JP2014181144A - Rice husk coal or rice straw coal including abundance of amorphous silica, method for manufacturing rice husk coal or rice straw coal including abundance of amorphous silica, and food, agricultural fertilizer, and fodder each including abundance of amorphous silica - Google Patents

Rice husk coal or rice straw coal including abundance of amorphous silica, method for manufacturing rice husk coal or rice straw coal including abundance of amorphous silica, and food, agricultural fertilizer, and fodder each including abundance of amorphous silica Download PDF

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JP2014181144A
JP2014181144A JP2013055725A JP2013055725A JP2014181144A JP 2014181144 A JP2014181144 A JP 2014181144A JP 2013055725 A JP2013055725 A JP 2013055725A JP 2013055725 A JP2013055725 A JP 2013055725A JP 2014181144 A JP2014181144 A JP 2014181144A
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rice
charcoal
amorphous silica
rice husk
rice straw
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JP6159110B2 (en
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Noriko Imama
典子 今間
Nobukazu Taguchi
信和 田口
Senshin Umeki
千真 梅木
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GAIA INST OF ENVIRONMENTAL TECHNOLOGY Inc
GAIA INSTITUTE OF ENVIRONMENTAL TECHNOLOGY Inc
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
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    • Y02P60/87—Re-use of by-products of food processing for fodder production

Abstract

PROBLEM TO BE SOLVED: To provide a rice husk coal or rice straw coal including an abundance of amorphous silica which includes an abundance of water-soluble amorphous silica but includes no carcinogenic substances; a method for manufacturing a rice husk coal or rice straw coal including an abundance of amorphous silica; and a food, an agricultural fertilizer, and a fodder each including an abundance of amorphous silica.SOLUTION: The provided rice husk coal or rice straw coal including an abundance of amorphous silica is obtained by carbonizing rice husks or rice straws within an oxygen-free atmosphere by using a carbonizing apparatus for executing carbonization in an agitated state, whereas the rice husk coal or rice straw coal is obtained by confining, to 500°C to 700°C, the temperature range for carbonizing the rice husks or rice straws within the carbonizing apparatus. Moreover, a method for manufacturing amorphous silica wherein the rice husk coal or rice straw coal is agitated within a body of ion-exchanged water within a range of 30 to 100°C so as to dissolve and extract, into and with the ion-exchanged water, amorphous silica included within the rice husk coal or rice straw coal is also provided.

Description

本発明は、もみ殻あるいは稲わらを無酸素雰囲気中にて、撹拌しながら炭化する炭化装置によって炭化された非晶質シリカを豊富に含むもみ殻炭あるいは稲わら炭、及び非晶質シリカを豊富に含むもみ殻炭あるいは稲わら炭の製造方法、並びに非晶質シリカを豊富に含むもみ殻炭食品、稲わら炭食品、食品添加物、飼料及びもみ殻あるいは稲わら炭から溶出させた非晶質シリカの食品、飼料、肥料、植物活性剤に関する。   The present invention provides rice husk charcoal, rice straw charcoal, and amorphous silica rich in amorphous silica carbonized by a carbonizer that carbonizes the rice husk or rice straw in an oxygen-free atmosphere while stirring. Process for producing abundant rice husk charcoal or rice straw charcoal, and rice husk charcoal food rich in amorphous silica, rice straw charcoal food, food additives, feed and rice husk or rice straw charcoal The present invention relates to crystalline silica foods, feeds, fertilizers, and plant activators.

従来のもみ殻炭からの非晶質シリカの製造方法に関しては、例えば、特許文献１に記載されている。特許文献１には、非晶質シリカの製造方法について記載されており、もみ殻を流動床焼成炉で第１次焼成し、ついで、外熱式回転炉にて第２次焼成してもみ殻炭を作成し、前記もみ殻炭から、非晶質シリカを製造する方法が開示されている。   For example, Patent Document 1 describes a conventional method for producing amorphous silica from rice husk charcoal. Patent Document 1 describes a method for producing amorphous silica. Rice husk is first fired in a fluidized bed firing furnace, and then secondly fired in an external heating rotary furnace. A method for producing charcoal and producing amorphous silica from the rice husk charcoal is disclosed.

特開平７−１９６３１２JP-A-7-19631

特許文献１の非晶質シリカの製造方法は、第１次焼成と、第２次焼成の２回の焼成工程が、必要であって、焼成工程が煩雑という問題点があった。また、非晶質シリカの用途については、コンクリートの補強材のみの開示であって、発がん性物質を含まないことが必須である食品や飼料、及び水溶性の非晶質シリカを用いることが必須である食品、飼料、肥料については開示されていない。   The method for producing amorphous silica of Patent Document 1 has a problem that two firing steps of primary firing and secondary firing are necessary, and the firing step is complicated. In addition, regarding the use of amorphous silica, it is only disclosure of concrete reinforcement, and it is essential to use foods and feeds that do not contain carcinogenic substances, and water-soluble amorphous silica. No food, feed, or fertilizer is disclosed.

本発明の課題は、水溶性の非晶質シリカを豊富に含み、かつ発がん性物質を含まないもみ殻炭あるいは稲わら炭、及び非晶質シリカ豊富に含むもみ殻炭あるいは稲わら炭の製造方法、並びに非晶質シリカを豊富に含む食品、農業用肥料および飼料を得ることである。   The object of the present invention is to produce rice husk charcoal or rice straw charcoal rich in water-soluble amorphous silica and free of carcinogenic substances, and rice husk charcoal or rice straw charcoal rich in amorphous silica. The method and to obtain foods, agricultural fertilizers and feeds rich in amorphous silica.

