EP1316255A1 - Utilisation de mineraux micronisés comme produit phytosanitaire - Google Patents

Utilisation de mineraux micronisés comme produit phytosanitaire Download PDF

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Publication number
EP1316255A1
EP1316255A1 EP02090409A EP02090409A EP1316255A1 EP 1316255 A1 EP1316255 A1 EP 1316255A1 EP 02090409 A EP02090409 A EP 02090409A EP 02090409 A EP02090409 A EP 02090409A EP 1316255 A1 EP1316255 A1 EP 1316255A1
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Prior art keywords
fan blades
der
micronized
die
und
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English (en)
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Tihomir Lelas
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/16—Inorganic salts, minerals or trace elements
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • A24D3/166—Silicic acid or silicates
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00—Medicinal preparations containing inorganic active ingredients
    • A61K33/06—Aluminium, calcium or magnesium; Compounds thereof, e.g. clay
    • A61K33/08—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00—Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/20—Disintegrating by mills having rotary beater elements ; Hammer mills with two or more co-operating rotors
    • B02C13/205—Disintegrating by mills having rotary beater elements ; Hammer mills with two or more co-operating rotors arranged concentrically
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0076—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials characterised by the grain distribution
    • C04B20/008—Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/18—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
    • C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
    • C12H1/02—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material
    • C12H1/04—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material
    • C12H1/0408—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material with the aid of inorganic added material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Definitions

  • the invention describes a device for fine grinding and micronizing of mineral and / or organic materials with a small Grain size distribution using impact and friction processes. Furthermore, new uses of this device for different areas of daily life, where it focuses on the Fine grinding of solids, but also the mixing of solid and / or liquid substances arrives.
  • the material micronized by the device according to the invention has many advantages for a wide range of uses:
  • the new device calls various for mineral raw material components chemical and chemical-physical changes.
  • the effects which arise through dynamic friction processes lend them Minerals new properties that arise in the manufacture of various products let it be used technologically and commercially.
  • the mineral heulandite / clinoptylolite has proven to be advantageous due to its properties, namely its ability to absorb water, its selectivity and ion exchange capacity, and its chemical composition, which showed that this mineral is absolutely harmless to human consumption.
  • the mineralogical and chemical properties of clinoptilolites have been examined and are as follows: component Proportion of [%] of to SiO 2 61.96 67.17 TiO 2 0.15 0.32 Al 2 O 3 12.46 15,12 Fe 2 O 0.98 2.05 MnO track 0.05 MgO 1.30 1.96 CaO 3.03 4.35 Na 2 O 0.70 1.11 K 2 O 0.78 1.32 H 2 O at 100 ° C 4.05 4.74 H 2 O at 1000 ° C 7.56 9.56
  • the calcium content of this mineral indicates that it is a calcium zeolite, which is formed in a tuff-like structure, ie it is a kind of the mineral clinoptilolite with the properties of the heulandite group.
  • the measured density of the mineral clinoptiloithes examined is in the range from 1.41 to 1.43 g / cm 3 . Diffractometric and thermo-gravimetric studies showed that all samples examined had approximately the same zeolite content.
  • the results of the X-ray examinations show the presence of the following types of minerals: Heulandite (clinoptilolite), and subsequently essentially quartz, sand, plagioclass and in a small amount also biothyte.
  • the loss on ignition is: Loss on ignition [% by weight] H 2 O at 100 ° C 3.34 to 3.36 H 2 O at 300 ° C 5.42 to 5.51 H 2 O at 500 ° C 2.60 to 2.64 H 2 O at 1000 ° C 2.50 to 2.51 All in all 13.86 to 13.92
  • the results of the electrical conductivity test showed that the zeolites treated according to the invention are able to bind significantly more hydrogen ions than the untreated zeolites. This is the direct consequence of the differences in the crystal structure of the zeolites investigated, which have arisen due to the fine grinding and micronization.
  • the following table shows examples of the measurements of the conductivity and the pH of the suspension in the case of untreated and treated zeolites: Mixing time of the suspensio Concentration of zeolite (mg / ml H 2 O) pH (deactivated Zeoith) pH (zeolite treated according to the invention) conductivity (inactive zeolite) ⁇ S / cm conductivity (Zeolite treated according to the invention) ⁇ S / cm 2 hours. 20 7.35 7.48 157 147 2 hours. 40 6.45 7.22 198 180 2 hours. 60 6.81 7.35 307 280 20 hours 40 6.67 6.90 259 218 20 hours 80 6.96 7.40 48 hours 80 6.87 7.44
  • the pH of the untreated to the treated Zeolites increase while conductivity decreases.
