Classifications

• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
  • C25D13/00—Electrophoretic coating characterised by the process
  • C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
  • C25D13/16—Wires; Strips; Foils
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
  • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
  • C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
  • C09D5/448—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications characterised by the additives used
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/60—Additives non-macromolecular
  • C09D7/61—Additives non-macromolecular inorganic
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
  • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/05—Accumulators with non-aqueous electrolyte
  • H01M10/052—Li-accumulators
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/05—Accumulators with non-aqueous electrolyte
  • H01M10/052—Li-accumulators
  • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/04—Processes of manufacture in general
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/04—Processes of manufacture in general
  • H01M4/0438—Processes of manufacture in general by electrochemical processing
  • H01M4/045—Electrochemical coating; Electrochemical impregnation
  • H01M4/0452—Electrochemical coating; Electrochemical impregnation from solutions
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/04—Processes of manufacture in general
  • H01M4/0438—Processes of manufacture in general by electrochemical processing
  • H01M4/045—Electrochemical coating; Electrochemical impregnation
  • H01M4/0457—Electrochemical coating; Electrochemical impregnation from dispersions or suspensions; Electrophoresis
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
  • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
  • H01M4/139—Processes of manufacture
  • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
  • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
  • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
  • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
  • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
  • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
  • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
  • H01M4/621—Binders
  • H01M4/622—Binders being polymers
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
  • H01M4/624—Electric conductive fillers
  • H01M4/625—Carbon or graphite
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/64—Carriers or collectors
  • H01M4/66—Selection of materials
  • H01M4/661—Metal or alloys, e.g. alloy coatings
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
  • H01M4/139—Processes of manufacture
  • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
  • Y02E60/10—Energy storage using batteries

Definitions

• the present invention relates to the coating of electrically conductive substrates by electrodeposition of compositions including grapheme carbon particles and a resin.
• Electrodeposition as a coating application method involves the deposition onto an electrically conductive substrate of a composition under the influence of an applied electrical potential.
• a coating is deposited as the substrate is immersed in the composition, the substrate serving as an electrode in an electrical circuit of the electrode and a counter-electrode immersed in the composition, the coating being applied to the substrate as electric current is passed between the electrodes.
• the composition used in an electrodeposition process includes a resinous phase dispersed in an aqueous medium.
• the composition into which the substrate is immersed may include pigments to provide color and other fillers and additives, the properties historically sought by electrodeposited coatings, such as outstanding corrosion resistance, arise primarily because of the deposition of a continuous resinous film. Therefore, the resin content of the composition into which the substrate is immersed is relatively high in relation to the amount of pigment and other fillers. For example, such compositions usually contain 0.02 to 1 parts by weight pigment to 1 part by weight resinous phase.
• Lithium ion batteries consist of a cathode, an anode, a separator, and an electrolyte.
• the cathode is a metal (often aluminum) foil substrate having a lithium-containing active material, such as LiFeP0 4 , deposited thereon.
• the lithium-containing active material is deposited on the substrate from a slurry containing the lithium-containing active material, conductive carbon, and binder (such as polyvinylidene difluoride) in organic solvent (such as n- methyl-2-pyrrolidone) via a slot die coater or a roll coater.
• the sum of the amount of lithium-containing active material and conductive carbon is high relative to the amount of binder, typically at least 9 parts by weight to 1 part by weight.
• the use of such solvent-borne slurries is, however, environmentally undesirable.
• An aspect of the invention provides a method comprising: immersing an electrically conductive substrate into an electrodepositable composition, the substrate serving as an electrode in an electrical circuit comprising the electrode and a counter-electrode immersed in the composition, a coating being applied onto or over at least a portion of the substrate as electric current is passed between the electrodes, the electrodepositable composition comprising: (a) an aqueous medium; (b) an ionic resin; and (c) solid particles comprising grapheme carbon particles, wherein the composition has a weight ratio of solid particles to ionic resin of at least 4: 1.
• Another aspect of the invention provides an electrodepositable composition
• an electrodepositable composition comprising: (a) an aqueous medium; (b) an ionic resin; and (c) solid particles comprising: (i) grapheme carbon particles; and (ii) lithium-containing particles, wherein the composition has a weight ratio of solid particles to ionic resin of at least 4: 1.
• a further aspect of the present invention provides a lithium ion battery electrode coating electrodeposited on a substrate, the electrodeposited coating comprising: (a) a cured ionic resin; and (b) solid particles comprising: (i) grapheme carbon particles; and (ii) lithium- containing particles, wherein the coating has a weight ratio of solid particles to cured ionic resin of at least 4: 1.
• any numerical range recited herein is intended to include all sub-ranges subsumed therein.
• a range of "1 to 10" is intended to include all sub-ranges between (and including) the recited minimum value of 1 and the recited maximum value of 10, that is, having a minimum value equal to or greater than 1 and a maximum value of equal to or less than 10.
• certain embodiments of the present invention are directed to methods that comprise immersing an electrically conductive substrate into an electrodepositable composition.
• Electrically conductive substrates suitable for use in the methods described herein include metallic substrates as well as electrically conductive composite materials, such as polymeric materials containing a sufficient amount of conductive filler, such as conductive carbon particles, carbon nanotubes, carbon fibers, fullerenes, graphene and the like.
• Suitable metallic substrates include, but are not limited to, ferrous and non-ferrous metals. Suitable ferrous metals include iron, steel, and alloys thereof.
• Non-limiting examples of useful steel materials include cold-rolled steel, galvanized (zinc coated) steel, electrogalvanized steel, stainless steel, pickled steel, GAL V ANNEAL, GALVALUME, and GAL VAN zinc-aluminum alloys coated upon steel, and combinations thereof.
• Useful non-ferrous metals include aluminum, copper, manganese, nickel, zinc, magnesium, and alloys thereof. Combinations or composites of ferrous and non-ferrous metals can also be used.
• the substrate is embodied in the form of a sheet, coil, or foil.
• foil refers to a thin and pliable sheet of metal.
• the foil may be a continuous sheet, or may be perforated, mesh-like, screen-like, etc.
• Such foils may be constructed of, for example, aluminum, iron, copper, manganese, nickel, combinations thereof, and/or alloys thereof.
• the thickness of the foil is no more than 8 mils (203.2 ⁇ ), such as no more than 4 mils (101.6 ⁇ ), no more than 2 mils (50.8 ⁇ ), or, in some cases no more than 1 mil (25.4 ⁇ ), and/or at least 0.1 mil (2.54 ⁇ ), such as at least 0.2 mil (5.08 ⁇ ), at least 0.4 mils (10.2 ⁇ ), or at least 0.5 mil (12.7 ⁇ ).
• the methods of the present invention comprise immersing the electrically conductive substrate into an electrodepositable composition, the substrate serving as an electrode in an electrical circuit comprising the electrode and a counter-electrode immersed in the composition, a coating being applied onto or over at least a portion of the substrate as electric current is passed between the electrodes.
• the phrase "onto or over” means that the coating may be applied directly on at least a portion of the substrate surface or the coating may be applied over any coating or pretreatment material which was previously applied to at least a portion of the substrate surface.
• electrodepositable composition refers to a composition that includes components that are electrodepositable.
• electrodepositable composition refers to a composition that includes components that are electrodepositable.
• Electrodepositable means capable of being deposited onto an electrically conductive substrate under the influence of an applied electrical potential.
• the electrodepositable compositions used in the methods of the present invention comprise an aqueous medium.
• aqueous medium refers to a medium that either consists exclusively of water or comprises predominantly water in combination with inert organic cosolvent(s).
• the organic cosolvents are at least partially soluble with water.
• solvents include oxygenated organic solvents, such as monoalkyl ethers of ethylene glycol, di ethylene glycol, propylene glycol, and dipropylene glycol which contain from 1 to 10 carbon atoms in the alkyl group, such as the monoethyl and monobutyl ethers of these glycols.
• At least partially water-miscible solvents examples include alcohols such as ethanol, isopropanol, butanol and diacetone alcohol.