本発明のもみ殻炭、あるいは稲わら炭は、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置を使用して、５００℃〜７００℃の温度域で炭化されたもみ殻炭、あるいは稲わら炭であり、水溶性の非晶質シリカを豊富に含み、かつ発がん性物質である結晶性シリカやベンツピレンを含まないため、食品（サプリメントを含む）、あるいは農業用肥料、あるいは飼料（家畜用及び愛がん動物用）の用途に利用し得るものである。   The rice husk charcoal or rice straw charcoal of the present invention is a rice husk charcoal carbonized in a temperature range of 500 ° C. to 700 ° C. using a carbonizing apparatus that is carbonized while stirring in an oxygen-free atmosphere, or Rice straw charcoal, rich in water-soluble amorphous silica and free of carcinogenic crystalline silica and benzpyrene, food (including supplements), agricultural fertilizer, or feed (livestock And can be used for use in pet animals.

請求項１に係る発明は、もみ殻が、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって５００℃〜７００℃の温度範囲によって炭化され、非晶質シリカを豊富に含む含むことを特徴とするもみ殻炭である。
もみ殻を炭化する温度が、５００℃を下回ると、炭化時に発がん性物質であるベンツピレンが生成し、また、もみ殻を炭化する温度が７００℃を上回ると、もみ殻中の非晶質シリカが結晶化して水に溶け難く、生体に吸収され難くなるばかりか、場合によっては、人体に対して発がん性を有してしまうという不具合が発生する。 In the invention according to claim 1, the rice husk is carbonized in a temperature range of 500 ° C. to 700 ° C. by a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere, and contains abundant amorphous silica. Rice husk charcoal characterized by
When the temperature for carbonizing the rice husk falls below 500 ° C., benzpyrene, which is a carcinogenic substance, is produced during carbonization, and when the temperature for carbonizing the rice husk exceeds 700 ° C., amorphous silica in the rice husk is reduced. In addition to being hardly crystallized and dissolved in water, it is difficult to be absorbed by a living body, and in some cases, it causes a problem of having carcinogenicity to the human body.

請求項２に係る発明は、前記もみ殻炭は、人体にとって発がん性を有する結晶性シリカやベンツピレンを含まないことを特徴とする請求項１記載のもみ殻炭である。   The invention according to claim 2 is the rice husk charcoal according to claim 1, characterized in that the rice husk charcoal does not contain crystalline silica or benzpyrene having carcinogenicity for the human body.

請求項３に係る発明は、前記もみ殻炭が含む非晶質シリカは、水溶性であることを特徴とする請求項１または２記載のもみ殻炭である。   The invention according to claim 3 is the rice husk charcoal according to claim 1 or 2, wherein the amorphous silica contained in the rice husk charcoal is water-soluble.

請求項４に係る発明は、稲わらが、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって５００℃〜７００℃の温度範囲によって炭化され、非晶質シリカを豊富に含む含むことを特徴とする稲わら炭である。
稲わら炭を炭化する温度が、５００℃を下回ると、炭化時に発がん性物質であるベンツピレンが生成し、また、稲わら炭を炭化する温度が７００℃を上回ると、もみ殻中の非晶質シリカが結晶化して水に溶け難く、生体に吸収され難くなるばかりか、場合によっては、人体に対して発がん性を有してしまうという不具合が発生する。 According to a fourth aspect of the present invention, rice straw is carbonized in a temperature range of 500 ° C. to 700 ° C. by a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere, and contains abundant amorphous silica. It is rice straw charcoal characterized by
When the temperature for carbonizing rice straw charcoal is below 500 ° C., benzpyrene, which is a carcinogenic substance, is produced during carbonization, and when the temperature for carbonizing rice straw charcoal is above 700 ° C., amorphous in rice husks In addition to the fact that silica is crystallized and hardly dissolves in water and is not easily absorbed by living bodies, in some cases, it has a problem of causing carcinogenicity to the human body.

請求項５に係る発明は、前記稲わら炭は、人体にとって発がん性を有する結晶性シリカやベンツピレンを含まないことを特徴とする請求項４記載の稲わら炭である。   The invention according to claim 5 is the rice straw charcoal according to claim 4, characterized in that the rice straw charcoal does not contain crystalline silica or benzpyrene having carcinogenicity for the human body.

請求項６に係る発明は、前記稲わら炭が含む非晶質シリカは、水溶性であることを特徴とする請求項４または５記載の稲わら炭である。   The invention according to claim 6 is the rice straw charcoal according to claim 4 or 5, wherein the amorphous silica contained in the rice straw charcoal is water-soluble.

請求項７に係る発明は、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって、温度範囲が５００℃〜７００℃にて、もみ殻を炭化してもみ殻炭を作成することを特徴とするもみ殻炭の製造方法である。   The invention according to claim 7 is to produce rice husk charcoal by carbonizing the rice husk in a temperature range of 500 ° C. to 700 ° C. with a carbonizer that is carbonized while stirring in an oxygen-free atmosphere. This is a characteristic method for producing rice husk charcoal.

請求項８に係る発明は、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって、温度範囲が５００℃〜７００℃にて、稲わらを炭化して稲わら炭を作成することを特徴とする稲わら炭の製造方法である。   The invention according to claim 8 is to produce rice straw charcoal by carbonizing rice straw at a temperature range of 500 ° C. to 700 ° C. by a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere. This is a characteristic method for producing rice straw charcoal.