  • the treated zeolite due to the sinking Conductivity is ideally predestined to be natural and physiological effective buffer material to be used because the buffering capacity of the treated zeolite powder and the associated resistance of the pH value means that the treated material, e.g. on his way through the digestive tract, from gastric acid not entirely, but is only slightly saturated.
  • the treated zeolite remains in the Small intestine active, which is ultimately a desirable result ..
  • the test patients with the indications listed above have the treated Powdered material mixed with water.
  • the dosage was between 1 g and 12 g daily; the frequency of taking was 3 to 12 times a day.
  • the dosage was 0.5 g to 1 g per dose with an interval of 1-6 hours between administration.
  • the intake of the dynamically finely ground and micronized zeolite also has good properties in chronic symptom relief Arthritis, especially rheumatic arthritis. There were also successes in dermatological diseases such. B. Psoriasis, Lupus Erritematodesa, Wound and burn healing observed.
  • Products such as jams, jams, fruit syrups and some juices include a significant amount of sucrose, which this sweetness as well which gives appropriate reological and organoleptic properties, but it also has a preservative effect.
  • sucrose which this sweetness as well which gives appropriate reological and organoleptic properties, but it also has a preservative effect.
  • Such products for The diet of diabetics does not include this sucrose, it will replaced with sorbitol or hydrocoloids and technical preservatives.
  • the conservation effect is in demand achieved (due to the control of the activity of some types of bacteria).
  • the biological value of the product is increased (favorable Influence of the treated zeolite on the general state of health). So adding chemical preservatives will not necessary.
  • Treated zeolites are also suitable as aids in decolorization processes of food (in the production of oils, lecithin, protein hydrolyzates, Glucose and the like), where the standard means such. B. activated carbon be replaced for better efficiency.
  • Fine grinding can be used in the production of syrup from starch become, d. H. in the production of confectionery products and protein hydrolyzates, which as additives in the manufacture of finished and semi-finished Serve courts; but also in the process of clarifying fruit juices, these processes replacing the process of depectinization.
  • the outer shell of the starch granules which is composed of amilopectin are severely damaged and mostly by the fine grinding disintegrated.
  • the molecules of amilopectin are on the shorter Chains broken, with some fractions such as glucose, maltose and dextrins, to be released.
  • Due to the measures according to the invention classical methods of flour grinding can be dispensed with, which means that It enables the production of flour with specific physical properties becomes. This means that the acid hydrolysis of the starch for the purpose of No starch syrup is produced. The addition of acids is not necessary just like the thermal treatment of the raw materials.
  • the described method also results in physical properties of raw materials changed. Above all through the destruction and damage of components of the starting material is the average grain size reduced. There are granules with a uniform grain size; the specific surface area of the granules is increased.
  • the processing described of powders leads to an increase in bulk density, as well an improvement in solubility and dispersibility. This is important for the stabilization of the production process in the manufacture of dehydrated Juices and drinks, because of the processing described the powders acquire the properties of instant substances (fruit juice, Cocoa, coffee, tea), which means that they are quick and easy in cold Media are reconstituted.
  • the absorption capacity of ammonium ions and ion exchange up to 300%, in Compared to the non-activated basic substance, increased.
  • This attribute of the treated material is suitable for the purpose of binding unpleasant smells.
  • the treated material can thus be used for binding unpleasant smells of organic origin in pork, calf, Turkey and chicken farms are used successfully. Because the odor control done in a very short period of time, the treated one is suitable Material for spraying in rooms, for animal fattening or breeding. It creates a more pleasant atmosphere for animals and humans.
  • the binding of the unpleasant smells has the consequence that the nitrogen content in the case of organic waste, not by evaporation or flushing out get lost.
  • the binding of nitrogen not only increases the fertilizer value, it also serves to protect the environment, especially the soil and Groundwater, since the nitrogen ions are so bound that they are caused by rainwater not be flushed into the groundwater.
  • Slurry, manure and chicken slurry can be achieved.
  • nitrogen compounds ammonium, nitrates, Nitrites, Kaptane
  • an addition of the treated material which the Solid content of the waste mentioned corresponds to the mass.
  • For acceleration composting and the production of mineral-organic Fertilizers have a solids ratio of 70%: 30% in favor of the treated material, preferred.
  • the material treated according to the invention shows surprising effects with a view to minimizing harmful ingredients of filter cigarettes.
  • the classic filter is the cellulose acetate filter.
