | ペルフルオロアルキル部分を含む撥水性及び撥油性付与エステルオリゴマー |
CN101679705B (zh) | 2007-06-08 | 2013-12-11 | 3M创新有限公司 | 含氟烷基的酯低聚物与聚碳二亚胺的共混物 |
US7897666B1 (en) | 2007-06-15 | 2011-03-01 | Daniel Berg | Release liner |
US8821984B2 (en) | 2007-09-14 | 2014-09-02 | 3M Innovative Properties Company | Composition and method for imparting increased water repellency to substrates and substrates treated with same |
US20090203276A1 (en) | 2008-02-13 | 2009-08-13 | Goulston Technologies, Inc. | Polymer additive for providing an alcohol repellency for polypropylene nonwoven medical barrier fabrics |
JP5338087B2 (ja) | 2008-03-03 | 2013-11-13 | Jfeスチール株式会社 | めっき性に優れる溶融亜鉛めっき鋼板の製造方法および連続溶融亜鉛めっき設備 |
CN101575478B (zh) | 2008-05-05 | 2011-06-22 | 中国科学院宁波材料技术与工程研究所 | 一种环氧树脂超疏水涂层的制备方法 |
CN101579672A (zh) | 2008-05-16 | 2009-11-18 | 3M创新有限公司 | 用于提高亲水性/透射率的二氧化硅涂层 |
US20090294724A1 (en) | 2008-05-27 | 2009-12-03 | Appealing Products, Inc. | Anti-icing material and surface treatments |
KR20110042268A (ko) | 2008-06-30 | 2011-04-26 | 에스티씨. 유엔엠 | 과불소 화합물을 필요로 하지 않거나 어떠한 불소를 포함하지 않는 초소수성 에어로겔 |
US20100035039A1 (en) | 2008-08-07 | 2010-02-11 | 3M Innovative Properties Company | Acicular silica coating for enhanced hydrophilicity/transmittivity |
US20130224478A1 (en) | 2008-08-07 | 2013-08-29 | 3M Innovative Properties Company | Acicular silica coating for enhanced hydrophilicity/transmittivity |
WO2010022107A2 (en) | 2008-08-18 | 2010-02-25 | The Regents Of The University Of California | Nanostructured superhydrophobic, superoleophobic and/or superomniphobic coatings, methods for fabrication, and applications thereof |
CN101358106B (zh) | 2008-09-25 | 2011-05-04 | 武汉工程大学 | 防覆冰纳米复合涂料及用途 |
ITBO20080666A1 (it) | 2008-11-03 | 2010-05-04 | Marchesini Group Spa | Dispositivo per l'alimentazione di articoli a corrispondenti alveoli di un nastro alveolato |
CN102282191A (zh) | 2008-11-25 | 2011-12-14 | 3M创新有限公司 | 氟化醚尿烷及其使用方法 |
US9197678B2 (en) | 2008-12-11 | 2015-11-24 | Skype | Method and system for data transmission |
JP5861101B2 (ja) | 2009-02-24 | 2016-02-16 | パナソニックIpマネジメント株式会社 | 塗装品 |
US20100314575A1 (en) | 2009-06-16 | 2010-12-16 | Di Gao | Anti-icing superhydrophobic coatings |
NL2005657A (en) | 2009-12-03 | 2011-06-06 | Asml Netherlands Bv | A lithographic apparatus and a method of forming a lyophobic coating on a surface. |
JP5837516B2 (ja) | 2010-02-22 | 2015-12-24 | アイティーダブリュ シーシーアイピー ホールディングス エルエルシーItw Ccip Holdingsllc | フロントガラス処理剤とワイパーブレードとの組合せ |
US20110207038A1 (en) | 2010-02-24 | 2011-08-25 | Xerox Corporation | Slippery surface imaging members |
JP2011240228A (ja) * | 2010-05-17 | 2011-12-01 | Meiwa Sangyo Kk | 塗装治具の付着塗料除去方法 |
US20110305738A1 (en) | 2010-06-09 | 2011-12-15 | Ladizinsky Daniel A | Oxygenating Oral Compositions |
US8497021B2 (en) | 2010-10-08 | 2013-07-30 | Ut-Battelle, Llc | Superoleophilic particles and coatings and methods of making the same |
BR112013008859A2 (pt) | 2010-10-11 | 2019-09-24 | Advanced Tech Materials Inc | sistema com base em revestimento, revestimento, e, métodos para dispensar os conteúdos de um sistema com base em revestimento, e para distribuir um material a um processo |
US9085019B2 (en) | 2010-10-28 | 2015-07-21 | 3M Innovative Properties Company | Superhydrophobic films |
CN102031057B (zh) | 2010-11-09 | 2012-07-18 | 上海康达新能源材料有限公司 | 一种适用于风电叶片的防冰、耐磨涂层 |