• Other at least partially water-miscible solvents may include coalescing solvents such as tri ethyl phosphate, triacetin, dipropylene diacetate, and the like. If used, the organic cosolvents are, in certain embodiments, used in amounts less than 25 percent by weight, less than 20 percent by weight, or, in some cases, less than 10 percent by weight, such as less than 5 percent by weight, based on total weight of water in the composition.
• the aqueous medium is present in the composition used in the methods of the present invention in an amount of at least 75 percent by weight, at least 90 percent by weight, or at least 95 percent by weight, such as 75 to 99.5 percent by weight, 90 to 99 percent by weight, or, in some cases, 95 to 99 percent by weight, based on the total weight of the composition.
• the compositions used in the methods of the present invention may have a relatively low total solids content, as described further below.
• the electrodepositable compositions used in the methods of the present invention comprise an ionic resin.
• ionic resin refers to any resin that carries a charge, including resins that carry a negatively charged ion and resins that carry a positively charged ion. Suitable ionic resins include, therefore, anionic resins and cationic resins.
• the ionic resin comprises an anionic salt group-containing resin.
• Suitable anionic resins include resins that contain at least partially neutralized anionic groups, such as acid groups, such as carboxylic acid groups, which impart a negative charge.
• suitable anionic resins therefore, include base-neutralized, carboxylic acid group-containing resins.
• the anionic resin comprises a water soluble anionic resin.
• water soluble resin means that a resin is capable of being essentially uniformly blended and/or molecularly or ionically dispersed in water to form a true solution. See R. Lewis, Sr., Hawley's Condensed Chemical Dictionary, (12th Ed. 1993) at page 586.
• the water soluble anionic resin comprises a cellulose derivative, such as is the case with carboxymethylcellulose and salts thereof (CMC).
• CMC is a cellulosic ether in which a portion of the hydroxyl groups on the anhydroglucose rings are substituted with carboxymethyl groups.
• the degree of carboxymethyl substitution can range from 0.4-3. Since CMC is a long chain polymer, its viscosity in aqueous solutions depends on its molecular weight that can vary between 50,000 and 2,000,000 on a weight average basis. In certain embodiments, the carboxymethylcellulose has a weight average molecular weight of at least 50,000, such as at least 100,000, or some cases, at least 200,000, such as 50,000 to 1,000,000, 100,000 to 500,000, or 200,000 to 300,000. Both the degree of substitution and the viscosity of aqueous solutions can be determined via ASTM D 1439-03. Molecular weight is typically estimated from the viscosity of standard CMC solutions.
• the water soluble anionic resin such as a cellulose derivative, such as carboxymethylcellulose
• the water soluble anionic resin is present in an amount of at least 50 percent by weight, such as at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, or, in some cases, at least 90 percent by weight, based on the total weight of resin solids in the composition.
• the water soluble anionic resin such as a cellulose derivative, such as carboxymethylcellulose
• the water soluble anionic resin is present in an amount of no more than 20 percent by weight, no more than 15 percent by weight, no more than 10 percent by weight, no more than 5 percent by weight, such as 1 to 20 percent by weight, 1 to 15 percent by weight, 5 to 15 percent by weight, or, in some cases, 1 to 3 percent by weight, based on the total weight of solids in the composition.
• total weight of solids refers to the total non-volatile content of the composition, i.e., the content of materials in the composition that will not volatilize when heated and excludes water and organic solvents.
• the composition in addition to a water soluble anionic resin, may also comprise a water dispersible anionic resin.
• a water dispersible resin means a resin that is capable of being distributed throughout water as finely divided particles. See Hawley's at page 435.
• water dispersible anionic resins that are suitable for use in the compositions described herein in combination with a water soluble anionic resin include the reaction product or adduct of a drying oil or semi-drying fatty acid ester with a dicarboxylic acid or anhydride; and the reaction product of a fatty acid ester, unsaturated acid or anhydride and any additional unsaturated modifying materials which are further reacted with polyol. Also suitable are the interpolymers of hydroxy-alkyl esters of unsaturated carboxylic acids, unsaturated carboxylic acid and at least one other ethylenically unsaturated monomer.
• Suitable water dispersible anionic resins are mixtures of alkyd resin and an amine-aldehyde resin, mixed esters of a resinous polyol, and phosphatized polyepoxides or phosphatized acrylic resins, such as those disclosed in EP0469491B1 at page 2, line 56 to page 3, line 56, U.S. Patent Application Publication No. 2009-0045071 at [0004]-[0015] and U.S. patent application Ser. No. 13/232,093 at [0014]-[0040], the cited portions of which being incorporated herein by reference. Also suitable are those resins comprising one or more pendent carbamate functional groups, such as those described in U.S. Pat. No. 6,165,338.
• the composition comprises an anionic resin composition comprising a water soluble anionic resin, such as a cellulose derivative, such as
• water dispersible anionic resin different from the cellulose derivative, wherein the water dispersible anionic resin is present in the composition in an amount of less than 50 percent by weight, such as less than 40 percent by weight, less than 30 percent by weight, less than 20 percent by weight, or, in some cases, less than 10 percent by weight, based on the total weight of anionic resin in the composition.
• Suitable bases include both organic and inorganic bases.
• suitable bases are ammonia, monoalkylamines, dialkylamines, or trialkylamines such as ethylamine, propylamine,
• dimethylamine, dibutylamine and cyclohexylamine monoalkanolamine, dialkanolamine or trialkanol amine such as ethanolamine, diethanolamine, triethanolamine, propanolamine, isopropanolamine, diisopropanolamine, dimethylethanolamine and diethylethanolamine;
• the composition comprises an alkali salt of a cellulose derivative, such as sodium carboxymethylcellulose, potassium carboxymethylcellulose and/or lithium carboxymethylcellulose.
• the resin(s) are at least partially neutralized from 20 to 200 percent, 40 to 150 percent, such as 60 to 120 percent neutralization.
• the water dispersible anionic resin described above comprises an active hydrogen-containing, anionic salt group-containing resin and the
• composition further comprises a curing agent that comprises reactive groups that are reactive with active hydrogen groups.
• active hydrogen-containing, anionic salt group-containing resin refers to resins that include active hydrogen functional groups and at least partially neutralized anionic groups.
• active hydrogen functional groups refers to those groups that are reactive with isocyanates as determined by the Zerewitnoff test as is described in the JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol. 49, page 3181 (1927) and include, for example, hydroxyl groups, primary or secondary amine groups, and thiol groups.
• the active hydrogen functional groups are hydroxyl groups, primary amine groups and/or secondary amine groups.
• Suitable curing agents for use in electrodepositable compositions comprising an active hydrogen-containing, anionic salt group-containing resin include, but are not necessarily limited to, aminoplast resins and phenolplast resins.
• Suitable aminoplast resins are condensation products of an aldehyde, e.g., formaldehyde, acetaldehyde, crotonaldehyde, and benzaldehyde and an amino or amido group containing material such as urea, melamine, and benzoguanamine. Products obtained from the reaction of alcohols and formaldehyde with melamine, urea and benzoguanamine are often used.
• Illustrative but non-limiting examples of useful aminoplast resins are those available under the trademark CYMEL from Cytec Industries and RESIMENE from Solutia Inc. Specific examples are CYMEL 1130 and 1156 and RESIMENE 750 and 753.
• the ionic resin comprises an cationic salt group-containing resin.
• Suitable cationic salt-group containing resins include resins that contain at least partially neutralized cationic groups, such as sulfonium groups and amine groups, which impart a positive charge.
• the cationic resin comprises a water soluble cationic resin.
• the water soluble cationic resin comprises a poly(C 2 -4)- alkyleneimine, which can be linear or branched, specific examples of which include
• PEIs polyethyleneimines
• the water soluble cationic resin such as those mentioned above, has a weight average molecular weight of at least 5,000, such as at least 10,000, or, in some eases, 5,000 to 50,000, or, in some cases 10,000 to 25,000.
• the water soluble cationic resin such as a PEI
• the water soluble cationic resin is present in an amount of at least 50 percent by weight, such as at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, or, in some cases, at least 90 percent by weight, based on the total weight of resin in the composition.