  • additives like it Activated carbon, zeolites, silica gel, magnesium silicate and artificial hemoglobin are used.
  • suction resistance pressure drop
  • Many additives and construction solutions increase suction resistance and unwanted effects when smoking. This is the simple reason why most of the simple cellulose acetate filters are still used.
  • the material treated according to the invention surprisingly increases the Efficiency and selection of the filters, as well as stopping and improvement the desired taste of the cigarette; thereby the suction resistance of the filter hardly changed.
  • the treated zeolites are larger Absorbance strength due to changes in the crystal lattice is.
  • a filter additive in cellulose acetate filters as a powder has also been advantageous a grain size of 0.2 to 0.5 ⁇ proved.
  • those treated according to the invention can be used Zeolites directly on the cellulose acetate fiber or the paper or crest apply - like an additive in the cavity of a multifilter, combined with the dual filter etc.
  • Filters that were the subject of a controlled experiment were passed through Adding zeolites treated according to the invention directly to the cellulose acetate fiber produced after using plasticizers (triacetin) before the filter sticks in the cylinder.
  • the powder was applied directly to the fiber using a specially designed dosimeter. This made it possible, almost uniformly, up to 70 mg of the invention add treated zeolite per filter stick. This How the powder is added affects the work of conventional machines and the shaping of the filter sticks is not essential since the machines a dedicated space in the workflow for the production of the filter sticks for this application. By this way of adding the powder
  • the technology of stick production does not change significantly. The technological process is only increased by the price of the additives.
  • the results obtained are averages of the measurements of 500 filter sticks from each sample.
  • the proportion of treated zeolite added was calculated based on the difference in the amount of ash obtained when the filter sticks were burned in the Mufon oven at 525 ° C.
  • essentially conventional filter paper without ventilation and a tobacco mixture were used, which is used in the production of full flavor American Blend cigarettes.
  • the processed cigarettes were sorted by weight and suction resistance and tested on the smoking machine (Borgwaldt RM 20) according to the ISO standard. Each sample was tested 5 times on the machine.
  • the amount of dry smoke condensate (total particulate matter), nicotine, CO 2 , water and tar were determined. All analyzes were carried out according to the applicable ISO standard; the amount of nicotine in the dry smoke condensate was carried out by extraction with 2-propanol and subsequent HPLC.
  • samples 5 - 11.3 mg and samples 4 - 1.66 mg have an improved smoke taste and a pronounced aroma, so that they are generally more pleasant are smoking.
  • the following table shows the measured average values of the filters after smoking.
  • the amount of dry smoke condensate was calculated from the difference in the amount of the production material before and after smoking.
  • the amount of nicotine was determined by extraction from the filter in 2-propanol and water by the Karl Fisher method.
  • the results show that the filters applied with the zeolite treated according to the invention have an increased ability to absorb dry smoke condensate, nicotine and water, which underlines the previous measurements and results.
  • the application of the zeolite treated according to the invention to cellulose acetate fiber from cigarette filters thus leads to an increased retention of harmful components of the main stream of cigarette smoke, satisfactory physical properties, but without having a negative influence on the tasting and smoking properties of a cigarette.
  • the addition of 0.50 mg of the zeolite treated according to the invention per filter eliminates 4% dry smoke condensate, CO 2 and nicotine, and 11% water.
  • An addition of 11.30 mg of the zeolite treated according to the invention per filter eliminates 27% dry smoke condensate, CO 2 and nicotine, and 42% water from the main stream of the smoke.
  • selenium up to 25 ⁇ g / filter
  • the processed material is a added a small amount of hydrated or non-slaked lime.
  • This method of manufacturing building material is based on the accelerated reaction between SiO 2 and Al 2 O 3 from the composition of the building material on one side and Ca (OH) 2 from lime on the other.
  • the proportions of the composition of technological parameters and the peculiarities of the finished products can be described with the following information become:
  • the proportion of finely ground and micronized desert sand is 90.6 - 95.4%; the lime content in the mixture 4.6 - 9.4%.
  • the mixture will homogenized and water in a ratio of 1.0: 0.08-0.12 (mixture: water) added.
  • the raw mixture prepared in this way is passed through Shaped presses; it then cures hydrothermally under the following conditions from: pressure of pressing: 40 - 90 MPa; Curing temperature: 90 and 170 ° C; Curing time: 4.5 - 7.0 h.
  • the desired physical-mechanical properties of the material depend directly on the machining process described, as well from the selected technological parameters used in the manufacturing process be applied from. Are comparable to these results if necessary, concrete bricks, which by adding cement (15-25 wt .-%) getting produced.
