ES2144089T3 - Procedimiento para la obtencion de polimeros de etileno. - Google Patents

Procedimiento para la obtencion de polimeros de etileno.

Info

Publication number
ES2144089T3
ES2144089T3 ES95117503T ES95117503T ES2144089T3 ES 2144089 T3 ES2144089 T3 ES 2144089T3 ES 95117503 T ES95117503 T ES 95117503T ES 95117503 T ES95117503 T ES 95117503T ES 2144089 T3 ES2144089 T3 ES 2144089T3
Authority
ES
Spain
Prior art keywords
different
metalochene
product
morphologies
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95117503T
Other languages
English (en)
Inventor
Walter Dr Spaleck
Martin Dr Antberg
Ludwig Dr Bohm
Jurgen Dr Rohrmann
Hartmut Dr Luker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Targor GmbH
Original Assignee
Targor GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6381117&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2144089(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Targor GmbH filed Critical Targor GmbH
Application granted granted Critical
Publication of ES2144089T3 publication Critical patent/ES2144089T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

LA ELABORACION DE COPOLIMEROS POLIETILENO Y ETILENO - 1 OLEFINA EN PROCESOS DE SUSPENSION O DE FASE GASEOSA CON LA AYUDA DE CATALIZADORES DE METALOCENO-ALUMINOXANO, CUYO COMPONENTE METALOCENO ES UN COMPLEJO BISCICLO PENTADIENILO PUENTEADO, OFRECE VENTAJAS ESPECIALES. MEDIANTE LA UTILIZACION DE ESTE COMPLEJO RESULTA EN ACTIVIDAD ALTA UN PRODUCTO DE ESTRUCTURA COMPLEJA EN UNA ZONA DE MASA MOLAR MUY AMPLIA Y PERMITE LA GENERACION DE MORFOLOGIAS DE GRANO DE TIPO DIFERENTE DEL PRODUCTO, TALES COMO DENSIDAD A GRANEL ALTA Y REDUCIDA, TAMAÑO DE GRANO EXTREMADAMENTE PEQUEÑO Y EXTREMADAMENTE GRANDE Y FORMAS DE GRANO DIFERENTE. LA MULTIPLICIDAD DE MORFOLOGIAS DE GRANO OBTENIBLES ABRE PASO A POSIBILIDADES DIFERENTES PARA APLICACION DE TALES POLVOS DE POLIETILENO EN PROCESOS DE SINTERIZADO.
ES95117503T 1989-05-20 1990-05-16 Procedimiento para la obtencion de polimeros de etileno. Expired - Lifetime ES2144089T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3916555A DE3916555A1 (de) 1989-05-20 1989-05-20 Verfahren zur herstellung von ethylenpolymeren

Publications (1)

Publication Number Publication Date
ES2144089T3 true ES2144089T3 (es) 2000-06-01

Family

ID=6381117

Family Applications (2)

Application Number Title Priority Date Filing Date
ES90109207T Expired - Lifetime ES2116263T3 (es) 1989-05-20 1990-05-16 Procedimiento para la obtencion de polimeros de etileno.
ES95117503T Expired - Lifetime ES2144089T3 (es) 1989-05-20 1990-05-16 Procedimiento para la obtencion de polimeros de etileno.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES90109207T Expired - Lifetime ES2116263T3 (es) 1989-05-20 1990-05-16 Procedimiento para la obtencion de polimeros de etileno.

Country Status (7)

Country Link
EP (2) EP0700937B1 (es)
JP (1) JP2904301B2 (es)
AU (1) AU630451B2 (es)
CA (1) CA2017190C (es)
DE (3) DE3916555A1 (es)
ES (2) ES2116263T3 (es)
ZA (1) ZA903831B (es)

Families Citing this family (46)

