JP2009509724A - ジメチルスルホキシド(dmso)若しくは関連化合物、又はそれに関連する臭気を除去するシステム - Google Patents
ジメチルスルホキシド(dmso)若しくは関連化合物、又はそれに関連する臭気を除去するシステム Download PDFInfo
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Abstract
【選択図】図5
Description
本願は、米国仮出願第60/716,271号、同第60/716,336号、同第60/716,278号、及び同第60/716,369号(これらは全て2005年9月12日に出願されており、参照により本明細書中に援用される)に対する優先権を主張する。
現在のところ、これらの有害な臭気を除去するのに実施される公知の有効な方法が存在しないと本出願人は確信している。他の用途のための活性炭を含有するこれまでの臭気を回収する使い捨て用品は、特異的な身体部位及び流体に対するものであったが、DMSOの代謝産物を除去するようなものではない。また、小型で、容易に位置付けられる空気洗浄機器の必要性は十分に検討されてこなかった。現在、DMSOの静脈内投与は、有害な臭気に関連する副作用によって制限されている。DMSOが、重病患者又は重傷患者の処置に選択される極めて日常的な薬剤となれば、これらの処置方法の成功は、医療スタッフ及び訪問者を保護する非常に効果的な空気清浄機器の有用性にかなり左右される可能性がある。また、現在のところ、これらの臭気化合物の検出のための本出願人にとって既知の唯一の方法は、頼りにならないヒトの嗅覚である。
吸着体
1つの実施形態において、本発明は、DMSO及び他の化合物の代謝産物、並びに/又は関連の臭気を部分的又は完全に除去するようになっている吸着体を含む。
吸着体の内層
1つの実施形態において、DMSO及び関連化合物、並びに/又はこれらに関連する臭気を吸着する材料は、内層を含む。図1は、本発明の1つの実施形態に記載の吸着体材料を示す。1つの実施形態において、内層1はコア粒子を含む。コア粒子は、吸着体材料全体を表わしてもよく又は表わさなくてもよく、また活性炭、無機酸化物、イオン交換能を有する化合物、それらの変性化合物、イオン交換樹脂、化学脱臭剤、シリカゲル、アルミナゲル、ゼオライト、モレキュラーシーブ、珪藻土、無機酸化物(例えば、酸化銅、酸化鉄)、キトサン、デキストラン硫酸、ポリアリルアミン、スルホン化ポリスチレン樹脂、ポリアクリル酸、ポリメタクリル酸又はそれらの誘導体の1つ又は複数を含んでいてもよい。これらの化合物の2つ以上の組合せが、実施形態によっては用いられる。
吸着体の中間層
1つの実施形態において、DMSO及び関連化合物、並びに/又はこれらに関連する臭気を吸着する材料は、中間層を含む。図1の参照番号2は、本発明の1つの実施形態に記載の中間層を示す。吸着体の中間層は、金属の酸化物、水酸化物、炭酸塩、硫酸塩、リン酸塩、メタケイ酸塩、ホウ酸塩、シュウ酸塩、タングステン酸塩、モリブデン酸塩、バナジン酸塩、クロム酸塩、セレン酸塩、及びマンガン酸塩、又は金属自体を含み得る。また、金属としては、チタン、ジルコニウム、シリコン、亜鉛、鉄、マンガン、アルミニウム、マグネシウム、ニッケル、銅、銀、バリウム、カルシウム、スカンジウム、ビスマス、モリブデン、ニオビウム、ネオジム、アンチモン、セレン、スズ、ストロンチウム、テルビウム、テルル、トリウム及びイットリウムが挙げられ得る。
吸着体の外層
1つの実施形態において、DMSO及び関連化合物、並びに/又はこれらに関連する臭気を吸着する材料は、外層を含む。図1の参照番号3は、本発明の1つの実施形態に記載の外層(例えば、多孔質材料)を示す。外層は、多孔質コーティング層を含み得る。外層は、フッ素樹脂、ポリアミド樹脂、ポリイミド樹脂、ポリエステル樹脂、ポリスチレン樹脂、ポリオレフィン樹脂、ポリカーボネート樹脂、ポリスルホン樹脂、アクリル樹脂、セルロース樹脂、塩化ビニル樹脂、ポリアセタール樹脂、ポリウレタン樹脂及びそれらのコポリマー、並びにそれらの誘導体、又はポリテトラフルオロエチレン、ポリヘキサフルオロプロピレン、ポリジフルオロエチレン、ポリビニリデンフルオライド、ポリビニルフルオライド、及びそれらのコポリマー又は誘導体の1つ又は複数を含み得る。これらの材料の2つ以上の組合せが、実施形態によっては用いられる。
空気清浄部材
本発明の1つの実施形態において、空気を清浄する機器及び方法は、空気を室内環境空気清浄部材(例えば、カートリッジ又はフィルタ)と接触させることを含む。1つの実施形態において、空気清浄部材は、前記の吸着体材料を含む。1つの実施形態において、空気清浄部材は、DMSO及び/若しくはDMSO関連化合物、並びに/又はこれらに関連する臭気を吸着する。実施形態によっては、空気清浄部材はまた、空気から、DMSOに無関係の1つ又は複数の望ましくない化合物(例えば、有毒煙霧又は有毒ガス)を除去する。