EP2638107A1 (en) | 2010-11-10 | 2013-09-18 | 3M Innovative Properties Company | Hydrophobic fluorinated coatings |
WO2012071370A2 (en) | 2010-11-23 | 2012-05-31 | Advanced Technology Materials, Inc. | Liner-based dispenser |
WO2012138992A2 (en) | 2011-04-06 | 2012-10-11 | The Trustees Of The University Of Pennsylvania | Design and manufacture of hydrophobic surfaces |
KR101373729B1 (ko) | 2011-05-12 | 2014-03-13 | 한국기계연구원 | 표면 에너지 제어를 이용한 슬롯다이 |
CN103596701B (zh) | 2011-06-15 | 2016-08-24 | 3M创新有限公司 | 疏水性烃涂层 |
JP5575712B2 (ja) | 2011-08-01 | 2014-08-20 | 理研ビタミン株式会社 | ポリプロピレン系樹脂組成物並びに該組成物を含有するポリオレフィン系樹脂組成物及びその成形品 |
MY163331A (en) | 2011-08-05 | 2017-09-15 | Massachusetts Inst Technology | Liquid-impregnated surfaces, methods of making and devices incorporating the same |
CN102321415A (zh) | 2011-08-11 | 2012-01-18 | 天津大学 | 一种氟硅丙烯酸树脂纳米复合防覆冰涂料及其制备方法 |
WO2013115868A2 (en) | 2011-11-04 | 2013-08-08 | President And Fellows Of Harvard College | Dynamic and switchable slippery surfaces |
US9182175B2 (en) | 2011-12-01 | 2015-11-10 | The Boeing Company | Anti-icing heat exchanger |
WO2013089204A1 (ja) | 2011-12-15 | 2013-06-20 | 旭硝子株式会社 | 撥液性化合物、撥液性重合体、硬化性組成物、塗布用組成物、ならびに硬化膜を有する物品、親液性領域と撥液性領域とのパターンを有する物品およびその製造方法 |
EP2607397A1 (en) | 2011-12-21 | 2013-06-26 | Clariant International Ltd. | Fluorochemical composition and use thereof |
US9650518B2 (en) | 2012-01-06 | 2017-05-16 | Massachusetts Institute Of Technology | Liquid repellent surfaces |
US9493265B2 (en) | 2012-01-20 | 2016-11-15 | Sabic Global Technologies B.V. | Articles prepared from thermoplastic compositions, and method of preparing such articles |
EP2820090A4 (en) | 2012-02-27 | 2015-10-28 | 3M Innovative Properties Co | BASIC COMPOSITIONS INCLUDING INORGANIC OXIDE NANOPARTICLES AND AN ORGANIC BASE, COATED SUBSTRATES, ARTICLES, AND METHODS |
BR112014023436B1 (pt) | 2012-03-23 | 2021-05-04 | Massachusetts Institute Of Technology | recipiente tendo superfície impregnada com líquido e seu processo de fabricação |
US9309162B2 (en) | 2012-03-23 | 2016-04-12 | Massachusetts Institute Of Technology | Liquid-encapsulated rare-earth based ceramic surfaces |
WO2013150781A1 (ja) | 2012-04-06 | 2013-10-10 | 日東電工株式会社 | 撥油性が付与された通気シート |
WO2013172823A1 (en) | 2012-05-15 | 2013-11-21 | 3M Innovative Properties Company | Polyurethane-based protective coatings for rotor blades |
EP2855603B1 (en) | 2012-05-24 | 2022-09-28 | Massachusetts Institute of Technology | Medical device or medical implement |
US9175188B2 (en) | 2012-06-27 | 2015-11-03 | 3M Innovative Properties Company | Moisture-curable polysiloxane coating composition |
EP2872572B1 (en) | 2012-07-12 | 2024-06-19 | President and Fellows of Harvard College | Slippery self-lubricating polymer surfaces |
KR101660886B1 (ko) | 2012-07-13 | 2016-09-28 | 도요세이칸 그룹 홀딩스 가부시키가이샤 | 내용물에 대한 미끄러짐성이 뛰어난 포장용기 |
WO2014012078A2 (en) | 2012-07-13 | 2014-01-16 | President And Fellows Of Harvard College | Selective wetting and transport surfaces |
CN104797662B (zh) | 2012-07-13 | 2019-03-08 | 哈佛学院 | 基于含金属的化合物的光滑面 |
WO2014012039A1 (en) | 2012-07-13 | 2014-01-16 | President And Fellows Of Harvard College | Slippery liquid-infused porous surfaces having improved stability |
