EP3323624B1 - Haftendes mikroporöses transfermaterial - Google Patents
Haftendes mikroporöses transfermaterial Download PDFInfo
- Publication number
- EP3323624B1 EP3323624B1 EP16199112.0A EP16199112A EP3323624B1 EP 3323624 B1 EP3323624 B1 EP 3323624B1 EP 16199112 A EP16199112 A EP 16199112A EP 3323624 B1 EP3323624 B1 EP 3323624B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- transfer material
- ink
- receiving layer
- transfer
- material according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000012546 transfer Methods 0.000 title claims description 82
- 239000000463 material Substances 0.000 title claims description 61
- 230000001070 adhesive effect Effects 0.000 title description 8
- 239000000853 adhesive Substances 0.000 title description 7
- 239000002245 particle Substances 0.000 claims description 56
- 229920001169 thermoplastic Polymers 0.000 claims description 32
- 239000004416 thermosoftening plastic Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 25
- 230000004888 barrier function Effects 0.000 claims description 24
- 238000000859 sublimation Methods 0.000 claims description 20
- 230000008022 sublimation Effects 0.000 claims description 18
- 239000011230 binding agent Substances 0.000 claims description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 12
- 230000035699 permeability Effects 0.000 claims description 11
- 229920000728 polyester Polymers 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920003169 water-soluble polymer Polymers 0.000 claims 1
- 239000010410 layer Substances 0.000 description 76
- 239000000123 paper Substances 0.000 description 67
- 239000004753 textile Substances 0.000 description 30
- 239000000976 ink Substances 0.000 description 25
- 238000007639 printing Methods 0.000 description 17
- 238000001035 drying Methods 0.000 description 16
- 239000000975 dye Substances 0.000 description 12
- 239000002998 adhesive polymer Substances 0.000 description 10
- 238000007641 inkjet printing Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000000835 fiber Substances 0.000 description 9
- 239000008199 coating composition Substances 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- -1 fatty acid salts Chemical class 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 235000019698 starch Nutrition 0.000 description 6
- 239000008107 starch Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- ZINJLDJMHCUBIP-UHFFFAOYSA-N ethametsulfuron-methyl Chemical compound CCOC1=NC(NC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC)=N1 ZINJLDJMHCUBIP-UHFFFAOYSA-N 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000007766 curtain coating Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000010023 transfer printing Methods 0.000 description 3
- 244000166124 Eucalyptus globulus Species 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000005092 sublimation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 101100229963 Drosophila melanogaster grau gene Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 240000003433 Miscanthus floridulus Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000011436 cob Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
- B41M5/0355—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the macromolecular coating or impregnation used to obtain dye receptive properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
- B41M5/506—Intermediate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
- D06P5/004—Transfer printing using subliming dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/02—Dye diffusion thermal transfer printing (D2T2)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/38—Intermediate layers; Layers between substrate and imaging layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/42—Multiple imaging layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5272—Polyesters; Polycarbonates
Definitions
- the invention relates to a sheet-like transfer material for the dye-sublimation transfer process of an inkjet print image with a support and a dye-receiving layer on the front side that is slightly adhering to the receiving material during transfer. It therefore relates to a transfer paper, which is provided for printing with sublimable dyes by the inkjet printing process and from which the dyes are transferred under heat influence to a receiving material by sublimation after printing.
- the invention also relates to the method for transferring an inkjet print image from the transfer paper according to the invention to an example textile receiving material.
- transfer printing For printing on materials such as textiles or rigid bodies, which are difficult to print for mechanical reasons by direct printing process, offer transfer printing, in which initially printed on a flexible sheet-shaped transfer material and the printed image is transferred from this to the object to be printed.
- a particular embodiment of such a transfer printing process is the dye sublimation process, which is described, for example, in US Pat Thompson: Printing Materials - Science and Technology (1998) on page 468 is described.
- the image to be printed on the transfer material is applied using printing inks, which are evaporated after the drying of the print under the action of heat and imagewise on the gas phase on the final material to be printed again.
- the sublimation inks can be advantageously applied to the transfer material by digital printing, especially the inkjet printing process, resulting in individualized and personalized prints for Example on textiles allows.