織物
本発明のいくつかの実施形態では、DMSO及び関連化合物の臭気を低減又は排除する織物が提供される。1つの実施形態において、織物としては、DMSOの代謝産物等を部分的又は完全に捕捉することができる、衣料、寝具、及び他の保護すべき物品の製造に適する臭気吸着織布又は不織布が含まれる。吸着としては、化学的な酸化若しくは還元、亀裂内の物理的な取込み、又は他の手段が挙げられ得る。吸着体織物は、吸着体繊維、又は吸着体でコーティングされた繊維を含んでいてもよく、又は層間に吸着体材料を有して層状にされてもよい。最終的に、織物は、これらの様式の臭気捕捉の任意のもの又は全てを同時に取り入れることができる。
1つの実施形態において、本発明は、DMSO及び関連化合物に関連する臭気を低減させるか、排除するか、又は臭気から使用者を防護するように設計されるマスクを含む。織物に関係する上記の実施形態は、マスクのいくつかの実施形態を構成するのに用いることができる。
清浄空気供給アセンブリ
1つの実施形態において、本発明は、DMSO及び関連化合物による患者の処置により生じる臭気及び化学物質を除去するためのシステムを含む。1つの実施形態において、当該システムは、清浄空気供給アセンブリである。
インジケータ
本発明はまた、視覚的な有色インジケータ、特に、DMS及びDMSOの他の代謝産物の検出に好適な金属過マンガン酸塩の視覚的な有色インジケータ材料を提供する。1つの実施形態において、DMS等の硫化物は、過マンガン酸カリウムによって酸化されスルホンを生成し、結果として生じる過マンガン酸イオンの還元によって特徴的な濃い紫色が消失する。インジケータは、1つ、2つ又は3つの部分を有する基層上の、本明細書に記載の吸着体(adsorbant)の相のいずれか1つに、又は付加的な層に含まれ得る。1つの実施形態において、DMS及びDMSOの代謝産物、並びに他の関連化合物用のインジケータは、本明細書に記載の吸着材を含有するコア粒子を含み、ここで、中間層が、1つ又は複数のインジケータと金属又は他の化合物とを含み、且つコア粒子と多孔質コーティング層との間に設けられる。コア粒子の構造及び構成成分は、前記で詳細に記載してある。色以外の視覚インジケータを使用してもよい。1つ又は複数のインジケータが、層内、層の内表面上に、層の外表面上に、又は層の1つ全体に含まれていてもよい。
Claims (22)
- ジメチルスルホキシド(DMSO)若しくは関連化合物、又は該化合物に関連する臭気を吸着する吸着体であって、
内層と、中間層と、外層とを含み、
前記内層が吸着コア粒子を含み、
前記吸着コア粒子が、ジメチルスルホキシド(DMSO)若しくは関連化合物、又は該化合物に関連する臭気を吸着し、
前記中間層が、前記内層及び前記外層と接触し、
前記外層が多孔質コーティングを含む、吸着体。 - ジメチルスルホキシド(DMSO)又は関連化合物の存在を指示するインジケータをさらに含む、請求項1に記載の吸着体。
- 前記インジケータが過マンガン酸塩を含む、請求項2に記載の吸着体。
- 前記インジケータが有色であり、ジメチルスルホキシド(DMSO)又は関連化合物が除去されるにつれて、色すなわち強度を低減させるようになっている、請求項2に記載の吸着体。
- 前記吸着コア粒子が、活性炭、無機酸化物、イオン交換能を有する化合物、イオン交換樹脂、及び化学脱臭剤の1つ又は複数から成る群から選択される、請求項1〜4のいずれか1項に記載の吸着体。
- 前記中間層が、前記コア粒子と前記多孔質コーティングとの間に設けられる、金属化合物と水溶性有機材料とを含む、請求項1〜5のいずれか1項に記載の吸着体。
- 前記外層が、多孔質コーティングのみから成る、請求項1〜6のいずれか1項に記載の吸着体。
- 前記外層が、フッ素樹脂、ポリアミド樹脂、ポリイミド樹脂、ポリエステル樹脂、ポリスチレン樹脂、ポリオレフィン樹脂、ポリカーボネート樹脂、ポリスルホン樹脂、アクリル樹脂、セルロース樹脂、塩化ビニル樹脂、ポリアセタール樹脂、ポリウレタン樹脂及びそれらのコポリマー又は誘導体の1つ又は複数から成る群から選択されるポリマーを含む、請求項1〜7のいずれか1項に記載の吸着体。
- 前記外層が、ポリテトラフルオロエチレン、ポリヘキサフルオロプロピレン、ポリジフルオロエチレン、ポリビニリデンフルオライド、ポリビニルフルオライド、及びそれらのコポリマー又は誘導体の1つ又は複数から成る群から選択されるポリマーを含む、請求項1〜8のいずれか1項に記載の吸着体。
