EP0806512B1 - Procédé et dispositif de fibrillation de fibres cellulosiques facilement fibrillables, notamment de fibres tencel - Google Patents

Procédé et dispositif de fibrillation de fibres cellulosiques facilement fibrillables, notamment de fibres tencel Download PDF

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Publication number
EP0806512B1
EP0806512B1 EP97810241A EP97810241A EP0806512B1 EP 0806512 B1 EP0806512 B1 EP 0806512B1 EP 97810241 A EP97810241 A EP 97810241A EP 97810241 A EP97810241 A EP 97810241A EP 0806512 B1 EP0806512 B1 EP 0806512B1
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EP
European Patent Office
Prior art keywords
fabric
web
fibres
storage means
fabric web
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP97810241A
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German (de)
English (en)
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EP0806512A1 (fr
Inventor
Christian Strahm
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Solipat AG
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Solipat AG
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Publication of EP0806512A1 publication Critical patent/EP0806512A1/fr
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/28Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics propelled by, or with the aid of, jets of the treating material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C19/00Breaking or softening of fabrics

Definitions

  • the invention relates to a method and a device according to the preamble of the independent claims.
  • Fibrillatable cellulose fibers especially Lyocell fibers (like Tencel fibers) enjoy good dyeing and Wearing properties and a variety of equipment options and method for influencing the "handle" increasing popularity.
  • “Lyocell” fibers are in a solvent spinning process Manufactured cellulose fibers, the sheath by mechanical Influence is fissile, so from the surface of the jacket Protruding fibrils.
  • Fibrillation in Lyocell fibers is common the strand treatment. Factors affecting the inclination to influence fibrillation are above all: pH value, Temperature and mechanical impact. Also be Commonly used cellulase enzymes to fibrillate promote.
  • Cellulase enzymes are protein substances that are capable To break down cellulose.
  • a cellulase enzyme consists of one Many different enzyme components. The 4 most important include: endocellulase, exocellulase, cellobiohydrolase and cellobiase.
  • the effect of exocellulases results in soluble glucose directly from cellulose.
  • the others Components systematically attack the cellulose chains, by arbitrarily making the formation of cellobiose more soluble Split glucose.
  • EP 535 287 A1 describes a method and a device for improving the grip and surface of textile fabrics and knitted fabrics.
  • the web to be treated will be alternating against a first and a second baffle hurled.
  • the web is conveyed pneumatically, with a feed difference in the back and forth movement causes the web from the device is dissipated.
  • polyester fibers to fibrillate an alkaline aqueous solution.
  • the fibers can be broken open, for example, by that the web of goods through a relatively small opening is forced.
  • JP 701566A it is known to act on fibers to fibrillate with a gas stream.
  • JP 1-298273A it is also known, chemically pretreated cellulose fibers to break up.
  • the invention proposes fibrillation of fibrillatable cellulose fibers such as Lyocell, in particular from Textile fabrics containing Tencel fibers carry out wider goods. This can be done according to the invention if the wide web is reached by a high one Velocity flowing fluid flow and accelerated by this and countered with the liquid flow an impact surface is thrown and if the acceleration and the spinning process is repeated until Surface areas of the fibers are split and up Form fibrils.
  • the invention can be used to primary goods fibrillate and e.g. in a downstream enzyme process the long fibrils in a known manner by enzyme treatment to remove.
  • the method according to the invention can also be used for secondary fibrillation is used, that is for a fibrillation process that is a first fibrillation, a subsequent treatment to reduce the too long fibrils and possibly other equipment steps after is switched.