- the transfer material on which the first printing step takes place by means of inkjet printing technology is preferably a paper transfer material.
- a paper transfer material In the EP 1101 682 A1 is a coated paper described, which has a low air permeability on the side to be printed. This is to avoid that in the sublimation transfer step, a part of the sublimable dyes penetrates into the porous paper interior and thus lost for transfer to the final material to be printed.
- such papers with a low porosity on the page to be printed take up the inkjet ink liquid only very slowly and lead to slow drying and bleeding of the ink on the surface and thus to an unsatisfactory print sharpness, especially at high printing speeds.
- tacy transfer papers are products that adhere to the textiles under the transfer conditions in the sublimation process. These products are used in particular for stretchable (knitted) textiles to prevent ghosting and to reduce the reject rate in textile printing.
- a typical application is the printing of sports textiles. Consequently, this type of adhesion involves preventing displacement of the print carrier relative to the receiving material arranged on the print substrate or vice versa.
- thermal transfer paper is also in the DE 10 2014 116550 A1 described.
- it proposes to use thermoplastic particles having a melting point of 35 ° C to 150 ° C having an average particle size of 0.3 to 5 ⁇ m in the thermal transfer layer. Due to the thermoplastic particles, the adhesion of the thermal sublimation paper is to be optimized when printing on flat textiles.
- the thermal transfer layer of this document has a binder content of 55 to 80% otro and may also contain pigments. In the case of this binder fraction in the thermal transfer layer, even in the presence of pigments, a closed film-like and therefore no porous layer is present.
- a disadvantage of the procedure described here is therefore that the drying rate is substantially lower than that when using microporous layers and also a large amount of thermoplastic particles must be used in order to obtain a noticeable adhesion effect at all. This can severely affect the print quality (line sharpness) and the transfer quality (optical densities on textile). It is also not possible with this approach to control the textile adhesion regardless of the printing and transfer quality.
- the invention has for its object to provide a transfer paper for the inkjet printing of sublimable dyes with a fast-drying (microporous) transfer layer and excellent adhesion to textile materials.
- a transfer material for the dye sublimation transfer method of an inkjet print image with a support and a pigment and binder-containing ink receiving layer on the front side of the transfer material wherein the ink receiving layer is porous and on the Ink receptive layer thermoplastic particles are arranged, wherein the porous ink receiving layer with the thermoplastic particles arranged thereon together has a Bendtsen air permeability of greater than 100 ml / min and wherein the thermoplastic particles have a diameter of 0.3 .mu.m to 5 .mu.m and a melting point of 60 ° C. have up to 170 ° C.
- the transfer material may include a barrier layer disposed either on the back side of the transfer material or between the support and the porous ink receiving layer.
- the invention further relates to a method for transferring an image to a surface by printing an inventive transfer material with an image by the inkjet printing process and transfers the image to the surface by sublimation.
- Advantages of the invention are a lower necessary amount of thermoplastic particles, better control of tack or adhesion, little influence on the print and image transfer quality, very fast drying and independent control of the print quality and the textile adhesion.
- this approach it is possible to achieve significantly higher adhesive forces with good print quality, if this is necessary. For example, it is possible to achieve not only adhesion to knitted (stretchable) textiles, but also to woven textiles.
- the transfer papers according to the invention comprise a paper support having at least pressure side applied adhesive polymer particles and an underlying porous ink receiving layer.
- a barrier layer is disposed between the ink receptive layer and the paper support, or preferably on the surface of the paper support opposite the ink receptive layer.
- the backing paper is preferably an uncoated or surface sized paper.
- the backing paper may be in addition to pulp fibers, sizing agents such as Alkylkend dimers, fatty acids and / or fatty acid salts, epoxidized fatty acid amides, alkenyl or Alkyl succinic anhydride, starch, tree resins, wet strength agents such as polyamine-polyamide-epichlorohydrin, dry strength agents such as anionic, cationic or amphoteric polyamides, optical brighteners, pigments, dyes, defoamers, and other chemical additives known in the paper industry.
- the base paper can be surface-sized. Examples of suitable sizing agents are polyvinyl alcohol or oxidized starch.
- the base paper can be produced on a Fourdrinier or a Yankee paper machine (cylinder paper machine).