- 前記多孔質コーティングが、約0.01μm〜約1000μmの厚みを有する、請求項1〜9のいずれか1項に記載の吸着体。
- 前記多孔質コーティングが、約0.01μm〜約500μmの平均孔径を有する、請求項1〜10のいずれか1項に記載の吸着体。
- 前記多孔質コーティングが、約3%〜約90%の多孔度を有する、請求項1〜11のいずれか1項に記載の吸着体。
- ジメチルスルホキシド(DMSO)代謝産物を除去する方法であって、該代謝産物と、請求項1〜12のいずれか1項に記載の吸着体とを接触させることを含む、方法。
- 前記ジメチルスルホキシド(DMSO)代謝産物が、ジメチルスルホキシド(DMSO)処置を受けた個体によって生成される、請求項13に記載の方法。
- ジメチルスルホキシド(DMSO)又は関連化合物に関連する臭気を除去する方法であって、前記臭気を請求項1〜12のいずれか1項に記載の吸着体に曝すことを含む、方法。
- ジメチルスルホキシド(DMSO)若しくは関連化合物、又は該ジメチルスルホキシド(DMSO)若しくは該関連化合物に関連する臭気を除去する空気清浄部材であって、請求項1〜12のいずれか1項に記載の吸着体を含む、空気清浄部材。
- ジメチルスルホキシド(DMSO)若しくは関連化合物、又は該ジメチルスルホキシド(DMSO)若しくは該関連化合物に関連する臭気を除去する清浄空気供給アセンブリであって、請求項1〜12のいずれか1項に記載の吸着体を含む、清浄空気供給アセンブリ。
- 医療用人工呼吸器の排気口から、ジメチルスルホキシド(DMSO)若しくは関連化合物、又は該ジメチルスルホキシド(DMSO)若しくは該関連化合物に関連する臭気を除去する装置であって、該装置が、請求項1〜12のいずれか1項に記載の吸着体を含む掃気機器を含み、該掃気機器が前記排気口に接続される、装置。
- ジメチルスルホキシド(DMSO)若しくは関連化合物、又は該ジメチルスルホキシド(DMSO)若しくは該関連化合物に関連する臭気の曝露を低減させるフェースマスクであって、請求項1〜12のいずれか1項に記載の吸着体を含む、フェースマスク。
- ジメチルスルホキシド(DMSO)若しくは関連化合物、又は該ジメチルスルホキシド(DMSO)若しくは該関連化合物に関連する臭気の曝露を低減させるフェースマスクであって、
合成繊維を含む外側シールド層と、
繊維と銅粉末とを含む銅層と、
繊維と活性炭とを含む炭素層と、
繊維と1つ又は複数の臭気吸収化学物質とを含む化学物質層と、
合成繊維を含む表層と
を含む、フェースマスク。 - 前記フェースマスクが発散バルブを含む、請求項19又は20に記載のフェースマスク。
- 前記フェースマスクがカモノハシマスクである、請求項19〜21のいずれか1項に記載のフェースマスク。
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Also Published As
Publication number | Publication date |
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JP5399072B2 (ja) | 2014-01-29 |
EP1966229A2 (en) | 2008-09-10 |
US20130052112A1 (en) | 2013-02-28 |
EP1966229A4 (en) | 2010-01-13 |
AU2006291134B2 (en) | 2013-02-21 |
EP1966229B1 (en) | 2015-10-21 |
CA2622204A1 (en) | 2007-03-22 |
AU2006291134A1 (en) | 2007-03-22 |
US7955418B2 (en) | 2011-06-07 |
US20140116444A1 (en) | 2014-05-01 |
WO2007033083A3 (en) | 2007-09-27 |
US8440001B2 (en) | 2013-05-14 |
US20110203584A1 (en) | 2011-08-25 |
US9186472B2 (en) | 2015-11-17 |
US8298320B2 (en) | 2012-10-30 |
AU2006291134C1 (en) | 2013-08-15 |
CA2622204C (en) | 2016-10-11 |
WO2007033083A2 (en) | 2007-03-22 |
US20080251081A1 (en) | 2008-10-16 |
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