EA201500779A1 - Каталитическая композиция для полимеризации олефинов - Google Patents

Каталитическая композиция для полимеризации олефинов

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Publication number
EA201500779A1
EA201500779A1 EA201500779A EA201500779A EA201500779A1 EA 201500779 A1 EA201500779 A1 EA 201500779A1 EA 201500779 A EA201500779 A EA 201500779A EA 201500779 A EA201500779 A EA 201500779A EA 201500779 A1 EA201500779 A1 EA 201500779A1
Authority
EA
Eurasian Patent Office
Prior art keywords
carbon atoms
polymerization
group
catalytic composition
electron donor
Prior art date
Application number
EA201500779A
Other languages
English (en)
Other versions
EA026624B1 (ru
Inventor
Мансур Тафтаф
Джайпракаш Брийлал Сайнани
Владимир Александрович Захаров
Геннадий Дмитриевич Букатов
Махендрабхай Патель Вималькумар
Сергей Андреевич Сергеев
Мартин Александр Зёйдевелд
Аурора Александра Батинас-Гёртс
Original Assignee
Сауди Бейсик Индастриз Корпорейшн
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Filing date
Publication date
Application filed by Сауди Бейсик Индастриз Корпорейшн filed Critical Сауди Бейсик Индастриз Корпорейшн
Publication of EA201500779A1 publication Critical patent/EA201500779A1/ru
Publication of EA026624B1 publication Critical patent/EA026624B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/23—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/67—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/68—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/69—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

Abstract

Настоящее изобретение относится к каталитической композиции, содержащей сложный моноэфир, соединение, представленное формулой (I), в качестве внутреннего донора электронов и, необязательно, дополнительный внутренний донор электронов, выбранный из группы, состоящей из сложных диэфиров и простых диэфировгде R, R, R, R, Rи Rявляются одинаковыми или различными и независимо выбраны из группы, состоящей из водорода, линейного, разветвленного и циклического алкила, содержащего не более 20 атомов углерода, и ароматического замещенного и незамещенного углеводорода, имеющего от 6 до 20 углеродных атомов; Rвыбран из группы, состоящей из линейного, разветвленного и циклического алкила, имеющего не более 20 атомов углерода, и ароматического замещенного и незамещенного углеводорода, имеющего от 6 до 20 атомов углерода; и Rвыбирают из группы, состоящей из ароматического замещенного и незамещенного углеводорода, имеющего от 6 до 20 атомов углерода. Настоящее изобретение также относится к способу получения указанной каталитической композиции полимеризации и к каталитической системе полимеризации, содержащей указанную каталитическую композицию, сокатализатор и, необязательно, внешний донор электронов. Кроме того, настоящее изобретение относится к применению указанной каталитической композиции для полимеризации олефинов.
EA201500779A 2013-01-31 2014-01-28 Каталитическая композиция для полимеризации олефинов EA026624B1 (ru)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
EP13000481 2013-01-31
EP13000492 2013-01-31
EP13199147 2013-12-20
EP13199160 2013-12-20
US201461927029P 2014-01-14 2014-01-14
US201461927034P 2014-01-14 2014-01-14
PCT/EP2014/051609 WO2014118164A1 (en) 2013-01-31 2014-01-28 Catalyst composition for polymerization of olefins

Publications (2)

Publication Number Publication Date
EA201500779A1 true EA201500779A1 (ru) 2015-12-30
EA026624B1 EA026624B1 (ru) 2017-04-28

Family

ID=51261483

Family Applications (2)

Application Number Title Priority Date Filing Date
EA201500779A EA026624B1 (ru) 2013-01-31 2014-01-28 Каталитическая композиция для полимеризации олефинов
EA201500781A EA025272B1 (ru) 2013-01-31 2014-01-28 Способ получения компонента катализатора полимеризации олефинов

Family Applications After (1)

Application Number Title Priority Date Filing Date
EA201500781A EA025272B1 (ru) 2013-01-31 2014-01-28 Способ получения компонента катализатора полимеризации олефинов

Country Status (7)

Country Link
US (3) US9663596B2 (ru)
EP (2) EP2951215B1 (ru)
KR (2) KR102123473B1 (ru)
CN (2) CN104981488B (ru)
BR (2) BR112015018202B1 (ru)
EA (2) EA026624B1 (ru)
WO (2) WO2014118165A1 (ru)

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EA026624B1 (ru) 2013-01-31 2017-04-28 Сауди Бейсик Индастриз Корпорейшн Каталитическая композиция для полимеризации олефинов
WO2015091982A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
EA032114B1 (ru) 2013-12-20 2019-04-30 Сауди Бейсик Индастриз Корпорейшн Каталитическая система для полимеризации олефинов
US10000591B2 (en) 2013-12-20 2018-06-19 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
EA033164B1 (ru) 2013-12-20 2019-09-30 Сауди Бейсик Индастриз Корпорейшн Каталитическая система для полимеризации олефина
KR20160102018A (ko) 2013-12-20 2016-08-26 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 전구 촉매
EA034562B1 (ru) 2013-12-20 2020-02-20 Сауди Бейсик Индастриз Корпорейшн Композиция катализатора для полимеризации олефинов
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Also Published As

Publication number Publication date
US20150368381A1 (en) 2015-12-24
EP2951215A1 (en) 2015-12-09
US20150353656A1 (en) 2015-12-10
KR20150113108A (ko) 2015-10-07
KR102123471B1 (ko) 2020-06-17
EA201500781A1 (ru) 2016-01-29
BR112015018202B1 (pt) 2020-12-22
BR112015017749A2 (pt) 2017-07-11
EP2951215B1 (en) 2018-10-10
CN104981488A (zh) 2015-10-14
EA025272B1 (ru) 2016-12-30
BR112015017749B1 (pt) 2021-01-12
EA026624B1 (ru) 2017-04-28
WO2014118165A1 (en) 2014-08-07
KR102123473B1 (ko) 2020-06-17
US10106632B2 (en) 2018-10-23
US20170129974A1 (en) 2017-05-11
EP2951214B1 (en) 2019-01-23
CN104981487B (zh) 2017-03-08
US9587051B2 (en) 2017-03-07
EP2951214A1 (en) 2015-12-09
WO2014118164A1 (en) 2014-08-07
KR20150113107A (ko) 2015-10-07
CN104981487A (zh) 2015-10-14
BR112015018202A2 (pt) 2017-07-18
CN104981488B (zh) 2017-10-03
US9663596B2 (en) 2017-05-30

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