  • the bricks produced according to the invention do not have any physical disadvantages.
  • Bricks, roof tiles, beams, blocks, pots and other ceramic products are traditionally made from such types of clay that do not contain various components that damage the baking process of the molded products.
  • the increased proportion of calcium carbonates (CaCO 3 ) in the composition of the raw material clay causes a so-called blooming on the finished product, since the baking temperature increases in the temperature range of the sintering process (in a range of 960 - 1200 ° C).
  • the material prepared in this way was mixed with water until it had reached the optimum moisture level and was then shaped by the pressing process.
  • a brick of normal size 6.5 x 12.5 x 25.0 cm was made. After being molded by the pressing method, the brick was dried at a temperature of up to 200 ° C. for 24 hours and then baked at a temperature of 560 ° C. The sintering process was successfully carried out at this temperature. This temperature was maintained for 60 minutes after the cooling process started gradually. The entire process of increasing the temperature, the sintering process and cooling down took 12 hours.
  • a brick of normal size 6.5 x 12.5 x 25.0 cm was used; the same raw material component clay was used as the raw material base as in the previous experiment, with the difference that the clay was not micronized.
  • the brick had to be dried by molding at a temperature of 240 ° C for 48 hours after molding. Then it was baked at a temperature up to 980 ° C, at which the temperature range of the sintering process was reached. This temperature had to be held for 120 minutes before the cooling process could be initiated. The whole process of raising the temperature, sintering and cooling took 22 hours. The process was repeated 25 times without significant changes to the process.
  • FIG. 1 shows a device 10 for fine grinding and micronization, as well as the homogenization of various solid and liquid raw material components.
  • the principle is such that the starting material through the center of the rotors sucked into the processing space of the device becomes. Entry is caused by the action of centrifugal forces in the Space between the fan blades favors and is due to the air currents there accelerate; so the material with that already processed material collides.
  • the source material changes Direction of movement in very short intervals; as a result, it is crushed and micronized.
  • the device 10 consists of a hinged housing 11 with a Material insertion shaft 11d, in which there are two rotor disks 12, which are placed against each other and by means of appropriate motors 13 can be operated in opposite directions via belts 13a, so that they are the same Rotate angular velocity.
  • the housing 11 and the motors 13 are on attached to the foundation 14 and form an independent unit.
  • FIG. 2 shows that the housing 11 is composed of two parts: one side of the housing 11a for the material introduction and a further housing side 11b with insertion shaft 11c. These two sides 11a, 11b are screwed together. On both sides of the housing 11 are the carriers 15, in which the bearings 16 and horizontal bars 17 are installed. On page 11a for the material import there is a tube 18 for the regulated import of the material; on the lower side there is an opening 19 for the discharge of the finished material.
  • Figures 3, 4 and 5 shows that on the rotor disks 12 several concentric Wreaths 20 with the pins 21 and fan blades 22 arranged are constructed and aligned in such a way that they are non-contact, while they turn in opposite directions, can run alongside each other - indicated due to the direction of rotation 25. At least two rings are required, which are driven by the two rotors.
  • the task of the firing pins 21 and the fan blades 22 is the generation of turbulent air flows for the acceleration of the processed material, so that bumps and friction under the granules at certain angles under dynamic Conditions.
  • the channels 23 on the disks prevent the passage of material under the fan blades 22, cf. figure 3 a and 3b.
  • the starting granulate (not shown) is through the central part 18 of the Engine system introduced by suction, through the air streams 26th accelerated and controlled so that the granules as a result of repeated movement collide with each other and collapse in very short time intervals rub against each other.
  • the work tools and others touch each other Parts of the device not or only slightly - but it does not matter Case of tool destruction. There is an interaction under the granules to such an extent that the internal energy of the granules is exchanged because the collisions are non-plastic (see FIG. 4 and 5).
  • the material shows which is finely ground by the device according to the invention and micronized, increased free energy and responsiveness.
  • the innovation therefore lies in the construction (shape, toothing, inclination) and interchangeability of pins and fan blades on the constructed Channels that are on the rotor disc and in the selection of the material for the preparation of fan blades.
  • the rotating disks the device rotate at the same angular velocity, but move in opposite directions.
  • the starting material is through the Intake pipe 18 inserted into the central part of the rotating disc, due to
  • the granules of the raw material component become from centrifugal forces accelerated towards the outer edge of the housing.
  • the granules hit the rings 20 of the fan blades 22, which are in the opposite direction rotate. You change the direction of movement due to the Change of direction of the fan blades.
  • Figure 3a and 3b shows that the channels 23 on the disks 12 into which the Reach through fan blades 22, the material passage under the fan blades 22 prevent.
  • Their shape is according to the properties the respective raw material components to be processed - i.e. granulation of the starting material, its moisture, hardness, origin, chemical Composition and the like - defined. If e.g. B. the input granulation of the material is ⁇ 1 mm, this means that the minimum Distance between the fan blades and the ducts on the Slices should be larger than 1 mm to prevent the material from going through at all to enable.
  • satisfactory parallelism is to be realized with the fan blades to reach through the channels because of the diameter the discs are relatively large (500 mm).
  • disc channels (23) are shown in more detail.
  • the channels (23) are mutually exclusive with the length a, which is 2 - 5 mm. They are like a labyrinth, which the passage of the material under the fan blades prevented. Resistance increases through the creation of the labyrinth for the flow under the fan blades. Thus it is achieved that the granules of the starting material through the main flow move between the fan blades.
  • the shape of the channels is according to technical-technological properties of the raw material components of the processed material defined (granulation of the starting material, its Moisture, hardness, origin, chemical composition and the like). If there were not the disc channels, the starting material would be due to the centrifugal forces, move it from the center to to the periphery of the discs on the fan blades and the disc passes. With the initial granulation of the material from 0 - 1 mm must the distance between the fan blades and the ducts is greater than 1 mm in order to allow the passage of the material at all, advantageous has a distance of 2 mm just as for the concealment a proved.
  • Figures 6, 6a, 6b and 6c show the geometry of the fan blades 22 and the pins 21.
  • the collar 20, the fan blades 22 and the pins 21 are made of high carbon steel.
  • An alternative is the porcelain pen and pencil to manufacture the fan blades from steel.
  • the degree of bending of the fan blades is related to the Lengths a and b defined, where b represents 10% of the tendon length. The order the fan blades are fixed.
  • the pin's axis of symmetry 21 is located in the axis of symmetry of the degree of bending of the fan blades 22, so the geometry of the system of fan blades / pins is optimally achieved. Beat during material processing the granules of material on the front of the fan blades and in particular on and in the pens. The pen will wear out. After wear the pin is exchanged for a new one by pressing or drilling. This has a decisive advantage: previous versions of the fan blades without pins have wear on the fan blades surrender themselves. The replacement of the worn fan blades is in the Comparison with the replacement of the pens very complicated, time-consuming and expensive. The pins can therefore be easily replaced; the fan blades remain undamaged and don't have to. Replacing the fan blades only occurs when there is general material fatigue.
  • the problem of vibrations and the strength of the pins is solved that the pin 21 with the area of 1/3 of its pen circumference to a corresponding one Recess of the fan blade 22 on these fan blades "leans", and not straight on the fan blades inspired.
  • the fan blades 22 are deformed by cold pressing or also by forging, the forging being the better hardening serves.
  • segment fan blades according to the invention ( Figure 7, 7a).
  • the segment fan blades 22 are made of ceramic or cast steel.
  • the channels are installed in the rotor disks 12, in which the segment fan blades with indefinite appeals.
  • the Accuracy of settings and the strength of the fan blades will due to the profile of the ducts and the friction between the segment fan blades and determines the supporting disc.
  • the classification of teeth 22b and their size is depending on the length of the fan blades 22, angle ⁇ is 30 ° - 120 °, and angle ⁇ is 60 ° - 120 °.
  • the degree of bending of the fan blades is defined with the ratio of the lengths a and b, where b is 10% of the Represents tendon length.
  • the shape of the fan blades, the profiled (toothed) collision surface and the slope ensure that the fan blades be filled with the starting material and thus from the Wear protection of the starting material are protected, which on the Extension of the lifespan of the fan blades works.
  • the teeth 22b hold the first layer of the starting material on the fan blades as in FIG on the collision surface 22a while the second layer slowly slips over the first layer and this second layer takes the Strikes of the incoming raw material.
  • This version has in Compared to the above version (Fig. 6) the advantage that the fan blades can be installed with different inclinations (angle ⁇ ); Consequently the replacement of the fan blades is easier.
  • the shape of the fan blades has no recess for the pens.