• the water soluble cationic resin, such as a PEI is present in an amount of no more than 20 percent by weight, no more than 15 percent by weight, no more than 10 percent by weight, no more than 5 percent by weight, such as 1 to 20 percent by weight, 1 to 15 percent by weight, 5 to 15 percent by weight, or, in some cases, 1 to 3 percent by weight, based on the total weight of solids in the
• the composition in addition to a water soluble cationic resin, also comprises a water dispersible cationic resin.
• water dispersible cationic resins that are suitable for use in the compositions described herein are active hydrogen- containing, cationic salt group-containing resins.
• active hydrogen- containing, cationic salt group-containing resin refers to resins that include active hydrogen functional groups and at least partially neutralized cationic groups.
• Suitable active hydrogen-containing, cationic salt group containing resins include polyepoxide-amine adducts, such as the adduct of a polyglycidyl ethers of a polyphenol, such as Bisphenol A, and primary and/or secondary amines, such as are described in U.S. Pat. No. 4,031,050 at col. 3, line 27 to col. 5, line 50, U.S. Pat. No. 4,452,963 at col. 5, line 58 to col. 6, line 66, and U.S. Pat. No. 6,017,432 at col. 2, line 66 to col. 6, line 26, these portions of which being incorporated herein by reference.
• a portion of the amine that is reacted with the polyepoxide is a ketamine of a polyamine, as is described in U.S. Pat. No. 4, 104,147 at col. 6, line 23 to col. 7, line 23, the cited portion of which being incorporated herein by reference.
• ungelled polyepoxide- polyoxyalkylenepolyamine resins such as are described in U.S. Pat. No. 4,432,850 at col. 2, line 60 to col. 5, line 58, the cited portion of which being incorporated herein by reference.
• cationic acrylic resins such as those described in U.S. Pat. Nos. 3,455,806 at col. 2, line 18 to col.
• quaternary ammonium salt group- containing resins can also be employed as a cationic salt group-containing resin in the compositions described herein.
• these resins are those which are formed from reacting an organic polyepoxide with a tertiary amine acid salt. Such resins are described in U.S. Pat. No. 3,962,165 at col. 2, line 3 to col. 11, line 7, U.S. Pat. No. 3,975,346 at col. 1, line 62 to col.
• Suitable cationic resins include ternary sulfonium salt group-containing resins, such as those described in U.S. Pat. No.
• Suitable cationic salt group-containing resins include those that may form photodegradation resistant electrodepositable coating compositions.
• Such resins include the resins comprising cationic amine salt groups which are derived from pendant and/or terminal amino groups that are disclosed in United States Patent Application Publication 2003/0054193 Al at [0064] to [0088], this portion of which being incorporated herein by reference.
• active hydrogen-containing, cationic salt group-containing resins derived from a polyglycidyl ether of a polyhydric phenol that is essentially free of aliphatic carbon atoms to which are bonded more than one aromatic group, which are described in United States Patent Application Publication US 2003/0054193 Al at [00961 to [0123], this portion of which being incorporated herein by reference.
• the compositions comprise a cationic resin composition comprising a water soluble cationic resin, such as a PEI, and a water dispersible cationic resin, different from the PEI, wherein the water dispersible cationic resin is present in the composition in an amount of less than 50 percent by weight, such as less than 40 percent by weight, less than 30 percent by weight, less than 20 percent by weight, or, in some cases, less than 10 percent by weight, based on the total weight of cationic resin in the composition.
• a water soluble cationic resin such as a PEI
• a water dispersible cationic resin different from the PEI
• the water dispersible cationic resin is present in the composition in an amount of less than 50 percent by weight, such as less than 40 percent by weight, less than 30 percent by weight, less than 20 percent by weight, or, in some cases, less than 10 percent by weight, based on the total weight of cationic resin in the composition.
• the resin in adapting the cationic resin to be solubilized or dispersed in an aqueous medium, the resin is at least partially neutralized by, for example, treating with an acid.
• suitable acids are inorganic acids, such as phosphoric acid and sulfamic acid, as well as organic acids, such as, acetic acid and lactic acid, among others.
• salts such as dimethylhydroxyethylammonium dihydrogenphosphate and ammonium dihydrogenphosphate can be used.
• the cationic resin is neutralized to the extent of at least 50 percent or, in some cases, at least 70 percent, of the total theoretical neutralization equivalent.
• the step of solubilization or dispersion may be
• the composition further includes a curing agent to react with the active hydrogen groups of the cationic salt group containing resin described above.
• suitable curing agents are polyisocyanates, including at least partially blocked polyisocyanates, aminoplast resins and phenolic resins, such as phenolformaldehyde condensates including allyl ether derivatives thereof.
• the composition may comprise a catalyst to catalyze the reaction between the curing agent and the active hydrogen-containing resin(s).
• Suitable cure catalysts include, without limitation, organotin compounds (e.g., dibutyltin oxide and dioctyltin oxide) and salts thereof (e.g., dibutyltin diacetate); other metal oxides (e.g., oxides of cerium, zirconium and bismuth) and salts thereof (e.g., bismuth sulfamate and bismuth lactate).
• the cure catalyst comprises a cyclic guanidine as described in U.S. Pat. No. 7,842,762 at col. 1, line 53 to col. 4, line 18 and col. 16, line 62 to col. 19, line 8, the cited portions of which being incorporated herein by reference.
• the cure catalyst comprises a cyclic guanidine as described in U.S. Pat. No. 7,842,762 at col. 1, line 53 to col. 4, line 18
• compositions do not include an organotin compound.
• compositions used in the methods of the present invention further comprise solid particles.
• solid particles refers to discrete three dimensional shaped solids which are chemically different from the ionic resin(s).
• the shape (or morphology) of the particles can vary.
• sheet or plate-like grapheme carbon particles as described below may be used.
• solid particles having generally spherical morphologies such as solid beads, microbeads, or hollow spheres
• particles that are cubic or acicular (elongated or fibrous) may be used.
• plate-like particles may be planar, or at least a portion may be curved, curled, creased or buckled.
• the additional particles can have an internal structure that is hollow, porous or void free, or a combination of any of the foregoing, e.g., a hollow center with porous or solid walls.
• suitable particle characteristics see H. Katz et al. (Ed.), Handbook of Fillers and Plastics (1987) at pages 9-10.
• the solid particles comprise grapheme carbon particles.
• the grapheme carbon particles may be provided in the electrodepositable compositions in any suitable amount.
• the weight ratio of the grapheme carbon particles to the ionic resin in the compositions may typically range from 0.05 : 1 to 5 : 1.
• the weight ratio of grapheme carbon particles to ionic resin may range from 0.1 : 1 to 2: 1, or from 0.1 : 1 to 1 : 1.
• grapheme carbon particles means carbon particles having structures comprising one or more layers of one-atom-thick planar sheets of sp 2 -bonded carbon atoms that are densely packed in a honeycomb crystal lattice.
• the average number of stacked layers may be less than 100, for example, less than 50. In certain embodiments, the average number of stacked layers is 30 or less, such as 20 or less, 10 or less, or, in some cases, 5 or less.
• the grapheme carbon particles may be substantially flat, however, at least a portion of the planar sheets may be substantially curved, curled, creased or buckled. The particles typically do not have a spheroidal or equiaxed morphology.
• the grapheme carbon particles have a thickness, measured in a direction perpendicular to the carbon atom layers, of no more than 10 nanometers, no more than 5 nanometers, or, in certain embodiments, no more than 4 or 3 or 2 or 1 nanometers, such as no more than 3.6 nanometers.
• the grapheme carbon particles may be from 1 atom layer up to 3, 6, 9, 12, 20 or 30 atom layers thick, or more.
• the graphenic carbon particles have a width and length, measured in a direction parallel to the carbon atoms layers, of at least 50 nanometers, such as more than 100 nanometers, in some cases more than 100 nanometers up to 500 nanometers, or more than 100 nanometers up to 200 nanometers.
