DE69815657D1 - Katalysatoren und verfahren für die polymerisation von olefinen - Google Patents

Katalysatoren und verfahren für die polymerisation von olefinen

Info

Publication number
DE69815657D1
DE69815657D1 DE69815657T DE69815657T DE69815657D1 DE 69815657 D1 DE69815657 D1 DE 69815657D1 DE 69815657 T DE69815657 T DE 69815657T DE 69815657 T DE69815657 T DE 69815657T DE 69815657 D1 DE69815657 D1 DE 69815657D1
Authority
DE
Germany
Prior art keywords
olefins
catalysts
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69815657T
Other languages
English (en)
Other versions
DE69815657T2 (de
Inventor
D Horton
Baar F Van
A Schut
Kessel M Van
Hebel L Von
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of DE69815657D1 publication Critical patent/DE69815657D1/de
Application granted granted Critical
Publication of DE69815657T2 publication Critical patent/DE69815657T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69815657T 1997-10-29 1998-10-23 Katalysatoren und verfahren für die polymerisation von olefinen Expired - Lifetime DE69815657T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP97203332 1997-10-29
EP97203332 1997-10-29
PCT/EP1998/006732 WO1999021899A1 (en) 1997-10-29 1998-10-23 Catalysts and processes for the polymerization of olefins

Publications (2)

Publication Number Publication Date
DE69815657D1 true DE69815657D1 (de) 2003-07-24
DE69815657T2 DE69815657T2 (de) 2004-04-29

Family

ID=8228869

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69815657T Expired - Lifetime DE69815657T2 (de) 1997-10-29 1998-10-23 Katalysatoren und verfahren für die polymerisation von olefinen

Country Status (19)

Country Link
US (1) US6559252B1 (de)
EP (1) EP0948549B1 (de)
JP (1) JP4383549B2 (de)
KR (1) KR20000069756A (de)
CN (1) CN1116314C (de)
AR (1) AR017401A1 (de)
AU (1) AU1031899A (de)
BR (1) BR9806724A (de)
CA (1) CA2276173A1 (de)
DE (1) DE69815657T2 (de)
ES (1) ES2201544T3 (de)
HU (1) HUP0001325A3 (de)
ID (1) ID22020A (de)
IL (1) IL130479A0 (de)
MY (1) MY133201A (de)
NO (1) NO993205L (de)
PL (1) PL334339A1 (de)
WO (1) WO1999021899A1 (de)
ZA (1) ZA989696B (de)

