ITMI20030969A1 - Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida. - Google Patents

Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.

Info

Publication number: ITMI20030969A1
Authority: IT; Italy
Prior art keywords: synthesis gas; hydrocarbons; separation; procedure; solid phase
Prior art date: 2003-05-15

Application number

IT000969A

Other languages

English (en)

Inventor

Giuseppe Belmonte

Gabriele Carlo Ettore Clerici

Original Assignee

Enitecnologie Spa

Inst Francais Du Petrole

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-05-15

Filing date

2003-05-15

Publication date

2004-11-16

2003-05-15 Application filed by Enitecnologie Spa, Inst Francais Du Petrole filed Critical Enitecnologie Spa

2003-05-15 Priority to IT000969A priority Critical patent/ITMI20030969A1/it

2004-05-05 Priority to US10/838,250 priority patent/US7098251B2/en

2004-05-13 Priority to GB0410719A priority patent/GB2403728B/en

2004-05-13 Priority to NO20041979A priority patent/NO337606B1/no

2004-05-14 Priority to EA200400542A priority patent/EA006275B1/ru

2004-05-15 Priority to EG2004050220A priority patent/EG25431A/xx

2004-06-20 Priority to SA04250178A priority patent/SA04250178B1/ar

2004-11-16 Publication of ITMI20030969A1 publication Critical patent/ITMI20030969A1/it

Links

230000015572 biosynthetic process Effects 0.000 title abstract 3
238000003786 synthesis reaction Methods 0.000 title abstract 3
229930195733 hydrocarbon Natural products 0.000 title abstract 2
150000002430 hydrocarbons Chemical class 0.000 title abstract 2
239000007791 liquid phase Substances 0.000 title abstract 2
238000000926 separation method Methods 0.000 title abstract 2
239000007790 solid phase Substances 0.000 title abstract 2
239000000725 suspension Substances 0.000 title abstract 2
238000010924 continuous production Methods 0.000 title 1
238000000034 method Methods 0.000 title 1
238000001914 filtration Methods 0.000 abstract 3
239000003054 catalyst Substances 0.000 abstract 2
239000011148 porous material Substances 0.000 abstract 2
238000006243 chemical reaction Methods 0.000 abstract 1
239000007795 chemical reaction product Substances 0.000 abstract 1
239000007788 liquid Substances 0.000 abstract 1
239000002245 particle Substances 0.000 abstract 1
239000012071 phase Substances 0.000 abstract 1
230000000630 rising effect Effects 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/147—Microfiltration
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/16—Feed pretreatment
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/18—Apparatus therefor
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/006—Separating solid material from the gas/liquid stream by filtration
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00292—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
- B01J2208/003—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids involving reactant slurries
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/301—Boiling range
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Water Supply & Treatment (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Combustion & Propulsion (AREA)
General Chemical & Material Sciences (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

IT000969A 2003-05-15 2003-05-15 Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida. ITMI20030969A1 (it)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
IT000969A ITMI20030969A1 (it)	2003-05-15	2003-05-15	Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.
US10/838,250 US7098251B2 (en)	2003-05-15	2004-05-05	Process for the production in continuous of hydrocarbons from synthesis gas, in slurry reactors and for the separation from the solid phase of the liquid phase produced
GB0410719A GB2403728B (en)	2003-05-15	2004-05-13	Process for the production in continuous of hydrocarbons from synthesis gas in slurry reactors and for the separation from the solid phase of the liquid
NO20041979A NO337606B1 (no)	2003-05-15	2004-05-13	Fremgangsmåte for kontinuerlig produksjon av hydrokarboner fra syntesegass i slurryreaktorer, og filtreringsinnsatser
EA200400542A EA006275B1 (ru)	2003-05-15	2004-05-14	Способ непрерывного получения углеводородов из синтез-газа в шламовых реакторах и отделения получаемой жидкой фазы от твёрдой фазы
EG2004050220A EG25431A (en)	2003-05-15	2004-05-15	Process for the production in the continuous of hydrocarbons from synthesis gas, in slurry reactors and for the separation from the solid phase of theliquid phase produced
SA04250178A SA04250178B1 (ar)	2003-05-15	2004-06-20	عملية لإنتاج مواد هيدروكربونية hydrocarbon من غاز تخليق synthesis gas بشكل مستمر

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT000969A ITMI20030969A1 (it)	2003-05-15	2003-05-15	Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.