請求項９に係る発明は、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって、温度範囲が５００℃〜７００℃にて、もみ殻を炭化してもみ殻炭を作製するか、あるいは温度範囲が５００℃〜７００℃にて、稲わらを炭化して稲わら炭を作製し、前記もみ殻炭あるいは稲わら炭を、イオン交換水に投入して、前記イオン交換水の温度範囲３０℃〜１００℃にて撹拌して、前記もみ殻炭あるいは稲わら炭に含まれる非晶質シリカをイオン交換水に溶かして抽出することを特徴とする非晶質シリカの製造方法である。   The invention according to claim 9 is to produce rice husk charcoal by carbonizing rice husk in a temperature range of 500 ° C. to 700 ° C. by a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere. Alternatively, at a temperature range of 500 ° C. to 700 ° C., rice straw is carbonized to produce rice straw charcoal, and the rice husk charcoal or rice straw charcoal is introduced into ion exchange water, and the temperature range of the ion exchange water is set. A method for producing amorphous silica, comprising stirring at 30 ° C. to 100 ° C. and dissolving and extracting amorphous silica contained in the rice husk charcoal or rice straw charcoal in ion-exchanged water.

請求項１０に係る発明は、請求項７記載のもみ殻炭の製造方法によって製造されたもみ殻炭、あるいは請求項８記載の稲わら炭の製造方法によって製造された稲わら炭、あるいは請求項９記載の非晶質シリカの製造方法によって製造された非晶質シリカを含有することを特徴とする食品である。   The invention according to claim 10 is the rice husk charcoal produced by the method for producing rice husk charcoal according to claim 7, or the rice straw charcoal produced by the method for producing rice straw charcoal according to claim 8, or 9. A food comprising amorphous silica produced by the method for producing amorphous silica according to 9.

請求項１１に係る発明は、請求項７記載のもみ殻炭の製造方法によって製造されたもみ殻炭、あるいは請求項８記載の稲わら炭の製造方法によって製造された稲わら炭、あるいは請求項９記載の非晶質シリカの製造方法によって製造された非晶質シリカを含有することを特徴とする農業用肥料である。   The invention according to claim 11 is rice husk charcoal produced by the method for producing rice husk charcoal according to claim 7, or rice straw charcoal produced by the method for producing rice straw charcoal according to claim 8, or 9. A fertilizer for agriculture, comprising amorphous silica produced by the method for producing amorphous silica according to 9.

請求項１２に係る発明は、請求項７記載のもみ殻炭の製造方法によって製造されたもみ殻炭、あるいは請求項８記載の稲わら炭の製造方法によって製造された稲わら炭、
あるいは請求項９記載の非晶質シリカの製造方法によって製造された非晶質シリカを含有することを特徴とする飼料である。 The invention according to claim 12 is a rice husk charcoal produced by the method for producing rice husk charcoal according to claim 7, or a rice straw charcoal produced by the method for producing rice straw charcoal according to claim 8,
Or it is the feed characterized by containing the amorphous silica manufactured by the manufacturing method of the amorphous silica of Claim 9.

請求項１、２、３によるもみ殻炭によれば、人体、あるいは植物、家畜に有用で、吸収され易い水溶性である非晶質シリカを豊富に含み、かつ発がん性物質、ベンツピレンを含まないもみ殻炭を得ることができ、食品、肥料、飼料等に用いることができる。   According to the rice husk charcoal according to claims 1, 2 and 3, it is abundant in water-soluble amorphous silica that is useful for human body, plant and livestock, and is easily absorbed, and does not contain carcinogenic substances and benzpyrene. Rice husk charcoal can be obtained and used for food, fertilizer, feed and the like.

請求項４、５、６による稲わら炭によれば、人体、あるいは植物、家畜に有用で、吸収され易い水溶性である非晶質シリカを豊富に含み、かつ発がん性物質、ベンツピレンを含まない稲わら炭を得ることができ、食品、肥料、飼料等に用いることができる。   According to the rice straw charcoal according to claims 4, 5 and 6, it contains abundant amorphous silica which is useful for human body, plant and livestock and is easily absorbed, and does not contain carcinogenic substances and benzpyrene. Rice straw charcoal can be obtained and used for food, fertilizer, feed and the like.

請求項７によるもみ殻炭の製造方法によれば、水溶性である非晶質シリカを豊富に含み、かつ発がん性物質、ベンツピレンを含まないもみ殻炭を得ることができる。   According to the method for producing rice husk charcoal according to claim 7, it is possible to obtain rice husk charcoal that is rich in water-soluble amorphous silica and does not contain carcinogenic substances and benzpyrene.

請求項８による稲わら炭の製造方法によれば、水溶性である非晶質シリカを豊富に含み、かつ発がん性物質、ベンツピレンを含まない稲わら炭を得ることができる。   According to the method for producing rice straw charcoal according to claim 8, rice straw charcoal containing abundant water-soluble amorphous silica and free of carcinogenic substances and benzpyrene can be obtained.

請求項９による非晶質シリカの製造方法によれば、もみ殻炭あるいは稲わら炭を用いて、吸収され易い水溶性である非晶質シリカを安定して製造することができる。   According to the method for producing amorphous silica according to the ninth aspect, water-soluble amorphous silica that is easily absorbed can be stably produced using rice husk charcoal or rice straw charcoal.

請求項１０による食品によれば、もみ殻炭、あるいは稲わら炭、あるいは前記もみ殻炭、稲わら炭から抽出した非晶質シリカを含む食品を提供することができ、人体の骨の強化、美肌効果、血管の栄養成分の補強、抗酸化力の強化等の効果がある。   According to the food according to claim 10, rice husk charcoal, rice straw charcoal, or food containing amorphous silica extracted from the rice husk charcoal, rice straw charcoal can be provided, strengthening of human bones, It has effects such as beautifying skin, reinforcing nutrients in blood vessels, and strengthening antioxidant power.

