HRP20010553A2 - Glass with high proportion of zirconium-oxide and its uses - Google Patents

Glass with high proportion of zirconium-oxide and its uses Download PDF

Info

Publication number: HRP20010553A2
Authority: HR; Croatia
Prior art keywords: glass; bao; mgo; sro; cao
Prior art date: 1999-02-15

Application number

HR20010553A

Other languages

English (en)

Croatian (hr)

Inventor

Karin Naumann

Norbert Greulich-Hickmann

Uwe Kolberg

Werner Kiefer

Original Assignee

Schott Glas

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-02-15

Filing date

2001-07-20

Publication date

2002-08-31

2001-07-20 Application filed by Schott Glas filed Critical Schott Glas

2002-08-31 Publication of HRP20010553A2 publication Critical patent/HRP20010553A2/hr

Links

239000011521 glass Substances 0.000 title claims abstract description 107
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 title claims description 5
229910001928 zirconium oxide Inorganic materials 0.000 title claims description 5
229940043774 zirconium oxide Drugs 0.000 title 1
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 47
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 22
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 21
239000002253 acid Substances 0.000 claims abstract description 21
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
239000000203 mixture Substances 0.000 claims abstract description 16
230000003301 hydrolyzing effect Effects 0.000 claims abstract description 14
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 12
229910052593 corundum Inorganic materials 0.000 claims abstract description 12
MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 12
KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 claims abstract description 12
229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 12
229910052681 coesite Inorganic materials 0.000 claims abstract description 8
229910052906 cristobalite Inorganic materials 0.000 claims abstract description 8
239000000377 silicon dioxide Substances 0.000 claims abstract description 8
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 8
229910052682 stishovite Inorganic materials 0.000 claims abstract description 8
229910052905 tridymite Inorganic materials 0.000 claims abstract description 8
239000006185 dispersion Substances 0.000 claims abstract description 7
239000003365 glass fiber Substances 0.000 claims description 16
239000000835 fiber Substances 0.000 claims description 14
150000007513 acids Chemical class 0.000 claims description 5
238000001228 spectrum Methods 0.000 claims description 5
230000009466 transformation Effects 0.000 claims description 5
238000005516 engineering process Methods 0.000 claims description 3
239000000758 substrate Substances 0.000 claims description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
239000007788 liquid Substances 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
229910052721 tungsten Inorganic materials 0.000 claims description 2
239000010937 tungsten Substances 0.000 claims description 2
239000012459 cleaning agent Substances 0.000 claims 3
239000005356 container glass Substances 0.000 claims 1
239000000155 melt Substances 0.000 claims 1
230000002547 anomalous effect Effects 0.000 abstract description 4
230000009477 glass transition Effects 0.000 abstract 1
239000005368 silicate glass Substances 0.000 abstract 1
230000003595 spectral effect Effects 0.000 abstract 1
239000003513 alkali Substances 0.000 description 13
239000000126 substance Substances 0.000 description 9
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 6
ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 6
230000003287 optical effect Effects 0.000 description 6
239000002994 raw material Substances 0.000 description 6
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 6
238000002425 crystallisation Methods 0.000 description 5
230000008025 crystallization Effects 0.000 description 5
238000012545 processing Methods 0.000 description 5
230000003014 reinforcing effect Effects 0.000 description 5
FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
238000000034 method Methods 0.000 description 4
229910052784 alkaline earth metal Inorganic materials 0.000 description 3
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 3
150000001342 alkaline earth metals Chemical class 0.000 description 3
239000004568 cement Substances 0.000 description 3
239000013078 crystal Substances 0.000 description 3
230000002349 favourable effect Effects 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
229910001404 rare earth metal oxide Inorganic materials 0.000 description 3
PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
229910000272 alkali metal oxide Inorganic materials 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
239000008395 clarifying agent Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
238000012937 correction Methods 0.000 description 2
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
230000007774 longterm Effects 0.000 description 2
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
-1 R2O3 Chemical compound 0.000 description 1
229910004369 ThO2 Inorganic materials 0.000 description 1
IKWTVSLWAPBBKU-UHFFFAOYSA-N a1010_sial Chemical compound O=[As]O[As]=O IKWTVSLWAPBBKU-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910000410 antimony oxide Inorganic materials 0.000 description 1
229910000413 arsenic oxide Inorganic materials 0.000 description 1
229960002594 arsenic trioxide Drugs 0.000 description 1
229910001626 barium chloride Inorganic materials 0.000 description 1
WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
239000002585 base Substances 0.000 description 1
239000005388 borosilicate glass Substances 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
235000011148 calcium chloride Nutrition 0.000 description 1
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
229910000420 cerium oxide Inorganic materials 0.000 description 1
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Chemical class O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
238000005352 clarification Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000005056 compaction Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000013500 data storage Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000006260 foam Substances 0.000 description 1
CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
238000007496 glass forming Methods 0.000 description 1
239000000156 glass melt Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
238000011068 loading method Methods 0.000 description 1
229910003443 lutetium oxide Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
238000009512 pharmaceutical packaging Methods 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/001—Alkali-resistant fibres
- C03C13/002—Alkali-resistant fibres containing zirconium
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
- C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/095—Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Glass Compositions (AREA)
Adhesives Or Adhesive Processes (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)
Containers Having Bodies Formed In One Piece (AREA)

HR20010553A 1999-02-15 2001-07-20 Glass with high proportion of zirconium-oxide and its uses HRP20010553A2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19906240A DE19906240A1 (de)	1999-02-15	1999-02-15	Hochzirkoniumoxidhaltiges Glas und dessen Verwendungen
PCT/EP2000/001049 WO2000048955A1 (de)	1999-02-15	2000-02-09	Hochzirconiumoxidhaltiges glas und dessen verwendungen