Families Citing this family (115)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE304556T1 (de) 1998-07-02 2005-09-15 Basell Polyolefine Gmbh Verfahren zur herstellung von amorphen alpha- olefinpolymeren, diese enthaltende zusammensetzungen und verfahren zur herstellung von verbrückten liganden
EP1131328B1 (de) 1998-11-18 2003-05-07 Basell Polyolefine GmbH Methylen-verbrückte metallocene als olefin-polymerisationskatalysatorkomponente
AU1658600A (en) 1998-12-15 2000-07-03 Basell Technology Company B.V. Catalyst system for olefin polymerization
AU3960500A (en) 1999-03-09 2000-09-28 Basell Technology Company B.V. Multi-stage process for the (co)polymerization of olefins
KR20010072229A (ko) 1999-06-04 2001-07-31 간디 지오프레이 에이치. 티타늄 착물의 제조 방법
JP2003501434A (ja) 1999-06-07 2003-01-14 バセル テクノロジー カンパニー ビー．ブイ． ジアニオン性の二座配位子を有する遷移−金属−アルキル錯体の製造
JP2003510381A (ja) 1999-09-22 2003-03-18 バセル テクノロジー カンパニー ビー．ブイ． オレフィンの重合用触媒系および方法
US6444833B1 (en) 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
AU3016401A (en) 1999-12-28 2001-07-09 Basell Technology Company B.V. Process for the preparation of ethylene polymers
EP1157046B1 (de) 1999-12-28 2005-12-07 Basell Polyolefine GmbH Verfahren zur herstellung von äthylen polymere
JP4358470B2 (ja) 1999-12-28 2009-11-04 バセル テクノロジー カンパニー ビー．ブイ． メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー
JP2003520869A (ja) 2000-01-18 2003-07-08 バセル テクノロジー カンパニー ビー．ブイ． 実質的に非晶質のプロピレンベースのポリマーの製造方法
US6710006B2 (en) * 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
AU783058B2 (en) 2000-02-24 2005-09-22 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
EP1222216B1 (de) 2000-05-24 2004-12-29 Basell Polyolefine GmbH Propylenpolymere und verfahren zur ihrer herstellung
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
DE60135502D1 (de) 2000-09-25 2008-10-02 Basell Polyolefine Gmbh Verfahren zur herstellung von ethylenpolymeren mit einer bis-amid-titanverbindung
US7037988B2 (en) * 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
EP1265933B1 (de) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Katalysatorkomponente fur die polymerisation von olefinen
WO2002051887A2 (en) 2000-12-22 2002-07-04 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
ATE286505T1 (de) 2001-05-21 2005-01-15 Basell Polyolefine Gmbh Katalysatorsystem für die polymerisierung von olefinen
WO2002100908A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
US7074864B2 (en) 2001-06-12 2006-07-11 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
JP4418228B2 (ja) 2001-06-22 2010-02-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン、オレフィンポリマー製造用の触媒系における使用
WO2003008496A1 (en) 2001-07-17 2003-01-30 Basell Polyolefine Gmbh Multistep process for the (co)polymerization of olefins
JP2004536154A (ja) * 2001-08-01 2004-12-02 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 線状アルファオレフィンへのエチレンオリゴマー化のための配位子およびその触媒系
ATE353343T1 (de) 2001-11-12 2007-02-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-buten und 1- buten polymeren
WO2003046022A1 (en) 2001-11-27 2003-06-05 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
JP2005510567A (ja) 2001-11-30 2005-04-21 バセル ポリオレフィン ジーエムビーエイチ メタロセン化合物およびプロピレンポリマー製造方法
JP2005517773A (ja) * 2002-02-25 2005-06-16 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
CN100354356C (zh) * 2002-06-26 2007-12-12 巴塞尔聚烯烃意大利有限公司 抗冲击聚烯烃组合物
EP1517954B1 (de) * 2002-06-26 2014-05-28 Basell Poliolefine Italia S.r.l. Schlagfeste polyolefinzusammensetzungen
US7314903B2 (en) 2002-07-09 2008-01-01 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
US7615597B2 (en) 2002-09-06 2009-11-10 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
