DE69406278T3 - Verfahren zur herstellung von hoch-glänzend, strahlunghärtbaren beschichtungen - Google Patents
Verfahren zur herstellung von hoch-glänzend, strahlunghärtbaren beschichtungenInfo
- Publication number
- DE69406278T3 DE69406278T3 DE69406278T DE69406278T DE69406278T3 DE 69406278 T3 DE69406278 T3 DE 69406278T3 DE 69406278 T DE69406278 T DE 69406278T DE 69406278 T DE69406278 T DE 69406278T DE 69406278 T3 DE69406278 T3 DE 69406278T3
- Authority
- DE
- Germany
- Prior art keywords
- coating
- radiation
- oxygen
- weight
- photoinitiator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 238000000576 coating method Methods 0.000 claims abstract description 70
- 239000011248 coating agent Substances 0.000 claims abstract description 45
- 239000008199 coating composition Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000012298 atmosphere Substances 0.000 claims abstract description 27
- 230000005855 radiation Effects 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 36
- 239000001301 oxygen Substances 0.000 claims description 36
- 229910052760 oxygen Inorganic materials 0.000 claims description 36
- -1 acryloxy groups Chemical group 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 22
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- 229920005989 resin Polymers 0.000 claims description 15
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical class FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 6
- 230000005865 ionizing radiation Effects 0.000 claims description 6
- 239000010410 layer Substances 0.000 claims description 6
- 239000002344 surface layer Substances 0.000 claims description 5
- 150000008062 acetophenones Chemical class 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims 2
- 238000010894 electron beam technology Methods 0.000 abstract description 18
- 238000001723 curing Methods 0.000 description 21
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000006233 lamp black Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
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- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- MRUJVILJKBDVQK-UHFFFAOYSA-N (2,2-dimethyl-3-prop-2-enoyloxypropyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C=C MRUJVILJKBDVQK-UHFFFAOYSA-N 0.000 description 1
- SZCWBURCISJFEZ-UHFFFAOYSA-N (3-hydroxy-2,2-dimethylpropyl) 3-hydroxy-2,2-dimethylpropanoate Chemical compound OCC(C)(C)COC(=O)C(C)(C)CO SZCWBURCISJFEZ-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
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- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- AKPLTHZVVWBOPT-UHFFFAOYSA-N 2,2-diethylbutane-1,3-diol Chemical compound CCC(CC)(CO)C(C)O AKPLTHZVVWBOPT-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- UTNFQABGIDNKDO-UHFFFAOYSA-N 2-(hydroxymethylidene)butanoic acid Chemical compound CCC(=CO)C(O)=O UTNFQABGIDNKDO-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- CYVMBANVYOZFIG-UHFFFAOYSA-N 2-ethylbutane-1,4-diol Chemical compound CCC(CO)CCO CYVMBANVYOZFIG-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
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- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- WOHXXIWTEHLCQK-UHFFFAOYSA-N 3-methylpentane-1,4-diol Chemical compound CC(O)C(C)CCO WOHXXIWTEHLCQK-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
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- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
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- 230000000977 initiatory effect Effects 0.000 description 1
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- 235000013980 iron oxide Nutrition 0.000 description 1
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- 239000011777 magnesium Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
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- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
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- 238000005259 measurement Methods 0.000 description 1
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- 229940117969 neopentyl glycol Drugs 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- IQOFOAJECLOAGR-UHFFFAOYSA-N nonane-4,5-diol Chemical compound CCCCC(O)C(O)CCC IQOFOAJECLOAGR-UHFFFAOYSA-N 0.000 description 1
- PKCKEGFHGRMLNH-UHFFFAOYSA-N octan-2-yl prop-2-enoate Chemical compound CCCCCCC(C)OC(=O)C=C PKCKEGFHGRMLNH-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001279 poly(ester amides) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/068—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using ionising radiations (gamma, X, electrons)
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paper (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Laminated Bodies (AREA)
- Electroluminescent Light Sources (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4109393A | 1993-04-01 | 1993-04-01 | |
PCT/US1994/002939 WO1994022596A1 (en) | 1993-04-01 | 1994-03-18 | Compositions and methods for producing high gloss radiaton curable coatings |
Publications (3)
Publication Number | Publication Date |
---|---|
DE69406278D1 DE69406278D1 (de) | 1997-11-20 |
