JP2013511623A - 電解鉛−ビスマス合金からアノードスライムを洗浄する方法 - Google Patents
電解鉛−ビスマス合金からアノードスライムを洗浄する方法 Download PDFInfo
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- JP2013511623A JP2013511623A JP2012540256A JP2012540256A JP2013511623A JP 2013511623 A JP2013511623 A JP 2013511623A JP 2012540256 A JP2012540256 A JP 2012540256A JP 2012540256 A JP2012540256 A JP 2012540256A JP 2013511623 A JP2013511623 A JP 2013511623A
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- anode slime
- immersion
- lead
- bismuth alloy
- anode
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/04—Obtaining lead by wet processes
- C22B13/045—Recovery from waste materials
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B30/00—Obtaining antimony, arsenic or bismuth
- C22B30/06—Obtaining bismuth
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/18—Electrolytic production, recovery or refining of metals by electrolysis of solutions of lead
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/22—Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
- B08B3/14—Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B7/00—Cleaning by methods not provided for in a single other subclass or a single group in this subclass
- B08B7/04—Cleaning by methods not provided for in a single other subclass or a single group in this subclass by a combination of operations
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G21/00—Compounds of lead
- C01G21/006—Compounds containing, besides lead, two or more other elements, with the exception of oxygen or hydrogen
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/007—Wet processes by acid leaching
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/34—Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (10)
- (1)アノードスライムの前処理と、
(2)アノードスライムの第1浸漬処理と、
(3)アノードスライムの第2浸漬処理と
より成ることを特徴とする高濃度の鉛弗化珪酸溶液を得るため原料として電解鉛−ビスマス合金内のアノードスライムを用いる電解鉛−ビスマス合金内のアノードスライムの洗浄方法。 - アノードスライムを粉末状とするため上記アノードスライムの前処理において、アノードスライムを空気にさらす前に残存アノード板からアノードスライムを分離せしめることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
- 上記アノードスライムの第1浸漬処理のための浸漬剤が浄水または上記第2浸漬処理液の上澄液であることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
- 上記アノードスライムの第2浸漬処理のための浸漬剤が弗化珪酸の稀釈溶液、pH3〜5の弗化珪酸の稀釈溶液またはpH4の弗化珪酸の稀釈溶液であることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
- 上記第1及び第2浸漬処理の浸漬温度が30〜50℃であることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
- 上記第1及び第2浸漬処理の浸漬温度が45℃であることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
- 上記第1及び第2浸漬処理の浸漬剤の量が湿ったアノードスライム 1トン当り0.2〜0.4m3 であることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
- 上記第1浸漬処理液を電解鉛−ビスマス合金の循環電解液に直接加えることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
- 第2浸漬処理液を電解鉛−ビスマス合金の循環電解液に直接加え得るか、または、第1浸漬処理のための浸漬剤として用い得ることを特徴とする請求項1記載の電解鉛−ビスマス合金のアノードスライムの洗浄方法。
- 上記第1及び第2浸漬処理が同一の浸漬プール内でなされることを特徴とする請求項1記載の電解鉛−ビスマス合金内のアノードスライムの洗浄方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200910238049.X | 2009-11-24 | ||
CN200910238049XA CN101713028B (zh) | 2009-11-24 | 2009-11-24 | 一种洗涤电解铅铋合金阳极泥的方法 |
PCT/CN2009/076294 WO2011063577A1 (zh) | 2009-11-24 | 2009-12-30 | 一种洗涤电解铅铋合金阳极泥的方法 |
Publications (2)
Publication Number | Publication Date |
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JP2013511623A true JP2013511623A (ja) | 2013-04-04 |
JP5567680B2 JP5567680B2 (ja) | 2014-08-06 |
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Application Number | Title | Priority Date | Filing Date |
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JP2012540256A Expired - Fee Related JP5567680B2 (ja) | 2009-11-24 | 2009-12-30 | 電解鉛−ビスマス合金からアノードスライムを洗浄する方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US9051624B2 (ja) |
EP (1) | EP2505678A1 (ja) |
JP (1) | JP5567680B2 (ja) |
KR (1) | KR101407347B1 (ja) |
CN (1) | CN101713028B (ja) |
