EP2867508A1 - Method for controlling an internal combustion engine, and a system comprising an internal combustion engine and a control device - Google Patents
Method for controlling an internal combustion engine, and a system comprising an internal combustion engine and a control deviceInfo
- Publication number
- EP2867508A1 EP2867508A1 EP13723467.0A EP13723467A EP2867508A1 EP 2867508 A1 EP2867508 A1 EP 2867508A1 EP 13723467 A EP13723467 A EP 13723467A EP 2867508 A1 EP2867508 A1 EP 2867508A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- injection valve
- internal combustion
- combustion engine
- valve
- injection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 64
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000002347 injection Methods 0.000 claims abstract description 131
- 239000007924 injection Substances 0.000 claims abstract description 131
- 239000000446 fuel Substances 0.000 claims abstract description 54
- 230000004913 activation Effects 0.000 claims description 7
- 238000004590 computer program Methods 0.000 claims description 6
- 238000011156 evaluation Methods 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 2
- 230000006978 adaptation Effects 0.000 description 15
- 230000001276 controlling effect Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 238000011217 control strategy Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/30—Controlling fuel injection
- F02D41/3094—Controlling fuel injection the fuel injection being effected by at least two different injectors, e.g. one in the intake manifold and one in the cylinder
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/24—Electrical control of supply of combustible mixture or its constituents characterised by the use of digital means
- F02D41/2406—Electrical control of supply of combustible mixture or its constituents characterised by the use of digital means using essentially read only memories
- F02D41/2425—Particular ways of programming the data
- F02D41/2429—Methods of calibrating or learning
- F02D41/2432—Methods of calibration
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D19/00—Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
- F02D19/06—Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with pluralities of fuels, e.g. alternatively with light and heavy fuel oil, other than engines indifferent to the fuel consumed
- F02D19/0663—Details on the fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
- F02D19/0686—Injectors
- F02D19/0692—Arrangement of multiple injectors per combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/30—Controlling fuel injection
- F02D41/32—Controlling fuel injection of the low pressure type
- F02D41/34—Controlling fuel injection of the low pressure type with means for controlling injection timing or duration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/30—Use of alternative fuels, e.g. biofuels
Definitions
- the invention relates to a method for controlling an internal combustion engine according to the preamble of claim 1. Furthermore, the invention relates to a system with an internal combustion engine and a control unit and a computer program and a computer program product.
- Internal combustion engines with intake manifold injection with two injection valves per cylinder are well known.
- the document DE 10 2008 044 244 A1 discloses an internal combustion engine having at least one combustion chamber, wherein the combustion chamber has two fuel inlet openings, which can each be closed by an inlet valve.
- the internal combustion engine also has a fuel injection device which, in association with the at least one combustion chamber, has a first and a separate second injection valve for the metered injection of fuel into at least one intake passage of the combustion chamber.
- the injectors spray the fuel while atomized in the form of spray cones in the direction of the intake valves.
- the so-called controlled operation of solenoid valves in which the real movement of the valve needle and its stroke can be evaluated via suitable feedback parameters (for example, the current or the voltage) and thus detectable.
- suitable feedback parameters for example, the current or the voltage
- CVO Controlled Valve Operation
- the movement of the valve needle (ie the needle movement) or the needle stroke by suitable algorithms from stroke to stroke of a valve or over several valves can be adjusted uniformly.
- the state of the art is also to determine the so-called valve delay time via special control strategies, for example by multiple injection.
- the inventive method for controlling an internal combustion engine, the inventive system with an internal combustion engine and a control unit and the computer program according to the invention or the computer program product according to the independent claims have the advantage over the prior art that both in the first Kalibrier istsmodus (based on the first injection valve) as well as in the second calibration operating mode (based on the second injection valve) can be carried out or carried out a determination of the optimal control of the respective injector or an adaptation of such control, in certain (part-load) operating ranges of the internal combustion engine either entirely without the fulfillment of others Boundary conditions or at least taking into account less boundary conditions or less restrictive-acting boundary conditions, the adaptation of the control of the respective injection valve can take place.