請求項１１による農業用肥料によれば、もみ殻炭、あるいは稲わら炭、あるいは前記もみ殻炭、稲わら炭から抽出した非晶質シリカを含む農業用肥料を提供することができ、植物の成長の促進、および茎の強度を向上させる等の効果がある。   According to the agricultural fertilizer according to claim 11, it is possible to provide an agricultural fertilizer containing rice husk charcoal, rice straw charcoal, or amorphous silica extracted from the rice husk charcoal, rice straw charcoal. There are effects such as promotion of growth and improvement of stem strength.

請求項１２による飼料によれば、もみ殻炭、あるいは稲わら炭、あるいは前記もみ殻炭、稲わら炭から抽出した非晶質シリカを含む飼料を提供することができ、家畜及び愛がん動物の健康維持、肉質の向上等の効果がある。   According to the feed according to claim 12, it is possible to provide a feed containing rice husk charcoal, rice straw charcoal, or amorphous silica extracted from the rice husk charcoal, rice straw charcoal, and health of domestic animals and pet animals. There are effects such as maintenance and improvement of meat quality.

本発明によれば、水溶性の非晶質シリカを豊富に含み、かつ発がん性物質を含まないもみ殻炭あるいは稲わら炭、及び非晶質シリカ豊富に含むもみ殻炭あるいは稲わら炭の製造方法、並びに非晶質シリカを豊富に含む食品、農業用肥料および飼料を得ることができる。   According to the present invention, rice husk charcoal or rice straw charcoal containing abundant water-soluble amorphous silica and free of carcinogenic substances, and production of rice husk charcoal or rice straw charcoal rich in amorphous silica Methods and foods, agricultural fertilizers and feeds rich in amorphous silica can be obtained.

もみ殻を、炭化温度５００℃で炭化したもみ殻炭の、シリカのＸ線回折データである。It is an X-ray diffraction data of silica of rice husk charcoal obtained by carbonizing rice husk at a carbonization temperature of 500 ° C. 炭化温度５００℃のもみ殻炭からの、シリカ溶出試験結果。Results of silica dissolution test from rice husk charcoal with a carbonization temperature of 500 ° C. 本実施例にて使用する炭化装置の図。The figure of the carbonization apparatus used in a present Example. もみ殻炭を含有するペレット型食品の図。The figure of the pellet type food containing rice husk charcoal. もみ殻炭を詰めたカプセル型食品の図。Illustration of capsule-type food stuffed with rice husk charcoal.

本発明の実施の形態による非晶質シリカを豊富に含むもみ殻炭は、もみ殻を、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって炭化されたもみ殻炭であって、前記炭化装置にて、もみ殻が炭化される温度範囲は、５００℃〜７００℃であることを特徴とする。   The rice husk charcoal rich in amorphous silica according to an embodiment of the present invention is rice husk charcoal carbonized by a carbonizer that carbonizes the rice husk while stirring in an oxygen-free atmosphere. The temperature range in which the rice husk is carbonized in the carbonization apparatus is 500 ° C to 700 ° C.

本発明の実施の形態による非晶質シリカを豊富に含む稲わら炭は、稲わらを、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって炭化された稲わら炭であって、前記炭化装置にて、稲わらが炭化される温度範囲は、５００℃〜７００℃であることを特徴とする。   Rice straw charcoal rich in amorphous silica according to an embodiment of the present invention is rice straw charcoalized by a carbonization apparatus that carbonizes rice straw while stirring in an oxygen-free atmosphere. The temperature range in which rice straw is carbonized in the carbonization apparatus is 500 ° C to 700 ° C.

ここで、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置の一例として、図３に本発明に使用するもみ殻、あるいは稲わらを炭化するための、炭化装置の１例の構成図を示した。図３に示すように、本発明で使用される炭化装置（還元炭化処理装置）は、内部に螺旋羽と攪拌羽１を配置した回転する一つのキルン２と、この一つのキルン２の内部に投入された廃棄物を含む有機物等を無酸素雰囲気の還元状態で間接加熱しつつ有機物等に蓄熱して一つのキルン２の内部全体に熱を供給する燃焼室３と、燃焼室３内に臨むバーナー等の加熱源４と、キルン２の内部に投入された有機物等に含まれる水分を燃焼室３の間接加熱によって蒸発させるようにキルン２の内部にエリア設定された乾燥部２ａと、乾燥部２ａで乾燥処理された有機物等を間接加熱分解させることで炭化させるようにキルン２の内部にエリア設定された炭化部２ｂと、を備えている。   Here, as an example of a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere, FIG. 3 is a configuration diagram of an example of a carbonization apparatus for carbonizing rice husk or rice straw used in the present invention. showed that. As shown in FIG. 3, the carbonization apparatus (reduction carbonization processing apparatus) used in the present invention includes a rotating kiln 2 in which a spiral blade and a stirring blade 1 are arranged, and an interior of the one kiln 2. Combustion chamber 3 that stores the organic matter, etc., including the input waste, in an organic material etc. while indirectly heating in a reduced state in an oxygen-free atmosphere and supplies heat to the entire interior of one kiln 2, and the combustion chamber 3 A heating unit 4 such as a burner, a drying unit 2a having an area set inside the kiln 2 so as to evaporate water contained in the organic matter and the like introduced into the kiln 2 by indirect heating of the combustion chamber 3, and a drying unit A carbonized portion 2b having an area set inside the kiln 2 so as to be carbonized by indirectly heating and decomposing the organic matter dried by 2a.

本発明の非晶質シリカを豊富に含むもみ殻炭あるいは稲わら炭、及び非晶質シリカ豊富に含むもみ殻炭あるいは稲わら炭の製造方法、並びに非晶質シリカを豊富に含む食品、農業用肥料および飼料の実施例について、以下記載する。   Rice husk charcoal or rice straw charcoal rich in amorphous silica of the present invention, a method for producing rice husk charcoal or rice straw charcoal rich in amorphous silica, and food and agriculture rich in amorphous silica Examples of fertilizer and feed are described below.

