DE69703438D1 - Metallocen cokatalysator - Google Patents

Metallocen cokatalysator

Info

Publication number
DE69703438D1
DE69703438D1 DE69703438T DE69703438T DE69703438D1 DE 69703438 D1 DE69703438 D1 DE 69703438D1 DE 69703438 T DE69703438 T DE 69703438T DE 69703438 T DE69703438 T DE 69703438T DE 69703438 D1 DE69703438 D1 DE 69703438D1
Authority
DE
Germany
Prior art keywords
cocalyst
metallocen
metallocen cocalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69703438T
Other languages
English (en)
Other versions
DE69703438T2 (de
Inventor
D Devore
J Timmers
R Neithamer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of DE69703438D1 publication Critical patent/DE69703438D1/de
Publication of DE69703438T2 publication Critical patent/DE69703438T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/603Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69703438T 1996-03-29 1997-03-20 Metallocen cokatalysator Expired - Fee Related DE69703438T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US1474596P 1996-03-29 1996-03-29
PCT/US1997/004247 WO1997036937A1 (en) 1996-03-29 1997-03-20 Metallocene cocatalyst

Publications (2)

Publication Number Publication Date
DE69703438D1 true DE69703438D1 (de) 2000-12-07
DE69703438T2 DE69703438T2 (de) 2001-03-08

Family

ID=21767441

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69703438T Expired - Fee Related DE69703438T2 (de) 1996-03-29 1997-03-20 Metallocen cokatalysator

Country Status (8)

Country Link
US (2) US6255246B1 (de)
EP (1) EP0889911B1 (de)
JP (1) JP2000507499A (de)
KR (1) KR20000005128A (de)
CN (1) CN1216996A (de)
DE (1) DE69703438T2 (de)
ES (1) ES2152653T3 (de)
WO (1) WO1997036937A1 (de)

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US6114270A (en) * 1998-08-07 2000-09-05 Equistar Chemicals, L.P. Polymerization-stable anionic ancillary ligand containing alkylimido catalysts and method of using the same
ES2280674T3 (es) * 1998-11-25 2007-09-16 Basell Polyolefine Gmbh Monohalogenuros de metaloceno.
KR20010110461A (ko) 1999-03-29 2001-12-13 스타르크, 카르크 올레핀의 중합 방법
DE19935592A1 (de) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
US6911516B1 (en) 1999-08-13 2005-06-28 Basell Polyolefine Gmbh Copolymers of ethylene with c3-c12 α-olefins
CN100434433C (zh) * 1999-10-08 2008-11-19 三井化学株式会社 茂金属化合物及制备方法、烯烃聚合催化剂、聚烯烃及制备方法
KR100786742B1 (ko) * 1999-10-08 2007-12-18 미쓰이 가가쿠 가부시키가이샤 폴리올레핀
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US6803339B2 (en) * 2001-09-14 2004-10-12 Bp Corporation North America Inc. Latent metallocene catalyst systems for olefin polymerization
US6998449B2 (en) * 2001-09-14 2006-02-14 Bp Corporation North America Latent metallocene catalyst systems for olefin polymerization
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US7507782B2 (en) 2003-05-21 2009-03-24 Basell Polyolefine Gmbh Transition-metal complexes with tridentate, nitrogen-containing ligands
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JP2007514685A (ja) 2003-12-19 2007-06-07 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
KR20060131874A (ko) * 2004-02-04 2006-12-20 프랙스에어 테크놀로지, 인코포레이티드 고밀도 핵생성 유기금속 화합물
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004039877A1 (de) 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
KR100676302B1 (ko) * 2005-01-06 2007-01-30 주식회사 엘지화학 안사-메탈로센 화합물의 제조방법
DE102005014395A1 (de) 2005-03-24 2006-09-28 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
CN101903413B (zh) 2007-12-19 2014-03-12 巴塞尔聚烯烃股份有限公司 乙烯三元共聚物
JP2011511760A (ja) * 2007-12-21 2011-04-14 バーゼル・ポリオレフィン・ゲーエムベーハー フェナントロリン含有コンプレックス
MX2010009009A (es) 2008-02-18 2010-12-15 Basell Polyolefine Gmbh Composicion polimerica adhesiva.
EP2344551B1 (de) 2008-09-25 2014-05-28 Basell Polyolefine GmbH Schlagzähe lldpe-zusammensetzungen und daraus hergestellte folien
KR20110061584A (ko) 2008-09-25 2011-06-09 바젤 폴리올레핀 게엠베하 내충격성 lldpe 조성물 및 이것으로 제조된 필름
US8435911B2 (en) * 2008-10-16 2013-05-07 Basell Polyolefine Gmbh Hybrid catalyst composition for polymerization of olefins
WO2010069527A1 (en) 2008-12-17 2010-06-24 Basell Polyolefine Gmbh Catalyst system for olefin polymerization, its production and use
BR112012001993B1 (pt) 2009-07-27 2019-06-25 Basell Polyolefine Gmbh Composto organometálico de metal de transição, sistema de catalisador e preparação de poliolefinas
CN102939311B (zh) 2010-05-28 2017-10-24 巴塞尔聚烯烃股份有限公司 制备用于烯烃聚合的负载型催化剂体系的方法,该催化剂体系及其用途
WO2011160828A1 (en) 2010-06-25 2011-12-29 Basell Polyolefine Gmbh Process for the production of high-strength polyolefin compositions and polyolefin compositions produced by this process
US8637616B2 (en) 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8629292B2 (en) 2010-10-07 2014-01-14 Chevron Phillips Chemical Company Lp Stereoselective synthesis of bridged metallocene complexes
US8609793B2 (en) 2010-10-07 2013-12-17 Chevron Phillips Chemical Company Lp Catalyst systems containing a bridged metallocene
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CN111138569A (zh) * 2018-11-05 2020-05-12 中国科学院化学研究所 有机硅烷化合物、聚烯烃树脂及其制备方法和应用
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Also Published As

Publication number Publication date
US6255246B1 (en) 2001-07-03
DE69703438T2 (de) 2001-03-08
KR20000005128A (ko) 2000-01-25
US20010007044A1 (en) 2001-07-05
EP0889911A1 (de) 1999-01-13
JP2000507499A (ja) 2000-06-20
US6365779B2 (en) 2002-04-02
CN1216996A (zh) 1999-05-19
ES2152653T3 (es) 2001-02-01
EP0889911B1 (de) 2000-11-02
WO1997036937A1 (en) 1997-10-09

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