JP2006501067A (ja) * 2002-09-25 2006-01-12 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エチレンをオリゴマー化して直鎖α−オレフィンを合成するための触媒系
WO2004033510A2 (de) 2002-10-10 2004-04-22 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
EP1622948B1 (de) * 2003-05-12 2019-11-20 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-buten
CN101163723B (zh) 2003-07-04 2010-12-22 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
US20050014983A1 (en) * 2003-07-07 2005-01-20 De Boer Eric Johannes Maria Process for producing linear alpha olefins
US7579417B2 (en) 2003-12-22 2009-08-25 Basell Polyolefine Gmbh Metallocene compounds
JP2007528925A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ １−ヘキセンまたは高級α−オレフィンの重合方法
CN101001892A (zh) 2004-03-12 2007-07-18 巴塞尔聚烯烃股份有限公司 用于烯烃聚合的催化剂体系
EP1723184A1 (de) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
DE602005005185T2 (de) 2004-03-24 2009-03-26 Shell Internationale Research Maatschappij B.V. Übergangsmetallkomplexe
ATE445650T1 (de) * 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
WO2006005648A1 (en) 2004-07-13 2006-01-19 Basell Polyolefine Gmbh Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom
AR049714A1 (es) * 2004-07-13 2006-08-30 Shell Int Research Proceso de preparacion de alfa olefinas lineales
BRPI0513108A (pt) 2004-07-22 2008-04-29 Basell Polyolefine Gmbh processo para produzir polìmeros de buteno-1 fracionáveis
CN100567338C (zh) 2004-07-22 2009-12-09 巴塞尔聚烯烃股份有限公司 制备可分级的1-丁烯聚合物的方法
EP1805231B1 (de) * 2004-10-18 2010-03-31 Basell Poliolefine Italia S.r.l. Buten-1-(co)polymere mit geringer isotaktizität
WO2006045687A1 (en) * 2004-10-21 2006-05-04 Basell Polyolefine Gmbh 1-butene polymer and process for the preparation thereof
EP1655314A1 (de) * 2004-11-09 2006-05-10 Basell Polyolefine GmbH Polymerisationsverfahren von 1-buten mit propen
WO2006053911A1 (en) * 2004-11-22 2006-05-26 Basell Polyolefine Gmbh Propylene based terpolymers
WO2006063905A1 (en) * 2004-12-13 2006-06-22 Basell Poliolefine Italia S.R.L. Polyolefin composition, fibres and nonwoven fabrics
WO2006067214A1 (en) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Fibres having elastic properties
ATE502080T1 (de) * 2005-02-03 2011-04-15 Basell Polyolefine Gmbh Verfahren zur herstellung von warmgeformten artikeln
EP1858934B1 (de) * 2005-03-18 2013-04-24 Basell Polyolefine GmbH Metallocen-verbindungen
ES2316050T3 (es) * 2005-03-18 2009-04-01 Basell Polyolefine Gmbh Compuestos metalocenos.
US7799880B2 (en) * 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
BRPI0612170B1 (pt) * 2005-03-23 2017-02-21 Basell Polyolefine Gmbh processo para a polimerização de olefinas
US7964679B2 (en) * 2005-05-03 2011-06-21 Basell Poliolefine Italia S.R.L. Process for the polymerization of alpha olefins
ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends
US8051611B2 (en) * 2005-06-24 2011-11-08 Dryvit Systems, Inc. Exterior insulation and finish system and method and tool for installing same
US20090234084A1 (en) * 2005-06-30 2009-09-17 Basell Polyolefine Gmbh Metallocene Compounds
US8394907B2 (en) * 2005-10-21 2013-03-12 Basell Polyolefine Gmbh Polypropylene for injection molding
JP5379480B2 (ja) * 2005-10-21 2013-12-25 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンポリマー
DE602006014708D1 (de) * 2005-10-21 2010-07-15 Basell Polyolefine Gmbh Statistische polypropylencopolymere mit hohen schmelzflussraten für spritzguss- und schmelzblasanwendungen
BRPI0707677A2 (pt) * 2006-02-02 2011-05-10 Basell Polylefine Gmbh resinas "melt-blown" de propilemo , fibras de resina " melt-blown" de propileno e tecido nço-tecido fabricado, a partir das mesmas, mÉtodos de fabricar os mesmos