（実施例１）
図１は、図３の炭化装置によって、もみ殻を、それぞれ上のカーブから、炭化温度２５０℃、３００℃、３５０℃、４５０℃、５００℃、７００℃で炭化したもみ殻炭中のシリカのＸ線回折データである。ここで、もみ殻炭中のシリカのＸ線回折データ６個のカーブ共に、ブロードなカーブを描いており、もみ殻炭中のシリカ炭化温度２５０℃〜７００℃の間にて非晶質であることが分かる。しかし、炭化温度５００℃未満では、発がん性のベンツビレンが発生するので、実際の使用できるのは、５００℃〜７００℃の範囲で炭化したもみ殻炭である。
なお、稲わら炭についても、図３の炭化装置によって炭化した稲わら炭については、もみ殻炭と同様の結果が得られている。 Example 1
FIG. 1 is a graph of silica in rice husk charcoal obtained by carbonizing at a carbonization temperature of 250 ° C., 300 ° C., 350 ° C., 450 ° C., 500 ° C. and 700 ° C. from the above curves by the carbonization apparatus of FIG. X-ray diffraction data. Here, 6 curves of X-ray diffraction data of silica in rice husk charcoal are broad curves, and are amorphous between silica carbonization temperatures of 250 ° C. and 700 ° C. in rice husk charcoal. I understand that. However, since carcinogenic benzbilene is generated at a carbonization temperature of less than 500 ° C., rice husk charcoal carbonized in the range of 500 ° C. to 700 ° C. can be actually used.
As for rice straw charcoal, the same result as rice husk charcoal is obtained for rice straw charcoalized by the carbonization apparatus of FIG.

（実施例２）
図２は、炭化温度５００℃のもみ殻炭からの、シリカ溶出試験結果である。
試験方法は、イオン交換水５００ｍＬをビーカーに入れ、乳鉢で軽く粉砕したもみ殻炭（炭化温度５００℃）１．０ｇを投入し、３０℃、４０℃、５０℃、６０℃の各温度条件に制御し、スターラーで撹拌（１０００ｒｐｍ）しながら１時間おきに溶液を採取〜ろ過（５Ａ）し、吸光光度計を用いて溶液中のＳｉ濃度を測定した。
ここで、３０℃、４０℃、５０℃、６０℃の各温度条件の順番に、Ｓｉ濃度が上昇していることがわかる。 (Example 2)
FIG. 2 is a result of silica dissolution test from rice husk charcoal having a carbonization temperature of 500 ° C.
The test method is to put 500 mL of ion-exchanged water in a beaker, add 1.0 g of rice husk charcoal (carbonization temperature 500 ° C.) that has been lightly crushed in a mortar, and each temperature condition of 30 ° C., 40 ° C., 50 ° C., 60 ° C. The solution was collected and filtered (5A) every hour while being controlled and stirred with a stirrer (1000 rpm), and the Si concentration in the solution was measured using an absorptiometer.
Here, it can be seen that the Si concentration increases in the order of the temperature conditions of 30 ° C., 40 ° C., 50 ° C., and 60 ° C.

（実施例３）
図４は、もみ殻炭を含有するペレット型食品５０１の図である。５０１は、ペレット型の形状であって、請求項７の製造方法にて製造されたもみ殻炭１０１が、バインダー６００により固められて形成されている。
ペレット型食品５０１は、もみ殻炭１０１に含まれる非晶質シリカの作用にて、人体の骨の強化、美肌効果、血管の栄養成分の補強、抗酸化力の強化等の効果がある。
なお、５０１の形態としては、固体でなく、ゼリー状の形態であっても構わない。この場合、水がなくても、人体が、飲み込むことができるという長所がある。
なお、もみ殻炭に変えて、稲わら炭を使用しても、同様の効果が期待できる。 (Example 3)
FIG. 4 is a diagram of a pellet-type food 501 containing rice husk charcoal. Reference numeral 501 denotes a pellet shape, which is formed by hardening rice husk charcoal 101 manufactured by the manufacturing method of claim 7 with a binder 600.
The pellet-type food 501 has effects such as strengthening of human bones, skin-beautifying effect, reinforcement of nutritional components of blood vessels, and strengthening of antioxidant power by the action of amorphous silica contained in rice husk charcoal 101.
Note that the form of 501 may be a jelly-like form instead of a solid form. In this case, there is an advantage that the human body can be swallowed even without water.
The same effect can be expected by using rice straw charcoal instead of rice husk charcoal.

（実施例４）
図５は、請求項７の製造方法にて製造されたもみ殻炭（炭化温度５００℃）を詰めたカプセル型食品５００の図である。カプセル４００の内部には、もみ殻炭１００と、乳酸菌、アップルペクチン、オリゴ糖を詰め、前記カプセルの原料は、非遺伝子組み換えのとうもろこしを用いた。
カプセル型食品５００は、もみ殻炭１００に含まれる非晶質シリカの作用にて、人体の骨の強化、美肌効果、血管の栄養成分の補強、抗酸化力の強化等の効果がある。 Example 4
FIG. 5 is a diagram of a capsule-type food 500 stuffed with rice husk charcoal (carbonization temperature 500 ° C.) produced by the production method of claim 7. The capsule 400 was filled with rice husk charcoal 100, lactic acid bacteria, apple pectin, and oligosaccharide, and the raw material of the capsule was non-genetically modified corn.
The capsule-type food 500 has effects such as strengthening of human bones, skin-beautifying effect, strengthening of nutritional components of blood vessels, and strengthening of antioxidant power by the action of amorphous silica contained in rice husk charcoal 100.