JP5947655B2 (ja) | 2012-08-02 | 2016-07-06 | 日東電工株式会社 | ポリテトラフルオロエチレン多孔質膜、並びに、それを用いた通気膜および通気部材 |
WO2014035742A2 (en) | 2012-08-30 | 2014-03-06 | The Trustees Of The University Of Pennsylvania | Sprayable superhydrophobic coatings |
LU92082B1 (en) | 2012-10-10 | 2014-04-11 | Ct De Rech Public Gabriel Lippmann | Method for manufacturing a superhydrophobic surface |
US20140178611A1 (en) | 2012-11-19 | 2014-06-26 | Massachusetts Institute Of Technology | Apparatus and methods employing liquid-impregnated surfaces |
KR20150086522A (ko) | 2012-11-19 | 2015-07-28 | 메사추세츠 인스티튜트 오브 테크놀로지 | 액체-함침된 표면을 사용하는 장치 및 방법 |
US9441079B2 (en) | 2012-11-20 | 2016-09-13 | 3M Innovative Properties Company | Block copolymer comprising polyorganosiloxane block and polyolefin block |
WO2014097309A1 (en) | 2012-12-17 | 2014-06-26 | Asian Paints Ltd. | Stimuli responsive self cleaning coating |
JP2016514168A (ja) | 2013-01-10 | 2016-05-19 | ステムセル テクノロジーズ インコーポレーティッド | メニスカス減少部材 |
WO2014209441A2 (en) | 2013-03-13 | 2014-12-31 | President And Fellows Of Harvard College | Solidifiable composition for preparation of liquid-infused slippery surfaces and methods of applying |
NL2010504C2 (en) | 2013-03-22 | 2014-09-24 | Estuary Holding B V | Use of ice-phobic coatings. |
US20140311940A1 (en) | 2013-04-17 | 2014-10-23 | Jonathan Braveman | Closeable silicon container |
US9187678B2 (en) | 2013-07-29 | 2015-11-17 | 3M Innovative Properties Company | Release films via solventless extrusion processes |
US9775972B2 (en) | 2013-07-30 | 2017-10-03 | Becton, Dickinson And Company | Interlocking needle hub and catheter hub actuator to increase rigidity of IV catheter assembly |
RU2547754C2 (ru) * | 2013-08-16 | 2015-04-10 | Игорь Леонидович Радченко | Полимерная порошковая композиция для супергидрофобного покрытия и способ получения супергидрофобного покрытия |
US20160296985A1 (en) | 2013-11-18 | 2016-10-13 | Massachusetts Institute Of Technology | Articles for manipulating impinging liquids and associated methods |
US20150307731A1 (en) * | 2013-11-25 | 2015-10-29 | Adam John Bechtel | Hydrophobic, Superhydrophobic, Oleophobic, and Paintphobic Tools, Devices, Systems, and Methods Using Solvent Resistant, Ultraviolet Resistant, Water Resistant, and Food Safe Phobic and Superphobic Coatings |
CA2932682C (en) | 2013-12-05 | 2023-08-22 | 3M Innovative Properties Company | Container for a spraying device |
JP6537240B2 (ja) | 2013-12-27 | 2019-07-03 | スリーエム イノベイティブ プロパティズ カンパニー | 被覆処理具 |
US10358561B2 (en) | 2014-04-09 | 2019-07-23 | Dow Silicones Corporation | Hydrophobic article |
US10493488B2 (en) | 2014-04-18 | 2019-12-03 | The University of Masachusetts | Methods and formulations for durable superhydrophic, self-cleaning, and superhydrophobic polymer coatings and objects having coatings thereon |
BR112017008787A2 (pt) | 2014-10-28 | 2017-12-26 | 3M Innovative Properties Co | componentes de um sistema de aplicação de aspersões que compreende uma superfície repelente & métodos |
US20170283316A1 (en) | 2014-10-28 | 2017-10-05 | 3M Innovative Properties Company | Repellent coatings comprising sintered particles and lubricant, articles & method |
CN107787342A (zh) | 2015-04-27 | 2018-03-09 | 密执安州立大学董事会 | 耐久性疏冰表面 |
CN108350289B (zh) | 2015-10-28 | 2021-10-12 | 3M创新有限公司 | 基于溶剂的拒斥性涂料组合物和经涂覆的基材 |