- An adaptation of the control of the respective injection valve according to the invention is particularly of particular interest in the small-quantity range, in which a non-linear behavior of the injection valve can be assumed. According to the invention, it is therefore advantageously possible that the needle stroke behavior can be determined in a particularly simple, accurate and rapid manner for a wide or wider range of possible situations compared with the prior art, in particular with a view to determining the valve delay time.
- one of the two injectors or injectors covers the full injection quantity (ie, the predetermined target fuel quantity) of fuel to ensure trouble-free combustion, while the other injector or the other injector (in the first calibration mode of operation first injection valve, in the second calibration operating mode, the second injection valve) is calibrated by being switched on with (slowly increasing, ie from one injection interval to the next injection interval) smallest actuation periods.
- the invention it is possible to evaluate and adapt the valve behavior when only short activation times of the injection valve are used (instead of having to alternately use both shorter and longer activation times in the double injection) so that the actual small-quantity operation of the injection valve is in accordance with the invention can be observed and adapted.
- the adaptation it is therefore also advantageously possible for the adaptation to be carried out more frequently, permanently in certain operating ranges, so that a possible temporal drift in the behavior of the injection valve or the valve needle of the injection valve can be detected early and regulated again and again.
- the internal combustion engine used for the inventive method is in particular a gasoline engine with intake manifold injection for a motor vehicle, preferably an automobile. This may be the fuel used to gasoline or ethanol or a mixture.
- the internal combustion engine preferably comprises more than one cylinder, wherein each of the cylinders comprises a combustion chamber with, for example, two inlet valves, wherein each inlet valve is preferably assigned in each case a separate injection valve or also two separate injection valves.
- the predetermined setpoint fuel quantity in the calibration operating mode corresponds to the sum of the first and second fuel quantities in the normal operating mode.
- the first or second calibration operating mode can replace the normal operating mode.
- the calibration control of the first injection valve in the first calibration operating mode or the second injection valve in the second calibration mode is such that during successive operating cycles the calibration control takes place starting from such short activation times that an opening movement of the first or second valve needle initially does not he follows. As a result, the valve delay time can be determined particularly accurately.
- the invention it is possible to design the first and second injection valves of the same size as the maximum amount of fuel injectable under specified operating conditions (so-called quantity QSTAT) or to have different sizes.
- quantity QSTAT the maximum amount of fuel injectable under specified operating conditions
- the uniform design of the injection valves in which the design quantity of an injection valve to fuel (compared to the total amount of fuel injected) is halved) has the advantage that a larger number of injectors with correspondingly feasible cost advantages possible.
- the subject of the present invention is a system with an internal combustion engine and a control unit for controlling the internal combustion engine.
- Figures 1 to 3 are schematic representations of different divisions of an amount of fuel to be injected on two injectors
- Figure 4 is a schematic representation of a fuel injection system.
- FIG. 1 is a schematic representation of the breakdown of a total injection quantity for a cylinder of an internal combustion engine into two injection valves (i.e., a first injection valve 21 and a second injection valve 22).
- An overall injection quantity QSTAT of fuel is realized in two injectors in that, for example, each of the injection valves injects in each case 50% of the maximum injection quantity QSTAT, which is realized, for example, with only one injection jet.
- the representation according to FIG. 1 corresponds to an example illustration of the normal operating mode of the internal combustion engine.
- the injection durations for the two injection valves 21, 22 are schematically indicated on the basis of the designations "ti A" and "ti B" and two horizontally oriented bars.
- a horizontal bar of the same length for both injection valves means that both injectors are driven at the same time (for opening the valve needle).
- FIGS. 2 and 3 is a schematic representation of the distribution of a total injection quantity for a cylinder of an internal combustion engine so shown on two injectors, that the required total amount of fuel is injected only by one of the injectors and the other of the Injectors is calibrated.
- the representation according to FIGS. 2 and 3 corresponds to an example illustration of the first calibration mode of operation (FIG. 2) or of the second calibration mode of operation (FIG. 3) of the internal combustion engine.
- FIG. 2 and Figure 3 is a schematic representation of the distribution of a total injection quantity for a cylinder of an internal combustion engine so shown on two injectors, that the required total amount of fuel is injected only by one of the injectors and the other of the Injectors is calibrated.
- the representation according to FIGS. 2 and 3 corresponds to an example illustration of the first calibration mode of operation (FIG. 2) or of the second calibration mode of operation (FIG. 3) of the internal combustion engine.
- FIG. 2 and Figure 3 corresponds to an example illustration
- the injection durations for the two injection valves 21, 22 are schematically indicated on the basis of the designations "ti A” and “ti B” and two horizontally oriented bars, ie the (shorter time) actuation time ("ti A") of FIG the first injection valve 21 is very low in the first calibration mode, so that possibly no movement of the valve needle and thus opening of the injector take place while the (longer time) driving time ("ti B") of the second injection valve 22 in the first calibration mode is such that the injected fuel quantity corresponds to the required fuel quantity at the respective operating point.
- the (shorter time) actuation time (ti A") of FIG the first injection valve 21 is very low in the first calibration mode, so that possibly no movement of the valve needle and thus opening of the injector take place while the (longer time) driving time ("ti B") of the second injection valve 22 in the first calibration mode is such that the injected fuel quantity corresponds to the required fuel quantity at the respective operating point.
- the injection durations for the two injectors 21, 22 are schematically indicated on the basis of the designations "ti A” and “ti B” and two horizontally oriented bars, ie the (shorter time) actuation time ("ti B") of FIG second injection valve 22 is very low in the second calibration mode, so that possibly no movement of the valve needle and thus opening of the injector take place while the (longer time) driving time ("ti A") of the first injector 21 is dimensioned in the second calibration mode such that the injected fuel quantity corresponds to the required fuel quantity at the respective operating point.
- FIG. 4 schematically shows a fuel supply system 10 of an internal combustion engine which is intended for use in a vehicle.
- the internal combustion engine typically has four cylinders and thus four combustion chambers, but also a different number of cylinders and thus combustion chambers is possible.
- the fuel preferably gasoline fuel
- the fuel is not injected directly into the combustion chambers, but works with a port injection.
- the fuel is pumped by a pump not shown from a container 18, in particular via a filter, not shown, in a pressure chamber or a pressure accumulator 12.
- injectors are connected, which are provided for injecting the fuel into the combustion chambers or in the suction pipes of the combustion chambers.
- FIG 2 the case of four cylinders and two injection valves per cylinder is shown schematically in Figure 2, wherein each cylinder has an injection valve 21 and a further injection valve 22.
- a different constellation for a number of cylinders and on the other also the number of injectors per cylinder is possible, for example, one injector per cylinder or more than two injectors per cylinder.
- twin Injection two suction pipe injection valves per suction channel, so that fuel is injected via two paths into a suction pipe
- these two injection valves are activated in particular via two separate electronic output stages, so that the two injection valves are controlled either synchronously or individually, ie with different phase and / or different duration of time.
- the control of the injection valves is performed by a control device 16 or a control unit 16.
- the internal combustion engine or the internal combustion engine requires a certain amount of fuel per cylinder, which corresponds to a particular injection time "ti" at the respective injection valve, depending on the system design Injection valve 21 and a second injection valve 22 per cylinder or per combustion chamber), the required amount of fuel per combustion chamber via two injection valves, in particular in the suction channel supplied.
- both twin injectors ie the injection valves 21 and 22, assume the task of metering fuel, which is shown in FIG.
- the function of both injection valves is separated, which is shown in FIGS. 2 and 3.
- one of the two injection valves (the second injection valve 22 in the first calibration operating mode and the first injection valve 21 in the first calibration operating mode) will cover this operating point operated necessary injection quantity.
- the further injection valve (the first injection valve in the first calibration operating mode and the second injection valve in the second calibration operating mode) is switched on with a very short drive time. Initially, the needle of the injection valve operated with a short activation time will not lift from the valve seat. The activation time is now slowly increased until the needle finally rises and initially reverses before reaching the upper stop and falls back on the valve seat. Finally, a drive duration is reached and exceeded, in which the valve needle also reaches the upper stop.
- the detection of the behavior of the valve needle according to the invention is carried out in particular via a signal evaluation of the behavior of current signals and / or voltage signals, in particular by the observation of a due to the closing movement of the valve needle negative voltage due to the induction effect in the magnetic circuit of the injector.
- the reversal of roles of the other injector can be started, d. H. the first calibration mode of operation and the second calibration mode of operation correspond, wherein (in particular with the same design (same QSTAT) of the first and second injection valves) the rollers are merely exchanged.
- the settled fuel amount of the injector to be adapted ie, the first injector in the first calibration mode and the second injector in the second calibration mode
- the influence on the fuel / air ratio of the combustion noise ie the so-called lambda value of the combustion chamber
- the uneven running influence or the exhaust gas influence can be neglected.
- an injector covers the entire injection quantity during the adaptation phase, it can also be adapted in dynamic operation since this only has an influence on the injector, which covers the injection quantity, but not on the injector to be adapted. This results in the execution of the adaptation independent of the operating range and the operating condition of the engine, which means a robustness increase and opens up new degrees of freedom for the implementation of the adaptation.
- the present invention can also be applied to systems with intake manifold injection and gasoline direct injection, so-called PDI systems, in which the operating point in which one of the two injectors is able to cover the entire quantity is the other Injector can be adapted.
- PDI systems intake manifold injection and gasoline direct injection
- bi-fuel systems in which the different fuels are injected with different injection valves.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Electrical Control Of Air Or Fuel Supplied To Internal-Combustion Engine (AREA)
- Fuel-Injection Apparatus (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012210937.4A DE102012210937A1 (en) | 2012-06-27 | 2012-06-27 | Method for controlling an internal combustion engine and system with an internal combustion engine and a control unit |
PCT/EP2013/059892 WO2014000946A1 (en) | 2012-06-27 | 2013-05-14 | Method for controlling an internal combustion engine, and a system comprising an internal combustion engine and a control device |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2867508A1 true EP2867508A1 (en) | 2015-05-06 |
Family
ID=48463968
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13723467.0A Withdrawn EP2867508A1 (en) | 2012-06-27 | 2013-05-14 | Method for controlling an internal combustion engine, and a system comprising an internal combustion engine and a control device |
Country Status (6)
Country | Link |
---|---|
US (1) | US9617946B2 (en) |
EP (1) | EP2867508A1 (en) |
JP (2) | JP2015521712A (en) |
KR (1) | KR102019649B1 (en) |
DE (1) | DE102012210937A1 (en) |
WO (1) | WO2014000946A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014094156A1 (en) * | 2012-12-22 | 2014-06-26 | Westport Power Inc. | Air-fuel ratio control in a multi-fuel internal combustion engine |
US10161371B2 (en) | 2015-02-27 | 2018-12-25 | Avl Powertrain Engineering, Inc. | Opposed piston three nozzle piston bowl design |
US10066590B2 (en) | 2015-02-27 | 2018-09-04 | Avl Powertrain Engineering, Inc. | Opposed piston three nozzle combustion chamber design |
GB2533464A (en) * | 2015-10-20 | 2016-06-22 | Gm Global Tech Operations Llc | Method of operating a fuel injector of an internal combustion engine |
FR3061746B1 (en) * | 2017-01-10 | 2020-09-25 | Continental Automotive France | PROCEDURE FOR CORRECTING A DURATION OF FUEL INJECTION INTO A MOTOR VEHICLE IC ENGINE CYLINDER |
DE102018219028B4 (en) * | 2018-11-08 | 2020-06-25 | Continental Automotive Gmbh | Method for operating an internal combustion engine by performing an injection quantity correction |
DE102021206409B3 (en) | 2021-06-22 | 2022-11-17 | Rolls-Royce Solutions GmbH | Method for diagnosing fuel injectors of an internal combustion engine and internal combustion engine set up for carrying out such a method |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010042852A1 (en) * | 2010-10-25 | 2012-04-26 | Robert Bosch Gmbh | Method for monitoring an adaptation of a delay time of an injection valve of an internal combustion engine |
Family Cites Families (19)
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JPS6036739A (en) * | 1983-08-09 | 1985-02-25 | Kawasaki Heavy Ind Ltd | Control apparatus for internal-combustion engine |
US4955345A (en) * | 1989-06-16 | 1990-09-11 | General Motors Corporation | Multi-fuel engine control with fuel composition responsive fuel viscosity correction |
JPH0436036A (en) | 1990-05-11 | 1992-02-06 | Mazda Motor Corp | Air-fuel ratio controller of engine |
US5159914A (en) * | 1991-11-01 | 1992-11-03 | Ford Motor Company | Dynamic fuel control |
JP3867413B2 (en) * | 1998-09-04 | 2007-01-10 | 株式会社デンソー | Fuel injection nozzle |
JP2001280189A (en) * | 2000-03-30 | 2001-10-10 | Hitachi Ltd | Control method for electromagnetic fuel injection valve |
JP2002004922A (en) | 2000-06-27 | 2002-01-09 | Mitsubishi Electric Corp | Injector driving device |
JP4342751B2 (en) * | 2001-07-23 | 2009-10-14 | 株式会社日本自動車部品総合研究所 | Fuel injection valve |
US6748928B2 (en) | 2002-04-26 | 2004-06-15 | Caterpillar Inc | In-chassis determination of fuel injector performance |
JP2007303336A (en) * | 2006-05-10 | 2007-11-22 | Toyota Motor Corp | Control unit of internal combustion engine |
JP2009114884A (en) | 2007-11-02 | 2009-05-28 | Toyota Motor Corp | Fuel injection quantity correction device |
EP2163750B1 (en) | 2008-09-16 | 2011-03-16 | Magneti Marelli S.p.A. | Method of driving fuel injectors arranged in an intake pipe above and below a butterfly valve |
DE102008044244A1 (en) | 2008-12-01 | 2010-06-02 | Robert Bosch Gmbh | Internal combustion engine |
JP5051627B2 (en) * | 2009-01-20 | 2012-10-17 | 株式会社デンソー | Air-fuel ratio learning control device for internal combustion engine |
JP5143774B2 (en) | 2009-03-23 | 2013-02-13 | 日立オートモティブシステムズ株式会社 | Air-fuel ratio control device for internal combustion engine |
DE102009031583B4 (en) | 2009-07-03 | 2020-01-30 | Bayerische Motoren Werke Aktiengesellschaft | Method for adapting a device for introducing fuel into a combustion chamber of an internal combustion engine, device for introducing fuel into a combustion chamber of an internal combustion engine and motor vehicle with such a device |
DE102010003209A1 (en) | 2010-03-24 | 2011-09-29 | Robert Bosch Gmbh | Method and device for adapting adaptation values for the control of injection valves in a multi-injection engine system |
DE102010064184B4 (en) * | 2010-12-27 | 2023-02-09 | Robert Bosch Gmbh | Method for operating an injection system for an internal combustion engine |
DE102011087961A1 (en) * | 2011-12-08 | 2013-06-13 | Robert Bosch Gmbh | Method for learning a minimum activation duration of injection valves of an internal combustion engine |
-
2012
- 2012-06-27 DE DE102012210937.4A patent/DE102012210937A1/en active Pending
-
2013
- 2013-05-14 EP EP13723467.0A patent/EP2867508A1/en not_active Withdrawn
- 2013-05-14 US US14/410,687 patent/US9617946B2/en active Active
- 2013-05-14 KR KR1020147036279A patent/KR102019649B1/en active IP Right Grant
- 2013-05-14 WO PCT/EP2013/059892 patent/WO2014000946A1/en active Application Filing
- 2013-05-14 JP JP2015518918A patent/JP2015521712A/en active Pending
-
2017
- 2017-06-01 JP JP2017109078A patent/JP6307653B2/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010042852A1 (en) * | 2010-10-25 | 2012-04-26 | Robert Bosch Gmbh | Method for monitoring an adaptation of a delay time of an injection valve of an internal combustion engine |
Non-Patent Citations (1)
Title |
---|
See also references of WO2014000946A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20150192086A1 (en) | 2015-07-09 |
US9617946B2 (en) | 2017-04-11 |
JP2015521712A (en) | 2015-07-30 |
DE102012210937A1 (en) | 2014-01-23 |
KR102019649B1 (en) | 2019-09-10 |
JP6307653B2 (en) | 2018-04-04 |
JP2017166491A (en) | 2017-09-21 |
KR20150023479A (en) | 2015-03-05 |
WO2014000946A1 (en) | 2014-01-03 |
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