- the basis weight of the base paper may be 30 to 200 g / m 2 , in particular 40 to 120 g / m 2 .
- the raw paper can be used in uncompacted or compacted form (smoothed).
- Particularly suitable are base papers with a density of 0.6 to 1.05 g / cm 3 , in particular 0.70 to 0.9 g / cm 3 .
- the smoothing can be done in the usual way with a calendering.
- the pulp for papermaking is preferably a eucalyptus pulp with a pulp content of less than 200 microns after grinding of 10 to 35 wt .-% and an average fiber length of 0.5 to 0.75 mm. It has been found that the use of a pulp with a limited proportion of fibers smaller than 200 microns reduces the loss of stiffness occurring when using filler.
- Hardwood pulps (NBHK - Northern Bleached Hardwood Kraft Pulp) and softwood pulps may also be used.
- pulp fibers it is also possible to use fractions of other natural or synthetic fibers for the production of the backing paper.
- the proportion of the other fibers in the total fiber mass is below 40 wt .-%, particularly preferred proportions of other fibers below 20 wt .-%.
- kaolins calcium carbonate in its natural form such as limestone, marble or dolomite, precipitated calcium carbonate, calcium sulfate, barium sulfate, titanium dioxide, talc, silica, alumina and mixtures thereof can be used in the base paper.
- Particularly suitable is calcium carbonate with a particle size distribution in which at least 60% of the particles smaller than 2 microns and at most 40% are smaller than 1 micron.
- calcite is used with a numerical particle size distribution, in which about 25% of the particles have a particle size of less than 1 micron and about 85% of the particles have a particle size of less than 2 microns.
- a calcium carbonate having a numerical particle size distribution can be used in which at least 70%, preferably at least 80%, of the particles are smaller than 2 ⁇ m and at most 70% of the particles are smaller than 1 ⁇ m.
- One or more further layers may be arranged between the carrier paper and the ink receptive layer and / or barrier layer.
- the dye-receiving layer disposed on the side of the support paper to be printed is a porous or microporous layer.
- a porous dye-receiving layer according to the invention contains contiguous air-filled cavities (pores) before printing. These pores can absorb ink fluid very quickly by capillary forces and thus lead to rapid drying of the printed image.
- pores contiguous air-filled cavities
- Such porous dye-receiving layers contain a high proportion of pigment particles and comparatively only small amounts of (film-forming) binder.
- Porous dye-receiving layers have a high air permeability, which can be determined by the Bendtsen method. Their pore volume can be detected and determined for example by liquid absorption measurements or by mercury porositometry.
- the porous receiving layer thus contains inorganic pigment and binder.
- pigments having an anionic, neutral or only weakly cationic surface such as silica, calcium carbonate, kaolin, talc, bentonite, aluminum oxides or alumina hydrates. But it can also be finely divided polymers Contain compounds, with high-melting thermoplastic or thermosetting polymers are preferred.
- the ink receptive layer may also contain a mixture of two or more pigments.
- the pigments preferably have an average particle size of 100 nm to 30 .mu.m, particularly preferably from 200 nm to 10 .mu.m.
- the dye-receiving layer preferably additionally contains a polymeric binder, preferably a hydrophilic polymeric binder.
- the binder may be a water-soluble or water-dispersed binder.
- Preferred binders are styrene copolymers, polyvinyl alcohol, starch, modified starch, polyvinyl acetate, acrylates or polyurethane dispersoids.
- the mass ratio of pigment to binder is 100: 1 to 100: 50, preferably 100: 40 to 100: 2.
- the application weight of the dye-receiving layer is preferably 1 g / m 2 to 50 g / m 2 , more preferably 3 g / m 2 to 30 g / m 2 .
- the air permeability of the dye-receiving layer, measured according to Bendtsen, is preferably greater than 100 ml / min, more preferably 200 ml / min to 500 ml / min.
- the adhesive polymer particles or thermoplastic particles are disposed on the surface of the dye-receiving layer. They are not part of the dye-receiving layer and therefore not distributed in the receiving layer. Compared to the relevant prior art, the amount of thermoplastic particles can thus be significantly reduced and yet an excellent adhesive effect can be achieved.