• the graphenic carbon particles may be provided in the form of ultrathin flakes, platelets or sheets having relatively high aspect ratios (aspect ratio being defined as the ratio of the longest dimension of a particle to the shortest dimension of the particle) of greater than 3 : 1, such as greater than 10: 1.
• the grapheme carbon particles have relatively low oxygen content.
• the graphenic carbon particles may, even when having a thickness of no more than 5 or no more than 2 nanometers, have an oxygen content of no more than 2 atomic weight percent, such as no more than 1.5 or 1 atomic weight percent, or no more than 0.6 atomic weight, such as about 0.5 atomic weight percent.
• the oxygen content of the graphenic carbon particles can be determined using X-ray Photoelectron Spectroscopy, such as is described in D. R. Dreyer et al., Chem. Soc. Rev. 39, 228-240 (2010).
• the graphenic carbon particles have a B.E.T. specific surface area of at least 50 square meters per gram, such as 70 to 1000 square meters per gram, or, in some cases, 200 to 1000 square meters per grams or 200 to 400 square meters per gram.
• B.E.T. specific surface area refers to a specific surface area determined by nitrogen adsorption according to the ASTMD 3663-78 standard based on the Brunauer- Emmett-Teller method described in the periodical "The Journal of the American Chemical Society", 60, 309 (1938).
• the graphenic carbon particles have a Raman
• 2D/G peak ratio of at least 1 : 1, for example, at least 1.2: 1 or 1.3 : 1.
• 2D/G peak ratio refers to the ratio of the intensity of the 2D peak at 2692 cm “1 to the intensity of the G peak at 1,580 cm "1 .
• the graphenic carbon particles have a relatively low bulk density.
• the graphenic carbon particles are characterized by having a bulk density (tap density) of less than 0.2 g/cm 3 , such as no more than 0.1 g/cm 3 .
• the bulk density of the graphenic carbon particles is determined by placing 0.4 grams of the graphenic carbon particles in a glass measuring cylinder having a readable scale. The cylinder is raised approximately one-inch and tapped 100 times, by striking the base of the cylinder onto a hard surface, to allow the graphenic carbon particles to settle within the cylinder. The volume of the particles is then measured, and the bulk density is calculated by dividing 0.4 grams by the measured volume, wherein the bulk density is expressed in terms of g/cm 3 .
• the graphenic carbon particles have a compressed density and a percent densification that is less than the compressed density and percent densification of graphite powder and certain types of substantially flat graphenic carbon particles such as those formed from exfoliated graphite.
• Lower compressed density and lower percent densification are each currently believed to contribute to better dispersion and/or rheological properties than grapheme carbon particles exhibiting higher compressed density and higher percent densification.
• the compressed density of the grapheme carbon particles is 0.9 or less, such as less than 0.8, less than 0.7, such as from 0.6 to 0.7.
• the percent densification of the grapheme carbon particles is less than 40%, such as less than 30%, such as from 25 to 30%.
• the compressed density of grapheme carbon particles is calculated from a measured thickness of a given mass of the particles after
• the measured thickness is determined by subjecting 0.1 grams of the grapheme carbon particles to cold press under 15,000 pound of force in a 1.3 centimeter die for 45 minutes, wherein the contact pressure is 500 MPa.
• the compressed density of the grapheme carbon particles is then calculated from this measured thickness according to the following equation:
• the percent densification of the grapheme carbon particles is then determined as the ratio of the calculated compressed density of the graphenic carbon particles, as determined above, to 2.2 g/cm 3 , which is the density of graphite.
• the graphenic carbon particles have a measured bulk liquid conductivity of at least 100 microSiemens, such as at least 120 microSiemens, such as at least 140 microSiemens immediately after mixing and at later points in time, such as at 10 minutes, or 20 minutes, or 30 minutes, or 40 minutes.
• percolation defined as long range interconnectivity, occurs between the conductive graphenic carbon particles. Such percolation may reduce the resistivity of the coating compositions.
• the conductive graphenic particles may occupy a minimum volume within the coating such that the particles form a continuous, or nearly continuous, network. In such a case, the aspect ratios of the graphenic carbon particles may affect the minimum volume required for percolation.
• the graphenic carbon particles may be made by thermal processes.
• thermally produced graphenic carbon particles are made from carbon-containing precursor materials that are heated to high temperatures in a thermal zone such as a plasma.
• the carbon-containing precursor materials are heated to a sufficiently high temperature, e.g., above 3,500°C, to produce graphenic carbon particles having characteristics as described above.
• the carbon-containing precursor such as a hydrocarbon provided in gaseous or liquid form, is heated in the thermal zone to produce the graphenic carbon particles in the thermal zone or downstream therefrom.
• thermally produced graphenic carbon particles may be made by the systems and methods disclosed in U.S. Patent Nos. 8,486,363 and 8,486,364.
• the thermally produced graphenic carbon particles may be made by using the apparatus and method described in U.S. Patent No. 8,486,363 at [0022] to [0048] in which (i) one or more hydrocarbon precursor materials capable of forming a two- carbon fragment species (such as n-propanol, ethane, ethylene, acetylene, vinyl chloride, 1,2- dichloroethane, allyl alcohol, propionaldehyde, and/or vinyl bromide) is introduced into a thermal zone (such as a plasma), and (ii) the hydrocarbon is heated in the thermal zone to form the graphenic carbon particles.
• one or more hydrocarbon precursor materials capable of forming a two- carbon fragment species such as n-propanol, ethane, ethylene, acetylene, vinyl chloride, 1,2- dichloroethane, allyl alcohol, propionaldehyde, and/or vinyl bromide
• the thermally produced graphenic carbon particles may be made by using the apparatus and method described in U.S. Patent No. 8,486,364 at [0015] to [0042] in which (i) a methane precursor material (such as a material comprising at least 50 percent methane, or, in some cases, gaseous or liquid methane of at least 95 or 99 percent purity or higher) is introduced into a thermal zone (such as a plasma), and (ii) the methane precursor is heated in the thermal zone to form the graphenic carbon particles.
• a methane precursor material such as a material comprising at least 50 percent methane, or, in some cases, gaseous or liquid methane of at least 95 or 99 percent purity or higher
• a thermal zone such as a plasma
• Such methods can produce graphenic carbon particles having at least some, in some cases all, of the characteristics described above.
• a carbon-containing precursor is provided as a feed material that may be contacted with an inert carrier gas.
• the carbon-containing precursor material may be heated in a thermal zone, for example, by a plasma system.
• the precursor material is heated to a temperature of at least 3,500°C, for example, from a temperature of greater than 3,500°C or 4,000°C up to 10,000°C or 20,000°C.
• the thermal zone may be generated by a plasma system, it is to be understood that any other suitable heating system may be used to create the thermal zone, such as various types of furnaces including electrically heated tube furnaces and the like.
• the gaseous stream may be contacted with one or more quench streams that are injected into the plasma chamber through at least one quench stream injection port.
• the quench stream may cool the gaseous stream to facilitate the formation or control the particle size or morphology of the graphenic carbon particles.
• the ultrafine particles may be passed through a converging member. After the graphenic carbon particles exit the plasma system, they may be collected. Any suitable means may be used to separate the graphenic carbon particles from the gas flow, such as, for example, a bag filter, cyclone separator or deposition on a substrate.
• the graphenic carbon particles may be obtained from commercial sources, for example, from Angstron, XG Sciences and other commercial sources.
• the commercially available graphenic carbon particles may comprise exfoliated graphite and have different characteristics in comparison with the thermally produced graphenic carbon particles, such as different size distributions, thicknesses, aspect ratios, structural morphologies, oxygen contents, and chemical functionalities at the basal planes/edges.
• the graphenic carbon particles are functionalized.
• “functionalized”, when referring to graphenic carbon particles, means covalent bonding of any non-carbon atom or any organic group to the graphenic carbon particles.
• the graphenic carbon particles may be functionalized through the formation of covalent bonds between the carbon atoms of a particle and other chemical moieties such as carboxylic acid groups, sulfonic acid groups, hydroxyl groups, halogen atoms, nitro groups, amine groups, aliphatic hydrocarbon groups, phenyl groups and the like.
