DE69703438D1 - Metallocen cokatalysator - Google Patents
Metallocen cokatalysatorInfo
- Publication number
- DE69703438D1 DE69703438D1 DE69703438T DE69703438T DE69703438D1 DE 69703438 D1 DE69703438 D1 DE 69703438D1 DE 69703438 T DE69703438 T DE 69703438T DE 69703438 T DE69703438 T DE 69703438T DE 69703438 D1 DE69703438 D1 DE 69703438D1
- Authority
- DE
- Germany
- Prior art keywords
- cocalyst
- metallocen
- metallocen cocalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/603—Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1474596P | 1996-03-29 | 1996-03-29 | |
PCT/US1997/004247 WO1997036937A1 (en) | 1996-03-29 | 1997-03-20 | Metallocene cocatalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69703438D1 true DE69703438D1 (de) | 2000-12-07 |
DE69703438T2 DE69703438T2 (de) | 2001-03-08 |
Family
ID=21767441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69703438T Expired - Fee Related DE69703438T2 (de) | 1996-03-29 | 1997-03-20 | Metallocen cokatalysator |
Country Status (8)
Country | Link |
---|---|
US (2) | US6255246B1 (de) |
EP (1) | EP0889911B1 (de) |
JP (1) | JP2000507499A (de) |
KR (1) | KR20000005128A (de) |
CN (1) | CN1216996A (de) |
DE (1) | DE69703438T2 (de) |
ES (1) | ES2152653T3 (de) |
WO (1) | WO1997036937A1 (de) |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000507499A (ja) * | 1996-03-29 | 2000-06-20 | ザ・ダウ・ケミカル・カンパニー | メタロセン用共触媒 |
US6114270A (en) * | 1998-08-07 | 2000-09-05 | Equistar Chemicals, L.P. | Polymerization-stable anionic ancillary ligand containing alkylimido catalysts and method of using the same |
ES2280674T3 (es) * | 1998-11-25 | 2007-09-16 | Basell Polyolefine Gmbh | Monohalogenuros de metaloceno. |
KR20010110461A (ko) | 1999-03-29 | 2001-12-13 | 스타르크, 카르크 | 올레핀의 중합 방법 |
DE19935592A1 (de) | 1999-08-02 | 2001-02-08 | Elenac Gmbh | Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation |
US6911516B1 (en) | 1999-08-13 | 2005-06-28 | Basell Polyolefine Gmbh | Copolymers of ethylene with c3-c12 α-olefins |
CN100434433C (zh) * | 1999-10-08 | 2008-11-19 | 三井化学株式会社 | 茂金属化合物及制备方法、烯烃聚合催化剂、聚烯烃及制备方法 |
KR100786742B1 (ko) * | 1999-10-08 | 2007-12-18 | 미쓰이 가가쿠 가부시키가이샤 | 폴리올레핀 |
SG83223A1 (en) | 1999-12-27 | 2001-09-18 | Sumitomo Chemical Co | Modified particles, catalyst for olefin polymerization using the same, and process of producing olefin polymer |
DE10145453A1 (de) | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
US6803339B2 (en) * | 2001-09-14 | 2004-10-12 | Bp Corporation North America Inc. | Latent metallocene catalyst systems for olefin polymerization |
US6998449B2 (en) * | 2001-09-14 | 2006-02-14 | Bp Corporation North America | Latent metallocene catalyst systems for olefin polymerization |
DE50212940D1 (de) | 2001-09-14 | 2008-12-04 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von olefinen |
US6452031B1 (en) * | 2001-11-21 | 2002-09-17 | Boulder Scientific Company | Preparation of titanium organometallic complexes comprising a titanium bisalkoxide or dihalide moiety |
US20060089253A1 (en) * | 2002-08-13 | 2006-04-27 | Shahram Mihan | Monocyclopentadienyl complexes |
DE10237646A1 (de) * | 2002-08-13 | 2004-02-19 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
AU2003264065A1 (en) | 2002-08-22 | 2004-03-11 | Basell Polyolefine Gmbh | Monocyclopentadienyl complexes |
US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
EP1620479B1 (de) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefinklebstoffzusammensetzungen und daraus hergestellte gegenstände |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
RU2349606C2 (ru) | 2002-12-20 | 2009-03-20 | Базелль Полиолефине Гмбх | СОПОЛИМЕРЫ ЭТИЛЕНА С α-ОЛЕФИНАМИ |
DE60321822D1 (de) | 2002-12-20 | 2008-08-07 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
US8115182B1 (en) * | 2003-02-27 | 2012-02-14 | Gordhanbhai N Patel | Personal and area self-indicating radiation alert dosimeter |