- the thermoplastic adhesive polymer particles may have a diameter of 0.3 to 5 ⁇ m, preferably 0.5 to 2 ⁇ m, more preferably 0.8 to 1.5 ⁇ m.
- the melting point of the staple polymer particles may be 60 ° C to 170 ° C, preferably 80 ° C to 150 ° C.
- the adhesive polymer particles are preferably polyolefins and polyolefin copolymers.
- Thermoplastic particles of ethylene and propylene, poly (meth) acrylates, acrylonitrile-butadiene-styrene polymers, polycarbonates, polyethylene terephthalates, polystyrene, polyvinyl chloride, polyamides and mixtures thereof are suitable.
- the thermoplastic particles may be applied to the dye-receiving layer from an aqueous dispersion.
- the basis weight of the thermoplastic particles in the receiving layer may be 0.3 g / m 2 to 5 g / m 2, preferably 0.5 g / m 2 to 3 g / m 2, more preferably 0.8 to 1.5 g / m 2, be.
- thermoplastic particles used in comparison with the prior art has the advantage that there is no impairment of the printing quality or of the transfer quality.
- the dye-receiving layer and the adhesive polymer particles are preferably applied to the paper carrier by application of aqueous coating compositions or dispersions, wherein all conventional application methods in the paper industry can be used.
- An application is preferred by means of blade, doctor blade, film press or curtain coating. Particularly preferred is a multilayer curtain coating process.
- the receiving layer for the ink-jet printing and the layer with thermoplastic particles are applied to the carrier or the receiving layer.
- the material can be easily manufactured, and the coating weight of the second layer containing the thermoplastic particles, the adhesive force can be accurately adjusted without affecting the print quality.
- the coating compositions may contain other conventional additives such as wetting agents, thickeners, rheology aids, dyes and optical brighteners.
- the barrier layer is characterized by a low permeability to air and gases as well as water vapor.
- the air permeability of the barrier layer measured according to Bendtsen, is less than 100 ml / min, preferably less than 25 ml / min.
- the barrier layer preferably contains one or more polymeric compounds.
- the barrier layer contains one or more thermoplastic polymers, wherein high-melting thermoplastic polymers such as polyester or polymethylpentene are particularly preferred.
- the barrier layer may be applied by the melt extrusion coating method.
- the barrier layer is formed by applying an aqueous solution or an aqueous dispersion of one or more water-soluble or water-dispersed film-forming polymers.
- Preferred polymers are styrene copolymers, polyvinyl alcohols or polyvinyl acetate.
- the barrier layer contains polymers based on renewable raw materials, such as starch, modified starch and / or cellulose derivatives, for example carboxymethylcellulose (CMC).
- the coating weight of the barrier layer is preferably 1 g / m 2 to 40 g / m 2 , more preferably 2 g / m 2 to 20 g / m 2 .
- a eucalyptus pulp was used. For milling, the pulp was milled as an approximately 5% aqueous suspension (thick matter) with the aid of a refiner to a freeness of 26 ° SR. The concentration of pulp fibers in the thin was 1 wt .-%, based on the mass of the pulp suspension. Additional additives such as a neutral sizing agent alkyl ketene dimer (AKD) in an amount of 0.23 wt.%, Wet strength agent polyamine-polyamide-epichlorohydrin resin (Kymene®) in an amount of 0.60 wt. C-Bond HR 35845) in an amount of 1.0% by weight and a natural ground CaCO 3 in an amount of 15% by weight. The quantities are based on the pulp mass.
- ALD neutral sizing agent alkyl ketene dimer
- Kymene® Wet strength agent polyamine-polyamide-epichlorohydrin resin
- the thinstock whose pH was adjusted to about 7.5, was transferred from the head box to the wire of the paper machine, followed by sheet formation by dewatering the web in the wire section of the paper machine.
- the further dewatering of the paper web to a water content of 60 wt .-%, based on the web weight. Further drying took place in the dryer section of the paper machine with heated drying cylinders.
- the result was a base paper with a basis weight of 90 g / m 2 , a filler content of 10 wt .-% and a humidity of about 5.5%.
- the base paper is surface-sized on both sides in a size press containing 3% by weight C-Film 05731 starch from Cargill and water.
- the amount of starch applied on both sides is about 1.5 g / m 2 .