ここで、ケイ素は人体にも含まれ、毛髪、爪、血管、骨、関節や細胞壁などに存在しており、生体内のケイ素はコラーゲンを束ねる作用を持ち、骨、毛髪、爪、コラーゲンの再生や補強、維持に役立つ他、肌の保湿などにも影響を及ぼす。
更に、ケイ素は腸壁から吸収され、血管を通る際、血管内部の付着物を可溶化する作用があり、動脈硬化の予防にも効果がある。
なお、もみ殻炭に変えて、稲わら炭を使用しても、同様の効果が期待できる。 Here, silicon is also contained in the human body and is present in hair, nails, blood vessels, bones, joints, cell walls, etc., and silicon in the living body has an action of binding collagen to regenerate bone, hair, nails and collagen. In addition to helping to reinforce and maintain, it also affects the moisture retention of the skin.
Furthermore, silicon is absorbed from the intestinal wall and has the effect of solubilizing deposits inside the blood vessel when passing through the blood vessel, and is effective in preventing arteriosclerosis.
The same effect can be expected by using rice straw charcoal instead of rice husk charcoal.

（実施例５）
本実施例は、請求項７により製造されたもみ殻炭、あるいは請求項８により製造された稲わら炭を農業用肥料として用いる例である。粉砕した前記もみ殻炭、あるいは稲わら炭を直接、田畑に散布する方法である。これにより、植物の成長の促進、あるいは茎の強化が行われる。なお、イチゴ栽培においては、うどんこ病の発生を１０分の１程度に抑えられる効果がある。 (Example 5)
In this example, rice husk charcoal produced according to claim 7 or rice straw charcoal produced according to claim 8 is used as an agricultural fertilizer. In this method, the crushed rice husk charcoal or rice straw charcoal is sprayed directly on the field. Thereby, the growth of the plant is promoted or the stem is strengthened. In addition, in strawberry cultivation, there exists an effect which can suppress generation | occurrence | production of powdery mildew to about 1/10.

（実施例６）
本実施例は、請求項７により製造されたもみ殻炭、あるいは請求項８により製造された稲わら炭を飼料として用いる例である。粉砕した前記もみ殻炭、あるいは稲わら炭を直接、家畜の飼料に混ぜる方法である。
これによって、家畜及び愛がん動物の健康を増進し、また肉質の改善も行われる。 (Example 6)
In this example, rice husk charcoal produced according to claim 7 or rice straw charcoal produced according to claim 8 is used as feed. In this method, the ground rice husk charcoal or rice straw charcoal is directly mixed with livestock feed.
As a result, the health of domestic animals and pet cancer animals is improved, and the meat quality is also improved.

（実施例７）
本実施例は、請求項７により製造されたもみ殻炭、あるいは請求項８により製造された稲わら炭から、非晶質シリカを抽出し、前記非晶質シリカを利用する使用方法である。
⇒人間向け食品、飼料の添加剤
ＤＨＡ強化食品やカルシウム強化食品のイメージである。
⇒酢やお酒のように使う液体状態の健康補助剤、健康補助剤

例えば、ご飯を炊くときに10ｍｌ添加とか、コーヒーに２滴とかいった使い方である。
⇒ゼリー状で利用する栄養補助食品への応用。
⇒原液で利用する栄養補助飲料
シリカ水のような応用である。
⇒濃縮されたものを希釈して利用する栄養補助飲料

⇒乾燥させたものの粉末利用
⇒肥料、液肥、植物活性剤 (Example 7)
The present embodiment is a method of using amorphous silica by extracting amorphous silica from rice husk charcoal produced according to claim 7 or rice straw charcoal produced according to claim 8.
⇒ Additives for human food and feed
It is an image of DHA-enriched food and calcium-enriched food.
⇒ Liquid health aids and health aids used like vinegar and liquor

For example, you can use 10ml when you cook rice or 2 drops of coffee.
⇒ Application to dietary supplements used in jelly form.
⇒ Nutritional supplement beverage used in stock solution
This is an application like silica water.
⇒ Nutritional supplement beverages that are used after dilution

⇒Use of dried powder
⇒ Fertilizer, liquid fertilizer, plant activator

本発明によれば、貴重な非晶質シリカを豊富に含み、かつ発がん性物質を含まない、食用も可能なもみ殻炭、稲わら炭、および非晶質シリカを提供することができ、人体の健康増進、及び植物の生育の促進、及び畜産業の発展に寄与する。   According to the present invention, it is possible to provide edible rice husk charcoal, rice straw charcoal, and amorphous silica that are rich in valuable amorphous silica and that do not contain carcinogenic substances. It contributes to the promotion of health, promotion of plant growth, and development of livestock industry.