  • the material web is sequential in the opposite direction from such Liquid flow entrained and thrown against impact surfaces becomes. So it is e.g. conceivable that in a gap promote wide-ranging goods through the flow of liquid, hurling against a baffle, the goods in one Collect goods store, then the liquid flow in the Reverse direction and the goods in the opposite Accelerate direction through the gap and up against one the other side of the gap arranged second baffle to hurl and there the goods back in a store accumulate. The goods would alternate “forward and backwards "through the leadership gap Duration for funding in the "forward" direction is longer than the length of time for promotion in the opposite Direction, there is a resulting "forward” funding.
  • the inventive method for fibrillation in a textile web containing cellulose fibers, in particular Lyocell fibers (such as Tencel fibers) can be particularly perform advantageously with a device in which a wide feed web in one of a liquid through the guide gap is accelerated when the Guide gap at least on one side through a nozzle element is limited, which is a feed channel for the liquid and the one on two opposite sides outlet gap narrowing towards the guide gap and a Valve element for alternately closing one of the Has exit column.
  • Lyocell fibers such as Tencel fibers
  • each exit gap towards the guide gap tapered and if the flow axis of the exit gap approximately at an angle ⁇ of 10 ° to 20 °, preferably about Is inclined 15 ° to the level of the guide gap.
  • Fig. 1 shows schematically a Tencel fiber 1 of which Protruding fibrils 2.
  • Tencel fiber 1 is a component of a fabric, not shown, that one according to the invention Has undergone treatment.
  • a material web 3 a device for fibrillation 4 via a conveyor roller 5 supplied by a conveyor, not shown.
  • the conveyor roller 5 continuously conveys the web into one Goods store 6. From there, the web 3 passes through the Guide gap 7 of an acceleration device 8.
  • the guide gap 7 is formed by an upper and a lower one Guideway 9 a and 9 b limited.
  • two exit gaps 10 are provided on the side, wherein one of the gaps can be closed by valve means 11 is.
  • 2 is the Exit gap 10 a closed during the exit gap 10 b is open, while in the embodiment according to Fig. 3, the outlet gap 10 b shown as closed is.
  • Water flows through the outlet gap at a speed of about 15 m / sec. from that of a feed line 12 is supplied. That from the exit column 10 b flowing water entrains the web 3, accelerates it and hurls it against a baffle 13, causing the Web 3 and the fibers from which web 3 is made, be mechanically stressed. From the baffle 13 falls the web down into a goods store 17, from which it can be transported away by conveyor rollers 14 and 15.
  • valve means can be moved laterally, so that alternately the exit columns 10 a or the Exit columns 10 b is closed. Depending on what outlet gap the liquid is at high speed emerges, the web 3 is either against the impact surface 13 or the impact surface 16 flung.
  • the mutual Skidding is particularly uniform and for the handle of the goods effective mechanical treatment of the web.
  • Fig. 3 shows an embodiment in which a guide gap 7 on both the top and bottom the web 3 with exit gaps 10 a, 10 b, provided is. Accordingly, two valve means 11 are also provided, the exit columns in the operating state shown Close 10 b so that the liquid Exit columns 10 a is fed and the goods in the direction of the arrow x is promoted and accelerated.
  • Fig. 4 shows a top view of the guide gap 7, according to Fig. 3, through which the web 3 through which transports water at high speed becomes.
  • the exit gaps 10a and 10b are on both sides indicated by dashed lines. (As stated above, the 2 only on the underside of the Guide gap 7 provided an outlet opening 10 a).
  • the number of treatment steps (spinning on one Impact surface), the regulation of the impact speed, by one-sided or mutual treatment in the invention, the degree of fibrillation and thus the Affect surface quality and the feel of the goods.
  • Upstream and downstream enzyme treatment steps can be used to fibrillate to influence in addition.
  • the force with which the wet goods hit the impact surfaces thrown obviously depends on both Velocity of the conveying liquid as well as the length of the Acceleration path, any braking effects and the mass wet goods at the moment of impact.
  • forces per centimeter of fabric width occur Of the order of 2.5 to 9 Newtons. Preferably lie the values between 5 and 9 Newtons per cm. this leads to particularly good fibrillation results.
  • the invention is particularly effective when used with fabrics, which are made entirely of fibrillatable cellulose fibers, such as "Lyocell” fibers (especially Tencel fibers) exist. It but it is also possible to treat goods made from mixed fibers or blended fabrics.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Nonwoven Fabrics (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Claims (9)

  1. Procédé pour fibriller des fibres de cellulose aptes à être fibrillées, en particulier des fibres Lyocell, qui sont contenues dans une bande de tissu textile (3), caractérisé en ce que la bande de tissu déployée est sollicitée et accélérée par un courant de liquide qui s'écoule à une vitesse élevée, en ce que la bande de tissu accélérée est projetée par le courant de liquide contre une surface de choc (13, 16), et en ce que l'opération d'accélération et de projection est renouvelée jusqu'à ce que les zones superficielles des fibres se fissurent et qu'il se forme des fibrilles.
  2. Procédé selon la revendication 1, caractérisé en ce que la bande de tissu (3) s'accumule dans un réservoir de tissu (6), puis amenée vers le courant de liquide.
  3. Procédé selon la revendication 1 ou 2, caractérisé en ce que la bande de tissu (3), à partir de la surface de choc (13), est amenée dans un second réservoir de tissu (17) et s'accumule dans celui-ci, et en ce qu'elle est ensuite extraite du second réservoir (17) par un courant de liquide qui s'écoule en sens inverse, et ramenée dans le premier réservoir de tissu (6), ladite bande de tissu (3) étant accélérée par le courant de liquide qui s'écoule à une vitesse élevée, et projetée contre une seconde surface de choc (16).
  4. Procédé selon la revendication 2 ou 3, caractérisé en ce que la bande de tissu (3) va et vient entre les deux réservoirs de tissu (6, 17) grâce à un courant de liquide alternatif, en étant projetée à chaque fois contre une surface de choc (13, 16).
  5. Procédé selon la revendication 4, caractérisé en ce que du tissu (3) supplémentaire est amené en continu dans le premier réservoir de tissu (6), en ce que du tissu est évacué en continu du second réservoir de tissu (17) et en ce que, en présence de cadences de transport et d'accélération prédéfinies, on amène dans le second réservoir (17) une bande de tissu (3) plus longue que la bande de tissu qui est ramenée dans le premier réservoir (6) lors de l'accélération suivante en sens inverse.
  6. Procédé selon l'une des revendications précédentes, caractérisé en ce que la bande de tissu est accélérée jusqu'à une vitesse d'au moins 8 m/s, de préférence jusqu'à une vitesse de 9 à 15 m/s.
  7. Dispositif pour fibriller des fibres de cellulose aptes à être fibrillées, en particulier des fibres Tencel, qui sont contenues dans une bande de tissu textile, caractérisé en ce qu'une bande de tissu (3) contenant les fibres à fibriller (1) est accélérée dans un interstice de guidage (7) traversé par un courant de liquide, l'interstice de guidage (7) étant limité au moins d'un côté par un élément formant injecteur (9a, 9b, 10a, 10b) qui comporte un conduit d'amenée (12) pour le liquide et, sur deux côtés opposés, un interstice de sortie (10a, 10b) qui va en rétrécissant vers l'interstice de guidage (7) à la manière d'un injecteur, ainsi qu'un élément formant soupape (11) destiné à fermer en alternance l'un des interstices de sortie (10a, 10b).
  8. Dispositif selon la revendication 7, caractérisé en ce qu'il est prévu des interstices de sortie (10a, 10b) des deux côtés de l'interstice de guidage (7).
  9. Dispositif selon la revendication 7 ou 8, caractérisé en ce que l'interstice de sortie (10a, 10b) définit un angle α de 10° à 25°, et de préférence de 15° à 20° par rapport au plan de l'interstice de guidage (7).
EP97810241A 1996-05-08 1997-04-18 Procédé et dispositif de fibrillation de fibres cellulosiques facilement fibrillables, notamment de fibres tencel Expired - Lifetime EP0806512B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH1173/96 1996-05-08
CH117396 1996-05-08
CH117396 1996-05-08

Publications (2)

Publication Number Publication Date
EP0806512A1 EP0806512A1 (fr) 1997-11-12
EP0806512B1 true EP0806512B1 (fr) 2001-08-08

Family

ID=4204209

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97810241A Expired - Lifetime EP0806512B1 (fr) 1996-05-08 1997-04-18 Procédé et dispositif de fibrillation de fibres cellulosiques facilement fibrillables, notamment de fibres tencel

Country Status (6)

Country Link
US (1) US5845355A (fr)
EP (1) EP0806512B1 (fr)
JP (1) JPH1088467A (fr)
AT (1) ATE204038T1 (fr)
DE (1) DE59704221D1 (fr)
ES (1) ES2165012T3 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19732230A1 (de) * 1997-07-26 1999-01-28 Kuesters Eduard Maschf Verfahren und Vorrichtung zum Fibrillieren oder Defibrillieren von Cellulosefasern
DE19825123C2 (de) * 1998-06-05 2003-07-03 Silke Baumann Verfahren zur Erzeugung einer Fibrillation auf textilen Flächengebilden, die mehrheitlich Zellulose-Regeneratfasern enthalten
US6110588A (en) 1999-02-05 2000-08-29 3M Innovative Properties Company Microfibers and method of making
US6630231B2 (en) 1999-02-05 2003-10-07 3M Innovative Properties Company Composite articles reinforced with highly oriented microfibers
ES2172364B1 (es) * 1999-05-20 2003-10-16 Jaume Anglada Vinas Sa Aparato para el tratamiento de tejidos
US6680114B2 (en) 2001-05-15 2004-01-20 3M Innovative Properties Company Fibrous films and articles from microlayer substrates
ITFI20010168A1 (it) * 2001-09-12 2003-03-12 Coramtex Srl Macchina e metodo per il trattamento in continuo di un tessuto
US6692823B2 (en) 2001-12-19 2004-02-17 3M Innovative Properties Company Microfibrillated articles comprising hydrophillic component
US6753080B1 (en) 2002-01-29 2004-06-22 3M Innovative Properties Company Receptor medium having a microfibrillated surface
ITMI20021220A1 (it) * 2002-06-05 2003-12-05 Savio Macchine Tessili Spa Procedimento e dispositivo per il mercerizzo in continuo dei filati tessili
WO2015132757A1 (fr) * 2014-03-05 2015-09-11 Biancalani S.R.L. Procédé et machine permettant de traiter des tissus textiles avec un flux d'air réglable
ITUB20153062A1 (it) * 2015-08-12 2017-02-12 Salvade S R L Macchina per il trattamento di tessuti
TWI646234B (zh) * 2015-08-28 2019-01-01 立信歐洲有限責任公司 處理裝置的繩狀紡織品
CN107475864A (zh) * 2017-08-30 2017-12-15 江苏箭鹿毛纺股份有限公司 一种纳米抗菌防臭花呢及其生产工艺

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US3626449A (en) * 1970-01-23 1971-12-07 Komatsu Seiren Co Apparatus for continuously relaxing textile material in a treating liquid
US4291442A (en) * 1978-10-02 1981-09-29 Milliken Research Corporation Process for fibrillating polyester
EP0126178B1 (fr) * 1982-08-16 1988-06-22 Toray Industries, Inc. Installation pour le rasage ou la production d'aspérités sur des tissus
JPS6170065A (ja) * 1984-09-13 1986-04-10 株式会社 日阪製作所 布帛の液流処理装置
JP2611334B2 (ja) * 1988-05-25 1997-05-21 東洋紡績株式会社 再生セルロース系繊維織編物の加工方法
JPH0735634B2 (ja) * 1991-07-29 1995-04-19 内外特殊染工株式会社 布帛の加工処理方法
ATE137542T1 (de) * 1991-09-21 1996-05-15 Solipat Ag Verfahren und vorrichtung zur griff- und oberflächenverbesserung von textilen geweben und gewirken
EP0535288B1 (fr) * 1991-09-21 1996-02-21 Solipat Ag Procédé et installation de rétrécissement de tissus
JPH0711566A (ja) * 1993-06-26 1995-01-13 Toyobo Co Ltd 絹様布帛の製造方法
ES2082694B1 (es) * 1993-09-28 1998-01-01 Jauma Anglada Vinas S A Maquina para tratamiento en humedo de tejidos.
IT1269065B (it) * 1994-01-03 1997-03-21 Biancalani F & C Off Mec Macchina e metodo per il lavaggio in continuo di un tessuto, in specie per il lavaggio in corda
IT1272912B (it) * 1995-01-19 1997-07-01 Zonco Federico & Figlio Macchina per il trattamento ad umido ed a secco di tessuti in corda o in largo

Also Published As

Publication number Publication date
ATE204038T1 (de) 2001-08-15
ES2165012T3 (es) 2002-03-01
EP0806512A1 (fr) 1997-11-12
US5845355A (en) 1998-12-08
DE59704221D1 (de) 2001-09-13
JPH1088467A (ja) 1998-04-07

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