EP1462464A1 (de) * | 2003-03-25 | 2004-09-29 | Borealis Technology Oy | Metallocenkatalysatoren, Verfahren zur Herstellung von Polyolefinen damit |
WO2004087776A1 (en) | 2003-04-03 | 2004-10-14 | Basell Polyolefine Gmbh | Preparation of polyolefins having high molecular weights in the presence of an organic transition metal compound in a gas-phase fluidized-bed reactor |
US7507782B2 (en) | 2003-05-21 | 2009-03-24 | Basell Polyolefine Gmbh | Transition-metal complexes with tridentate, nitrogen-containing ligands |
ES2321947T3 (es) | 2003-12-16 | 2009-06-15 | Basell Polyolefine Gmbh | Complejos de monociclopentadienilo. |
JP2007514685A (ja) | 2003-12-19 | 2007-06-07 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | モノシクロペンタジエニル錯体 |
KR20060131874A (ko) * | 2004-02-04 | 2006-12-20 | 프랙스에어 테크놀로지, 인코포레이티드 | 고밀도 핵생성 유기금속 화합물 |
DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
DE102004039877A1 (de) | 2004-08-17 | 2006-02-23 | Basell Polyolefine Gmbh | Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6 |
KR100676302B1 (ko) * | 2005-01-06 | 2007-01-30 | 주식회사 엘지화학 | 안사-메탈로센 화합물의 제조방법 |
DE102005014395A1 (de) | 2005-03-24 | 2006-09-28 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
DE102005019393A1 (de) | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Polyethylenformmassen für Spritzgussanwendungen |
DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
CN101903413B (zh) | 2007-12-19 | 2014-03-12 | 巴塞尔聚烯烃股份有限公司 | 乙烯三元共聚物 |
JP2011511760A (ja) * | 2007-12-21 | 2011-04-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | フェナントロリン含有コンプレックス |
MX2010009009A (es) | 2008-02-18 | 2010-12-15 | Basell Polyolefine Gmbh | Composicion polimerica adhesiva. |
EP2344551B1 (de) | 2008-09-25 | 2014-05-28 | Basell Polyolefine GmbH | Schlagzähe lldpe-zusammensetzungen und daraus hergestellte folien |
KR20110061584A (ko) | 2008-09-25 | 2011-06-09 | 바젤 폴리올레핀 게엠베하 | 내충격성 lldpe 조성물 및 이것으로 제조된 필름 |
US8435911B2 (en) * | 2008-10-16 | 2013-05-07 | Basell Polyolefine Gmbh | Hybrid catalyst composition for polymerization of olefins |
WO2010069527A1 (en) | 2008-12-17 | 2010-06-24 | Basell Polyolefine Gmbh | Catalyst system for olefin polymerization, its production and use |
BR112012001993B1 (pt) | 2009-07-27 | 2019-06-25 | Basell Polyolefine Gmbh | Composto organometálico de metal de transição, sistema de catalisador e preparação de poliolefinas |
CN102939311B (zh) | 2010-05-28 | 2017-10-24 | 巴塞尔聚烯烃股份有限公司 | 制备用于烯烃聚合的负载型催化剂体系的方法,该催化剂体系及其用途 |
WO2011160828A1 (en) | 2010-06-25 | 2011-12-29 | Basell Polyolefine Gmbh | Process for the production of high-strength polyolefin compositions and polyolefin compositions produced by this process |
US8637616B2 (en) | 2010-10-07 | 2014-01-28 | Chevron Philips Chemical Company Lp | Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects |
US8629292B2 (en) | 2010-10-07 | 2014-01-14 | Chevron Phillips Chemical Company Lp | Stereoselective synthesis of bridged metallocene complexes |
US8609793B2 (en) | 2010-10-07 | 2013-12-17 | Chevron Phillips Chemical Company Lp | Catalyst systems containing a bridged metallocene |
TWI555574B (zh) * | 2011-03-09 | 2016-11-01 | 亞比馬利股份有限公司 | 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途 |
CN111138569A (zh) * | 2018-11-05 | 2020-05-12 | 中国科学院化学研究所 | 有机硅烷化合物、聚烯烃树脂及其制备方法和应用 |
US20230183401A1 (en) * | 2019-04-30 | 2023-06-15 | Dow Global Technologies Llc | Alkene functionalized activators and their use in electrical applications |
CN112745364A (zh) * | 2019-10-30 | 2021-05-04 | 中国石油化工股份有限公司 | 一种芴基含n,n双齿配位的茂金属化合物及其应用 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1071703B (de) * | 1959-12-24 | |||
DE1034176B (de) * | 1956-02-21 | 1958-07-17 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von Boralkylen |
US2858339A (en) * | 1956-06-21 | 1958-10-28 | Olin Mathieson | 1-n-butyl boracyclopentane and process for its preparation |
