EP1262509B1 - Imid-benzoxazolpolykondensat sowie verfahren zur herstellung - Google Patents
Imid-benzoxazolpolykondensat sowie verfahren zur herstellung Download PDFInfo
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- EP1262509B1 EP1262509B1 EP00974822A EP00974822A EP1262509B1 EP 1262509 B1 EP1262509 B1 EP 1262509B1 EP 00974822 A EP00974822 A EP 00974822A EP 00974822 A EP00974822 A EP 00974822A EP 1262509 B1 EP1262509 B1 EP 1262509B1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/22—Polybenzoxazoles
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/022—Quinonediazides
- G03F7/023—Macromolecular quinonediazides; Macromolecular additives, e.g. binders
- G03F7/0233—Macromolecular quinonediazides; Macromolecular additives, e.g. binders characterised by the polymeric binders or the macromolecular additives other than the macromolecular quinonediazides
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/0346—Organic insulating material consisting of one material containing N
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24917—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
Definitions
- the present invention relates to an imide-benzoxazole-based polycondensate and process for producing the same.
- the polycondensate according to the present invention may suitably be used as an insulation film which does not warp the foil, by coating a copper foil with the polycondensate and heating the coated copper foil.
- Polyimides are excellent in heat resistance, electric insulation performance, mechanical properties, chemical resistance and the like, so that they are widely used in electric and electronic parts, airplane parts, car parts, peripheral circuits of semiconductors and the like, with the compaction and precision of these.
- Flexible printed boards made of a polyimide are subjected to a number of steps accompanying heat treatments at high temperatures, so that dimensional change occurs, which is problematic to processing of the boards.
- a material for forming a composite board for use as a flexible printed board or a film for TAB, which is prepared by coating copper foil with a polyimide to form a multi-layered board, and which is free from warping, is demanded.
- a flexible printed board with good adhesion and reduced warping may be obtained by employing a solvent-soluble polyimide and treating the polyimide film-coated substrate at a low temperature (Japanese Laid-open Patent Application (Kokai) No. 10-224017).
- a method in which a polyimide having ether imide group is employed Japanese Laid-open Patent Application (Kokai) No. 8-217877
- a method in which a polyimide composition in which the polyimide components are variously changed Japanese Laid-open Patent Application (Kokai) Nos. 7-41556 and 60-243120
- polyimides are also applied to circuit boards or the like as photosensitive resins. They are used as negative-type photoresists by converting the polyamic acid to acrylic acid ester thereof, irradiating the resultant with light after adding a radical generator, thereby curing the irradiated portions, and dissolving the non-irradiated portions in an alkaline developer to form negative-type images. Since positive-type photoresists are more sensitive and give higher resolutions than the negative-type photoresists, a positive-type photoresist is demanded for forming patterns of through holes.
- Novolak resins have phenolic hydroxyl groups, and upon being irradiated with light together with a photoacid generator, they come to be soluble in alkaline developers, so that they are widely used as positive-type photoresists.
- Polyimides having phenolic hydroxyl groups have been prepared, and it has been confirmed that upon irradiating such a polyimide together with a photoacid generator, they come to be soluble in alkaline developers so as to form positive-type images (Japanese Laid-open Patent Application (Kokai) No. 64-60630, USP4,927,736, Japanese Laid-open Patent Application (Kokai) Nos. 3-209478 and 4-110348). It has been shown that polyimide having no phenolic hydroxyl groups do not form positive-type images (Japanese Laid-open Patent Application (Kokai) No. 3-209478).
- An object of the present invention is to provide a novel imide-benzoxazole-based polycondensate which may give a flexible circuit board free from deformation such as curling and twisting, by coating a copper foil with the polycondensate and heating it to make a coating film, and which may give photosensitivity by adding a photoacid generator, as well as a production process thereof.
- the present inventors intensively studied to discover that a polycondensate containing an imide component having a phenolic hydroxyl group and a benzoxazole component having a carboxyl group as constituting units is obtained by polycondensing one or more tetracarboxylic dianhydrides with one or more aromatic diamines having an amino group and a phenolic hydroxyl group under prescribed conditions, the amino group and the phenolic hydroxyl group in the diamine being located at ortho positions with respect to each other, and the polycondensate attains the above-mentioned object of the present invention, thereby completing the present invention.
- the present invention provides a process for producing a solvent-soluble polycondensate containing a benzoxazole component having a carboxylic group and an imide component having a phenolic hydroxyl group, which process comprising dehydration-condensing one or more tetracarboxylic dianhydrides with one or more aromatic diamines having an amino group and a phenolic hydroxyl group, said amino group and said phenolic hydroxyl group being located at ortho positions with respect to each other, by heating said one or more tetracarboxylic dianhydrides and said one or more aromatic diamines at 150°C to 220°C in the presence of an acid catalyst.
- the present invention further provides a composite copper substrate obtainable by coating a copper foil with the polycondensate according to the present invention and heating the resultant at 150°C to 250°C.
- the present invention still further provides a method for forming a positive-type image comprising coating a substrate with a photosensitive polycondensate composition containing the polycondensate according to the present invention and a photoacid generator; irradiating the composition with a light through a mask pattern; and developing the resulting composition with an alkaline developer.
- the present invention still further provides a circuit board produced by subjecting a copper foil to the above-described method for forming positive-type images.
- the present invention still further provides a method comprising heating the polycondensate according to the present invention at 300°C to 350°C so as to convert it to polyimide.
- a novel imide-benzoxazole-based polycondensate which may give a flexible circuit board free from deformation such as curling and twisting, by coating a copper foil with the polycondensate and heating it to make a coating film, and which may give photosensitivity by adding a photoacid generator, as well as a production process thereof, is provided.
- one or more tetracarboxylic dianhydrides are dehydration-condensed with one or more aromatic diamines having an amino group and a phenolic hydroxyl group, the amino group and the phenolic hydroxyl group being located at ortho positions with respect to each other, by heating the one or more tetracarboxylic dianhydrides and the one or more aromatic diamines at 150°C to 220°C in the presence of an acid catalyst.
- the tetracarboxylic dianhydride used in the method of the present invention is not restricted and aromatic tetracarboxylic dianhydrides are preferred.
- Preferred examples include 3,4,3',4'-biphenyltetracarboxylic dianhydride, 2,3,3',4'-biphenyltetracarboxylic dianhydride, 3,4,3',4'-benzophenonetetracarboxylic dianhydride, bicyclo(2,2,2)-oct-7-ene-2,3,5,6-tetracarboxylic dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, bis(3,4-dicarboxyphenyl)sulfone dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride and 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, but the tetracar
- the diamine used in the method of the present invention is an aromatic diamine having an amino group and a phenolic hydroxyl group which are located at ortho position with respect to each other. That is, the aromatic diamine used here is one having, on an aromatic ring, preferably benzene ring, a hydroxyl group (i.e., phenolic hydroxyl group) and an amino group located at ortho position of the phenolic hydroxyl group, and another amino group located at a different position. As long as these requirements are met, the diamine is not restricted.