• functionalization with carbonaceous materials may result in the formation of carboxylic acid groups on the graphenic carbon particles.
• the graphenic carbon particles may also be functionalized by other reactions such as Diels-Alder addition reactions, 1,3-dipolar cycloaddition reactions, free radical addition reactions and diazonium addition reactions.
• the hydrocarbon and phenyl groups may be further functionalized. If the graphenic carbon particles already have some hydroxyl functionality, the functionality can be modified and extended by reacting these groups with, for example, an organic isocyanate.
• different types of graphenic carbon particles may be used in the electrodepositable composition.
• a bi-modal distribution, tri-modal distribution, etc. of graphenic carbon particle characteristics may be achieved.
• the graphenic carbon particles contained in the compositions may have multi-modal particle size distributions, aspect ratio distributions, structural morphologies, edge functionality differences, oxygen content, and the like.
• the relative amounts of the different types of graphenic carbon particles are controlled to produce desired conductivity properties of the coatings.
• the thermally produced graphenic particles may comprise from 1 to 50 weight percent, and the commercially available graphenic carbon particles may comprise from 50 to 99 weight percent, based on the total weight of the graphenic carbon particles.
• the thermally produced graphenic carbon particles may comprise from 2 or 4 to 40 weight percent, or from 6 or 8 to 35 weight percent, or from 10 to 30 weight percent.
• co-dispersions of the present invention having such relative amounts of thermally produced graphenic carbon particles and commercially available graphenic carbon particles are incorporated in coatings, inks, or other materials, such materials may exhibit significantly increased electrical conductivities in comparison with similar materials containing mixtures of such types of grapheme carbon particles at similar ratios.
• the co- dispersions may increase electrical conductivity by at least 10 or 20 percent compared with the mixtures.
• the electrical conductivity may be increased by at least 50, 70 or 90 percent, or more.
• the solid particles in addition to the grapheme carbon particles, also comprise lithium-containing particles, such as, mixed metal oxides comprising Li and at least one element selected from Ni, Co, Fe, Mn, Al and P.
• the lithium-containing particles may include LiCo0 2 , LiNi0 2 , LiFeP0 4 , L1C0PO4, LiMnC , LiMn 2 0 4 , Li(NiMnCo)0 2 , and/or Li(NiCoAl)0 2 , wherein the relative amounts of the transition metals may be varied as desired.
• Ni, Mn and Co may not be always in a relative atomic ratio of 1 : 1 : 1 and may contain more nickel such as 5 :3 :2 or 8:2:2 in some embodiments.
• such lithium-containing particles have an average particle size, prior o incorporation into the composition, of no more than 10 micron, no more than 5 micron, no more than 3 micron, no more than 1 micron, such as 10 nanometers to 1,000 nanometers, or, in some eases 500 nanometers to 1,000 nanometers or 600 nanometers to 800 nanometers,
• such lithium-containing solid particles are present in an amount of at least 50 percent by weight, at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, such as at least 85 percent by weight, or, in some cases, at least 90, 93 or 96 percent by weight, based on the total weight of solids in the composition.
• the solid particles comprise lithium-containing particles and grapheme carbon particles
• their relative weight percentages based on the total combined weight of the lithium-containing particles and grapheme carbon particles typically range from 85 to 99.5 weight percent lithium-containing particles and from 0.5 to 15 weight percent grapheme carbon particles, for example, from 90 to 99 weight percent lithium-containing particles and from 1 to 10 weight percent grapheme carbon particles, or from 92 to 98 weight percent lithium-containing particles and from 2 to 8 weight percent grapheme carbon particles.
• the compositions may comprise additional electrically conductive particles, such as electrically conductive carbon particles.
• additional electrically conductive particles include electrically conductive carbon blacks, acetylene blacks, carbon nano tubes, carbon fibers, fullerenes and the like.
• Examples of commercially available electrically conductive carbon blacks include, but are not limited to, Cabot MonarchTM 1300, Cabot XC-72R, Cabot LiTX 50, Cabot LiTX 200, Cabot LiTX 300, Denka Black HS-100L, Black Pearls 2000 and Vulcan XC 72 sold by Cabot Corporation; Acheson ElectrodagTM 230 sold by Acheson Colloids Co.; Columbian RavenTM 3500 sold by Columbian Carbon Co.; and PrintexTM XE 2, Printex 200, Printex L and Printex L6 sold by DeGussa Corporation, Pigments Group, and Super P® and Super P® Li, C-NergyTM Super C45 and C-NergyTM Super C65 sold by TIMCAL Ltd.
• the electrically conductive carbon black used in the compositions described herein has an average primary particle size, prior to incorporation into the composition, of less than 300 nanometers, such as 1 to 200 nanometers, 10 to 100 nanometers, or, in some cases, 30 to 50 nanometers.
• metal-coated particles are commercially available from Advanced Ceramics Corp.
• Other metal-coated particles which may be used include ceramic microballoons, chopped glass fibers, graphite powder and flake, boron nitride, mica flake, copper powder and flake, nickel powder and flake, aluminum coated with metals such as carbon, copper, nickel, palladium, silicon, silver and titanium coatings. These particles are typically metal-coated using fluidized bed chemical vacuum deposition techniques.
• Such metal-coated particles are commercially available from Powdermet, Inc. Mixtures of different electrically conductive particles can be used.
• the electrically conductive particles are present in the composition in an amount such that the relative weight ratio of lithium-containing particles to the grapheme carbon particles or other electrically conductive particles in the composition is at least 3 : 1, at least 4: 1, at least 5: 1, at least 8: 1, at least 10: 1, or, in some cases, at least 15: 1, or at least 30: 1, or at least 45: 1, or at least 60: 1.
• such electrically conductive particles are present in an amount of no more than 20 percent by weight, no more than 10 percent by weight, such as 1 to 10 percent by weight, or 1 to 5 percent by weight, based on the total weight of the solids in the composition.
• solid particles may be included in the electrodepositable materials.
• Such solid particles can be polymeric and/or non-polymeric inorganic materials, polymeric and/or non-polymeric organic materials, composite materials, as well as mixtures of any of the foregoing.
• polymer is meant to encompass oligomers, and includes without limitation both homopolymers and copolymers,
• polymeric inorganic material means a polymeric material having a backbone repeat unit based on an element or elements other than carbon.
• polymeric organic materials means synthetic polymeric materials, semi-synthetic polymeric materials and natural polymeric materials, all of which have a backbone repeat unit based on carbon.
• organic material means carbon containing compounds wherein the carbon is typically bonded to itself and to hydrogen, and often to other elements as well, and excludes binary compounds such as the carbon oxides, the carbides, carbon disulfide, etc.; such ternary compounds as the metallic cyanides, metallic carbonyls, phosgene, carbonyl sulfide, etc.; and carbon-containing ionic compounds such as metallic carbonates, for example calcium carbonate and sodium carbonate.
• inorganic material means any material that is not an organic material.
• composite material means a combination of two or more differing materials.
• the particles formed from composite materials may have a hardness at their surface that is different from the hardness of the internal portions of the particle beneath its surface. More specifically, the surface of the particle can be modified in any manner well known in the art, including, but not limited to, chemically or physically changing its surface
• a particle can be formed from a primary material that is coated, clad or encapsulated with one or more secondary materials to form a composite particle that has a softer surface.
• particles formed from composite materials can be formed from a primary material that is coated, clad or encapsulated with a different form of the primary material.
• the solid particles can include any of a variety of inorganic materials, such as ceramic materials, metallic materials, and mixtures of any of the foregoing.
• ceramic materials can comprise metal oxides, mixed metal oxides, metal nitrides, metal carbides, metal sulfides, metal silicates, metal borides, metal carbonates, and mixtures of any of the foregoing.
• a specific, non-limiting example of a metal nitride is boron nitride; a specific, non-limiting example of a metal oxide is zinc oxide; non- limiting examples of suitable mixed metal oxides are aluminum silicates and magnesium silicates; non-limiting examples of suitable metal sulfides are molybdenum disulfide, tantalum disulfide, tungsten disulfide, and zinc sulfide; non-limiting examples of metal silicates are aluminum silicates and magnesium silicates, such as vermiculite.