- the carrier paper is again dried and smoothed.
- the carrier paper thus obtained has an air permeability, measured by the Bendtsen method according to DIN 53120-1, of 700 ml / min.
- a dilute dispersion of precipitated calcium carbonate (Precarb® 800 from Schaefer Kalk) having a solids content of 48% by weight
- 557 g of an aqueous 9.5% by weight solution of a partially hydrolyzed polyvinyl alcohol (Mowiol® 18-88 from the company Kuraray) was added and the mixture was mixed with a dissolver stirrer. Thereafter, 0.5 g surfactant Surfynol® 440 from Air Products is mixed.
- the coating obtained has a solids content of 26.6% by weight, a viscosity of 150 mPas, a pH of 7.5 and a surface tension of 36 mN / m.
- a dispersion of polyolefin particles (HYPOD 2000, manufactured by Dow Chemical Company) is diluted with water to a solids content of 48% by weight.
- the glass transition temperature of the polyolefin particles (adhesive polymer particles) in the dispersion is -26 ° C.
- the average particle diameter of these adhesive polymer particles is about 1 ⁇ m.
- 4% by weight of Surfynol® 440 from Air Products are added to the dispersion.
- the viscosity of the coating obtained is 50 mPas, the surface tension 33 mN / m and the pH 9.9.
- the coating composition comprising the thermoplastic particles is applied by the curtain-coating process together with the dye-receiving layer as an aqueous dispersion.
- comparison material V1 a commercially available transfer material with a release and barrier layer (Transjet Sportsline 9310-100 g / m 2 ) is used.
- This comparative material has a textile adherent but non-porous coating on the print side (industrial benchmark for adhesion).
- the comparative material V2 a commercially available transfer material having a microporous dye-receiving layer (Transjet Boost 8340, 85 g / m 2 ) is used.
- This comparison material V2 has a fast-drying, but non-adhesive transfer layer (industrial benchmark regarding drying).
- comparison material V3 is a laboratory product according to the line formulation of Example 1 in the DE 10 2014 116550 A1 , namely thermoplastic particles in a binder-rich layer, applied to the carrier paper described in 1..
- the dry application of the adhering dye-receiving layer is 8 g / m 2
- Example 2 On the carrier paper of Example 1, the coating composition for the ink receiving layer (Example 2) and the coating composition for the thermoplastic particles (Example 3) is applied simultaneously, the thermoplastic particles on top (on the side facing away from the backing paper) .
- the dry application of the Ink receiving layer of Example 2 is 12 g / m 2 and that of the adhesive particles of Example 3 is 1 g / m 2 .
- Example 4 It is additionally applied to the transfer paper produced under Invention 1, the coating composition of Example 4 with a doctor and dried.
- the dry coating was 5 g / m 2 and the coating was applied to the opposite side of the carrier paper to the ink receptive layer and the thermoplastic particles.
- the resulting transfer materials were printed with a color image using the inkjet printer EPSON WP4015 with Sublijet IQ sublimation inks from Sawgrass.
- Transfer of the printed image to a textile fabric by sublimation In a transfer press Rotex Autoswing X from Sefa, the image side of the printed transfer material is brought into contact with a knitted polyester fabric (sport jersey 140 g / m 2 from A. Berger, article No. 4245-3) on the back side of the Transfer material is additionally a sheet of office paper with a basis weight of 80 g / m 2 inserted to evaluate the color breakdown. At a temperature of 200 ° C, a level 30 contact pressure is applied for 30 seconds according to the height indicator scale of the press. Thereafter, the fabric and the copy paper are separated from the transfer material.
- a knitted polyester fabric sports jersey 140 g / m 2 from A. Berger, article No. 4245-3
- a sheet of office paper with a basis weight of 80 g / m 2 inserted to evaluate the color breakdown.
- a level 30 contact pressure is applied for 30 seconds according to the height indicator scale of the press. Thereafter, the fabric and the copy paper are separated from
- the print definition is evaluated visually and with a microscope both on the transfer material before image transfer and after sublimation transfer to the fabric.
- the color density is measured for the full color fields CMYK with a spectrophotometer SpectroEye from X-rite.