２…キルン
２ａ 乾燥部
２ｂ 炭化部
２ｄ 蓄熱部
２ｃ 内部空間
２in 入口
２out 出口
３…燃焼室
３ａ…排気管
４…加熱源
５…配管部
６…冷却部
７…脱臭部
８…乾留ガス回収部
９…補助加熱源
１０…蒸気煙経路
１１…油化部
１２…配水管
１３…ファン
１４…ホッパ
１５…原料供給配管
１６…供給スクリュー
１７…第２排出配管
１８…冷却装置
１９…接続管（下流側排ガス管）
１９ａ 下流側排ガス管上管
１９b 下流側排ガス管下管
２０…搬送スクリュー
２１…搬送スクリュー
２２…蒸気抜きパイプ（上流側排ガス管）
２２ａ 上流側排ガス管上管
２２b 上流側排ガス管下管
２３ 煙突部
２４ 循環管
２５ ガス抜きパイプ
３０ 接続部
６０ 回収部
Ｐ 投入素材
Ｑ 炭化された素材
１００、１０１ もみ殻炭
２００ カプセルのフタ
３００ カプセルの容器
４００ カプセル
５００ カプセル型食品
５０１ ペレット型食品
６００ バインダー DESCRIPTION OF SYMBOLS 2 ... Kiln 2a Drying part 2b Carbonization part 2d Heat storage part 2c Internal space 2in Inlet 2out Outlet 3 ... Combustion chamber 3a ... Exhaust pipe 4 ... Heat source 5 ... Piping part 6 ... Cooling part 7 ... Deodorizing part 8 ... Dry distillation gas recovery part 9 ... Auxiliary heating source 10 ... Steam smoke path 11 ... Oilification section 12 ... Water distribution pipe 13 ... Fan 14 ... Hopper 15 ... Raw material supply pipe 16 ... Supply screw 17 ... Second discharge pipe 18 ... Cooling device 19 ... Connection pipe (downstream side) Exhaust pipe)
19a Downstream exhaust pipe upper pipe
19b Downstream exhaust pipe
20 ... Conveying screw 21 ... Conveying screw 22 ... Steam vent pipe (upstream exhaust gas pipe)
22a Upper side exhaust pipe upper pipe
22b Upstream exhaust pipe lower pipe
23 Chimney part 24 Circulation pipe 25 Gas vent pipe 30 Connection part 60 Collection part P Input material Q Carbonized material 100, 101 Rice husk charcoal 200 Caps lid 300 Capsule container 400 Capsule 500 Capsule type food 501 Pellet type food 600 Binder

Claims (12)

もみ殻が、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって５００℃〜７００℃の温度範囲によって炭化され、
非晶質シリカを豊富に含む含むことを特徴とするもみ殻炭。 Rice husks are carbonized in a temperature range of 500 ° C. to 700 ° C. by a carbonizer that is carbonized with stirring in an oxygen-free atmosphere,
Rice husk charcoal characterized by containing abundant amorphous silica. 前記もみ殻炭は、人体にとって発がん性を有する結晶性シリカやベンツピレンを含まないことを特徴とする請求項１記載のもみ殻炭。 The rice husk charcoal according to claim 1, wherein the rice husk charcoal does not contain crystalline silica or benzpyrene having carcinogenicity for a human body. 前記もみ殻炭が含む非晶質シリカは、水溶性であることを特徴とする請求項１または２記載のもみ殻炭。 The rice husk charcoal according to claim 1 or 2, wherein the amorphous silica contained in the rice husk charcoal is water-soluble. 稲わらが、無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって
５００℃〜７００℃の温度範囲によって炭化され、
非晶質シリカを豊富に含む含むことを特徴とする稲わら炭。 Rice straw is carbonized in a temperature range of 500 ° C. to 700 ° C. by a carbonization device that is carbonized with stirring in an oxygen-free atmosphere,
Rice straw charcoal characterized by containing abundant amorphous silica. 前記稲わら炭は、人体にとって発がん性を有する結晶性シリカやベンツピレンを含まないことを特徴とする請求項４記載の稲わら炭。 The rice straw charcoal according to claim 4, wherein the rice straw charcoal does not contain crystalline silica or benzpyrene which is carcinogenic to a human body. 前記稲わら炭が含む非晶質シリカは、水溶性であることを特徴とする請求項４または５記載の稲わら炭。 6. The rice straw charcoal according to claim 4, wherein the amorphous silica contained in the rice straw charcoal is water-soluble. 無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって、温度範囲が５００℃〜７００℃にて、もみ殻を炭化してもみ殻炭を作成することを特徴とするもみ殻炭の製造方法。 Production of rice husk charcoal, characterized in that husk charcoal is produced by carbonizing rice husk in a temperature range of 500 ° C. to 700 ° C. with a carbonizer that is carbonized while stirring in an oxygen-free atmosphere. Method. 無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって、温度範囲が５００℃〜７００℃にて、稲わらを炭化して稲わら炭を作成することを特徴とする稲わら炭の製造方法。 Production of rice straw charcoal by carbonizing rice straw and producing rice straw charcoal at a temperature range of 500 ° C. to 700 ° C. by a carbonization apparatus that is carbonized while stirring in an oxygen-free atmosphere. Method. 無酸素雰囲気中にて、撹拌しながら炭化される炭化装置によって、温度範囲が５００℃〜７００℃にて、もみ殻を炭化してもみ殻炭を作製するか、あるいは温度範囲が５００℃〜７００℃にて、稲わらを炭化して稲わら炭を作製し、前記もみ殻炭あるいは稲わら炭を、イオン交換水に投入して、前記イオン交換水の温度範囲３０℃〜１００℃にて撹拌して、
前記もみ殻炭あるいは稲わら炭に含まれる非晶質シリカをイオン交換水に溶かして抽出することを特徴とする非晶質シリカの製造方法。 Even if the rice husk is carbonized at a temperature range of 500 ° C. to 700 ° C. by a carbonization apparatus that is carbonized with stirring in an oxygen-free atmosphere, the husk charcoal is produced or the temperature range is 500 ° C. Rice straw is carbonized to produce rice straw charcoal at ℃, and the rice husk charcoal or rice straw charcoal is added to ion-exchanged water and stirred at a temperature range of 30 to 100 ° C. do it,
A method for producing amorphous silica, comprising extracting amorphous silica contained in the rice husk charcoal or rice straw charcoal in ion-exchanged water. 請求項７記載のもみ殻炭の製造方法によって製造されたもみ殻炭、あるいは請求項８記載の稲わら炭の製造方法によって製造された稲わら炭、あるいは請求項９記載の非晶質シリカの製造方法によって製造された非晶質シリカを含有することを特徴とする食品。 The rice husk charcoal produced by the method for producing rice husk charcoal according to claim 7, the rice straw charcoal produced by the method for producing rice straw charcoal according to claim 8, or the amorphous silica according to claim 9. A food comprising amorphous silica produced by the production method. 請求項７記載のもみ殻炭の製造方法によって製造されたもみ殻炭、あるいは請求項８記載の稲わら炭の製造方法によって製造された稲わら炭、あるいは請求項９記載の非晶質シリカの製造方法によって製造された非晶質シリカを含有することを特徴とする農業用肥料。 The rice husk charcoal produced by the method for producing rice husk charcoal according to claim 7, the rice straw charcoal produced by the method for producing rice straw charcoal according to claim 8, or the amorphous silica according to claim 9. An agricultural fertilizer comprising amorphous silica produced by a production method. 請求項７記載のもみ殻炭の製造方法によって製造されたもみ殻炭、あるいは請求項８記載の稲わら炭の製造方法によって製造された稲わら炭、あるいは請求項９記載の非晶質シリカの製造方法によって製造された非晶質シリカを含有することを特徴とする飼料。 The rice husk charcoal produced by the method for producing rice husk charcoal according to claim 7, the rice straw charcoal produced by the method for producing rice straw charcoal according to claim 8, or the amorphous silica according to claim 9. A feed comprising amorphous silica produced by the production method.
JP2013055725A 2013-03-18 2013-03-18 Rice husk charcoal or rice straw charcoal rich in amorphous silica, method for producing rice husk charcoal or rice straw charcoal rich in amorphous silica, food rich in amorphous silica, fertilizer for agriculture and feed. Active JP6159110B2 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017091822A (en) * 2015-11-10 2017-05-25 三重県 Negative electrode active material for nonaqueous electrolyte secondary battery using chaff or rice straw carbide
CN111517334A (en) * 2020-05-25 2020-08-11 合肥学院 Device for preparing rice hull-based silicon dioxide
CN115703636A (en) * 2021-08-17 2023-02-17 山东乾西新材料科技有限公司 Preparation technology of porous nano silicon carbide and carbon composite material thereof
WO2023154547A1 (en) 2022-02-14 2023-08-17 Axial Therapeutics, Inc. Colon targeted drug delivery
JP7462868B2 (en) 2018-10-26 2024-04-08 炭プラスラボ株式会社 Composition containing lactic acid bacteria production substance, method for producing equol, and method for producing composition containing lactic acid bacteria production substance