JP6873122B2 (ja) | 2015-10-28 | 2021-05-19 | スリーエム イノベイティブ プロパティズ カンパニー | 撥性表面を含むスプレー塗布システム構成要素及び方法 |
CN108350290B (zh) | 2015-10-28 | 2021-10-15 | 3M创新有限公司 | 包括拒斥性表面的经历冰形成的制品 |
WO2017189475A1 (en) | 2016-04-26 | 2017-11-02 | 3M Innovative Properties Company | Articles subject to ice formation comprising a repellent surface comprising a siloxane material |
EP3448945A4 (en) | 2016-04-26 | 2019-12-11 | 3M Innovative Properties Company | ARTICLES SUBJECT TO ICE FORMATION COMPRISING A REPELLENT SURFACE COMPRISING A FLUOROCHEMICAL MATERIAL |
-
2015
- 2015-10-28 BR BR112017008787A patent/BR112017008787A2/pt not_active Application Discontinuation
- 2015-10-28 WO PCT/US2015/057686 patent/WO2016069674A1/en active Application Filing
- 2015-10-28 CN CN201580058370.3A patent/CN107073494B/zh active Active
- 2015-10-28 MX MX2017005336A patent/MX2017005336A/es unknown
- 2015-10-28 RU RU2017114143A patent/RU2687436C2/ru not_active IP Right Cessation
- 2015-10-28 AU AU2015339342A patent/AU2015339342B2/en active Active
- 2015-10-28 KR KR1020177013933A patent/KR20170077162A/ko not_active Application Discontinuation
- 2015-10-28 JP JP2017502797A patent/JP6616395B2/ja active Active
- 2015-10-28 EP EP15793976.0A patent/EP3122470A1/en not_active Ceased
- 2015-10-28 SG SG11201703320QA patent/SG11201703320QA/en unknown
- 2015-10-28 US US15/306,224 patent/US10391506B2/en active Active
- 2015-10-28 CA CA2966343A patent/CA2966343A1/en not_active Abandoned
-
2019
- 2019-06-25 US US16/451,702 patent/US10987685B2/en active Active
-
2020
- 2020-02-05 US US16/782,105 patent/US10987686B2/en active Active
-
2021
- 2021-03-23 US US17/301,041 patent/US20210205828A1/en not_active Abandoned
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56154860U (ja) * | 1980-04-20 | 1981-11-19 | ||
JPH04270649A (ja) * | 1991-02-26 | 1992-09-28 | Toray Ind Inc | 離型フイルム |
WO1996001152A1 (en) * | 1994-07-01 | 1996-01-18 | The Procter & Gamble Company | Improved anti-clogging atomizer nozzle |
JP2001508698A (ja) * | 1997-01-24 | 2001-07-03 | ミネソタ・マイニング・アンド・マニュファクチャリング・カンパニー | 液体噴霧装置、並びに該装置とともに使用するのに適する使い捨て収納容器およびライナー |
JP2001511477A (ja) * | 1997-07-28 | 2001-08-14 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 合成有機ポリマーに対する疎水性で疎油性の添加剤としての高温安定フルオロケミカル |
JP2004531598A (ja) * | 2001-03-09 | 2004-10-14 | スリーエム イノベイティブ プロパティズ カンパニー | パーフルオロアルキル部分を含む撥水撥油性付与エステルオリゴマー |
JP2007515498A (ja) * | 2003-07-22 | 2007-06-14 | ライプニッツ−インスティトゥート フィア ノイエ マテリアーリエン ゲマインニュッツィゲ ゲゼルシャフト ミット ベシュレンクタ ハフトゥンク | 撥液性コーティング組成物及び高アルカリ耐性を有するコーティング |
JP2007523971A (ja) * | 2003-12-31 | 2007-08-23 | スリーエム イノベイティブ プロパティズ カンパニー | 撥水撥油性フルオロアクリレート |
JP2008524376A (ja) * | 2004-12-15 | 2008-07-10 | スリーエム イノベイティブ プロパティズ カンパニー | ポリマー溶融体の忌避性添加剤としてのフルオロケミカルジエステル |
JP2007297543A (ja) * | 2006-05-01 | 2007-11-15 | Shin Etsu Chem Co Ltd | 防汚コーティング剤がハードコート層に固着された複合ハードコート層を有する基材及びその形成方法 |
JP2011067710A (ja) * | 2009-09-23 | 2011-04-07 | Ransburg Industry Kk | 静電塗装機用の塗料カートリッジの洗浄方法及び塗料バッグ |
JP2014509959A (ja) * | 2011-01-19 | 2014-04-24 | プレジデント アンド フェローズ オブ ハーバード カレッジ | 高圧力安定性、光透過性、および自己修復特性を伴う易滑性表面 |
WO2012121858A1 (en) * | 2011-03-09 | 2012-09-13 | 3M Innovative Properties Company | Antireflective film comprising large particle size fumed silica |