- the color bleed is visually evaluated on the basis of the color transferred in the sublimation transfer operation to the backside inserted copy paper.
- the test results of the table show that the transfer materials according to the invention have a very good drying behavior after inkjet printing, show a high line sharpness even in the image transferred to the tissue, transfer the sublimation dye to the tissue to a high degree in the sublimation transfer process, and additionally excellent Textile adhesion (E1).
- E1 Textile adhesion
- the textile adhesion of V1 with the Ink drying of V2 achieved, which was not possible by the prior art.
- the additional application of a barrier layer (E2) results in a product which exhibits outstanding properties in all essential quality properties for sublimation papers.
- the barrier layer can be arranged both on the back and on the top of the backing paper.
- the application of the barrier layer on the back results in an even higher drying performance, since in addition the water absorption capacity of the backing paper can be used.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
- Decoration By Transfer Pictures (AREA)
- Laminated Bodies (AREA)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL16199112T PL3323624T3 (pl) | 2016-11-16 | 2016-11-16 | Adhezyjny mikroporowy materiał transferowy |
EP16199112.0A EP3323624B1 (de) | 2016-11-16 | 2016-11-16 | Haftendes mikroporöses transfermaterial |
SI201630224T SI3323624T1 (sl) | 2016-11-16 | 2016-11-16 | Lepilni mikroporozni transferni material |
ES16199112T ES2708857T3 (es) | 2016-11-16 | 2016-11-16 | Material de transferencia microporoso adherente |
PCT/EP2017/074240 WO2018091179A1 (de) | 2016-11-16 | 2017-09-25 | Haftendes mikroporöses transfermaterial |
US16/347,920 US10632778B2 (en) | 2016-11-16 | 2017-09-25 | Tacky microporous transfer material |
CN201780021983.9A CN109153276B (zh) | 2016-11-16 | 2017-09-25 | 粘附性微孔转印材料 |
JP2018546704A JP6937772B2 (ja) | 2016-11-16 | 2017-09-25 | 接着性微孔性転写材料 |
KR1020187026485A KR102220467B1 (ko) | 2016-11-16 | 2017-09-25 | 접착성 미세다공성 전사 재료 |
BR112018068322-1A BR112018068322B1 (pt) | 2016-11-16 | 2017-09-25 | Material de transferência microporoso aderente |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16199112.0A EP3323624B1 (de) | 2016-11-16 | 2016-11-16 | Haftendes mikroporöses transfermaterial |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3323624A1 EP3323624A1 (de) | 2018-05-23 |
EP3323624B1 true EP3323624B1 (de) | 2019-01-02 |
Family
ID=57345765
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16199112.0A Active EP3323624B1 (de) | 2016-11-16 | 2016-11-16 | Haftendes mikroporöses transfermaterial |
Country Status (10)
Country | Link |
---|---|
US (1) | US10632778B2 (zh) |
EP (1) | EP3323624B1 (zh) |
JP (1) | JP6937772B2 (zh) |
KR (1) | KR102220467B1 (zh) |
CN (1) | CN109153276B (zh) |
BR (1) | BR112018068322B1 (zh) |
ES (1) | ES2708857T3 (zh) |
PL (1) | PL3323624T3 (zh) |
SI (1) | SI3323624T1 (zh) |
WO (1) | WO2018091179A1 (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL3754109T3 (pl) | 2019-06-18 | 2022-12-27 | Schoeller Technocell Gmbh & Co. Kg | Preimpregnat o ulepszonej płaskości |
NL2023347B1 (en) | 2019-06-19 | 2021-01-27 | Coldenhove Know How B V | Pigment Transfer Paper |
EP3896953B1 (de) | 2020-04-17 | 2024-05-01 | Felix Schoeller GmbH & Co. KG | Verfahren zur steuerung eines dekor-druckprozesses |
EP4039484A1 (en) * | 2021-02-09 | 2022-08-10 | Sihl GmbH | Inkjet printable transfer medium |
WO2022223130A1 (en) * | 2021-04-23 | 2022-10-27 | Sappi Netherlands Services B.V. | Sublimation transfer printing paper |
CN115071299B (zh) * | 2022-08-09 | 2023-12-05 | 吴江翔丰丝绸整理有限公司 | 可再生热转印工艺 |
CN115848048A (zh) * | 2023-02-09 | 2023-03-28 | 南京泽之晨数码科技有限公司 | 一种环保型水性数码打印膜材 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05301465A (ja) * | 1992-02-26 | 1993-11-16 | Ricoh Co Ltd | 昇華型熱転写用受像体 |