- Preferred examples of the aromatic diamine having an amino group and a phenolic hydroxyl group, which are located at ortho positions with respect to each other, include 1-hydroxy-2,4-diaminobenzene, 1-hydroxy-2,5-diaminobenzene, 3,3'-dihydroxybenzidine, 3,3'-dihydroxy-4,4'-diaminodiphenyl ether, 1,4-bis(3-hydroxy-4-aminophenoxy)benzene, 2,2-bis(4-amino-3-hydroxyphenyl)propane, bis(3-amino-4-hydroxyphenyl)propane, bis(3-amino-4-hydroxyphenyl)sulfide and 2,2-bis(3-amino-4-hydroxyphyenyl)hexafluoropropane, but the aromatic diamine is not restricted to these examples. These aromatic diamines may be employed individually or in combination.
- the dehydration condensation reaction is carried out by heating the above-mentioned tetracarboxylic dianhydride(s) and the aromatic diamine(s) at 150°C to 220°C, preferably 170°C to 200°C, in the presence of an acid catalyst. If the reaction temperature is lower than 150°C, the dehydration condensation does not well proceed, and if it is higher than 220°C, benzoxazole component is not well formed.
- the acid catalyst although inorganic acids such as sulfuric acid and organic acids such as p-toluenesulfonic acid, which are usually used for the production of polyimides, may be employed, these acid catalysts remain in the polymer solution after completion of the reaction, thereby causing degradation of the quality of the polymer product. Therefore, it is necessary to remove these catalysts from the polymer product by precipitating and re-dissolving the polymer.
- Dehydration condensation may be carried out using the ⁇ acid ⁇ + ⁇ base ⁇ - as a catalyst.
- the produced water is eliminated from the reaction system by azeotropic distillation with toluene.
- ⁇ acid ⁇ + ⁇ base ⁇ - is converted to the lactone and the base, and they lose the catalytic activity and are removed from the reaction system with the toluene.
- the polyimide solution produced by this process can be industrially used as it is as a polyimide solution with high purity because the above-mentioned catalytic substances are not contained in the polyimide solution after the reaction.
- lactone used here, ⁇ -valerolactone is preferred.
- base pyridine and/or methylmorpholine is(are) preferred.
- Preferred reaction solvents used for the dehydration condensation reaction include, in addition to the above-mentioned toluene, organic polar solvents.
- organic polar solvents examples include N-methylpyrrolidone, dimethylformamide, dimethylacetamide, tetramethylurea and sulfolane. In view of environmental protection, N-methylpyrrolidone and sulfolane are preferred.
- the concentration of the acid dianhydride(s) at the beginning of the reaction based on the total reaction mixture may preferably be about 4 to 16% by weight
- the concentration of the lactone may preferably be about 0.2 to 0.6% by weight
- the concentration of the base may preferably be about 0.3 to 0.9% by weight
- the concentration of toluene may preferably be about 6 to 15% by weight.
- the amount of the aromatic diamine(s) may preferably be 0.95 to 1.05 times (by mole) of the tetracarboxylic dianhydride(s) (production of a copolymer will be described later).
- a solvent-soluble polycondensate containing a benzoxazole component having a carboxylic group and imide component having a phenolic hydroxyl group since the polycondensate contains an imide component and benzoxazole component as mentioned above, the polycondensate according to the present invention may be referred to as "PI-BO polymer" ( p oly i mide- b enz o xazole polymer) for convenience in the present specification).
- PI-BO polymer p oly i mide- b enz o xazole polymer
- the carboxylic group does not necessarily exist on the benzoxazole structure.
- imide component having a phenolic hydroxyl group means a constituent unit containing an imide moiety and a phenolic hydroxyl group in one constituent unit (recurring unit).
- the structures of the benzoxazole component and of the imide component are defined by the structures of the above-described tetracarboxylic dianhydride and of the above-described aromatic diamine used as the reactants.
- solvent-soluble means that the polyimide is dissolved in N-methyl-2-pyrrolidone (NMP) to a concentration of not less than 5% by weight, preferably not less than 10% by weight.
- NMP N-methyl-2-pyrrolidone
- Chart 1 The route through which the benzoxazole component having a carboxyl group and the imide component having a phenolic hydroxyl group are generated is shown in Chart 1.
- Chart 1 (and in other charts and formulae), only the structures necessary for understanding how the benzoxazole component and the imide component are generated are described, and all of the other structures and substituents are schematically and collectively represented by a straight line crossing the benzene ring.
- the tetracarboxylic dianhydride used as a reactant is shown to have only one carboxylic dianhydride, another carboxylic dianhydride (and also other additional substituents when it has such additional substituents) is schematically represented by the straight line crossing the benzene ring.
- the aromatic diamine used as a reactant is shown to have only one amino group, another amino group (and also other additional substituents when it has such additional substituents) is schematically represented by the straight line crossing the benzene ring.
- the benzoxazole component having a carboxyl group is indicated as simply “benzoxazole”
- the imide component having a phenolic hydroxyl group is indicated as simply “imide”.
- the acid catalyst and the amic acid are indicated as "acid catalyst” and "amic acid” in English, respectively.
- the ratio of the formed benzoxazole component to the formed imide component varies depending on the types of the reactants, reaction temperature and reaction time. The higher the reaction temperature, the higher the ratio of the imide component, and the longer the reaction time, the higher the ratio of the imide component. Thus, the desired ratio may easily be attained by adjusting the reaction temperature and the reaction time.
- the content of the benzoxazole component in the polycondensate may preferably be 13 to 60 mol%, more preferably 20 to 50 mol%.
- the reaction conditions for obtaining such a desired content of the benzoxazole component may easily be selected by routine experiments employing varying reaction temperature and reaction time, and a number of examples are described below.
- the content of the benzoxazole component may also be adjusted by further employing an aromatic diamine for imidation which will be described below.
- reaction time varies depending on the reaction temperature and the types of reactants, and may appropriately be selected. Usually, the reaction time of about 30 minutes to 180 minutes is preferred in most cases.
- the entire benzoxazole component is converted to the imide component having a phenolic hydroxyl group as shown in Chart 2 below, and the polycondensate becomes a polyimide.
- an aromatic diamine which does not have an amino group and a phenolic hydroxyl group which are located at ortho positions with respect to each other in addition to the above-described aromatic diamine having an amino group and a phenolic hydroxyl group which are located at ortho positions with respect to each other, is preferred because the physical properties of the PI-BO polymer may be freely controlled. Since such an aromatic diamine does not yield the benzoxazole component but yields an imide component (but the imide component formed is not restricted to the above-mentioned imide component having a phenolic hydroxyl group), such an aromatic diamine is referred to as "aromatic diamine for imidation" for convenience in the specification and claims.