WO2007096209A1 (en) * 2006-02-23 2007-08-30 Basell Poliolefine Italia S.R.L. Propylene polymers for injection molding applications
US7858717B2 (en) * 2006-03-17 2010-12-28 Basell Polyolefine Gmbh Metallocene compounds
WO2007116034A1 (en) * 2006-04-12 2007-10-18 Basell Polyolefine Gmbh Metallocene compounds
US8785575B2 (en) * 2006-04-21 2014-07-22 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
WO2007122098A1 (en) * 2006-04-21 2007-11-01 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers
WO2008025721A1 (en) * 2006-08-30 2008-03-06 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
KR101374142B1 (ko) * 2006-08-30 2014-03-17 바젤 폴리올레핀 게엠베하 1-부텐 프로필렌 공중합체 조성물
US20100136078A1 (en) * 2007-05-23 2010-06-03 Pierre Herben Insecticidal composition and article obtained thereof
DE602008003124D1 (en) * 2007-06-25 2010-12-02 Basell Polyolefine Gmbh 1-butenethylencopolymere
US20100249346A1 (en) * 2007-10-19 2010-09-30 Basell Polyolefine Gmbh Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands
EP2227493B1 (de) * 2007-12-20 2011-09-14 Basell Polyolefine GmbH Verfahren zur gewinnung von polymeren aus ethylen und zykloolefinen
RU2010139855A (ru) * 2008-02-29 2012-04-10 Базелль Полиолефин Италия С.Р.Л. (It) Полиолефиновые композиции
US8097679B2 (en) * 2008-03-20 2012-01-17 Basell Poliolefine Italia Compositions of 1-butene based polymers
KR20100127226A (ko) * 2008-03-20 2010-12-03 바셀 폴리올레핀 이탈리아 에스.알.엘 1-부텐 공중합체
BRPI0910237A2 (pt) * 2008-03-20 2015-09-29 Basell Poliolefine Srl copolímeros de 1-buteno
US20100324238A1 (en) * 2008-03-20 2010-12-23 Basell Poliolefine Italia S.R.L 1-butene terpolymers
CN102216347B (zh) * 2008-04-22 2013-09-18 巴塞尔聚烯烃意大利有限责任公司 1-丁烯三元共聚物
EP2376568B1 (de) 2009-01-13 2013-05-08 Basell Poliolefine Italia S.r.l. Polymerzusammensetzung
CN102282182B (zh) 2009-01-13 2014-11-12 巴塞尔聚烯烃股份有限公司 聚乙烯共聚物
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
EP2606970A1 (de) 2011-12-19 2013-06-26 Basell Polyolefine GmbH Monocyclopentadienyl zweikernige Komplexe, bei ihrer Herstellung verwendete Liganden, Katalysatorsysteme und Verfahren zur Olefin-Polymerisation
EP2676972A1 (de) 2012-06-19 2013-12-25 Basell Polyolefine GmbH Verfahren zum Erhalt einer Polyolefinzusammensetzung
EP2743000A1 (de) 2012-12-13 2014-06-18 Basell Poliolefine Italia S.r.l. Katalysatorsystem zur Herstellung von Polyolefinen
EP2767542A1 (de) 2013-02-18 2014-08-20 Basell Polyolefine GmbH Oligomerisierungskatalysator
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
WO2015009480A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
SG11201508750SA (en) 2013-07-17 2015-11-27 Exxonmobil Chem Patents Inc Cyclopropyl substituted metallocene catalysts
WO2015009471A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
CN110845546A (zh) 2013-07-17 2020-02-28 埃克森美孚化学专利公司 取代的茂金属催化剂
WO2015065784A1 (en) * 2013-10-29 2015-05-07 Exxonmobil Chemical Patents Inc. Novel aluminum alkyl with c5 cyclic and pendent olefin polymerization catalyst
US9321854B2 (en) 2013-10-29 2016-04-26 Exxonmobil Chemical Patents Inc. Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst
CN107690441A (zh) 2015-06-05 2018-02-13 埃克森美孚化学专利公司 聚合物在气相或淤浆相中的单反应器制备
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
EP3464390A1 (de) 2016-05-27 2019-04-10 ExxonMobil Chemical Patents Inc. Metallocenkatalysatorzusammensetzungen und und polymerisationsverfahren damit
WO2019072695A1 (en) 2017-10-11 2019-04-18 Basell Polyolefine Gmbh CATALYST SUPPORTED SYSTEM
KR102656243B1 (ko) * 2018-11-20 2024-04-08 주식회사 엘지화학 신규한 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀계 중합체의 제조방법
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2023117512A1 (en) 2021-12-23 2023-06-29 Basell Poliolefine Italia S.R.L. Soft polyolefin composition