Publications (1)

Publication Number	Publication Date
ITMI20030969A1 true ITMI20030969A1 (it)	2004-11-16

Family

ID=32587889

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IT000969A ITMI20030969A1 (it)	2003-05-15	2003-05-15	Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.

Country Status (7)

Country	Link
US (1)	US7098251B2 (it)
EA (1)	EA006275B1 (it)
EG (1)	EG25431A (it)
GB (1)	GB2403728B (it)
IT (1)	ITMI20030969A1 (it)
NO (1)	NO337606B1 (it)
SA (1)	SA04250178B1 (it)

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ITMI20031288A1 (it) *	2003-06-25	2004-12-26	Enitecnologie Spa	Processo per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.
FR2877950B1 (fr) *	2004-11-17	2006-12-29	Inst Francais Du Petrole	Dispositif de production d'hydrocarbures liquides par synthese fischer-tropsch dans un reacteur a lit triphasique
US7378452B2 (en) *	2005-12-28	2008-05-27	Exxonmobil Research And Engineering Company	Filtration system for slurry hydrocarbon synthesis process using both small and large pore filter elements
CN100443155C (zh)	2006-05-31	2008-12-17	中国石油化工股份有限公司	一种浆态床环流反应器及其应用
GB2444055B (en) *	2006-11-23	2011-11-23	Gtl F1 Ag	Gas to liquids plant with consecutive Fischer-Tropsch reactors and hydrogen make-up
PL2158294T3 (pl) *	2007-05-28	2019-07-31	The Petroleum Oil And Gas Corporation Of South Africa (Pty) Ltd.	Usuwanie drobnych cząstek ze strumienia Fishera-Tropscha
US8222305B2 (en) *	2007-08-24	2012-07-17	Sasol Technology (Proprietary) Limited	Process for producing liquid and gaseous products from gaseous reactants
KR100992835B1 (ko) *	2008-02-29	2010-11-08	한국화학연구원	피셔-트롭쉬 합성반응용 고체촉매와 생성물의 연속분리배출장치 및 방법
US8569387B2 (en) *	2008-09-30	2013-10-29	Japan Oil, Gas And Metals National, Corporation	Hydrocarbon compound synthesis reaction unit and operating method thereof
US8092628B2 (en) *	2008-10-31	2012-01-10	Brewer Science Inc.	Cyclic olefin compositions for temporary wafer bonding
GB2465554B (en)	2008-11-18	2013-03-13	Gtl F1 Ag	Slurry bubble column reactor
GB2466315B (en) *	2008-12-22	2013-01-09	Gtl F1 Ag	Apparatus and method for conducting a Fischer-Tropsch synthesis reaction
GB2471338B (en)	2009-06-26	2014-12-24	Gtl F1 Ag	Apparatus and process for three-phase reacton
US8252251B2 (en) *	2010-03-30	2012-08-28	General Electric Company	Fluid cooled reformer and method for cooling a reformer
US20120020847A1 (en) *	2010-07-20	2012-01-26	Lurgi, Inc.	Retention Of Solid Powder Catalyst By In-Situ Cross Flow Filtration In Continuous Stirred Reactors
KR101210397B1 (ko)	2010-09-17	2012-12-10	한국화학연구원	합성가스로부터 탄화수소를 제조하기 위한 반응장치
CN102451651B (zh) *	2010-10-28	2014-12-31	中国石油化工股份有限公司	一种浆态床环流反应器及其应用
CN103071481B (zh) *	2012-12-29	2014-05-21	万华化学集团股份有限公司	一种费托合成钴基催化剂及其制备方法
US9180436B1 (en)	2013-11-19	2015-11-10	Emerging Fuels Technology, Inc.	Optimized fischer-tropsch catalyst
US9358526B2 (en)	2013-11-19	2016-06-07	Emerging Fuels Technology, Inc.	Optimized fischer-tropsch catalyst