AU (1) | AU2009355804B2 (ja) |
WO (1) | WO2011063577A1 (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101713028B (zh) | 2009-11-24 | 2012-06-20 | 江西稀有金属钨业控股集团有限公司 | 一种洗涤电解铅铋合金阳极泥的方法 |
CN101906643B (zh) * | 2010-09-08 | 2012-02-01 | 江西稀有金属钨业控股集团有限公司 | 高铅铋银合金电解法脱铅工艺 |
CN102703719B (zh) * | 2012-07-03 | 2014-03-05 | 阳谷祥光铜业有限公司 | 一种从贵金属熔炼渣中回收有价金属的工艺 |
CN103938223B (zh) * | 2014-03-26 | 2016-08-17 | 湖南水口山有色金属集团有限公司 | 一种高铋粗铅的提纯方法 |
CN103938228B (zh) * | 2014-03-26 | 2016-08-10 | 湖南水口山有色金属集团有限公司 | 铅电解液及阳极泥洗水杂质金属离子的净化方法 |
CN104162536A (zh) * | 2014-08-01 | 2014-11-26 | 西安建筑科技大学 | 一种废旧阴极无害化处理与资源利用方法 |
CN105132706A (zh) * | 2015-08-31 | 2015-12-09 | 白银有色集团股份有限公司 | 一种电解银粉除杂方法 |
JP6927035B2 (ja) * | 2016-02-15 | 2021-08-25 | 東レ株式会社 | イオン伝導膜の製造方法および製造装置 |
CN106916954B (zh) * | 2017-01-20 | 2019-03-29 | 株洲冶炼集团股份有限公司 | 一种洗涤铅阳极泥并回收铅阳极泥中铅的方法 |
CN112981111B (zh) * | 2021-02-09 | 2022-11-29 | 深圳市中金岭南有色金属股份有限公司韶关冶炼厂 | 一种铅阳极泥中选择性回收铜的方法和铅阳极泥回收金属的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57149437A (en) * | 1981-03-04 | 1982-09-16 | Inst Obu Niyuukuria Enaajii Re | Treatment of copper refinement anode slime |
US4352786A (en) * | 1981-02-24 | 1982-10-05 | Institute Of Nuclear Energy Research | Treatment of copper refinery anode slime |
JPH05311259A (ja) * | 1992-04-13 | 1993-11-22 | Nikko Kinzoku Kk | 鉛電解アノードスライムの湿式処理方法 |
JP2003089827A (ja) * | 2001-09-14 | 2003-03-28 | Nippon Mining & Metals Co Ltd | 銀の製錬方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4026776A (en) * | 1970-12-02 | 1977-05-31 | Mitsui Mining & Smelting Co., Ltd. | Method for producing high purity lead |
US4500398A (en) * | 1984-06-20 | 1985-02-19 | The United States Of America As Represented By The Secretary Of The Interior | Production of lead from sulfides |
CA2017032C (en) * | 1990-05-17 | 1995-10-10 | Khay Gie J. Tan | Hydrometallurgical silver refining |
JPH05247552A (ja) * | 1992-03-06 | 1993-09-24 | Nikko Kyodo Co Ltd | 鉛電解アノードスライムの湿式処理による脱銅方法 |
CN100545318C (zh) * | 2005-11-01 | 2009-09-30 | 株洲冶炼集团有限责任公司 | 一种高铋粗铅的电解方法 |
CN101713028B (zh) * | 2009-11-24 | 2012-06-20 | 江西稀有金属钨业控股集团有限公司 | 一种洗涤电解铅铋合金阳极泥的方法 |
CN102703719B (zh) * | 2012-07-03 | 2014-03-05 | 阳谷祥光铜业有限公司 | 一种从贵金属熔炼渣中回收有价金属的工艺 |
-
2009
- 2009-11-24 CN CN200910238049XA patent/CN101713028B/zh not_active Expired - Fee Related
- 2009-12-30 US US13/511,782 patent/US9051624B2/en not_active Expired - Fee Related
- 2009-12-30 WO PCT/CN2009/076294 patent/WO2011063577A1/zh active Application Filing
- 2009-12-30 JP JP2012540256A patent/JP5567680B2/ja not_active Expired - Fee Related
- 2009-12-30 AU AU2009355804A patent/AU2009355804B2/en not_active Ceased
- 2009-12-30 EP EP20090851590 patent/EP2505678A1/en not_active Withdrawn
- 2009-12-30 KR KR1020127015305A patent/KR101407347B1/ko not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4352786A (en) * | 1981-02-24 | 1982-10-05 | Institute Of Nuclear Energy Research | Treatment of copper refinery anode slime |
JPS57149437A (en) * | 1981-03-04 | 1982-09-16 | Inst Obu Niyuukuria Enaajii Re | Treatment of copper refinement anode slime |
JPH05311259A (ja) * | 1992-04-13 | 1993-11-22 | Nikko Kinzoku Kk | 鉛電解アノードスライムの湿式処理方法 |
JP2003089827A (ja) * | 2001-09-14 | 2003-03-28 | Nippon Mining & Metals Co Ltd | 銀の製錬方法 |
Also Published As
Publication number | Publication date |
---|---|
EP2505678A1 (en) | 2012-10-03 |
AU2009355804A1 (en) | 2012-06-21 |
US9051624B2 (en) | 2015-06-09 |
JP5567680B2 (ja) | 2014-08-06 |
KR20120083526A (ko) | 2012-07-25 |
CN101713028B (zh) | 2012-06-20 |
CN101713028A (zh) | 2010-05-26 |
WO2011063577A1 (zh) | 2011-06-03 |
AU2009355804B2 (en) | 2013-03-28 |
KR101407347B1 (ko) | 2014-06-13 |
US20120247509A1 (en) | 2012-10-04 |
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