ES2025768T3 - Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles. - Google Patents

Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles.

Info

Publication number
ES2025768T3
ES2025768T3 ES198888202018T ES88202018T ES2025768T3 ES 2025768 T3 ES2025768 T3 ES 2025768T3 ES 198888202018 T ES198888202018 T ES 198888202018T ES 88202018 T ES88202018 T ES 88202018T ES 2025768 T3 ES2025768 T3 ES 2025768T3
Authority
ES
Spain
Prior art keywords
procedure
hydrogels
preparing
pores
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888202018T
Other languages
English (en)
Inventor
Richard Alan Kemp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/100,662 external-priority patent/US4810684A/en
Priority claimed from US07/100,659 external-priority patent/US4820680A/en
Priority claimed from US07/100,661 external-priority patent/US4810687A/en
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of ES2025768T3 publication Critical patent/ES2025768T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR CATALIZADORES DE HIDROTRATAMIENTO MUY ACTIVOS, INCORPORANDO UN ELEMENTO ELEGIDO DEL GRUPO QUE CONSTA DE NIQUEL, COBALTO Y SUS MEZCLAS, Y UN METAL PESADO ELEGIDO DEL GRUPO QUE CONSTA DE MOLIBDENO, WOLFRAMIO Y SUS MEZCLAS (CON UNA CANTIDAD ESTABILIZANTE DE FOSFORO) EN UN SOPORTE DE HIDROGEL DE ALUMINA (FOSFATADO). EL CATALIZADOR CALCINADO FINAL TIENE UN AREA SUPERFICIAL DE 300 M2/G POR LO MENOS, POR LO MENOS EL 20 % DEL VOLUMEN DE POROS EN POROS QUE TIENEN DIAMETROS MAYORES QUE 35 NM, Y POR LO MENOS EL 20 % DEL VOLUMEN DE POROS EN POROS QUE TIENEN DIAMETROS MENORES QUE 7 NM.
ES198888202018T 1987-09-24 1988-09-14 Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles. Expired - Lifetime ES2025768T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/100,662 US4810684A (en) 1987-09-24 1987-09-24 Hydrotreating catalysts prepared from hydrogels
US07/100,659 US4820680A (en) 1987-09-24 1987-09-24 Hydrotreating catalysts prepared from hydrogels
US07/100,661 US4810687A (en) 1987-09-24 1987-09-24 Hydrotreating catalysts prepared from hydrogels

Publications (1)

Publication Number Publication Date
ES2025768T3 true ES2025768T3 (es) 1992-04-01

Family

ID=27379046

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888202018T Expired - Lifetime ES2025768T3 (es) 1987-09-24 1988-09-14 Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles.

Country Status (7)

Country Link
EP (1) EP0309045B1 (es)
JP (1) JP2822044B2 (es)
AU (1) AU602794B2 (es)
CA (1) CA1317277C (es)
DE (1) DE3865794D1 (es)
DK (1) DK172385B1 (es)
ES (1) ES2025768T3 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4810686A (en) * 1987-09-24 1989-03-07 Shell Oil Company Hydrotreating catalysts prepared from hydrogels
CA2056511C (en) * 1990-12-24 1999-06-01 Clyde Lee Aldridge Supported hydrogenation and hydrotreating catalysts and process
US5227353A (en) * 1991-07-24 1993-07-13 Mobil Oil Corporation Hydroprocessing catalyst composition
CA2455011C (en) 2004-01-09 2011-04-05 Suncor Energy Inc. Bituminous froth inline steam injection processing
JP4934417B2 (ja) * 2006-12-08 2012-05-16 千代田化工建設株式会社 金属担持触媒の製造方法
JP6196837B2 (ja) * 2012-09-10 2017-09-13 日揮触媒化成株式会社 ニッケル系触媒、ニッケル系還元触媒およびそれらの製造方法
RU2639159C2 (ru) * 2015-11-30 2017-12-20 федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" (ФГБОУ ВО "СамГТУ), RU. Катализатор, способ приготовления носителя, способ приготовления катализатора и способ гидроочистки углеводородного сырья

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4456699A (en) * 1981-06-17 1984-06-26 Standard Oil Company (Indiana) Catalyst and support, and their methods of preparation
US4717706A (en) * 1986-10-28 1988-01-05 Shell Oil Company Wide-pore hydrogel-derived catalysts
CA1304347C (en) * 1986-10-28 1992-06-30 Richard Alan Kemp Process for the preparation of hydrotreating catalysts from hydrogels
CA1312595C (en) * 1986-10-28 1993-01-12 Richard Alan Kemp Process for the preparation of hydrotreating catalysts from hydrogels
CA1304348C (en) * 1986-10-28 1992-06-30 Richard Alan Kemp Process for preparing hydrotreating catalysts from hydrogels

Also Published As

Publication number Publication date
DK525788A (da) 1989-03-25
AU602794B2 (en) 1990-10-25
EP0309045B1 (en) 1991-10-23
DE3865794D1 (de) 1991-11-28
EP0309045A1 (en) 1989-03-29
DK525788D0 (da) 1988-09-22
JP2822044B2 (ja) 1998-11-05
DK172385B1 (da) 1998-05-11
AU2273288A (en) 1989-04-06
CA1317277C (en) 1993-05-04
JPH01123634A (ja) 1989-05-16

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