- aromatic diamine for imidation is not restricted at all and any aromatic diamine may be employed as long as it does not substantially adversely affect the effects of the present invention.
- Preferred examples of the aromatic diamine for imidation include aromatic diamines such as 4,4'- (or 3,4'-, 3,3'- or 2,4'-)diaminodiphenyl ether, 4,4'- (or 3,3'-)diaminodiphenylsulfone, 4,4'- (or 3,3'-)diaminodiphenyl sulfide, 4,4'-benzophenonediamine, 3,3'-benzophenonediamine, 4,4'-di(4-aminophenoxy)phenylsulfone, 4,4-di(3-aminophenoxy)phenylsulfone, 4,4'-bis(4-aminophenoxy)biphenyl, 1,4-bis(4-aminophenoxy)benzene, 1,3-bis(3-a
- polyimides having a high modulus of elasticity are straight rigid polymers, so that their solubilities in solvents are small. Therefore, to obtain a flexible printed board free from warping, it is important to design a PI-BO polymer having a molecular alignment which meets the demanded properties, i.e., solubility and high modulus of elasticity, which contradict to each other. To this end, it is preferred to use the above-mentioned aromatic diamine for imidation, and to form a block copolycondensate in which the molecular alignment is defined, rather than a random copolycondensate.
- a block copolycondensate which is a PI-BO polymer according to the present may be obtained by a two-step polycondensation method in which an oligomer is produced by reacting a diamine and a tetracarboxylic dianhydride such that one of these reactants is used in excess, and then a diamine and/or tetracarboxylic dianhydride is(are) added (the molar ratio of the total aromatic diamines to the total tetracarboxylic dianhydride is 1.05 to 0.95).
- a variety of processes according to this method are concretely described in the Examples below.
- a polycondensate containing not less than 4 components may be produced by increasing the number of times of addition of each monomer accordingly.
- a block copolycondensate may be obtained by using not less than two tetracarboxylic dianhydrides and/or not less than two aromatic diamines having an amino group and a phenolic hydroxyl group which are located at ortho positions with respect to each other.
- a solvent-soluble PI-BO polymer is formed by heating the tetracarboxylic dianhydride(s) and the aromatic diamine(s) having an amino group and a phenolic hydroxyl group which are located at ortho positions with respect to each other at 150°C to 220°C in the presence of an acid catalyst is a novel discovery originally discovered by the present inventors, and the PI-BO polymer per se is also novel. How the new discovery was experimentally made and confirmed will now be described.
- the present inventors studied in detail the solvent-soluble polycondensate obtained by heating a tetracarboxylic dianhydride and a diamine having an ortho-aminophenol group in an organic polar solvent in the presence of an acid catalyst to dehydration-condense the reactants.
- binary polycondensates were synthesized from diamines containing ortho-aminophenol and tetracarboxylic dianhydrides, and the characteristics of the polycondensates were compared.
- 6FDA 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane
- BCD bicyclooct-7-ene-2,3,5,6-t
- the weight average molecular weights in terms of polystyrene of the polycondensates were 225,000, 134,000 and 46,200, respectively, and each of them was a single polymer (each product showed a sharp peak).
- absorption by imide bond is observed at 1785, 1773 and 1775 cm -1
- the benzoimidazole component formed therein contains benzoimidazole groups which do not have a carboxylic group.
- a PI-BO polymer By heating 1-hydroxy-2,4-diaminobenzene instead of 3,3'-dihydroxybenzidine, and the tetracarboxylic dianhydride in the presence of an acid catalyst in an organic solvent at 180°C, a PI-BO polymer is formed. By heating this PI-BO polymer at 350°C for 1 hour, the PI-BO polymer is converted to polyimide.
- this block copolymer The molecular weight, molecular weight distribution, glass transition point, modulus of elasticity and coefficient of linear expansion of this block copolymer were measured.
- this polycondensate is a polymer having a high modulus of elasticity, and the molecular weight and the molecular weight distribution of the polymer containing the two components of PI-BO polymer are of a single polymer.
- this block copolymer exhibited two glass transition points and showed shrinkage at two different temperature ranges (see Fig. 3).
- the first shrinkage range is the low temperature range of not higher than 100°C (especially between 30°C and 100°C). Since the polymers treated at 90°C and at 200°C showed the same infrared spectrum, no change in composition occurs. This shrinkage is presumably caused by the interaction, i.e., hydrogen bond, between a carboxyl group and a hydroxyl group in different molecules in the PI-BO polymer.
- the polycondensate synthesized using a diamine having an ortho-aminomethoxy group instead of the diamine having the ortho-aminophenol group does not exhibit this shrinkage.
- Ordinary polyimides also do not exhibit the shrinkage.
- PI-BO polymer The second shrinkage occurs in a temperature range near the glass transition point.
- Figs. 6 and 7 show shrinkage properties in terms of glass transition points (Tg) measured by DSC and coefficient of linear expansion.
- Tg glass transition points measured by DSC and coefficient of linear expansion.
- a model of shrinkage of this PI-BO polymer is shown in the following formula:
- the copper foil-block copolymer laminate prepared by coating the copper foil with the BI-PO polymer according to the present invention and heating the resultant at 90°C for 30 minutes and then at 200°C for 1 hour is a laminate free from curling or warping.
- the laminate is a copper foil flexible printed board free from warping.
- the polycondensate according to the present invention which is a polymer having a constant molecular alignment and have hydroxyl groups and carboxyl groups in one molecule showed shrinkage by intermolecular interaction, i.e., hydrogen bonds. It is presumed that the copper foil flexible printed board does not warp or curl because the coefficients of expansion at room temperature and in the range of 150°C to 200°C are close.
- the PI-BO polymer according to the present invention is obtained in the form of a solution when the polymer is produced by the process described above, the polymer in the form of solution may be used industrially as it is.
- the concentration of the PI-BO polymer in the solution is preferably 5 to 50% by weight, more preferably 10 to 40% by weight. If desired, however, the produced polyimide solution may be diluted with a diluent.
- a solvent which does not largely decrease the solubility such as dioxane, dioxolane, ⁇ -butyrolactone, cyclohexanone, propylene glycol monomethyl ether acetate, methyl lactate, anisole, ethyl acetate or the like may be employed, although the diluent is not restricted to these.
- the PI-BO polymer according to the present invention in the form of solution may be applied to a substrate, and may be used as an insulation film after being dried.
- photosensitivity may be given to the polymer.
- the PI-BO polymer according to the present invention forms positive-type images by irradiating the polymer with a light after adding a photoacid generator, and then developing the resultant with an alkaline developer, preferably with amino alcohol solution.
- the photoacid generator employed in the present invention is not restricted and any compound which generates an acid upon being irradiated with light or electron beam may be employed.