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EP02090409A 1999-04-26 1999-04-26 Utilisation de mineraux micronisés comme produit phytosanitaire Withdrawn EP1316255A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99913546A EP1107826A1 (fr) 1999-04-26 1999-04-26 Dispositif pour microniser des materiaux
PCT/IB1999/000757 WO2000064586A1 (fr) 1999-04-26 1999-04-26 Dispositif pour microniser des materiaux

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EP99913546A Withdrawn EP1107826A1 (fr) 1999-04-26 1999-04-26 Dispositif pour microniser des materiaux
EP02090411A Expired - Lifetime EP1317886B1 (fr) 1999-04-26 1999-04-26 Utilisation de zéolites micronisées comme matériel filtrant
EP02090409A Withdrawn EP1316255A1 (fr) 1999-04-26 1999-04-26 Utilisation de mineraux micronisés comme produit phytosanitaire
EP02090410A Revoked EP1316530B1 (fr) 1999-04-26 1999-04-26 Zeolithes micronisées destinés à être utilisés comme préparations pharmaceutiques

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EP02090411A Expired - Lifetime EP1317886B1 (fr) 1999-04-26 1999-04-26 Utilisation de zéolites micronisées comme matériel filtrant

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AT (2) ATE365002T1 (fr)
AU (1) AU3164899A (fr)
DK (1) DK1316530T3 (fr)
ES (2) ES2234981T3 (fr)
HR (1) HRP990263A2 (fr)
PT (1) PT1316530E (fr)
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013050599A2 (fr) 2011-10-07 2013-04-11 Sanoviva Ag Procédé de modification de la structure de minéraux
DE102012109527A1 (de) * 2012-10-08 2014-04-10 Sanoviva Ag Verfahren zum Behandeln von Samen
CN109718627A (zh) * 2019-03-11 2019-05-07 杨松 一种制备辊道窑除尘用滤料工艺装置

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10323759A1 (de) * 2003-05-22 2004-12-16 Bauer, Wulf, Dr. Heilmittel zur inneren Anwendung, insbesondere gegen Krebserkrankungen
DE10323758A1 (de) * 2003-05-22 2004-12-16 Bauer, Wulf, Dr. Heilmittel zur inneren Anwendung, insbesondere gegen Krebserkrankungen
DE112006002041A5 (de) * 2005-05-18 2008-04-30 Mijo Ljubicic Pharmazeutisch wirksame Zusammensetzung zur Behandlung von Diabetes
DE102005053090A1 (de) * 2005-11-04 2007-05-10 Hubert Danz Verwendung eines aktivierten Zeolithen als pharmazeutisches Mittel für die Reduzierung giftiger Stoffe
EP1839666A1 (fr) * 2006-02-15 2007-10-03 Tihomir Lelas Composition pour traiter l'hypertension comprenant des zeolites activés tribomécaniquement
WO2007056996A2 (fr) * 2005-11-15 2007-05-24 Ljubicic, Mijo Antihypertenseur et son utilisation
DE102005059757A1 (de) * 2005-12-12 2007-06-14 Beharrysingh-Pracejus, Ramona Brenda Ökologische Schimmelbekämpfung durch natürlichen Massenrohstoff (Zeolith) als Fungizidersatz
EP1938825B1 (fr) * 2006-12-22 2014-06-25 Jakob Hraschan Utilisation de la zéolithe naturelle pour le traitment et la prévention de la ostéoporose
DE102008022726A1 (de) 2008-05-06 2009-11-12 Winkler, Kurt, Dr. Verfahren für den Kontakt einer Gasphase mit einer Flüssigkeit in Anwesenheit eines Feststoffes
DE102009012774A1 (de) * 2008-07-11 2010-01-14 Sanoviva Ag Vorrichtung zur Strukturänderung von Mineralien und Verwendung von derart veränderten Mineralien
WO2010057849A1 (fr) 2008-11-21 2010-05-27 Froximun Ag Procédé de réduction de la concentration des amines et de leurs sels
DE202010013541U1 (de) 2010-02-22 2010-12-23 Biotake Gmbh Zeolith-haltige Zubereitungen enthaltend Clinoptilolith
IT1401589B1 (it) * 2010-08-03 2013-07-26 Ecobase Gmbh Zeoliti ad azione neuroprotettiva.
WO2012025770A2 (fr) * 2010-08-23 2012-03-01 Creogen D.O.O. Dispositif pour la micronisation de matières solides et son utilisation
CN103167912B (zh) * 2010-08-23 2015-07-01 莱姆巴诺贸易有限公司 用于微粉化固体材料的设备
DE102010052608A1 (de) 2010-11-02 2012-05-03 Zeovita Gmbh Verwendung von aktivierten Zeolithen zur optimalen Absorption von Zigarettenschadstoffen
WO2012064294A1 (fr) 2010-11-09 2012-05-18 KAYA, Selçuk Moyen de réduction des constituants nocifs de la fumée, comprenant une colonne de tabac et un élément filtrant
WO2012095182A1 (fr) 2011-01-14 2012-07-19 DURMUS, Zeynel Aérosol pour le transfert d'énergie thermique
EP2689855B1 (fr) 2012-07-24 2015-07-01 Oekomineral AG Dispositif de micronisation modifié et son utilisation
CN103446468B (zh) * 2013-06-04 2015-12-09 北京友合攀宝科技发展有限公司 一种沸石药物组合物及其用途
US11324244B2 (en) 2013-07-03 2022-05-10 Conopco Inc. Potato derived flavour enhancing composition and method for the manufacture thereof
EP3167890A1 (fr) * 2015-11-12 2017-05-17 Glock Health, Science and Research GmbH Traitement de la vaginite
PL3329926T3 (pl) 2016-12-02 2020-03-31 Jakob Hraschan Kompozycje zeolitowe i sposób ich wytwarzania
WO2018121803A1 (fr) 2016-12-28 2018-07-05 Houdek Jan Dispositif et procédé de micronisation de matériaux solides
RU2768552C2 (ru) * 2016-12-29 2022-03-24 Филип Моррис Продактс С.А. Фильтр курительного изделия с аморфным карбонатом магния
US11154868B2 (en) * 2017-02-24 2021-10-26 Greenvolt Nano Inc. Apparatus and method for forming nanoparticles
PL238905B1 (pl) * 2018-02-16 2021-10-18 Centrum Badawczo Rozwojowe Glokor Spolka Z Ograniczona Odpowiedzialnoscia Sposób wytwarzania koncentratu do produkcji napoju prozdrowotnego zawierającego związki krzemu, stosowanego jako enterotransporter lub enterosorbent oraz modułowa instalacja do wytwarzania koncentratu
US11305343B2 (en) 2018-02-28 2022-04-19 Nanom Inc. Apparatus and method for programming a crystal lattice structure of nanoparticles
RU2668752C1 (ru) * 2018-03-07 2018-10-02 Михаил Григорьевич Макаренко Фильтр для сигарет

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58149639A (ja) * 1982-02-26 1983-09-06 Shiraishi Calcium Kk 果実の品質向上方法
EP0125370A1 (fr) * 1983-04-19 1984-11-21 NICO-PYROTECHNIK Hanns-Jürgen Diederichs GmbH & Co. KG Procédé de traitement de végétation endommagée et dispositif pour la mise en oeuvre du procédé
JPS60149508A (ja) * 1984-01-17 1985-08-07 Tomono Noyaku Kk スリツプスの被害防止方法
DE19505382A1 (de) * 1995-02-17 1996-08-22 Norbert Kaschel Mittel zur Steigerung der Assimilationsintensität von Kulturpflanzen
WO1998038867A1 (fr) * 1997-03-05 1998-09-11 Engelhard Corporation Procede de protection de surfaces contre l'infestation par des arthropodes
DE19755921A1 (de) * 1997-12-16 1999-06-17 Utp Dr Snyckers Gmbh Verfahren und Vorrichtung zur Verbesserung der Wirksamkeit von Wirkstoffen, die mindestens aus Mineralstoffen bestehen

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE13260C (de) * C. G. W. KAPLER in Berlin Neuerungen an Schlagstiftenmaschinen
DE625873C (de) * 1936-02-17 Wilhelm Grube Schleudermuehle mit gegenlaeufigen Schlagstiftscheiben
US3047243A (en) * 1959-09-23 1962-07-31 J M J Ind Inc Disintegrating mill
NL294141A (fr) * 1962-07-06
GB1009535A (en) * 1963-10-15 1965-11-10 British American Tobacco Co Improvements in tobacco-smoke filters
US4038992A (en) * 1975-09-29 1977-08-02 The Japan Tobacco & Salt Public Corporation Granular composition for tobacco filter
US4173622A (en) * 1978-01-03 1979-11-06 Fmc Corporation Zeolite A crystals of uniformly small particle size and the manufacture thereof
DE3034849A1 (de) * 1980-09-16 1982-04-29 Kasa-Forschungs- und Entwicklungs-Gesellschaft mbH & Co KG für Verfahrenstechnik, 6000 Frankfurt Desintegrator und verfahren zum betrieb des desintegrators
US4580736A (en) * 1983-12-29 1986-04-08 Toshiba Ceramics Co., Ltd. Cage mill
DE3802260A1 (de) * 1988-01-27 1989-08-10 Kasa Technoplan Rotierende desintegrationsvorrichtung
EP0695216B1 (fr) * 1993-04-23 1998-07-22 Exxon Chemical Patents Inc. Couches a tamis moleculaire cristallin et leurs procedes de fabrication
DE4322757C1 (de) * 1993-07-08 1994-07-21 Holger Hannemann Desintegrator
US5612522A (en) * 1994-06-17 1997-03-18 Levy; Ehud Adsorption and ion exchange zeolite gel media to improve the quality and carbonation of water
US5871650A (en) * 1994-07-08 1999-02-16 Exxon Research And Engineering Company Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer
GB9508821D0 (en) * 1995-05-01 1995-06-21 Unilever Plc Small particle size p-type zeolite
DE69524059T2 (de) * 1995-05-03 2002-07-18 British American Tobacco (Investments) Ltd., London Rauchartikel
US5704556A (en) * 1995-06-07 1998-01-06 Mclaughlin; John R. Process for rapid production of colloidal particles

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58149639A (ja) * 1982-02-26 1983-09-06 Shiraishi Calcium Kk 果実の品質向上方法
EP0125370A1 (fr) * 1983-04-19 1984-11-21 NICO-PYROTECHNIK Hanns-Jürgen Diederichs GmbH & Co. KG Procédé de traitement de végétation endommagée et dispositif pour la mise en oeuvre du procédé
JPS60149508A (ja) * 1984-01-17 1985-08-07 Tomono Noyaku Kk スリツプスの被害防止方法
DE19505382A1 (de) * 1995-02-17 1996-08-22 Norbert Kaschel Mittel zur Steigerung der Assimilationsintensität von Kulturpflanzen
WO1998038867A1 (fr) * 1997-03-05 1998-09-11 Engelhard Corporation Procede de protection de surfaces contre l'infestation par des arthropodes
DE19755921A1 (de) * 1997-12-16 1999-06-17 Utp Dr Snyckers Gmbh Verfahren und Vorrichtung zur Verbesserung der Wirksamkeit von Wirkstoffen, die mindestens aus Mineralstoffen bestehen

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
"CHEMICAL ABSTRACTS + INDEXES, AMERICAN CHEMICAL SOCIETY. COLUMBUS, US", CHEMICAL ABSTRACTS + INDEXES, AMERICAN CHEMICAL SOCIETY. COLUMBUS, US, vol. 23, no. 103, 9 December 1985 (1985-12-09), XP002069874, ISSN: 0009-2258 *
"CHEMICAL ABSTRACTS + INDEXES, AMERICAN CHEMICAL SOCIETY. COLUMBUS, US", CHEMICAL ABSTRACTS + INDEXES, AMERICAN CHEMICAL SOCIETY. COLUMBUS, US, vol. 5, no. 114, 4 February 1991 (1991-02-04), XP002069875, ISSN: 0009-2258 *
PATENT ABSTRACTS OF JAPAN vol. 007, no. 268 (C - 197) 30 November 1983 (1983-11-30) *
PATENT ABSTRACTS OF JAPAN vol. 009, no. 309 (C - 318) 5 December 1985 (1985-12-05) *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013050599A2 (fr) 2011-10-07 2013-04-11 Sanoviva Ag Procédé de modification de la structure de minéraux
DE102011054293A1 (de) 2011-10-07 2013-04-11 Sanoviva Ag Verfahren zum Herstellen eines Mittels
DE102012109527A1 (de) * 2012-10-08 2014-04-10 Sanoviva Ag Verfahren zum Behandeln von Samen
CN109718627A (zh) * 2019-03-11 2019-05-07 杨松 一种制备辊道窑除尘用滤料工艺装置
CN109718627B (zh) * 2019-03-11 2021-06-11 杨松 一种制备辊道窑除尘用滤料工艺装置

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EP1317886B1 (fr) 2007-06-20
PT1316530E (pt) 2005-04-29
EP1107826A1 (fr) 2001-06-20
EP1317886A1 (fr) 2003-06-11
EP1316530A1 (fr) 2003-06-04
WO2000064586A1 (fr) 2000-11-02
HRP990263A2 (en) 2009-04-30
AU3164899A (en) 2000-11-10
ES2289051T3 (es) 2008-02-01
DK1316530T3 (da) 2005-04-25
SI1316530T1 (en) 2005-06-30
ES2234981T3 (es) 2005-07-01
ATE284840T1 (de) 2005-01-15
EP1316530B1 (fr) 2004-12-15
ATE365002T1 (de) 2007-07-15

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