GB818137A (en) * | 1958-04-09 | 1959-08-12 | Olin Mathieson | A novel cyclic organo-boron compound and the preparation thereof |
GB818138A (en) * | 1958-04-09 | 1959-08-12 | Olin Mathieson | 1-n-butyl boracyclopentane and process for its preparation |
DE1089384B (de) * | 1959-03-21 | 1960-09-22 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von ringfoermigen Borkohlenwasserstoffen |
DE1127899B (de) * | 1960-02-13 | 1962-04-19 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von aliphatischen Borheterocyclen |
US3101376A (en) * | 1962-04-30 | 1963-08-20 | Exxon Research Engineering Co | Reactions of organo boranes |
DE3041843C2 (de) | 1980-11-06 | 1984-10-18 | Henkel KGaA, 4000 Düsseldorf | Verwendung von 9-Borabicyclo[3.3.1]-nonan und dessen Additionsprodukten an ethylenisch ungesättigte Verbindungen als Polymerisationsinitiatoren für Reaktionsklebstoffe auf Basis ethylenische Doppelbindungen enthaltender Systeme |
US5089536A (en) | 1982-11-22 | 1992-02-18 | Minnesota Mining And Manufacturing Company | Energy polmerizable compositions containing organometallic initiators |
US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
DE4203753A1 (de) | 1992-02-10 | 1993-08-12 | Basf Ag | Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen |
US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
FI945958A (fi) | 1993-12-21 | 1995-06-22 | Hoechst Ag | Menetelmä polyolefiinien valmistamiseksi |
US5486632A (en) | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
US5554775A (en) * | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
WO1996034021A1 (en) * | 1995-04-25 | 1996-10-31 | Lyondell Petrochemical Company | Azaborolinyl metal complexes as olefin polymerization catalysts |
ES2135239T3 (es) * | 1995-06-28 | 1999-10-16 | Shell Int Research | Composiciones cataliticas que comprenden compuestos organometalicos. |
TW467933B (en) * | 1995-11-24 | 2001-12-11 | Ciba Sc Holding Ag | Photopolymerizable compositions comprising borate photoinitiators from monoboranes and the use thereof |
US6107421A (en) * | 1996-03-27 | 2000-08-22 | The Dow Chemical Company | Heterocyclic metal complexes and olefin polymerization process |
JP2000507499A (ja) * | 1996-03-29 | 2000-06-20 | ザ・ダウ・ケミカル・カンパニー | メタロセン用共触媒 |
US6034027A (en) * | 1996-05-17 | 2000-03-07 | Equistar Chemicals, Lp | Borabenzene based olefin polymerization catalysts containing a group 3-10 metal |
US5756611A (en) * | 1997-02-21 | 1998-05-26 | Lyondell Petrochemical Company | α-olefin polymerization catalysts |
US6114270A (en) * | 1998-08-07 | 2000-09-05 | Equistar Chemicals, L.P. | Polymerization-stable anionic ancillary ligand containing alkylimido catalysts and method of using the same |
-
1997
- 1997-03-20 JP JP9535291A patent/JP2000507499A/ja not_active Ceased
- 1997-03-20 EP EP97909048A patent/EP0889911B1/de not_active Expired - Lifetime
- 1997-03-20 WO PCT/US1997/004247 patent/WO1997036937A1/en not_active Application Discontinuation
- 1997-03-20 ES ES97909048T patent/ES2152653T3/es not_active Expired - Lifetime
- 1997-03-20 CN CN97194226A patent/CN1216996A/zh active Pending
- 1997-03-20 KR KR1019980707774A patent/KR20000005128A/ko not_active Application Discontinuation
- 1997-03-20 DE DE69703438T patent/DE69703438T2/de not_active Expired - Fee Related
-
2000
- 2000-01-18 US US09/487,399 patent/US6255246B1/en not_active Expired - Fee Related
-
2001
- 2001-02-20 US US09/789,411 patent/US6365779B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US6255246B1 (en) | 2001-07-03 |
DE69703438T2 (de) | 2001-03-08 |
KR20000005128A (ko) | 2000-01-25 |
US20010007044A1 (en) | 2001-07-05 |
EP0889911A1 (de) | 1999-01-13 |
JP2000507499A (ja) | 2000-06-20 |
US6365779B2 (en) | 2002-04-02 |
CN1216996A (zh) | 1999-05-19 |
ES2152653T3 (es) | 2001-02-01 |
EP0889911B1 (de) | 2000-11-02 |
WO1997036937A1 (en) | 1997-10-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8339 | Ceased/non-payment of the annual fee |