- Preferred examples of the photoacid generator include photosensitive quinone diazide compounds including esters of 1,2-naphthoquinone-2-diazide-5-sulfonic acid and 1,2-naphthoquinone-2-diazide-4-sulfonic acid, the counterparts of the esters being low molecular aromatic hydroxyl compounds such as 2,3,4-trihydroxybenzophenone, 1,3,5-trihydroxybenzene, 2- and 4-methylphenol and 4,4'-hydroxy-propane.
- the photoacid generator may be added in an amount of 0.05 to 0.3 based on the weight of the polycondensate.
- the substrate to be coated with the photosensitive PI-BO composition is not restricted, to exhibit the advantageous effect that warping does not occur when coated on copper foil, copper foil is especially preferred.
- Coating is usually performed by applying PI-BO solution on the substrate by a method such as immersion, spraying, roll-coating, spin-coating or the like.
- the coating thickness after the drying is not restricted, and usually about 1 to 50 ⁇ m is suitable.
- the photosensitive PI-BO polymer layer is subjected to irradiation.
- irradiation usually, UV light is used, but high energy radiation, such as X-ray, electron beam or high power oscillation beam from an extra-high pressure mercury lamp may be employed.
- Irradiation or exposure is carried out through a mask, or the surface of the photosensitive polyimide layer may also be directly irradiated with a beam.
- Irradiation is usually carried out using a UV lamp which emits a light having a wavelength of 250 to 450 nm, preferably 300 to 400 nm.
- Exposure may be carried out using monochromatic ray or polychromatic ray. It is preferred to use a commercially available irradiation apparatus, such as a contact or interlayer exposer, scanning projector or a wafer stepper.
- the irradiated regions may be removed. This treatment may be carried out by immersion or by spraying with pressure of the developer, thereby dissolving the exposed regions.
- the alkali employed as the developer is not restricted, and examples thereof include amino alcohols such as aminoethanol, methylmorpholine, potassium hydroxide, sodium hydroxide, sodium carbonate, dimethylaminoethanol and tetramethylammonium hydroxide.
- the concentration of the alkali in the developer is not restricted, and is usually about 30 to 5% by weight.
- the duration of development varies depending on the exposure energy, strength of the developer, mode of development, pre-drying temperature, the temperature of the developer and the like. In general, in immersion development, the developing time is usually about 1 to 10 minutes, and in spray development, the developing time is usually about 10 to 60 seconds.
- the development is stopped by immersing the film in an inactive solvent such as isopropanol or in deionized water, or by spraying such a liquid on the film.
- Positive-type images are usually formed by adding a photoacid generator to a novolak resin, irradiating the composition and then developing the resulting composition.
- the novolak resin has a low molecular weight of not more than 10,000, and the solubility in aqueous alkaline solution is increased by the hydroxyl groups in the novolak resin and the carboxyl groups in the photoacid generator.
- the polycondensate according to the present invention is a high molecular polymer having a weight average molecular weight in terms of polystyrene of not less than 30,000. If the weight average molecular weight is not more than 30,000, strong insulation film is not formed.
- High molecular polymers are not easily dissolved in alkaline solution. The polymer is not dissolved in an alkaline solution upon irradiated with light in the presence of a photoacid generator due to the interaction between the hydroxyl groups or carboxyl groups and the carboxylic acid generated by the light irradiation, but dissolved due to decomposition to low molecular compounds by the amino alcohol-containing developer, so as to form positive-type images.
- the molecular weight of a polymer in the light-irradiated regions in the coating layer containing the polymer having a weight average molecular weight of 68,300 and a photoacid generator was 70,600, so that the molecular weight was not substantially changed.
- the light-irradiated regions are dissolved.
- the molecular weights of the dissolved compounds were measured to find that most of them were low molecular compounds having a molecular weight of 3000.
- the light-irradiated regions were dissolved in dimethylformamide and the molecular weight was measured, which was 70,600, so that no change in the weight average molecular weight was observed.
- the polymer was easily decomposed to low molecular compounds having a weight average molecular weight of 3510.
- the BI-PO polymer according to the present invention which is a polycondensate containing a benzoxazole component having a carboxyl group and an imide component having a phenolic hydroxyl group, is converted to an amic acid by the photoacid generator and decomposed by the aminophenol-containing developer to low molecular weight compounds having a molecular weight of about 3000, thereby being dissolved.
- the resin according to the present invention By coating the resin according to the present invention on a copper foil together with the photoacid generator, preheating the composition, irradiating the composition with light, and developing the resultant with an amino alcohol-containing developer, a line-and-space pattern of 15 ⁇ m interval as well as through holes of 15 ⁇ m diameter are clearly formed.
- the substrate may be used as a circuit board as it is, if desired, the composition may be heated at 350°C so as to form a polyimide circuit board.
- a condenser comprising a trap and a cooling tube having balls and mounted on the trap was attached.
- the flask was heated by immersing the flask in a silicone oil bath under stirring under nitrogen gas flow.
- the reaction solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- Infrared absorption spectrum (reflected light) was measured using an infrared spectrophotometer SPECTRAONE commercially available from Perkin-Elmer.
- the coated polycondensate after the heat treatment at 90°C for 1 hour was heated at 200°C for 30 minutes, and the infrared absorption spectrum was measured.
- the infrared absorption spectrum did not change from that of the sample heated at 90°C.
- the sample heated at 200°C was further heated at 350°C for 1 hour in a furnace.
- a polycondensate solution was prepared as in Example 1.
- BCD bicyclo(2,2,2)-oct-7-ene-2,3,5,6-tetracarboxylic dianhydride
- HO-AB 3,3'-dihydroxy-benzidine
- 1.0 g (10 mmol) of ⁇ -valerolactone, 2.4 g (30 mmol) of pyridine, 171 g of N-methylpyrrolidone and 30 g of toluene were added and the mixture was heated at a silicone bath temperature of 180°C under stirring at 180 rpm for 65 minutes and then at 100 rpm for 35 minutes.
- distillate of toluene and water was removed.
- 71 g of NMP was added to obtain a 15% polycondensate solution.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- the coated polycondensate after the heat treatment at 90°C for 1 hour was heated at 200°C for 30 minutes, and the infrared absorption spectrum was measured. As a result, the infrared absorption spectrum did not change from that of the sample heated at 90°C.
- the sample heated at 200°C was further heated at 350°C for 1 hour in a furnace.
- a polycondensate solution was prepared as in Example 1.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- the coated polycondensate after the heat treatment at 90°C for 1 hour was heated at 200°C for 30 minutes, and the infrared absorption spectrum was measured. As a result, the infrared absorption spectrum did not change from that of the sample heated at 90°C.
- the sample heated at 200°C was further heated at 350°C for 1 hour in a furnace.
- Polycondensate solutions were prepared as in Example 1 changing the polycondensation catalyst.