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1237398B (it) 1989-01-31 1993-06-01 Ausimont Srl Catalizzatori per la polimerizzazione di olefine.
DE3922546A1 (de) 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
ATE173746T1 (de) 1991-02-27 1998-12-15 Ticona Gmbh Verfahren zur herstellung von cycloolefin(co)polymeren mit enger molekulargewichtsverteilung
AU660808B2 (en) 1992-06-18 1995-07-06 Montell Technology Company B.V. Catalysts for the polymerization of olefins
DE4325824A1 (de) * 1993-07-31 1995-02-02 Basf Ag Verfahren zur Herstellung von Homopolymerisaten des Ethylens oder Copolymerisaten des Ethylens
IT1271406B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti
IT1273661B (it) 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
CN1242778A (zh) * 1997-10-29 2000-01-26 蒙特尔技术有限公司 烯烃聚合的催化剂及其制备方法

Also Published As

Publication number Publication date
HUP0001325A3 (en) 2002-02-28
PL334339A1 (en) 2000-02-28
NO993205D0 (no) 1999-06-28
CA2276173A1 (en) 1999-05-06
AR017401A1 (es) 2001-09-05
EP0948549A2 (de) 1999-10-13
BR9806724A (pt) 2000-04-04
ES2201544T3 (es) 2004-03-16
NO993205L (no) 1999-06-28
ID22020A (id) 1999-08-26
KR20000069756A (ko) 2000-11-25
DE69815657T2 (de) 2004-04-29
CN1116314C (zh) 2003-07-30
JP4383549B2 (ja) 2009-12-16
WO1999021899A1 (en) 1999-05-06
US6559252B1 (en) 2003-05-06
MY133201A (en) 2007-10-31
CN1248270A (zh) 2000-03-22
HUP0001325A2 (hu) 2000-08-28
ZA989696B (en) 1999-04-29
JP2001507401A (ja) 2001-06-05
IL130479A0 (en) 2000-06-01
AU1031899A (en) 1999-05-17
EP0948549B1 (de) 2003-06-18

Similar Documents

Publication Publication Date Title
DE69815657D1 (de) Katalysatoren und verfahren für die polymerisation von olefinen
DE69802491D1 (de) Komponenten und katalysatoren für die polymerisation von olefinen
DE69813444D1 (de) Katalysatorkomponenten und katalysatoren für die polymerisation von olefinen
DE69603211D1 (de) Verfahren zur Herstellung von festen Katalysatorkomponenten für die Olefinpolymerisation
DE69611554D1 (de) Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten
DE69600892D1 (de) Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
DE69524333T2 (de) Metallocen verbindungen und ihre verwendung in katalysatoren für die polymerisation von olefinen
DE69632189D1 (de) Katalysator und verfahren für die bereitung von kohlenwasserstoffen
DE69633569D1 (de) Übergangsmetallkomplex enthaltender polymerisationskatalysator und verfahren zur herstellung von olefinpolymeren
DE69505762D1 (de) Verfahren zur Herstellung von einem festen Katalysatorbestandteil für Olefinpolymerisation und Verfahren zur Olefinpolymerisation
DE69816281D1 (de) Katalysatorzusammensetzungen für die polymerisation von olefinen
DE69520400T2 (de) Katalysator zur Olefinpolymerisation und Verfahren zur Olefinpolymerisation
DE69307015D1 (de) Katalysatoren und Verfahren zur Herstellung von Olefinpolymeren
ATE204301T1 (de) Verfahren und apparat für die polymerisation von olefinmonomeren
DE69714830D1 (de) Olefinpolymerisationskatalysatore und Verfahren zur Herstellung von Olefinpolymeren
DE60036852D1 (de) Katalysatorkomponenten für die polymerisation von olefinen und daraus erhaltene katalysatoren
DE69611386D1 (de) Katalysatorzusammensetzung für die additionspolymerisation von olefinen
DE69605372D1 (de) Katalysatorbestandteil für Olefinpolymerisation, Katalysator für Olefinpolymerisation, und Verfahren zur Herstellung von Olefinpolymeren
DE69509458T2 (de) Olefinpolymerisationskatalysator und Verfahren zur Olefinpolymerisation
DE19882563T1 (de) Feste Katalysator-Komponenten für die Olefinpolimerisation, Katalysatoren für die Olefinpolymerisation und Verfahren zur Herstellung von Olefinpolymeren
DE69502561D1 (de) Katalysator zur Olefinpolymerisation und Verfahren zur Olefinpolymerisation
DE19981705T1 (de) y-Oxo-Bis-Metallocen-Komplexvrbindungen und Katalysatoren, die dieselben für die Polymerisation von Olefinen verwenden, sowie Polymerisationsverfahren
DE69409133D1 (de) Komponenten und Katalysatoren für die Polymerisation von Äthylen
DE69606521T2 (de) Bestandteile und katalysatoren für die olefinpolymerisation
DE69826633D1 (de) Katalysatoren für die polymerisation von olefinen und verfahren zur herstellung derselben

Legal Events

Date Code Title Description
8364 No opposition during term of opposition