• the solid particles comprise inorganic materials selected from aluminum, barium, bismuth, boron, cadmium, calcium, cerium, cobalt, copper, iron, lanthanum, magnesium, manganese, molybdenum, phosphorus, selenium, silicon, silver, sulfur, tin, titanium, tungsten, vanadium, yttrium, zinc, and zirconium, including oxides thereof, nitrides thereof, phosphides thereof; phosphates thereof, selenides thereof;
• Suitable non-limiting examples of the foregoing inorganic particles include alumina, silica, titania, cera, zirconia, bismuth oxide, magnesium oxide, iron oxide, aluminum silicate, boron carbide, nitrogen doped titania, and cadmium selenide.
• the solid particles used in the present invention have a lamellar structure.
• Particles having a lamellar structure are composed of sheets or plates of atoms or particles in a hexagonal array.
• a non-limiting example of a lamellar structure is a hexagonal crystal structure.
• Inorganic solid particles having a lamellar fullerene buckyball) structure are also useful.
• Non-limiting examples of suitable materials having a lamellar structure include boron nitride, graphite, metal dichalcogenides, mica, tale, gypsum, kaolinite, calcite, cadmium iodide, silver sulfide and mixtures thereof.
• Suitable metal dichalcogenides include molybdenum disulfide, molybdenum disclenide, tantalum disulfide, tantalum diselenide, tungsten disulfide, tungsten diselenide and mixtures thereof.
• the solid particles can be formed from non-polymeric, organic material.
• non-polymeric, organic materials useful in the present invention include, but are not limited to, stearates (such as zinc stearate and aluminum stearate), diamond, carbon black and stearamide.
• the solid particles comprise an organic pigment, such as for example, azo compounds (monoazo, di-azo, ⁇ -Naphthol, Naphthol AS, azo pigment lakes, benzimidazolone, di-azo condensation, metal complex, isoindolinone, isoindoline), and polycyclic (phthalocyaninc, quinacridone, perylene, perinone, diketopyrrolo pyrrole, thioindigo, anthraquinone, indanthrone, anthrapyrimidine, flavanthrone, pyranthrone, anthanthrone, dioxazine, triarylcarbonium, quinophthalone) pigments, and mixtures of any of the foregoing.
• azo compounds monoazo, di-azo, ⁇ -Naphthol, Naphthol AS, azo pigment lakes, benzimidazolone, di-azo condensation, metal complex, isoindolinone, isoindoline
• the additional solid particles described above have an average particle size of less than 100 microns prior to incorporation into the composition, such as less than 50 microns prior to incorporation into the composition. In certain embodiments, the solid particles have an average particle size ranging from 1 to 10,000 nanometers prior to incorporation into the composition, 1 to 1000 nanometers prior to incorporation into the composition, or 1 to 100 nanometers prior to incorporation into the composition.
• the average particle size of the solid particles is at least about one micron
• the average particle size can be measured according to known laser scattering techniques.
• the average particle size of such particles can be measured using a Horiba Model LA 900 laser diffraction particle size instrument, which uses a helium- neon laser with a wave length of 633 nm to measure the size of the particles and assumes the particle has a spherical shape, i.e., the "particle size" refers to the smallest sphere that will completely enclose the particle.
• the average particle size of the solid particles is less than or equal to one micron
• the average particle size can be determined by visually examining an electron micrograph of a transmission electron microscopy ("TEM") image, measuring the diameter of the particles in the image, and calculating the average particle size based on the magnification of the TEM image.
• TEM transmission electron microscopy
• the diameter of the particle refers to the smallest diameter sphere that will completely enclose the particle.
• the composition may include other typical ingredients, such as corrosion inhibitors, anti-oxidants, flow control agents, surfactants and the like.
• the electrodepositable compositions described above can be prepared in any desired manner, including the methods described in the Examples.
• Exemplary ionic resins suitable for this purpose include the water soluble resins mentioned above.
• the solids content of such a composition may be relatively high, such as 2 times, 3 times, or 4 times or more the total solids content of the composition in the methods of the present invention.
• the composition may be mixed, such as by sonification, to provide a uniform dispersion. This sonication may take 15 to 30 minutes or more.
• the resulting composition may then subsequently be combined with further liquid carrier, i.e., water and optionally organic solvent, to provide the final composition for use in the methods of the present invention.
• the substrate is immersed in a composition that has a weight ratio of solid particles to ionic resin of at least 4: 1, such as at least 5: 1, at least 6: 1, at least 7: 1, at least 8: 1, at least 9: 1, at least 10: 1, at least 11 : 1, at least 12: 1, at least 13 : 1, at least 14: 1, at least 15: 1, at least 16: 1, at least 17: 1, or higher.
• the solid particles may comprise from 0.05 to 100 weight percent grapheme carbon particles, for example, from 0.1 to 10 weight percent, or from 0.1 to 5 weight percent.
• the substrate is immersed in a composition that has a total solids content of 0.5 to 25 percent by weight, such as 1 to 10 percent by weight, or, in some cases, 1 to 5 percent by weight, based on the total weight of the composition.
• a composition that has a total solids content of 0.5 to 25 percent by weight, such as 1 to 10 percent by weight, or, in some cases, 1 to 5 percent by weight, based on the total weight of the composition.
• stable dispersion refers to a dispersion that does not gel, flocculate or precipitate when maintained at a temperature of 25°C for at least 60 days, or, if some precipitation does occur, the precipitate can be redispersed upon agitation.
• a coating is applied onto or over at least a portion of the substrate via an electrodeposition process.
• an electrically conductive substrate (such as any of those described earlier) serving as an electrode (such as an anode in anionic electrodeposition) in an electrical circuit comprising the electrode and a counter-electrode (such as a cathode in anionic electrodeposition)
• a composition of the type described above is immersed a composition of the type described above.
• An electric current is passed between the electrodes to cause the coating to deposit on the substrate.
• the applied voltage may be varied and can be, for example, as low as one volt to as high as several thousand volts, but is often between 50 and 500 volts.
• the current density is often between 0.5 ampere and 15 amperes per square foot.
• the residence time of the substrate in the composition is from 30 to 180 seconds.
• the substrate is removed from the bath and may, in certain embodiments and depending upon the particulars of the composition and the preferences of the end user, be baked in an oven.
• the coated substrate may be baked at temperatures of 225°F or lower, such as 200°F or lower for 10 to 60 minutes. In other cases, after
• the coated substrate may simply be allowed to dry under ambient conditions.
• ambient conditions refers to atmospheric air having a relative humidity of 10 to 100 percent and a temperature in the range of -10 to 120°C, such as 5 to 80°C, in some eases 10 to 60°C and, in yet other cases, 15 to 40°C.
• the present invention is directed to methods comprising: immersing an electrically conductive substrate into an electrodepositable composition, the substrate serving as an electrode in an electrical circuit comprising the electrode and a counter-electrode immersed in the composition, a coating being applied onto or over at least a portion of the substrate as electric current is passed between the electrodes, the electrodepositable composition comprising: (a) an aqueous medium; (b) an ionic resin; and (c) solid particles comprising grapheme carbon particles, wherein the composition has a weight ratio of solid particles to ionic resin of at least 4: 1.
• the substrate is a foil comprising aluminum, iron, copper, manganese, nickel, a combination thereof, and/or an alloy thereof, wherein any of these foils may have a thickness of no more than 8 mils (203.2 ⁇ ), such as no more than 4 mils (101.6 ⁇ ), no more than 2 mils (50.8 ⁇ ), or, in some eases no more than 1 mil (25.4 ⁇ ), and/or at least 0.1 mil (2.54 ⁇ ), such as at least 0.2 mil (5.08 ⁇ ), at least 0.4 mils (10.2 ⁇ ), or at least 0.5 mil (12.7 ⁇ ).