Publications (1)

Publication Number	Publication Date
HRP20010553A2 true HRP20010553A2 (en)	2002-08-31

Family

ID=7897535

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
HR20010553A HRP20010553A2 (en)	1999-02-15	2001-07-20	Glass with high proportion of zirconium-oxide and its uses

Country Status (14)

Country	Link
US (1)	US6627569B1 (cs)
EP (1)	EP1169274B1 (cs)
JP (1)	JP2002537207A (cs)
KR (1)	KR100709800B1 (cs)
CN (1)	CN1188362C (cs)
AT (1)	ATE236859T1 (cs)
AU (1)	AU764638B2 (cs)
CA (1)	CA2361147A1 (cs)
CZ (1)	CZ294456B6 (cs)
DE (2)	DE19906240A1 (cs)
ES (1)	ES2193945T3 (cs)
HR (1)	HRP20010553A2 (cs)
MX (1)	MXPA01008175A (cs)
WO (1)	WO2000048955A1 (cs)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
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FR2867775B1 (fr)	2004-03-17	2006-05-26	Saint Gobain Vetrotex	Fils de verre aptes a renforcer des matieres organiques et/ou inorganiques
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FR2892716B1 (fr) *	2005-10-28	2008-04-18	Saint Gobain Vetrotex	Composition de verre resistant aux alcalis et aux acides pour la fabrication de fils de verre
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1999
- 1999-02-15 DE DE19906240A patent/DE19906240A1/de not_active Withdrawn
2000
- 2000-02-09 MX MXPA01008175A patent/MXPA01008175A/es not_active Application Discontinuation
- 2000-02-09 AU AU32794/00A patent/AU764638B2/en not_active Ceased
- 2000-02-09 KR KR1020017009160A patent/KR100709800B1/ko not_active IP Right Cessation
- 2000-02-09 AT AT00910659T patent/ATE236859T1/de not_active IP Right Cessation
- 2000-02-09 CA CA002361147A patent/CA2361147A1/en not_active Abandoned
- 2000-02-09 CN CNB008037507A patent/CN1188362C/zh not_active Expired - Fee Related
- 2000-02-09 CZ CZ20012745A patent/CZ294456B6/cs not_active IP Right Cessation
- 2000-02-09 ES ES00910659T patent/ES2193945T3/es not_active Expired - Lifetime
- 2000-02-09 WO PCT/EP2000/001049 patent/WO2000048955A1/de active IP Right Grant
- 2000-02-09 EP EP00910659A patent/EP1169274B1/de not_active Expired - Lifetime
- 2000-02-09 JP JP2000599699A patent/JP2002537207A/ja active Pending
- 2000-02-09 DE DE50001713T patent/DE50001713D1/de not_active Expired - Lifetime
- 2000-11-09 US US09/869,818 patent/US6627569B1/en not_active Expired - Lifetime
2001
- 2001-07-20 HR HR20010553A patent/HRP20010553A2/hr not_active Application Discontinuation

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WO2000048955A1 (de)	2000-08-24
JP2002537207A (ja)	2002-11-05
AU764638B2 (en)	2003-08-28
EP1169274B1 (de)	2003-04-09
US6627569B1 (en)	2003-09-30
CZ20012745A3 (cs)	2002-03-13
MXPA01008175A (es)	2002-10-23
AU3279400A (en)	2000-09-04
DE50001713D1 (de)	2003-05-15
ATE236859T1 (de)	2003-04-15
CN1340034A (zh)	2002-03-13
KR100709800B1 (ko)	2007-04-23
CN1188362C (zh)	2005-02-09
EP1169274A1 (de)	2002-01-09
CZ294456B6 (cs)	2005-01-12
CA2361147A1 (en)	2000-08-24
DE19906240A1 (de)	2000-08-17
ES2193945T3 (es)	2003-11-16
KR20010105327A (ko)	2001-11-28

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Publication	Publication Date	Title
HRP20010553A2 (en)	2002-08-31	Glass with high proportion of zirconium-oxide and its uses
HRP20010552A2 (en)	2002-08-31	Glass with high proportion of zirconium-oxide and its uses
RU2127709C1 (ru)	1999-03-20	Боросиликатное стекло с высокой химической стойкостью и низкой вязкостью, которое содержит оксид циркония и оксид лития
JP5415065B2 (ja)	2014-02-12	光ファイバーライトガイドのためのアルカリ亜鉛珪酸塩ガラス系におけるコアガラスと前記コアガラスにより製造される光ファイバーライトガイド
JP4739721B2 (ja)	2011-08-03	光学ガラス
JP2565813B2 (ja)	1996-12-18	光学ガラス
JP5368571B2 (ja)	2013-12-18	高屈折率低分散光学ガラス
JPH0149649B2 (cs)	1989-10-25
JP2007070194A (ja)	2007-03-22	光学ガラス
WO2020078075A1 (zh)	2020-04-23	一种具有高应变点、可快速离子交换和耐弱酸性的锌磷铝硅酸盐玻璃
JPS63230536A (ja)	1988-09-27	タリウム含有光学ガラス
JP2795334B2 (ja)	1998-09-10	光学ガラス
EP0500325A1 (en)	1992-08-26	Chemically resistant glass fiber composition
JPWO2008111620A1 (ja)	2010-06-24	光学ガラス
JPH10167753A (ja)	1998-06-23	無鉛クラウンガラス
JP7269957B2 (ja)	2023-05-09	ガラス組成物
JPS6324938B2 (cs)	1988-05-23
KR20010105326A (ko)	2001-11-28	고비율의 산화지르코늄을 갖는 유리 및 이의 사용
JP2006036595A (ja)	2006-02-09	光学ガラス
JPH0640739A (ja)	1994-02-15	無アルカリガラス