- Table 1 The results of measurements of molecular weights based on polystyrene of the thus produced polycondensate solutions are shown in Table 1 below.
- Table 1 Catalyst M Mn Mw Mz 1) 253,000 89,000 345,000 736,000 2) 402,000 108,000 480,000 980,000 3) 1,155,000 119,000 746,000 1,703,000
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- Infrared absorption spectrum (reflected light) was measured using an infrared spectrophotometer SPECTRAONE commercially available from Perkin-Elmer.
- a polycondensate solution was prepared as in Example 1.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- the film coated on the copper foil was further heated at 350°C in a heating furnace for 1 hour and infrared absorption spectrum was measured. However, most of the product was thermally decomposed and absorption characteristics were not observed.
- a polycondensate solution was prepared as in Example 1.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 54,000, Number Average Molecular Weight (Mn): 31,700; Weight Average Molecular Weight (Mw): 57,200; Z Average Molecular Weight (Mz): 99,500.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- a polycondensate solution was prepared as in Example 1.
- the mixture was stirred at room temperature for 30 minutes at 180 rpm, and then 8.83 g (30 mmol) of BPDA, 8.77 g (30 mmol) of bis(3-aminophenoxy)-1,3-benzene, 6.01 g (30 mmol) of 4,4'-diamino-diphenyl ether, 84 g of NMP and 20 g of toluene were added, followed by stirring the mixture at room temperature for 1 hour. The resulting mixture was heated at 180°C under stirring at 180 rpm for 2 hours and the refluxed solution was removed. The mixture was then heated at 180°C for 1 hour and 50 minutes at 100 rpm. The polycondensate after the reaction was in the form of a solution with a resin concentration of 20%.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 64,500, Number Average Molecular Weight (Mn): 33,100; Weight Average Molecular Weight (Mw): 71,800; Z Average Molecular Weight (Mz): 130,300.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- the DSC of this polycondensate was measured.
- the differential calorie decreased from 170°C and the Tg was 203°C.
- the linear coefficient of expansion was also measured (TMA).
- the measurement results are shown in Fig. 3 and Table 2 below.
- the polycondensate elongates in the temperature range between 0°C and 50°C.
- the polycondensate shrinks in the temperature range between 50°C and 90°C. It elongates again from 90°C to 230°C. It shrinks in the temperature range of 230°C and 250°C, and it elongates in the temperature range of not lower than 250°C.
- the polycondensate is coated on a copper foil having a thickness of 25 ⁇ m, and cured at 90°C while clamping the foil with a metal frame. Twenty four hours later, the foil is removed from the metal frame.
- the polycondensate coating (resin thickness was 20 ⁇ m) on the 35 mm x 35 mm copper foil was post-cured by leaving the coated foil at 90°C for 30 minutes, at 150°C for 30 minutes or at 230°C for 30 minutes, and the degree of warping of the copper foil/polycondensate films was measured. Each of them was placed on a flat plane, and the maximum distance from the plane was measured. The measured distance of any of them was not more than 1.0 mm.
- a polycondensate solution was prepared as in Example 6.
- the mixture was stirred at room temperature for 30 minutes at 180 rpm, and then 17.60 g (60 mmol) of BPDA, 6.49 g (30 mmol) of HO-AB, 12.01 g (60 mmol) of 3,4'-diaminodiphenyl ether, 106 g ofNMP and 20 g of toluene were added, followed by stirring the mixture at room temperature for 1 hour.
- the resulting mixture was heated at 180°C under stirring at 180 rpm for 1 hour and the refluxed solution was removed.
- the mixture was then heated at 180°C for 1 hour at 100 rpm. After the reaction, 100 g of NMP was added.
- the polycondensate was in the form of a solution with a resin concentration of 15%.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 76,300, Number Average Molecular Weight (Mn): 37,500; Weight Average Molecular Weight (Mw): 180,000; Z Average Molecular Weight (Mz): 362,000.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- the DSC of this polycondensate was measured. There are two Tgs in the vicinity of 76°C and 203°C (see Fig. 6).
- the linear coefficient of expansion was also measured (TMA). The measurement results are shown in Fig. 7 and Table 3 below.
- the polycondensate shrinks in the temperature range between 60°C and 90°C, and shrinks again from 185°C to 200°C.
- Table 3 Measurement Coefficient of Coefficient of Temperature (°C) Expantion*1) Linear Expansion*2) 30 0.13 4.43 60 0.21 3.53 85 0.01 0.16 185 0.53 2.87 200 0.52 0.58 215 1.22 5.69 *1): x 10 -3 *2): x10 -5 /K
- the polycondensate was coated on a copper foil having a thickness of 25 ⁇ m, and cured at 90°C while clamping the foil with a metal frame. Twenty four hours later, the foil was removed from the metal frame.
- the polycondensate coating (resin thickness was 20 ⁇ m) on the 35 mm x 35 mm copper foil was post-cured by leaving the coated foil at 90°C for 30 minutes, at 150°C for 30 minutes or at 230°C for 30 minutes, and the degree of warping of the copper foil/polycondensate films was measured. Each of them was placed on a flat plane, and the maximum distance from the plane was measured. The measured distance of any of them was not more than 1.0 mm.
- a polycondensate solution was prepared as in Example 6.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 54,700, Number Average Molecular Weight (Mn): 29,700; Weight Average Molecular Weight (Mw): 62,700; Z Average Molecular Weight (Mz): 111,700.
- the DSC of this polycondensate was measured.
- the Tg is 230°C.
- the linear coefficient of expansion was also measured (TMA). The results are shown in Table 4 below.
- the polycondensate elongates in the temperature range between 0°C and 30°C, and shrinks in the temperature range between 70°C and 80°C. It elongates in the temperature range between 80°C and 180°C, and shrinks again in the temperature range from 180°C to 240°C. It elongates at temperatures of not lower than 240°C.
- the polycondensate was coated on a copper foil having a thickness of 25 ⁇ m, and cured at 90°C while clamping the foil with a metal frame. Twenty four hours later, the foil was removed from the metal frame.
- the polycondensate coating (resin thickness was 20 ⁇ m) on the 35 mm x 35 mm copper foil was post-cured by leaving the coated foil at 90°C for 30 minutes, at 150°C for 30 minutes or at 230°C for 30 minutes, and the degree of warping of the copper foil/polycondensate films was measured. Each of them was placed on a flat plane, and the maximum distance from the plane was measured. The measured distance of any of them was not more than 1.0 mm.
- a polycondensate solution was prepared as in Example 6.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 65,500, Number Average Molecular Weight (Mn): 30,900; Weight Average Molecular Weight (Mw): 86,300; Z Average Molecular Weight (Mz): 190,000.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- the polycondensate was coated on a copper foil having a thickness of 25 ⁇ m, and cured at 90°C while clamping the foil with a metal frame. Twenty four hours later, the foil was removed from the metal frame.
- the polycondensate coating (resin thickness was 20 ⁇ m) on the 35 mm x 35 mm copper foil was post-cured by leaving the coated foil at 90°C for 30 minutes, at 150°C for 30 minutes or at 230°C for 30 minutes, and the degree of warping of the copper foil/polycondensate films was measured. Each of them was placed on a flat plane, and the maximum distance from the plane was measured. The measured distance of any of them was not more than 1.0 mm.
- a polycondensate solution was prepared as in Example 6. In place of HO-AB, 3,3'-dimethoxy-benzidine (CHO-AB) is used.
- CHO-AB 3,3'-dimethoxy-benzidine
- the mixture was stirred at room temperature for 30 minutes at 180 rpm, and then 8.83 g (30 mmol) of BPDA, 8.77 g (30 mmol) of bis(3-aminophenoxy)-1,3-benzene, 6.01 g (30 mmol) of 4,4'-diaminodiphenyl ether, 80 g of NMP and 30 g of toluene were added, followed by stirring the mixture at room temperature for 1 hour. The resulting mixture was heated at 180°C under stirring at 180 rpm for 3 hours and 45 minutes and the refluxed solution was removed. After the reaction, 100 g of NMP was added. The polycondensate was in the form of a solution with a resin concentration of 20%.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 36,500, Number Average Molecular Weight (Mn): 21,900; Weight Average Molecular Weight (Mw): 41,600; Z Average Molecular Weight (Mz): 74,600.
- the polycondensate solution was cast on a copper foil with a thickness of 18 ⁇ m and heated at 90°C for 1 hour in an infrared drying furnace such that the final thickness of the coated resin was 20 ⁇ m.
- NT-200 1,2-naphthoquinone-2-diazide-5-sulfonic acid with 2,3,4-trihydroxybenzophenone
- This uniform solution was applied on the surface of a surface-treated copper foil having a diameter of 5 cm and a thickness of 18 ⁇ m (commercial product of Mitsui Metal and Mining Co., Ltd.) by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking).
- the thickness of the resin film was about 10 ⁇ m.
- a test pattern through holes and line-and-space pattern having diameters and widths of 10, 15, 20, 25, ---, and 200 ⁇ m, respectively
- the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus (JP-200G, commercial product of Oak Seisakusho).
- the coating film After irradiating the coating film at a dose of exposure of 1000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at 35°C for 2 minutes and 30 seconds. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- Example 10 The operations as in Example 10 were carried out.
- This solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking). The thickness of the resin film was about 10 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the coating film After irradiating the coating film at a dose of exposure of 1000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at 37°C for 7 minutes. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- Example 10 The operations as in Example 10 were carried out.
- This solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking). The thickness of the resin film was about 10 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the coating film After irradiating the coating film at a dose of exposure of 1000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at 40°C for 8 minutes and 35 seconds. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- Example 10 The operations as in Example 10 were carried out.
- This solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking). The thickness of the resin film was about 10 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the coating film After irradiating the coating film at a dose of exposure of 1000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at 37°C for 5 minutes and 54 seconds. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- the mixture was stirred at room temperature for 30 minutes at 180 rpm, and then 35.31 g (120 mmol) of BPDA, 25.95 g (60 mmol) of bis(4-aminophenoxy)phenyl ⁇ sulfone, 24.02 g (120 mmol) of 4,4'-diamino-diphenyl ether, 234 g of butyrolactone and 40 g of toluene were added, followed by stirring the mixture at room temperature for 1 hour. The resulting mixture was heated at 180°C under stirring at 180 rpm for 90 minutes and the refluxed solution was removed. The mixture was then heated at 180°C for 120 minutes at 100 rpm. The polycondensate after the reaction was in the form of a solution with a resin concentration of 20%.
- the polycondensate solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking).
- the thickness of the resin film was about 20 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the molecular weight of the polycondensate film does not substantially change.
- the results show that a part of the polycondensate cross-links to increase the molecular weight by the heat treatment at 90°C, 120°C and 200°C after the irradiation and development.
- the molecular weight is the largest in peak 1, second largest in peak 2 and smallest in peak 3.
- Mw weight average molecular weight
- the polycondensate film irradiated with light is decomposed by aminoethanol and its weight average molecular weight is decreased from 101,800 to 3,500.
- polyamic acid is generated and decomposed by aminoethanol in the developer so as to be dissolved therein.
- the mixture was stirred at room temperature for 30 minutes at 180 rpm, and then 17.65 g (60 mmol) of BPDA, 25.95 g (60 mmol) of bis(4-(3-aminophenoxy)phenyl)sulfone, 24.63 g (60 mmol) of 2,2-bis(4-aminophenoxyphenyl)propane, 119 g of butyrolactone and 40 g of toluene were added, followed by stirring the mixture at room temperature for 1 hour. The resulting mixture was heated at 180°C under stirring at 180 rpm for 4 hours and 30 minutes and the refluxed solution was removed. The polycondensate after the reaction was in the form of a solution with a resin concentration of 25%.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 37,700, Number Average Molecular Weight (Mn): 23,100; Weight Average Molecular Weight (Mw): 45,000; Z Average Molecular Weight (Mz): 83,500.
- NT-200 was added to a concentration of 15% and Michler's ketone was added to a concentration of 15%, followed by dissolving the added products in a dark room.
- the polycondensate solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking).
- the thickness of the resin film was about 10 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the coating film After irradiating the coating film at a dose of exposure of 2000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at room temperature for 19 minutes. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- the polycondensate obtained by using CHO-AB in place of HO-AB is an entirely aromatic polyimide.
- the development of the images formed by light irradiation took a little longer time than in the case where HO-AB was used.
- the mixture was stirred at room temperature for 30 minutes at 180 rpm, and then 17.65 g (60 mmol) of BPDA, 7.33 g (30 mmol) of CHO-AB, 12.01 g (60 mmol) of 4,4'-diaminodiphenyl ether, 110 g of NMP and 20 g of toluene were added, followed by stirring the mixture at room temperature for 1 hour.
- the resulting mixture was heated at 180°C under stirring at 180 rpm for 2 hours and the refluxed solution was removed.
- the mixture was then heated at 180°C for 1 hour at 100 rpm.
- the polycondensate after the reaction was in the form of a solution with a resin concentration of 20%.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 34,500, Number Average Molecular Weight (Mn): 20,000; Weight Average Molecular Weight (Mw): 42,800; Z Average Molecular Weight (Mz): 79,900.
- NT-200 was added to a concentration of 20% and dissolved in a dark room.
- the polycondensate solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking).
- the thickness of the resin film was about 10 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the coating film After irradiating the coating film at a dose of exposure of 1000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at room temperature for 15 minutes and 15 seconds. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- the polycondensate obtained by using CHO-AB in place of HO-AB is an entirely aromatic polyimide.