US20140287243A1 (en) * | 2013-03-06 | 2014-09-25 | University Of Pittsburgh - Of The Commonwealth System Of Higher Education | Superhydrophobic coatings |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020080167A1 (ja) * | 2018-10-16 | 2020-04-23 | Agc株式会社 | 含フッ素エーテル化合物および物品 |
WO2021100827A1 (ja) * | 2019-11-22 | 2021-05-27 | ダイキン工業株式会社 | フルオロポリエーテル基シラン含有化合物 |
JP2021088551A (ja) * | 2019-11-22 | 2021-06-10 | ダイキン工業株式会社 | フルオロポリエーテル基シラン含有化合物 |
CN114729117A (zh) * | 2019-11-22 | 2022-07-08 | 大金工业株式会社 | 含氟代聚醚基的硅烷化合物 |
JP7319242B2 (ja) | 2019-11-22 | 2023-08-01 | ダイキン工業株式会社 | フルオロポリエーテル基シラン含有化合物 |
Also Published As
Publication number | Publication date |
---|---|
JP6616395B2 (ja) | 2019-12-04 |
US20190314838A1 (en) | 2019-10-17 |
RU2687436C2 (ru) | 2019-05-13 |
US10391506B2 (en) | 2019-08-27 |
BR112017008787A2 (pt) | 2017-12-26 |
EP3122470A1 (en) | 2017-02-01 |
CA2966343A1 (en) | 2016-05-06 |
AU2015339342A1 (en) | 2017-05-11 |
US10987686B2 (en) | 2021-04-27 |
RU2017114143A3 (ja) | 2018-11-29 |
KR20170077162A (ko) | 2017-07-05 |
CN107073494B (zh) | 2019-10-01 |
SG11201703320QA (en) | 2017-05-30 |
WO2016069674A1 (en) | 2016-05-06 |
MX2017005336A (es) | 2017-08-15 |
CN107073494A (zh) | 2017-08-18 |
RU2017114143A (ru) | 2018-11-29 |
US20210205828A1 (en) | 2021-07-08 |
US10987685B2 (en) | 2021-04-27 |
US20200171521A1 (en) | 2020-06-04 |
US20170252761A1 (en) | 2017-09-07 |
AU2015339342B2 (en) | 2018-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6616395B2 (ja) | 撥性表面を含むスプレー塗布システム構成要素及び方法 | |
JP6873122B2 (ja) | 撥性表面を含むスプレー塗布システム構成要素及び方法 | |
JP5950925B2 (ja) | 疎水性フッ素化コーティング | |
Latthe et al. | Development of sol–gel processed semi-transparent and self-cleaning superhydrophobic coatings | |
WO2016069239A2 (en) | Repellent coatings comprising sintered particles and lubricant, articles & method | |
JP2002038102A (ja) | 難湿性表面を形成するための組成物 | |
US20220145084A1 (en) | Improvements relating to superhydrophobic surfaces | |
US20180304287A1 (en) | Spray application system components comprising a repellent surface & methods | |
US20220315775A1 (en) | Coating compositions for hydrophobic films and articles having hydrophobic surfaces | |
WO2020205879A1 (en) | Coating compositions for hydrophobic films and articles having hydrophobic surfaces | |
Chiera | Fabrication of liquid-infused surfaces via mussel-inspired chemistry | |
WO2016004195A1 (en) | Hydrophobic coating composition comprising alkoxy silane monomer and fluorinated monomer in an organic solvent |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170117 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170117 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180322 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180403 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20180416 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20180418 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180703 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190108 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20190405 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190606 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20191008 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20191107 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6616395 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |