GB751395A - Compositions containing tarnish inhibitors - Google Patents
Compositions containing tarnish inhibitorsInfo
- Publication number
- GB751395A GB751395A GB8639/54A GB863954A GB751395A GB 751395 A GB751395 A GB 751395A GB 8639/54 A GB8639/54 A GB 8639/54A GB 863954 A GB863954 A GB 863954A GB 751395 A GB751395 A GB 751395A
- Authority
- GB
- United Kingdom
- Prior art keywords
- potassium
- sodium
- sulphonates
- hydroxamate
- hydroxamic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
To reduce the tendency of aqueous detergent solutions, to tarnish certain metals or alloys, e.g. copper and nickel alloys, there is included in the solutions a hydroxamic acid of the formula RC(O)NHOH or the tautomeric formula RC(OH) : NOH, where R is an aliphatic hydrocarbon radical of 7-17 carbon atoms, which may be substituted. Salts of these acids, e.g. the sodium, pottasium, ammonium, barium, calcium or magnesium salts, may also be used. Specified compounds are caprylyl hydroxamic acid, capryl hydroxamic acid, potassium palmityl hydroxamate, potassium myristyl hydroxamate, potassium stearyl hydroxamate, and lauryl hydroxamic acid and its potassium salt. The proportion of hydroxamic compound may be 0.1-5 per cent, based on the detergent composition. The detergent solutions may contain (1) condensed phosphates, e.g. pentasodium or pentapotassium tripolyphosphate, tetrasodium or tetrapotassium pyrophosphate or sodium or potassium hexametaphosphate, and/or (2) anionic organic soapless detergents, e.g. alkylaryl sulphonates such as dodecylbenzene sulphonates or kerylnaphthalene sulphonates, alkyl sulphates such as sodium lauryl sulphate, sulphuric esters of monoglycerides or substituted alkyl sulphonates such as sodium palmityl methyltauride, and/or (3) non-ionic detergents, such as the condensation products of alkylphenols or mercaptans with ethylene oxide. Other ingredients which may be present are alkali sulphates, chlorides, silicates, borates, carbonates or orthophosphates, starch, salts of carboxymethyl cellulose, and fluorescent whitening agents. Cationic detergents should not be included. Specific compositions are formulated.ALSO:To reduce the tendency of aqueous solutions to tarnish certain metals or alloys, e.g. copper and nickel alloys, there is included in the solutions a hydroxamic acid of the formula RC(O) NHOH or the tautomeric formula RC(OH): NOH, where R is an aliphatic hydrocarbon radical of 7-17 carbon atoms, which may be substituted. Salts of these acids, e.g. the sodium, potassium, ammonium, barium, calcium, or magnesium salts, may also be used. Specified compounds are caprylyl hydroxamic acid, caprylhydroxamic acid, potassium palmityl hydroxamate, potassium myristyl hydroxamate, potassium stearyl hydroxamate, and lauryl hydroxamic acid and its potassium salt. The proportion of hydroxamic compound may be 0,1-5 per cent, based on the solute in the solution. The solutions may be detergent solutions and these may contain (1) condensed phosphates, e.g. pentasodium or pentapotassium tripolyphosphate, tetrasodium or tetrapotassium pyrophosphate or sodium or potassium hexametaphosphate, and (or) (2) anionic organic soapless detergents, e.g. alkylaryl sulphonates such as dodecylbenzene sulphonates or kerylnaphthalene sulphonates, alkyl sulphates such as sodium lauryl sulphate, sulphuric esters of monoglycerides or substituted alkyl sulphonates such as sodium palmityl methyltauride, and (or) (3) non-ionic detergents, such as the condensation products of alkylphenols or mercaptans with ethylene oxide. Other ingredients which may be present are alkali sulphates, chlorides, silicates, borates, carbonates, or orthophosphates, starch, salts of carboxymethyl cellulose, and fluorescent whitening agents. Cationic detergents should not be included. Specific compositions are formulated.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US751395XA | 1953-03-25 | 1953-03-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB751395A true GB751395A (en) | 1956-06-27 |
Family
ID=22123810
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8639/54A Expired GB751395A (en) | 1953-03-25 | 1954-03-24 | Compositions containing tarnish inhibitors |
Country Status (4)
Country | Link |
---|---|
US (1) | US2733215A (en) |
DE (1) | DE944811C (en) |
FR (1) | FR1097183A (en) |
GB (1) | GB751395A (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1217738B (en) * | 1955-12-17 | 1966-05-26 | Daimler Benz Ag | Process for cleaning objects made of iron, steel and zinc and for producing a protective layer adhering to them, and for cleaning objects made of aluminum |
US2870092A (en) * | 1956-01-09 | 1959-01-20 | Lever Brothers Ltd | Polyphosphate compositions containing tallow methyl tauride and 2-mercaptothiazoline |
US2969329A (en) * | 1956-04-12 | 1961-01-24 | Monsanto Chemicals | Detergent compositions |
US3037937A (en) * | 1956-11-21 | 1962-06-05 | Monsanto Chemicals | Detergent compositions |
US2992996A (en) * | 1956-11-21 | 1961-07-18 | Monsanto Chemicals | Nontarnishing detergent composition |
US2986526A (en) * | 1957-05-16 | 1961-05-30 | Nalco Chemical Co | Metal cleaning |
US3344174A (en) * | 1962-08-21 | 1967-09-26 | Monsanto Co | Vicinal acylamido sulfonate compounds |
US3367878A (en) * | 1964-09-10 | 1968-02-06 | Army Usa | Alkaline water-based cleaner |
US3933872A (en) * | 1970-02-11 | 1976-01-20 | Ashland Oil, Inc. | Method for preparing fatty hydroxamates |
DE102014212622A1 (en) * | 2014-06-30 | 2015-12-31 | Henkel Ag & Co. Kgaa | Cleaning agent comprising hydroxamic acid and / or salts thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2618603A (en) * | 1949-02-04 | 1952-11-18 | Procter & Gamble | Detergent compositions containing metal discoloration inhibitors |
US2618606A (en) * | 1949-02-04 | 1952-11-18 | Procter & Gamble | Detergent compositions containing metal discoloration inhibitors |
US2618605A (en) * | 1949-02-04 | 1952-11-18 | Procter & Gamble | Detergent compositions containing metal discoloration inhibitors |
US2618608A (en) * | 1952-09-12 | 1952-11-18 | Procter & Gamble | Detergent compositions containing metal discoloration inhibitors |
-
0
- US US2733215D patent/US2733215A/en not_active Expired - Lifetime
-
1954
- 1954-03-24 GB GB8639/54A patent/GB751395A/en not_active Expired
- 1954-03-25 DE DEU2684A patent/DE944811C/en not_active Expired
- 1954-03-25 FR FR1097183D patent/FR1097183A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1097183A (en) | 1955-06-30 |
US2733215A (en) | 1956-01-31 |
DE944811C (en) | 1956-06-21 |
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