• the present invention is also directed to any method set forth in this paragraph, wherein the aqueous medium either consists exclusively of water or comprises predominantly water in combination with inert organic cosolvent(s), such as organic cosolvents that are at least partially soluble with water, such as oxygenated organic solvents, such as monoalkyl ethers of ethylene glycol, diethylene glycol, propylene glycol, and dipropylene glycol which contain from 1 to 10 carbon atoms in the alkyl group, such as the monoethyl and monobutyl ethers of these glycols and alcohols, such as ethanol, isopropanol, butanol and diacetone alcohol.
• organic cosolvents such as organic cosolvents that are at least partially soluble with water
• oxygenated organic solvents such as monoalkyl ethers of ethylene glycol, diethylene glycol, propylene glycol, and dipropylene glycol which contain from 1 to 10 carbon atoms in the alkyl group, such as the monoeth
• the present invention is also directed to any method set forth in this paragraph, wherein an organic cosolvent is present in an amount of less than 25 percent by weight, less than 20 percent by weight, or, in some cases, less than 10 percent by weight, such as less than 5 percent by weight, based on total weight of water in the electrodepositable
• the present invention is also directed to any method set forth in this paragraph, wherein the aqueous medium is present in the electrodepositable composition in an amount of at least 75 percent by weight, at least 90 percent by weight, or at least 95 percent by weight, such as 75 to 99.5 percent by weight, 90 to 99 percent by weight, or, in some cases, 95 to 99 percent by weight, based on the total weight of the composition.
• the ionic resin comprises an anionic resin, such as a base-neutralized, carboxylic acid group-containing resin, such as where the base-neutralized, carboxylic acid group-containing resin is water soluble, such as where the water soluble resin comprises a cellulose derivative, such as an alkali salt of a carboxymethylcellulose, such as a carboxymethylcellulose having a weight average molecular weight of at least 50,000, at least 100,000, at least 200,000, such as 50,000 to 1,000,000, 100,000 to 500,000 or 200,000 to 300,000.
• an anionic resin such as a base-neutralized, carboxylic acid group-containing resin
• the base-neutralized, carboxylic acid group-containing resin is water soluble
• the water soluble resin comprises a cellulose derivative, such as an alkali salt of a carboxymethylcellulose, such as a carboxymethylcellulose having a weight average molecular weight of at least 50,000, at least 100,000, at least 200,000, such as 50,000 to 1,000,000, 100,000 to 500,000 or 200,000
• the present invention is also directed to any method set forth in this paragraph, wherein a water soluble resin is present in the composition in an amount of at least 50 percent by weight, such as at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, or at least 90 percent by weight, the weight percent being based on the total weight of resin in the composition.
• the present invention is also directed to any method set forth in this paragraph, wherein a water soluble resin is present in the composition in an amount of no more than 20 percent by weight, such as no more than 15 percent by weight, no more than 10 percent by weight, no more than 5 percent by weight, such as 1 to 20 percent by weight, 1 to 15 percent by weight, 5 to 15 percent by weight, or 1 to 3 percent by weight, the weight percent being based on the total weight of solids in the composition.
• the present invention is also directed to any method set forth in this paragraph, wherein the solid particles comprise lithium-containing particles, such as lithium-containing particles comprising mixed metal oxides comprising Li and at least one element selected from Ni, Co, Fe, Mn, Al and P.
• the lithium- containing particles may include LiCoC , LiM0 2 , LiFeP0 4 , LiCoP0 4 , LiMn0 2 , LiMn 2 04, Li(NiMnCo)0 2 , and/or Li(NiCoAl)0 2 , wherein the relative amounts of the transition metals may be varied as desired.
• Ni, Mn and Co may not be always in a relative atomic ratio of 1 : 1 : 1 and may contain more nickel such as 5:3 :2 or 8:2:2.
• the present invention is also directed to any method set forth in this paragraph, wherein lithium-containing particles are present in an amount of at least 50 percent by weight, at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, at least 85 percent by weight, or at least 90 percent by weight, based on the total weight of the solids in the composition.
• the present invention is also directed to any method set forth in this paragraph, wherein the solid particles comprise electrically conductive particles, such as grapheme carbon particles, or grapheme carbon particles in combination with other electrically conductive carbon particles, such as electrically conductive carbon black.
• the present invention is also directed to any method set forth in this paragraph, wherein a relative weight ratio of lithium-containing particles to electrically conductive grapheme carbon particles in the composition is at least 3 : 1, at least 4: 1, at least 5: 1, at least 8: 1, at least 10: 1, or at least 15: 1, or at least 30: 1, or at least 45: 1, or at least 60: 1.
• the present invention is also directed to any method set forth in this paragraph, wherein electrically conductive graphenic carbon particles are present in an amount of no more than 20 percent by weight, no more than 10 percent by weight, such as 1 to 10 percent by weight or 1 to 5 percent by weight, based on the total weight of the solids in the composition.
• the present invention is also directed to any method set forth in this paragraph, wherein the electrodepositable composition has a weight ratio of solid particles to ionic resin of at least 5: 1, at least 6: 1, at least 7: 1, at least 8: 1, at least 9: 1, at least 10: 1, at least 11 : 1, at least 12: 1, at least 13 : 1, at least 14: 1, at least 15: 1, at least 16: 1, or at least 17: 1.
• the weight ratio of solid particles to ionic resin may be at least 45: 1, or at least 60: 1.
• the present invention is also directed to any method set forth in this paragraph, wherein the electrodepositable composition has a total solids content of 0.5 to 25 percent by weight, such as 1 to 10 percent by weight, such as 1 to 5 percent by weight, based on the total weight of the composition.
• the present invention is also directed to electrodepositable compositions comprising: (a) an aqueous medium; (b) an ionic resin; and (c) solid particles comprising: (i) graphenic carbon particles, and (ii) lithium-containing particles, wherein the composition has a weight ratio of solid particles to ionic resin of at least 4: 1.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein the composition has a weight ratio of solid particles to ionic resin of at least 4: 1, at least 5: 1, at least 6: 1, at least 7: 1, at least 8: 1, at least 9: 1, at least 10: 1, at least 11 : 1, at least 12: 1, at least 13 : 1, at least 14: 1, at least 15: 1, at least 16: 1, or at least 17: 1, or at least 45: 1, or at least 60: 1.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein the aqueous medium either consists exclusively of water or comprises predominantly water in combination with inert organic cosolvent(s), such as organic cosolvents that are at least partially soluble with water, such as oxygenated organic solvents, such as monoalkyl ethers of ethylene glycol, diethylene glycol, propylene glycol, and dipropylene glycol which contain from 1 to 10 carbon atoms in the alkyl group, such as the monoethyl and monobutyl ethers of these glycols and alcohols, such as ethanol, isopropanol, butanol and diacetone alcohol.
• organic cosolvents such as organic cosolvents that are at least partially soluble with water
• oxygenated organic solvents such as monoalkyl ethers of ethylene glycol, diethylene glycol, propylene glycol, and dipropylene glycol which contain from 1 to 10 carbon atoms in the alkyl group, such as the
• At least partially water-miscible solvents may include coalescing solvents such as triethyl phosphate, triacetin, dipropylene diacetate, and the like.
• coalescing solvents such as triethyl phosphate, triacetin, dipropylene diacetate, and the like.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein an organic cosolvent is present in an amount of less than 25 percent by weight, less than 20 percent by weight, or, in some cases, less than 10 percent by weight, such as less than 5 percent by weight, based on total weight of water in the electrodepositable composition.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein the aqueous medium is present in the
• electrodepositable composition in an amount of at least 75 percent by weight, at least 90 percent by weight, or at least 95 percent by weight, such as 75 to 99.5 percent by weight, 90 to 99 percent by weight, or, in some cases, 95 to 99 percent by weight, based on the total weight of the composition.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein the ionic resin comprises an anionic resin, such as a base- neutralized, carboxylic acid group-containing resin, such as where the base-neutralized, carboxylic acid group-containing resin is water soluble, such as where the water soluble resin comprises a cellulose derivative, such as an alkali salt of a carboxymethylcellulose, such as a carboxymethylcellulose having a weight average molecular weight of at least 50,000, at least 100,000, at least 200,000, such as 50,000 to 1,000,000, 100,000 to 500,000 or 200,000 to 300,000.