- the development of the images formed by light irradiation took a little longer time than in the case where HO-AB was used.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 87,700, Number Average Molecular Weight (Mn): 57,800; Weight Average Molecular Weight (Mw): 108,100; Z Average Molecular Weight (Mz): 192,300.
- NT-200 was added to a concentration of 30% and dissolved in a dark room.
- the polycondensate solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 5 minutes (prebaking).
- the thickness of the resin film was about 10 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the coating film After irradiating the coating film at a dose of exposure of 1000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at room temperature for 2 minutes. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- the polycondensate obtained by using HFBAPP in place of HO-AB in Example 1 is an aromatic polyimide, and positive images are obtained similarly by light irradiation in the presence of a photoacid generator.
- the molecular weights based on polystyrene of the thus produced polycondensate solution were: Most Frequent Molecular Weight (M): 110,000, Number Average Molecular Weight (Mn): 28,300; Weight Average Molecular Weight (Mw): 131,000; Z Average Molecular Weight (Mz): 406,700.
- NT-200 was added to a concentration of 10% and dissolved in a dark room.
- the polycondensate solution was applied on the surface of a surface-treated copper foil having a thickness of 18 ⁇ m by spin-coating method, and dried in an infrared dryer at 90°C for 10 minutes (prebaking).
- the thickness of the resin film was about 10 ⁇ m.
- a test pattern for positive-type photomask was placed, and the coating film was irradiated at a dose of exposure at which images are obtained using 2 kW extra-high pressure mercury lamp apparatus.
- the coating film After irradiating the coating film at a dose of exposure of 1000 mJ/cm 2 , the coating film was immersed in a mixture of 40 g of NMP, 40 g of aminoethanol and 40 g of water at room temperature for 9 minutes and 45 seconds. After washing the coating film with deionized water, the coating film was dried at 90°C for 30 minutes and then at 200°C for 30 minutes in an infrared dryer, followed by observation of the resolution. The thickness of the coating film was about 8 ⁇ m.
- the through hole patterns in the coating film formation of through holes having sharp and circular sections having a diameter of 15 ⁇ m was confirmed.
- the line-and-space pattern formation of sharp positive-type images of lines having a width of 15 ⁇ m was confirmed.
- the polycondensate obtained by using (BCD + 3,4'-diaminodiphenyl ether) in place of (BCD + HO-AB) gives positive-type images by irradiation with light.
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Claims (16)
- Verfahren zur Herstellung eines in Lösungsmittel löslichen Polykondensats, das eine Benzoxazolkomponente mit einer Carboxylgruppe und eine Imidkomponente mit einer phenolischen Hydroxygruppe enthält, wobei das Verfahren das Erhitzen einer oder mehrerer Tetracarbonsäuredianhydride und einer oder mehrerer aromatischer Diamine mit einer Aminogruppe und einer phenolischen Hydroxygruppe auf 150 °C bis 220 °C in Gegenwart eines sauren Katalysators umfasst, wobei sich die Aminogruppe und die phenolische Hydroxygruppe im aromatischen Diamin in ortho-Stellung zueinander befinden, sodass das eine oder die mehreren Tetracarbonsäuredianhydride und das eine oder die mehreren aromatischen Diamine unter Wasserabspaltung kondensiert werden.
- Verfahren nach Anspruch 1, worin die Kondensationsreaktion unter Wasserabspaltung in einem organischen polaren Lösungsmittel durchgeführt wird.
- Verfahren nach Anspruch 1 oder 2, worin das Diamin zumindest ein aus der aus 1-Hyxdroxy-2,4-diaminobenzol, 1-Hydroxy-2,5-diaminobenzol, 3,3'-Dihydroxybenzidin, 3,3'-Dihydroxy-4,4'-diaminodiphenylether, 1,4-Bis(3-hydroxy-4-aminophenoxy)-benzol, 2,2-Bis(4-amino-3-hydroxyphenyl)propan, Bis(3-amino-4-hydroxyphenyl)propan, Bis(3-amino-4-hydroxyphenyl)sulfid und 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluorpropan bestehenden Gruppe ausgewähltes ist.
- Verfahren nach einem der Ansprüche 1 bis 3, worin das Tetracarbonsäuredianhydrid zumindest ein aus der aus 3,4,3',4'-Biphenyltetracarbonsäuredianhydrid, 2,3,3',4'-Biphenyltetracarbonsäuredianhydid, 3,4,3',4'-Benzophenontetracarbonsäuredianhydrid, Bicyclo(2,2,2)-oct-7-en-2,3,5,6-tetracarbonsäuredianhydrid, 2,2-Bis-(3,4-dicarboxyphenyl)propandianhydrid, Bis(3,4-dicarboxyphenyl)sulfondianhydrid, Bis(3,4-dicarboxyphenyl)etherdianhydrid und 2,2-Bis(3,4-dicarboxyphenyl)hexafluorpropandianhydrid ausgewähltes ist.
- Verfahren nach einem der Ansprüche 1 bis 4, worin der saure Katalysator eine in situ durch die Kondensation unter Wasserabspaltung in Gegenwart eines Katalysators auf Lactonbasis gebildete Säure ist.
- Verfahren nach Anspruch 5, worin neben dem genannten aromatischen Diamin auch ein aromatisches Diamin, das keine Aminogruppe und phenolische Hydroxygruppe in ortho-Stellung zueinander aufweist, einer Kondensationsreaktion unter Wasserabspaltung unterzogen wird.
- Verfahren nach Anspruch 6, worin ein erstes Tetracarbonsäuredianhydrid und ein erstes aromatisches Diamin zuerst polykondensiert werden, sodass eines davon im Überschuss vorhanden ist, und danach ein Tetracarbonsäuredianhydrid und/oder ein aromatisches Diamin zugesetzt wird/werden, um eine Polykondensation bei einem Molverhältnis zwischen dem gesamten Tetracarbonsäuredianhydrid und dem gesamten aromatischen Diamin von 0,95 bis 1,05 durchzuführen.
- Verfahren nach Anspruch 6 oder 7, worin das aromatische Diamin zur Imidierung zumindest ein aus der aus 4,4'- oder 3,4'-Diaminodiphenylether, 4,4'-Diaminodiphenylsulfon, Bis{4(3-phenoxyphenyl)diphenyl}sulfon, Bis{4(4-phenoxyphenyl)diphenyl}sulfon, 1,4-Bis(3-aminophenoxy)benzol, 1,4-Bis(4-aminophenoxy)benzol, 1,3-Bis-(3-aminophenoxy)benzol, 3,3'-Diaminobenzophenon, 4,4'-Diaminodiphenylslfid, 3,3'-Bis{(4-aminophenoxy)phenyl}propan, 2,2'-Bis(4-aminophenyl)hexafluorpropan, 2,2'-Bis{(4-aminophenoxy)phenyl}hexafluorpropan, 3,3'-Dimethylbenzidin, 3,3'-Dimethoxybenzidin, 1,4-Diaminobenzol, 1,3-Diaminobenzol, 1,3-Diaminotoluol, 1,3-Bis(γ-aminopropyl)siloxan und Diaminosiloxan bestehenden Gruppe ausgewähltes ist.