JP3315488B2 (ja) * | 1993-08-30 | 2002-08-19 | 日本製紙株式会社 | インクジェット記録用紙 |
DE19743854C2 (de) * | 1997-10-04 | 1999-09-30 | Schoeller Felix Jun Foto | Verwendung eines Bildträgermaterials für die thermische Bildübertragung |
JP4008663B2 (ja) | 1998-07-29 | 2007-11-14 | ダブリュー.エー. サンデルス パピエルファブリック コッデンホーヴェ ビー.ヴィー | インクジェット印刷用転写紙 |
ATE409629T1 (de) * | 1999-04-21 | 2008-10-15 | Nippon Shooter Ltd Kyoto Japan | Fördersystem |
JP2002292995A (ja) * | 2001-03-28 | 2002-10-09 | Mitsubishi Paper Mills Ltd | 昇華インク用インクジェット被記録媒体及び転写記録方法 |
DE10246209A1 (de) | 2002-10-04 | 2004-04-15 | Basf Ag | Farbstoffzubereitungen |
JP2007118532A (ja) * | 2005-10-31 | 2007-05-17 | Mitsubishi Paper Mills Ltd | 昇華インク転写用インクジェット記録媒体及び転写記録方法 |
EP1878829A1 (de) | 2006-07-12 | 2008-01-16 | Papierfabriken Cham-Tenero AG | Beschichtetes Trägerpapier |
US20080229962A1 (en) | 2007-03-19 | 2008-09-25 | Matthew Warren Shedd | Sublimation transfer paper, method of making, and method for sublimation printing |
DE102014116550A1 (de) | 2014-11-12 | 2016-05-12 | Papierfabrik August Koehler Se | Thermosublimationspapier |
TWI614959B (zh) | 2016-12-13 | 2018-02-11 | Excel Cell Electronic Co Ltd | 端子台 |
-
2016
- 2016-11-16 PL PL16199112T patent/PL3323624T3/pl unknown
- 2016-11-16 ES ES16199112T patent/ES2708857T3/es active Active
- 2016-11-16 EP EP16199112.0A patent/EP3323624B1/de active Active
- 2016-11-16 SI SI201630224T patent/SI3323624T1/sl unknown
-
2017
- 2017-09-25 KR KR1020187026485A patent/KR102220467B1/ko active IP Right Grant
- 2017-09-25 WO PCT/EP2017/074240 patent/WO2018091179A1/de active Application Filing
- 2017-09-25 US US16/347,920 patent/US10632778B2/en active Active
- 2017-09-25 CN CN201780021983.9A patent/CN109153276B/zh active Active
- 2017-09-25 BR BR112018068322-1A patent/BR112018068322B1/pt active IP Right Grant
- 2017-09-25 JP JP2018546704A patent/JP6937772B2/ja active Active
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
PL3323624T3 (pl) | 2019-04-30 |
US20190263164A1 (en) | 2019-08-29 |
JP2019515814A (ja) | 2019-06-13 |
WO2018091179A1 (de) | 2018-05-24 |
SI3323624T1 (sl) | 2019-05-31 |
KR20180110124A (ko) | 2018-10-08 |
BR112018068322B1 (pt) | 2023-04-25 |
KR102220467B1 (ko) | 2021-02-25 |
CN109153276B (zh) | 2020-08-04 |
CN109153276A (zh) | 2019-01-04 |
JP6937772B2 (ja) | 2021-09-22 |
BR112018068322A2 (pt) | 2019-06-18 |
US10632778B2 (en) | 2020-04-28 |
ES2708857T3 (es) | 2019-04-11 |
EP3323624A1 (de) | 2018-05-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3323624B1 (de) | Haftendes mikroporöses transfermaterial | |
DE60316583T2 (de) | Beschichtetes druckblatt und sein herstellungsverfahren | |
EP3302991A2 (de) | Transfer-material für den sublimationsdruck | |
DE69310107T2 (de) | Aufzeichnungsblatt für Tintenstrahlschreiber und Verfahren zu seiner Herstellung | |
DE69011991T2 (de) | Registriermittel und Verfahren zum Registrieren damit. | |
DE69912339T2 (de) | Aufzeichnungsmedium und Tintenstrahlaufzeichnungsverfahren damit | |
EP2861429B1 (de) | Empfangsschicht für digitale druckverfahren mit nanofibrillierter cellulose | |
CH690726A5 (de) | Verfahren zum Bedrucken einer Oberfläche mittels Transferdruck und Transferpapier hierfür. | |
EP2537981B1 (de) | Verfahren zur Oberflächenbehandlung von Papier sowie Papier | |
DE69907993T2 (de) | Tintenstrahlaufzeichnungsmaterial | |
DE60107725T3 (de) | Für eine pigmenthaltige Tinte geeignetes Tintenstrahlaufzeichnungsmaterial | |
DE112011103316T5 (de) | Beschichtetes Druckpapier und Verfahren zur Erzeugung gedruckter Bilder | |
EP0192252A1 (de) | Verfahren zur Verbesserung des Holdouts von Druckfarben, Lacken und Beschichtungsmassen auf Flächengebilden aus Fasern sowie zur Verbesserung des De-Inkings der Fasern sowie Masse zur Durchführung des Verfahrens und damit erzeugte Flächengebilde | |
