GB714348A - Improvements relating to detergent compositions - Google Patents

Improvements relating to detergent compositions

Info

Publication number
GB714348A
GB714348A GB25087/51A GB2508751A GB714348A GB 714348 A GB714348 A GB 714348A GB 25087/51 A GB25087/51 A GB 25087/51A GB 2508751 A GB2508751 A GB 2508751A GB 714348 A GB714348 A GB 714348A
Authority
GB
United Kingdom
Prior art keywords
per cent
detergent
synthetic organic
alkali
detergents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25087/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of GB714348A publication Critical patent/GB714348A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A minor proportion of a 2.4.6-triamino- 1.3.5 triazine compound is added to detergent compositions to inhibit their tarnishing action on metals, such as German silver. The detergent compositions may contain or comprise water-soluble inorganic polyphosphates, such as hexasodium hexametaphosphate, hexasodium tetraphosphate or the alkali-metal or ammonium salts of tripolyphosphoric, tetraphosphoric or pyrophosphoric acid, and/or synthetic organic detergents. The latter include the sulphated and sulphonated detergents such as the sulphates of aliphatic compounds having, preferably 12 to 26 carbon atoms in the molecule, and more particularly those having an acyl radical of about 8 to 22 carbon atoms. Such compounds include the sulphuric acid esters of polyhydric alcohols incompletely esterified with higher fatty acids, e.g. coconut oil monoglyceride monosulphate, and tallow diglyceride monosulphate; the pure or mixed higher alkyl sulphates, e.g. laceryl sulphate, cetyl sulphate and those derived from reduced coconut oil fatty acids; the hydroxy sulphonated higher fatty acid esters, e.g. higher fatty acid esters of 2.3-dihydroxy-propane sulphonic acid and the oleic ester of isethionic acid; the higher fatty acid ethanolamide sulphates and the higher fatty acid amides of amino alkyl sulphonic acids, e.g. lauric acid tauride. The synthetic organic detergent may also be an alkyl aryl sulphonate wherein the nucleus may be derived from benzene, toluene, xylene, phenol, cresols or naphthalene, and the alkyl groups may have 8 to 22 and preferably 12 to 16 carbon atoms. These detergents are generally used in the form of their water-soluble salts such as alkali-metal, alkaline-earth metal, magnesium, ammonium, amine or alkylolamine salts The synthetic organic detergent may also comprise a non-ionic detergent such as the polyoxyethylene ether of an alkyl phenol or of a long chain aliphatic alcohol. The inhibitor may be melamine itself, or melamine in which the hydrogen atoms have been replaced by substituents such as methyl or alkylol, but it is desirable that one free hydrogen atom and preferably one primary amino group be present in the molecule. Although the inhibitor may be used in amounts up to 5 per cent. by weight of the total composition, the percentage will normally be less than 1 per cent. and preferably up to 0.5, e.g. 0.3 per cent. Less than 1 per cent of additive is particularly effective for use with built detergent compositions containing from 10 to 50 per cent. and preferably 15 to 40 per cent. by weight of a synthetic organic detergent, preferably of the sulphated or sulphonated type, and about 10 to 80 per cent. and usually 20 to 60 per cent. by weight of polyphosphates. The compositions may contain other additives such as alkali-metal phosphates, silicates, sulphates, chlorides, hydroxides and carbonates, sodium carboxymethylcellulose and fatty acid amides, alcohols or esters. Specifications 681,642, 686,805 and 696,357 are referred to.ALSO:A minor proportion of a 2. 4. 6-triamino-1. 3. 5 triazine compound is added to detergent compositions to inhibit their tarnishing action on metals, such as German silver. The detergent composition may contain or comprise water-soluble inorganic polyphosphates, such as hexasodium hexametaphosphate, hexasodium tetraphosphate or the alkali-metal or ammonium salts of tripolyphosphoric, tetraphosphoric or pyrophosphoric acid, and/or synthetic organic detergents. The latter include the sulphated and sulphonated detergents (see Group III). These detergents are generally employed in the form of their water-soluble salts such as alkali-metal, alkaline-earth metal, magnesium, ammonium, amine or alkylolamine salts. The synthetic organic detergent may also comprise a non-ionic detergent such as the polyoxyethylene ether of an alkyl phenol or of a long chain aliphatic alcohol. The inhibitor may be melamine itself, or melamine in which the hydrogen atoms have been replaced by substitutents such as methyl or alkylol, but it is desirable that one free hydrogen atom and preferably one primary amino group be present in the molecule. Although the inhibitor may be used in amounts up to 5 per cent. by weight of the total composition, the percentage will normally be less than 1 per cent. and preferably up to 0.5 e.g. 0.3 per cent. Less than 1 per cent. of additive is particularly effective for use with detergent compositions containing from 10 to 50 per cent. and preferably 15 to 40 per cent. by weight of a synthetic organic detergent, preferably of the sulphated or sulphonated type, and about 10 to 80 per cent. and usually 20 to 60 per cent. by weight of polyphosphates. The compositions may contain other additives such as alkali-metal phosphates, silicates, sulphates, chlorides, hydroxides and carbonates, sodium carboxymethylcellulose and fatty acid amides, alcohols or esters. Specifications 681,642, 686,805 and 696,357, [all in Group III], are referred to.
GB25087/51A 1951-02-03 1951-10-26 Improvements relating to detergent compositions Expired GB714348A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US302102XA 1951-02-03 1951-02-03

Publications (1)

Publication Number Publication Date
GB714348A true GB714348A (en) 1954-08-25

Family

ID=21853074

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25087/51A Expired GB714348A (en) 1951-02-03 1951-10-26 Improvements relating to detergent compositions

Country Status (6)

Country Link
BE (1) BE508905A (en)
CH (1) CH302102A (en)
DE (1) DE931973C (en)
FR (1) FR1048676A (en)
GB (1) GB714348A (en)
NL (1) NL77813C (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE539762A (en) * 1954-07-12
DE1081590B (en) * 1955-04-18 1960-05-12 Procter & Gamble cleaning supplies
JPH0621042B2 (en) * 1988-06-21 1994-03-23 三愛石油株式会社 Detergent for constant temperature bath

Also Published As

Publication number Publication date
CH302102A (en) 1954-10-15
DE931973C (en) 1955-08-22
BE508905A (en)
NL77813C (en)
FR1048676A (en) 1953-12-23

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