• an anionic resin such as a base- neutralized, carboxylic acid group-containing resin
• the base-neutralized, carboxylic acid group-containing resin is water soluble
• the water soluble resin comprises a cellulose derivative, such as an alkali salt of a carboxymethylcellulose, such as a carboxymethylcellulose having a weight average molecular weight of at least 50,000, at least 100,000, at least
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein a water soluble resin is present in the composition in an amount of at least 50 percent by weight, such as at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, or at least 90 percent by weight, the weight percent being based on the total weight of resin in the composition.
• a water soluble resin is present in the composition in an amount of at least 50 percent by weight, such as at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, or at least 90 percent by weight, the weight percent being based on the total weight of resin in the composition.
• Electropositable composition set forth in this paragraph wherein a water soluble resin is present in the composition in an amount of no more than 20 percent by weight, has no more than 15 percent by weight, no more than 10 percent by weight, no more than 5 percent by weight, such as 1 to 20 percent by weight, 1 to 15 percent by weight, 5 to 15 percent by weight, or 1 to 3 percent by weight, the weight percent being based on the total weight of solids in the composition.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein the lithium-containing particles comprise mixed metal oxides comprising Li and at least one element selected from Ni, Co, Fe, Mn, Al and P.
• the lithium-containing particles may include LiCo0 2 , LiNiC , LiFeP0 4 , LiCoP0 4 , LiMn0 2 , LiMn 2 04, Li(NiMnCo)0 2 , and/or Li(NiCoAl)0 2 , wherein the relative amounts of the transition metals may be varied as desired.
• Ni, Mn, and Co may not be always in a ratio of 1 : 1 : 1 or 3 :3 :3 and may contain more nickel such as 5:3 :2 or as high as 8:2:2.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein lithium-containing particles are present in an amount of at least 50 percent by weight, at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, at least 85 percent by weight, or at least 90 percent by weight, based on the total weight of the solids in the composition.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein a relative weight ratio of lithium-containing particles to grapheme carbon particles in the composition is at least 3 : 1, at least 4: 1, at least 5: 1, at least 8: 1, at least 10: 1, or at least 15: 1, or at least 30: 1, or at least 45: 1, or at least 60: 1.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein the graphenic carbon particles are present in an amount of no more than 20 percent by weight, no more than 10 percent by weight, such as 1 to 10 percent by weight or 1 to 5 percent by weight, based on the total weight of the solids in the composition.
• the present invention is also directed to any electrodepositable composition set forth in this paragraph, wherein the electrodepositable composition has a total solids content of 0.5 to 25 percent by weight, such as 1 to 10 percent by weight, such as 1 to 5 percent by weight, based on the total weight of the composition.
• the present invention is also directed to a lithium ion battery electrode coating electrodeposited on a substrate, the electrodeposited coating comprising: (a) a cured ionic resin; and (b) solid particles comprising: (i) graphenic carbon particles; and (ii) lithium-containing particles, wherein the coating has a weight ratio of solid particles to cured ionic resin of at least 4: 1.
• the present invention is also directed to any electrodepositable coating set forth in this paragraph, wherein the coating has a weight ratio of solid particles to ionic resin of at least 4: 1, at least 5: 1, at least 6: 1, at least 7: 1, at least 8: 1, at least 9: 1, at least 10: 1, at least 11 : 1, at least 12: 1, at least 13 : 1, at least 14: 1, at least 15: 1, at least 16: 1, or at least 17: 1, or at least 45: 1, or at least 60: 1.
• the present invention is also directed to any electrodepositable coating set forth in this paragraph, wherein a water soluble resin is present in the coating in an amount of no more than 20 percent by weight, has no more than 15 percent by weight, no more than 10 percent by weight, no more than 5 percent by weight, such as 1 to 20 percent by weight, 1 to 15 percent by weight, 5 to 15 percent by weight, or 1 to 3 percent by weight, the weight percent being based on the total weight of solids in the coating.
• a water soluble resin is present in the coating in an amount of no more than 20 percent by weight, has no more than 15 percent by weight, no more than 10 percent by weight, no more than 5 percent by weight, such as 1 to 20 percent by weight, 1 to 15 percent by weight, 5 to 15 percent by weight, or 1 to 3 percent by weight, the weight percent being based on the total weight of solids in the coating.
• the present invention is also directed to any electrodepositable coating set forth in this paragraph, wherein a water soluble resin is present in the coating in an amount of no more than
• the lithium-containing particles comprise mixed metal oxides comprising Li and at least one element selected from Ni, Co, Fe, Mn, Al and P.
• the lithium-containing particles may include LiCoC , LiNiC , LiFeP0 4 , LiCoP0 4 , LiMnOi, LiMn 2 0 4 , Li(NiMnCo)0 2 , and/or Li(NiCoAl)0 2 , wherein the relative amounts of the transition metals may be varied as desired.
• Ni, Mn, and Co may not be always in a ratio of 1 : 1 : 1 or 3 :3 :3 and may contain more nickel such as 5 :3 :2 or as high as 8:2:2.
• the present invention is also directed to any electrodepositable coating set forth in this paragraph, wherein lithium-containing particles are present in an amount of at least 50 percent by weight, at least 60 percent by weight, at least 70 percent by weight, at least 80 percent by weight, at least 85 percent by weight, or at least 90 percent by weight, based on the total weight of the solids in the coating.
• the present invention is also directed to any electrodepositable coating set forth in this paragraph, wherein a relative weight ratio of lithium-containing particles to graphenic carbon particles in the coating is at least 3 : 1, at least 4: 1, at least 5: 1, at least 8: 1, at least 10: 1, or at least 15: 1, or at least 30: 1, or at least 45: 1, or at least 60: 1.
• the present invention is also directed to any electrodepositable coating set forth in this paragraph, wherein the graphenic carbon particles are present in an amount of no more than 20 percent by weight, no more than 10 percent by weight, such as 1 to 10 percent by weight or 1 to 5 percent by weight, based on the total weight of the solids in the coating.
• the present invention is also directed to any electrodepositable coating set forth in this paragraph, wherein the electrodepositable coating has a total solids content of 0.5 to 25 percent by weight, such as 1 to 10 percent by weight, such as 1 to 5 percent by weight, based on the total weight of the coating.
• a viscosity of 470 cps at 2 weight percent concentration estimates a calculated molecular weight of 267,500 using the equation above.
• TPG thermally produced grapheme
• 4.2 grams of thermally produced grapheme (TPG) carbon particles produced in the thermal zone of a plasma reactor in accordance with the method described in U.S. Patent No. 8,486,364 using methane as a precursor material was added and then the mixture was sonicated for 25 minutes.
• 14.75 g of LiFeP0 4 (“LFP", Life Power® P2 commercially available from Phostech Lithium Inc.) was added in 4 equivalent portions with each addition followed by 5 minutes of sonication.
• a coating was prepared according to the same procedure as Example 1, except the thermally produced graphenic carbon particles were functionalized by the following procedure.
• Maleic anhydride (1.5 g) was dissolved in Aromatic 150 solvent (423 g) and the plasma produced TPGs (7.5 g) were added.
• the mixture was ultra- sonicated for 1 hour, then heated to 180°C under nitrogen with stirring and held for 4 hours.
• the mixture was cooled, filtered and the product was washed well with acetone and dried.
• the product was screened through a 100 mesh screen.
• Jeffamine M-2005 14 g was dissolved in 300 g of toluene, and 7 g of the TPG product was added with stirring and the mixture ultra-sonicated for 1 hour.
• the mixture was transferred to a reaction flask with 300 g of additional toluene, heated to 100°C with stirring under nitrogen and held for 2 hours. After cooling, the mixture was filtered, washed with toluene then acetone, redispersed in acetone then filtered and washed with acetone and dried. The product was screened through a 100 mesh screen. The functionalized graphenic carbon particles were then combined with lithium-containing particles and ionic resin in a similar manner as described in Example 1 and electrodeposited. The coating was 35 microns thick.

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