EP2770105A1 (de) | Basispapier für dekorative Beschichtungswerkstoffe | |
DE69301717T2 (de) | Tintenstrahlaufzeichnungsblatt und Verfahren zu deren Herstellung | |
DE10082462B4 (de) | Aufzeichnungsblatt und Verfahren zu dessen Herstellung | |
DE69804176T2 (de) | Substrat für giessbeschichtetes Papier und Papier die dieses Substrat verwendet | |
EP0387893A1 (de) | Aufzeichnungsblatt für Tintenstrahldrucker | |
EP2076398B1 (de) | Ink-jet-aufzeichnungsmaterial mit perforierter rückseitenkunstharzschicht | |
DE602004007492T2 (de) | Tintenstrahlaufzeichnungsblatt | |
EP2054236A1 (de) | Gussstrichähnliches tintenstrahlaufzeichnungsmaterial | |
EP3028866B1 (de) | Aufzeichnungsmaterial für thermische Druckverfahren | |
EP4053333B1 (de) | Transfermaterial für den sublimationsdruck basierend auf papier als träger mit sperrfunktion gegenüber tinten | |
DE69901408T2 (de) | Aufzeichnungsmaterial für den Elektrokoagulationsdruck und damit verbundenes Verfahren | |
EP0935695B1 (de) | Papier mit tintenstrahlaufzeichnungsschicht |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20170814 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20180615 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1247164 Country of ref document: HK |
|
INTC | Intention to grant announced (deleted) | ||
GRAR | Information related to intention to grant a patent recorded |
Free format text: ORIGINAL CODE: EPIDOSNIGR71 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
INTG | Intention to grant announced |
Effective date: 20181025 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP Ref country code: AT Ref legal event code: REF Ref document number: 1083869 Country of ref document: AT Kind code of ref document: T Effective date: 20190115 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502016003062 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2708857 Country of ref document: ES Kind code of ref document: T3 Effective date: 20190411 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190502 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190402 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190402 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190502 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190403 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502016003062 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 |
|
26N | No opposition filed |
Effective date: 20191003 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191130 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191116 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191130 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20191130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191116 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20161116 Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190102 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 1083869 Country of ref document: AT Kind code of ref document: T Effective date: 20211116 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211116 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230519 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20231120 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20231123 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20231114 Year of fee payment: 8 Ref country code: SI Payment date: 20231102 Year of fee payment: 8 Ref country code: SE Payment date: 20231120 Year of fee payment: 8 Ref country code: IT Payment date: 20231124 Year of fee payment: 8 Ref country code: FR Payment date: 20231120 Year of fee payment: 8 Ref country code: FI Payment date: 20231121 Year of fee payment: 8 Ref country code: DE Payment date: 20231121 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20231103 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20240129 Year of fee payment: 8 |