EA200600491A1 - Промотированный ниобием катализатор на основе смешанного оксида ванадия / фосфора - Google Patents

Промотированный ниобием катализатор на основе смешанного оксида ванадия / фосфора

Info

Publication number
EA200600491A1
EA200600491A1 EA200600491A EA200600491A EA200600491A1 EA 200600491 A1 EA200600491 A1 EA 200600491A1 EA 200600491 A EA200600491 A EA 200600491A EA 200600491 A EA200600491 A EA 200600491A EA 200600491 A1 EA200600491 A1 EA 200600491A1
Authority
EA
Eurasian Patent Office
Prior art keywords
phosphorus
niobih
vanadium oxide
catalyst based
promoted catalyst
Prior art date
Application number
EA200600491A
Other languages
English (en)
Other versions
EA010522B1 (ru
Inventor
Федерико Гельфи
Джанлука Маццони
Карло Фумагалли
Фабрицио Кавани
Франческа Пьерелли
Original Assignee
Лонца С.П.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Лонца С.П.А. filed Critical Лонца С.П.А.
Publication of EA200600491A1 publication Critical patent/EA200600491A1/ru
Publication of EA010522B1 publication Critical patent/EA010522B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Настоящее изобретение описывает способ получения модифицированного катализатора на основе смешанного оксида ванадия/фосфора для парциального окисления н-бутана в малеиновый ангидрид. Катализатор включает пирофосфат ванадила в качестве основного компонента и ниобий в качестве промотирующего элемента в количестве, которое соответствует атомному отношению ванадия к ниобию в интервале от 250:1 до 60:1. Катализатор проявляет улучшенную активность, повышенный выход малеинового ангидрида и оптимальные каталитические свойства с самого начала его работы в качестве катализатора.
EA200600491A 2003-09-15 2004-09-15 Промотированный ниобием катализатор на основе смешанного оксида ванадия/фосфора EA010522B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03425597A EP1514598A1 (en) 2003-09-15 2003-09-15 Niobium doped vanadium/phosphorus mixed oxide catalyst
PCT/EP2004/010336 WO2005025742A1 (en) 2003-09-15 2004-09-15 Niobium-doped vanadium/phosphorus mixed oxide catalyst

Publications (2)

Publication Number Publication Date
EA200600491A1 true EA200600491A1 (ru) 2006-10-27
EA010522B1 EA010522B1 (ru) 2008-10-30

Family

ID=34130436

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200600491A EA010522B1 (ru) 2003-09-15 2004-09-15 Промотированный ниобием катализатор на основе смешанного оксида ванадия/фосфора

Country Status (15)

Country Link
US (1) US7638457B2 (ru)
EP (2) EP1514598A1 (ru)
JP (1) JP4960095B2 (ru)
KR (1) KR101111373B1 (ru)
CN (1) CN1849170B (ru)
AT (1) ATE467456T1 (ru)
BR (1) BRPI0414393A (ru)
CA (1) CA2534293C (ru)
DE (1) DE602004027149D1 (ru)
EA (1) EA010522B1 (ru)
ES (1) ES2342289T3 (ru)
MX (1) MXPA06002957A (ru)
PL (1) PL1663482T3 (ru)
WO (1) WO2005025742A1 (ru)
ZA (1) ZA200602150B (ru)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1514598A1 (en) * 2003-09-15 2005-03-16 Lonza S.p.A. Niobium doped vanadium/phosphorus mixed oxide catalyst
WO2009061167A1 (en) * 2007-11-09 2009-05-14 Universiti Putra Malaysia An improved process to produce high surface area nanoparticle vanadium phosphorus oxide catalyst and product derives thereof
US8765629B2 (en) 2011-09-16 2014-07-01 Eastman Chemical Company Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US9573119B2 (en) 2011-09-16 2017-02-21 Eastman Chemical Company Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8993801B2 (en) 2011-09-16 2015-03-31 Eastman Chemical Company Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8883672B2 (en) 2011-09-16 2014-11-11 Eastman Chemical Company Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8658557B2 (en) * 2011-10-25 2014-02-25 Ineos Usa Llc Catalyst for n-butane oxidation to maleic anhydride
US9675966B2 (en) 2015-07-16 2017-06-13 Ineos Europe Ag Catalyst for n-butane oxidation to maleic anhydride
CN106582745B (zh) * 2015-10-19 2019-12-10 中国石油化工股份有限公司 用于精制钒磷氧催化剂中钒源的方法
WO2017100165A1 (en) * 2015-12-07 2017-06-15 Rutgers, The State University Of New Jersey Electrode material for lithium batteries
US11289700B2 (en) 2016-06-28 2022-03-29 The Research Foundation For The State University Of New York KVOPO4 cathode for sodium ion batteries
CN107649155A (zh) * 2017-09-29 2018-02-02 吉林大学 一种掺杂Nb的VPO催化剂、制备方法及其在制取丙烯酸中的应用
CN109293495B (zh) * 2018-10-15 2022-02-08 南京大学 一种复合相vpo催化剂及其制法和应用
KR102158638B1 (ko) * 2019-01-28 2020-09-22 한국화학연구원 수소생성 촉매 전극용 이차원 바나듐 탄화물의 제조방법
WO2022043323A1 (en) 2020-08-25 2022-03-03 Basf Se Mixed oxide comprising nb, v, and p suitable as catalyst for partial oxidation of hydrocarbons

Family Cites Families (18)

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US3255211A (en) * 1963-04-19 1966-06-07 Petro Tex Chem Corp Preparation of dicarboxylic acid anhydrides
GB1591307A (en) * 1976-11-11 1981-06-17 Ici Ltd Production of maleic anhydride and catalysts therefor
CA1197230A (en) * 1982-06-30 1985-11-26 Dennis E. Dria Preparation of improved mixed vanadium phosphorus oxide catalysts and their use in oxidation processes
US4649205A (en) * 1983-04-14 1987-03-10 Standard Oil Company (Indiana) Process for the manufacture of maleic anhydride utilizing catalysts reactivated with alkyl esters of orthophosphoric acid in the presence of water
US4654425A (en) 1983-08-17 1987-03-31 Lummus Crest, Inc. Process for making maleic anhydride
US4594433A (en) 1983-08-17 1986-06-10 Lummus Crest, Inc. Production of maleic anhydride
US4732885A (en) * 1983-09-30 1988-03-22 Amoco Corporation Process for the preparation of catalysts useful for the manufacture of maleic anhydride
IT1177272B (it) 1984-11-20 1987-08-26 Alusuisse Italia Spa Catalizzatore per reazioni di ossidazione e procedimento per la sua produzione
US5019545A (en) * 1988-07-28 1991-05-28 Amoco Corporation Process for manufacture of maleic anhydride catalysts
US5095125A (en) * 1989-01-17 1992-03-10 Amoco Corporation Maleic anhydride production
US4950769A (en) * 1989-08-23 1990-08-21 Amoco Corporation Process for the manufacture of maleic anhydride utilizing peroxides to improve catalytic activity
US5137860A (en) 1991-06-27 1992-08-11 Monsanto Company Process for the transformation of vanadium/phosphorus mixed oxide catalyst precursors into active catalysts for the production of maleic anhydride
US5235071A (en) * 1991-07-10 1993-08-10 Nippon Shokubai Co., Ltd. Catalyst for producing phthalic anhydride and process by using the same
US5506187A (en) * 1992-12-18 1996-04-09 Amoco Corporation Catalysts for the production of maleic anhydride by the oxidation of butane
US5474960A (en) * 1994-06-15 1995-12-12 The Standard Oil Company Process for reactivating a fluid bed catalyst in a reactor dipley
IT1290407B1 (it) 1996-04-29 1998-12-03 Lonza Spa Procedimento per la trasformazione di un precursore di catalizzatore a base di ossido misto di vanadio/fosforo nel catalizzatore attivo
ITMI991233A1 (it) * 1999-06-01 2000-12-01 Lonza Spa Procedimento per preparare un precursore di catalizzatore di ossido misto vanadio/fosforo
EP1514598A1 (en) * 2003-09-15 2005-03-16 Lonza S.p.A. Niobium doped vanadium/phosphorus mixed oxide catalyst

Also Published As

Publication number Publication date
ATE467456T1 (de) 2010-05-15
ES2342289T3 (es) 2010-07-05
ZA200602150B (en) 2007-07-25
US7638457B2 (en) 2009-12-29
US20060173197A1 (en) 2006-08-03
EP1663482B1 (en) 2010-05-12
MXPA06002957A (es) 2006-06-14
EA010522B1 (ru) 2008-10-30
EP1514598A1 (en) 2005-03-16
JP4960095B2 (ja) 2012-06-27
DE602004027149D1 (de) 2010-06-24
CN1849170B (zh) 2010-05-05
EP1663482A1 (en) 2006-06-07
CA2534293C (en) 2012-12-18
PL1663482T3 (pl) 2010-12-31
JP2007505730A (ja) 2007-03-15
BRPI0414393A (pt) 2006-11-21
WO2005025742A1 (en) 2005-03-24
KR20060092212A (ko) 2006-08-22
CA2534293A1 (en) 2005-03-24
KR101111373B1 (ko) 2012-04-10
CN1849170A (zh) 2006-10-18

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TC4A Change in name of a patent proprietor in a eurasian patent

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Designated state(s): AM AZ BY KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

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