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4952472A (en) * 1972-07-28 1974-05-21
JPH09268292A (en) * 1996-04-01 1997-10-14 Hiroaki Anada Chaff acetic acid liquid, its production and apparatus for producing chaff charcoal
JP2001213614A (en) * 2000-01-26 2001-08-07 Natl Res Inst Of Agricultural Engineering Functional carbonized material and production process thereof
JP2002526356A (en) * 1998-09-23 2002-08-20 アグリテック，インク． Highly activated carbon by caustic digestion of rice husk ash and its method
WO2006051829A1 (en) * 2004-11-12 2006-05-18 Saiseiko Co., Ltd. Pig farming method
JP2007522069A (en) * 2004-02-13 2007-08-09 ナン，ゲリー，ロバート Soluble biogenic silica and uses thereof
JP2012171938A (en) * 2011-02-23 2012-09-10 Gaia Kankyo Gijutsu Kenkyusho:Kk Paulownia charcoal supplement
JP2012206011A (en) * 2011-03-29 2012-10-25 Gaia Kankyo Gijutsu Kenkyusho:Kk Water purifying material and method for production thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4952472A (en) * 1972-07-28 1974-05-21
JPH09268292A (en) * 1996-04-01 1997-10-14 Hiroaki Anada Chaff acetic acid liquid, its production and apparatus for producing chaff charcoal
JP2002526356A (en) * 1998-09-23 2002-08-20 アグリテック，インク． Highly activated carbon by caustic digestion of rice husk ash and its method
JP2001213614A (en) * 2000-01-26 2001-08-07 Natl Res Inst Of Agricultural Engineering Functional carbonized material and production process thereof
JP2007522069A (en) * 2004-02-13 2007-08-09 ナン，ゲリー，ロバート Soluble biogenic silica and uses thereof
WO2006051829A1 (en) * 2004-11-12 2006-05-18 Saiseiko Co., Ltd. Pig farming method
JP2012171938A (en) * 2011-02-23 2012-09-10 Gaia Kankyo Gijutsu Kenkyusho:Kk Paulownia charcoal supplement
JP2012206011A (en) * 2011-03-29 2012-10-25 Gaia Kankyo Gijutsu Kenkyusho:Kk Water purifying material and method for production thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017091822A (en) * 2015-11-10 2017-05-25 三重県 Negative electrode active material for nonaqueous electrolyte secondary battery using chaff or rice straw carbide
JP7133121B2 (en) 2015-11-10 2022-09-08 三重県 Negative electrode active material for non-aqueous electrolyte secondary battery using rice husk or rice straw carbide
JP7462868B2 (en) 2018-10-26 2024-04-08 炭プラスラボ株式会社 Composition containing lactic acid bacteria production substance, method for producing equol, and method for producing composition containing lactic acid bacteria production substance
CN111517334A (en) * 2020-05-25 2020-08-11 合肥学院 Device for preparing rice hull-based silicon dioxide
CN111517334B (en) * 2020-05-25 2022-11-08 合肥学院 Device for preparing rice hull-based silicon dioxide
CN115703636A (en) * 2021-08-17 2023-02-17 山东乾西新材料科技有限公司 Preparation technology of porous nano silicon carbide and carbon composite material thereof
WO2023154547A1 (en) 2022-02-14 2023-08-17 Axial Therapeutics, Inc. Colon targeted drug delivery

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