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US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
ATE199911T1 (de) * 1991-05-27 2001-04-15 Targor Gmbh Verfahren zur herstellung von polyolefinen mit breiter molmassenverteilung
DE4121368A1 (de) * 1991-06-28 1993-01-07 Hoechst Ag Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
TW300901B (es) * 1991-08-26 1997-03-21 Hoechst Ag
DE4130352A1 (de) * 1991-09-12 1993-03-18 Basf Ag Des- und reaktivierte metallocenkatalysatorsysteme
DE4139261A1 (de) * 1991-11-29 1993-06-03 Basf Ag Ethylen-copolymerisate niederer dichte
GB9125934D0 (en) 1991-12-05 1992-02-05 Exxon Chemical Patents Inc Process for polymerising olefinic feeds under pressure
US5302733A (en) * 1992-03-30 1994-04-12 Ethyl Corporation Preparation of metallocenes
DE59310131D1 (de) * 1992-08-03 2001-01-25 Targor Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung spezieller Metallocene
JP2007146183A (ja) * 1992-12-07 2007-06-14 Mitsubishi Chemicals Corp 押出成形体用樹脂組成物
JPH06271594A (ja) * 1993-03-22 1994-09-27 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
DE4436113A1 (de) 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
DE69533310T2 (de) * 1994-12-20 2005-07-21 Mitsui Chemicals, Inc. Verfahren zur herstellung von ethylenpolymer und ethylenpolymer
DE4446922A1 (de) * 1994-12-28 1996-07-04 Hoechst Ag Metallocenverbindung und ihre Verwendung als Katalysatorkomponente
EP1217013A3 (en) * 1995-05-16 2004-12-22 Univation Technologies LLC Production of polyethylene using stereoisomeric metallocenes
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
DE19637669A1 (de) * 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
US6184317B1 (en) * 1997-07-14 2001-02-06 The Board Of Trustees Of The Leland Stanford Jr. University Catalysts and processes for the synthesis of alternating ethylene/α-olefin copolymers, and isotactic copolymers thereof
GB9718073D0 (en) * 1997-08-28 1997-10-29 Zeneca Ltd Organometallic compounds,their preparation and use
ES2239439T3 (es) 1998-03-04 2005-09-16 Exxonmobil Chemical Patents Inc. Proceso de polimerizacion de olefinas a alta temperatura.
KR20010014072A (ko) 1998-04-21 2001-02-26 간디 지오프레이 에이치. 에틸렌과 알파-올레핀의 공중합체의 제조 방법
EP0953582A1 (en) * 1998-04-27 1999-11-03 Fina Research S.A. Polyolefin production
DE69926339T2 (de) 1998-11-20 2006-01-26 Basell Polyolefine Gmbh Verbrückte metallocene, herstellung und verwendung als olefinpolymerisationskatalysator
US6818585B2 (en) 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
EP1059332A1 (en) 1999-06-10 2000-12-13 Fina Research S.A. Polypropylene with high melt strength and drawability
CA2392949A1 (en) * 1999-12-01 2001-06-07 Univation Technologies Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
JP2003518530A (ja) 1999-12-28 2003-06-10 バセル テクノロジー カンパニー ビー．ブイ． エチレンポリマー類の製造方法
US6960676B2 (en) * 2000-02-08 2005-11-01 Exxonmobil Chemical Patents Inc. Method of preparing group 14 bridged biscyclopentadienyl ligands
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
EP1788006B1 (en) * 2004-08-16 2013-12-25 Mitsui Chemicals, Inc. Ethylene polymer and use thereof
EP1659136A1 (en) 2004-11-19 2006-05-24 Total Petrochemicals Research Feluy Solid state properties of polyethylene prepared with tetrahydroindenyl-based catalyst system
CN100390256C (zh) 2004-11-26 2008-05-28 三井化学株式会社 合成润滑油和润滑油组合物
EP1671983B1 (en) * 2004-12-03 2009-02-25 Repsol Quimica S.A. Catalysts compositions for the polymerization and copolymerization of alpha-olefins
CN101815727B (zh) * 2007-08-27 2013-05-15 保瑞利斯科技公司 催化剂
ES2428013T3 (es) 2009-04-21 2013-11-05 Mitsui Chemicals, Inc. Método para producción de un polímero de olefina
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
US8796409B2 (en) 2011-10-04 2014-08-05 Exxonmobil Chemical Patents Inc. Use of temperature and ethylene partial pressure to introduce long chain branching in high density polyethylene
CN107722148B (zh) 2013-02-08 2021-06-08 三井化学株式会社 固体状聚铝氧烷组合物、烯烃聚合用催化剂、烯烃聚合物的制造方法
CN107428863B (zh) 2015-03-31 2020-03-06 日本聚乙烯株式会社 管与接头用聚乙烯、及其成形体
JP6651938B2 (ja) 2016-03-28 2020-02-19 日本ポリエチレン株式会社 ポリエチレン及びその成形体

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JP2538588B2 (ja) 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
JP2538595B2 (ja) 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
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IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
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Also Published As

Publication number Publication date
EP0399348A3 (de) 1992-08-12
DE3916555A1 (de) 1990-11-22
EP0700937A3 (de) 1997-02-19
CA2017190A1 (en) 1990-11-20
ZA903831B (en) 1991-02-27
EP0399348A2 (de) 1990-11-28
CA2017190C (en) 2001-01-30
EP0399348B1 (de) 1998-05-20
EP0700937B1 (de) 2000-02-16
JPH0321607A (ja) 1991-01-30
JP2904301B2 (ja) 1999-06-14
EP0700937A2 (de) 1996-03-13
AU5577190A (en) 1991-01-10
AU630451B2 (en) 1992-10-29
ES2116263T3 (es) 1998-07-16
DE59010898D1 (de) 2000-03-23
DE59010821D1 (de) 1998-06-25

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