- In Lösungsmittel lösliches Polykondensat, eine Benzoxazolkomponente mit einer Carboxylgruppe und eine Imidkomponente mit einer phenolischen Hydroxygruppe umfassend, das durch ein Verfahren nach einem der Ansprüche 1 bis 8 hergestellt ist.
- Polykondensat nach Anspruch 9, das bei 30 °C bis 100 °C schrumpfbar ist.
- Kupferverbundsubstrat, durch Beschichten einer Kupferfolie mit einem Polykondensat nach Anspruch 9 oder 10 und Erhitzen des Endprodukts auf 150 °C bis 250 °C erhältlich.
- Verfahren zur Ausbildung eines Bildes vom positiven Typ, das Beschichten eines Substrats mit einer lichtempfindlichen Polykondensatzusammensetzung, die ein Polykondensat nach Anspruch 9 oder 10 und einen Photosäurebildner umfasst; das Bestrahlen der Zusammensetzung durch eine Strukturmaske mit Licht; und das Entwickeln der resultierenden Zusammensetzung mit einem alkalischen Entwickler umfassend.
- Verfahren nach Anspruch 12, worin der alkalische Entwickler Aminoalkohol enthält.
- Verfahren nach Anspruch 12 oder 13, worin das Substrat eine Kupferfolie ist.
- Leiterplatte, durch das Verfahren nach Anspruch 14 hergestellt.
- Verfahren, das Erhitzen eines Polykondensats nach Anspruch 9 oder 10 auf 300 °C bis 350 °C umfassend, um es in ein Polyimid zu überführen.
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Application Number | Priority Date | Filing Date | Title |
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JP35637399 | 1999-11-10 | ||
JP35637399 | 1999-11-10 | ||
PCT/JP2000/007840 WO2001034679A1 (fr) | 1999-11-10 | 2000-11-08 | Polycondensat d'imide-benzoxazole et procede de production de celui-ci |
Publications (3)
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EP1262509A1 EP1262509A1 (de) | 2002-12-04 |
EP1262509A4 EP1262509A4 (de) | 2003-08-06 |
EP1262509B1 true EP1262509B1 (de) | 2007-01-10 |
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EP00974822A Expired - Lifetime EP1262509B1 (de) | 1999-11-10 | 2000-11-08 | Imid-benzoxazolpolykondensat sowie verfahren zur herstellung |
Country Status (5)
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US (1) | US6890626B1 (de) |
EP (1) | EP1262509B1 (de) |
JP (1) | JP4969751B2 (de) |
DE (1) | DE60032943T2 (de) |
WO (1) | WO2001034679A1 (de) |
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US7455949B2 (en) | 2002-10-15 | 2008-11-25 | Agfa Graphics, N.V. | Polymer for heat-sensitive lithographic printing plate precursor |
US20060060096A1 (en) * | 2002-10-15 | 2006-03-23 | Agfa-Gevaert | Polymer for heat-sensitive lithographic printing plate precursor |
WO2004035645A1 (en) * | 2002-10-15 | 2004-04-29 | Agfa-Gevaert | Polymer for heat-sensitive lithographic printing plate precursor |
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JPWO2005116152A1 (ja) * | 2004-05-27 | 2008-04-03 | 株式会社ピーアイ技術研究所 | 印刷用ブロック共重合ポリイミドインク組成物 |
JP5086526B2 (ja) * | 2004-09-24 | 2012-11-28 | 富士フイルム株式会社 | ポリマー、該ポリマーの製造方法、光学フィルムおよび画像表示装置 |
JP4876396B2 (ja) * | 2005-01-05 | 2012-02-15 | 東洋紡績株式会社 | プリント配線板 |
JP2008535003A (ja) * | 2005-03-25 | 2008-08-28 | フジフィルム・エレクトロニック・マテリアルズ・ユーエスエイ・インコーポレイテッド | 新規な感光性樹脂組成物 |
KR100640659B1 (ko) * | 2005-08-01 | 2006-11-01 | 삼성전자주식회사 | 가요성 인쇄회로 및 이의 제조방법 |
WO2007029614A1 (ja) * | 2005-09-05 | 2007-03-15 | Asahi Kasei Emd Corporation | ポジ型感光性樹脂組成物 |
US20090186295A1 (en) * | 2006-03-03 | 2009-07-23 | Maw Soe Win | Photosensitive Ink Composition for Screen Printing and Method of Forming Positive Relief Pattern with Use Thereof |
JP5193446B2 (ja) * | 2006-08-31 | 2013-05-08 | 旭化成イーマテリアルズ株式会社 | ポジ型感光性樹脂組成物 |
JP4918313B2 (ja) * | 2006-09-01 | 2012-04-18 | 旭化成イーマテリアルズ株式会社 | 感光性樹脂組成物 |
WO2008120398A1 (ja) | 2007-04-03 | 2008-10-09 | Solpit Industries, Ltd. | 溶剤に可溶な6,6-ポリイミド共重合体及びその製造方法 |
KR100932765B1 (ko) * | 2008-02-28 | 2009-12-21 | 한양대학교 산학협력단 | 폴리이미드-폴리벤조옥사졸 공중합체, 이의 제조방법, 및이를 포함하는 기체 분리막 |
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KR20120095347A (ko) * | 2009-06-30 | 2012-08-28 | 소지쯔 코포레이션 | Pmda, dade, bpda 및 9,9-비스(4-아미노페닐)플루오렌 성분을 함유하는 유기 용매에 가용인 폴리이미드 조성물 및 그 제조 방법 |
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-
2000
- 2000-11-08 WO PCT/JP2000/007840 patent/WO2001034679A1/ja active IP Right Grant
- 2000-11-08 US US10/129,844 patent/US6890626B1/en not_active Expired - Lifetime
- 2000-11-08 DE DE60032943T patent/DE60032943T2/de not_active Expired - Lifetime
- 2000-11-08 EP EP00974822A patent/EP1262509B1/de not_active Expired - Lifetime
- 2000-11-08 JP JP2001537388A patent/JP4969751B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
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DE60032943T2 (de) | 2007-10-25 |
WO2001034679A1 (fr) | 2001-05-17 |
EP1262509A1 (de) | 2002-12-04 |
DE60032943D1 (de) | 2007-02-22 |
JP4969751B2 (ja) | 2012-07-04 |
US6890626B1 (en) | 2005-05-10 |
EP1262509A4 (de) | 2003-08-06 |
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