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2003
- 2003-05-15 IT IT000969A patent/ITMI20030969A1/it unknown
2004
- 2004-05-05 US US10/838,250 patent/US7098251B2/en active Active
- 2004-05-13 NO NO20041979A patent/NO337606B1/no not_active IP Right Cessation
- 2004-05-13 GB GB0410719A patent/GB2403728B/en not_active Expired - Fee Related
- 2004-05-14 EA EA200400542A patent/EA006275B1/ru not_active IP Right Cessation
- 2004-05-15 EG EG2004050220A patent/EG25431A/xx active
- 2004-06-20 SA SA04250178A patent/SA04250178B1/ar unknown

Also Published As

Publication number	Publication date
GB2403728A (en)	2005-01-12
GB0410719D0 (en)	2004-06-16
GB2403728B (en)	2005-07-27
US7098251B2 (en)	2006-08-29
EA006275B1 (ru)	2005-10-27
SA04250178B1 (ar)	2007-10-29
US20050000861A1 (en)	2005-01-06
NO337606B1 (no)	2016-05-09
EG25431A (en)	2012-01-03
EA200400542A1 (ru)	2004-12-30
NO20041979L (no)	2004-11-16

Publication	Publication Date	Title
ITMI20030969A1 (it)	2004-11-16	Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida.
MY129311A (en)	2007-03-30	Process for producing liquid and gaseous products from gaseous reactants
GB2429714A (en)	2007-03-07	The production of liquid and,optionally,gaseous hydrocarbons from gaseous reactants into an expanded slurry bed
CA2114275A1 (en)	1994-07-28	Process for producing liquid and, optionally, gaseous products from gaseous reactants
MY139281A (en)	2009-09-30	Process for producing liquid and, optionally, gaseous products from gaseous reactants
CA2267569A1 (en)	1999-10-23	Process for the preparation of hydrocarbons from synthesis gas
DK0627959T3 (da)	1997-05-26	Fremgangsmåde til at foretage en flerfasereaktion med en katalytisk konverter
CA2392343A1 (en)	2001-05-31	Process for converting synthesis gas into higher hydrocarbons
RU99115090A (ru)	2001-05-27	Способ получения углеводородов
WO2009027914A3 (en)	2009-07-09	Process for producing liquid and gaseous products from gaseous reactants
van de Graaf et al.	1999	Application of a zeolite membrane reactor in the metathesis of propene
CA2293659A1 (en)	1999-01-28	A process for producing liquid and, optionally, gaseous products from gaseous reactants
TW370525B (en)	1999-09-21	Multizone downcomer for slurry hydrocarbon synthesis process
EA200400728A1 (ru)	2004-12-30	Способ непрерывного получения углеводородов из синтез-газа в шламовых реакторах и отделения получаемой жидкой фазы от твердой фазы
EA200400567A1 (ru)	2004-12-30	Способ непрерывного получения углеводородов из синтез-газа
EA200400136A1 (ru)	2004-06-24	Способ получения жидких углеводородов
WO2002096836A3 (en)	2003-06-12	Fischer-tropsch process
EA200400349A1 (ru)	2004-08-26	Способ получения углеводородов
CA2286847A1 (en)	1998-11-12	Gas and solids reducing slurry downcomer
AR018034A1 (es)	2001-10-31	Procedimiento para producir particulas catalizadoras en base a hierro precipitadas autoportantes, para usar en un proceso de lecho fluidizado fischer-tropsch, particulas catalizadoras fischer-tropsch producidas por dicho procedimiento, y procedimiento para mantener la capacidad de un sistema de sepa
MY121180A (en)	2005-12-30	Process for the separation of a hydroxylammonium salt solution.
TH18206C3 (th)	2005-02-25	กรรมวิธีสำหรับการเตรียมไฮโดรคาร์บอนจากก๊าซสังเคราะห์
MY158533A (en)	2016-10-14	Catalyst separation system
AR028680A1 (es)	2003-05-21	Procedimiento fischer-tropsch
MXPA04001485A (es)	2004-05-14	Reaccion de solido / liquido.