DE69406278T2 DE69406278T2 (de) | 1998-04-30 |
DE69406278T3 true DE69406278T3 (de) | 2001-09-27 |
Family
ID=21914697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69406278T Expired - Fee Related DE69406278T3 (de) | 1993-04-01 | 1994-03-18 | Verfahren zur herstellung von hoch-glänzend, strahlunghärtbaren beschichtungen |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0693002B2 (es) |
AT (1) | ATE159276T1 (es) |
CA (1) | CA2156293C (es) |
DE (1) | DE69406278T3 (es) |
DK (1) | DK0693002T3 (es) |
ES (1) | ES2109687T5 (es) |
GR (1) | GR3025646T3 (es) |
WO (1) | WO1994022596A1 (es) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10321812A1 (de) * | 2003-05-15 | 2004-12-09 | Daimlerchrysler Ag | Verfahren zur Herstellung von Lackschichten mittels Härtung durch UV-Licht |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06172471A (ja) * | 1992-10-09 | 1994-06-21 | Henkel Hakusui Kk | 重合硬化性組成物とこれを用いて成形または被覆する方法 |
SE504783C2 (sv) | 1995-08-10 | 1997-04-21 | Triline Ab | Förfarande och anläggning för pulverlackering |
SE504784C2 (sv) * | 1995-08-10 | 1997-04-21 | Herberts Powder Coatings Ab | Förfarande för pulverlackering samt pulver för genomförande av förfarandet |
GB2327892B (en) * | 1997-07-31 | 2001-11-14 | Perstorp Ltd | Improvements in or relating to curable coating |
US7661387B2 (en) | 2004-01-30 | 2010-02-16 | Dunfries Investment Limited | Dual laser coating apparatus and process |
WO2006056482A1 (en) * | 2004-11-29 | 2006-06-01 | Dsm Ip Assets B.V. | Method for reducing the amount of migrateables of polymer coatings |
EP3443040B1 (en) | 2016-04-11 | 2022-02-23 | Sun Chemical Corporation | Electron beam curable inkjet formulation with improved adhesion |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3918393A (en) † | 1971-09-10 | 1975-11-11 | Ppg Industries Inc | Method of producing flat (non-glossy) films |
US4048036A (en) * | 1974-10-24 | 1977-09-13 | Ppg Industries, Inc. | Process for producing films of low gloss by exposure to ultraviolet light |
EP0003002B1 (de) † | 1977-12-22 | 1984-06-13 | Ciba-Geigy Ag | Verwendung von aromatisch-aliphatischen Ketonen als Photoinitiatoren, photopolymerisierbare Systeme enthaltend solche Ketone und neue aromatisch-aliphatische Ketone |
EP0030213A1 (de) * | 1979-11-29 | 1981-06-10 | Ciba-Geigy Ag | Durch Licht vernetzbare Schicht auf Druckformen und Verfahren zur Herstellung von Offset-Druckplatten |
US4317858A (en) * | 1980-06-27 | 1982-03-02 | Westinghouse Electric Corp. | Ultraviolet curable solvent-free wire enamel blends |
US4326001A (en) * | 1980-10-01 | 1982-04-20 | Gaf Corporation | Radiation cured coating and process therefor |
US4309452A (en) * | 1980-10-01 | 1982-01-05 | Gaf Corporation | Dual gloss coating and process therefor |
JPS5897132A (ja) * | 1981-12-07 | 1983-06-09 | Fuji Photo Film Co Ltd | 磁気記録材料の製造方法 |
DE3738567A1 (de) † | 1987-03-12 | 1988-09-22 | Merck Patent Gmbh | Coreaktive fotoinitiatoren |
EP0311288A3 (en) * | 1987-09-30 | 1992-01-08 | Westinghouse Electric Corporation | Improvements in or relating to resin compositions curable with ultraviolet light |
JP2546871B2 (ja) † | 1988-01-12 | 1996-10-23 | 三菱化学株式会社 | 金属光沢を有する樹脂積層体およびその製造方法 |
AU615563B2 (en) * | 1988-07-29 | 1991-10-03 | Nippon Kayaku Kabushiki Kaisha | Polyurrethane (meth)acrylate resin/n-vinyl- pyrrolidone/acryloylmorpholine resin composition |
US4999136A (en) * | 1988-08-23 | 1991-03-12 | Westinghouse Electric Corp. | Ultraviolet curable conductive resin |
DE4031732A1 (de) † | 1990-10-06 | 1992-04-09 | Basf Ag | Strahlenhaertbare, waessrige bindemitteldispersionen |
RU2091385C1 (ru) † | 1991-09-23 | 1997-09-27 | Циба-Гейги АГ | Бисацилфосфиноксиды, состав и способ нанесения покрытий |
-
1994
- 1994-03-18 ES ES94912806T patent/ES2109687T5/es not_active Expired - Lifetime
- 1994-03-18 AT AT94912806T patent/ATE159276T1/de not_active IP Right Cessation
- 1994-03-18 DE DE69406278T patent/DE69406278T3/de not_active Expired - Fee Related
- 1994-03-18 EP EP94912806A patent/EP0693002B2/en not_active Expired - Lifetime
- 1994-03-18 WO PCT/US1994/002939 patent/WO1994022596A1/en active IP Right Grant
- 1994-03-18 DK DK94912806.0T patent/DK0693002T3/da active
- 1994-03-18 CA CA002156293A patent/CA2156293C/en not_active Expired - Fee Related
-
1997
- 1997-12-10 GR GR970403298T patent/GR3025646T3/el unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10321812A1 (de) * | 2003-05-15 | 2004-12-09 | Daimlerchrysler Ag | Verfahren zur Herstellung von Lackschichten mittels Härtung durch UV-Licht |
DE10321812B4 (de) * | 2003-05-15 | 2009-10-08 | Daimler Ag | Verfahren zur Herstellung von Lackschichten mittels Härtung durch UV-Licht sowie dessen Verwendung |
Also Published As
Publication number | Publication date |
---|---|
WO1994022596A1 (en) | 1994-10-13 |
EP0693002B2 (en) | 2001-05-02 |
EP0693002A1 (en) | 1996-01-24 |
CA2156293C (en) | 1998-12-01 |
EP0693002B1 (en) | 1997-10-15 |
DK0693002T3 (da) | 1998-06-02 |
ES2109687T5 (es) | 2001-09-01 |
GR3025646T3 (en) | 1998-03-31 |
DE69406278T2 (de) | 1998-04-30 |
DE69406278D1 (de) | 1997-11-20 |
ES2109687T3 (es) | 1998-01-16 |
CA2156293A1 (en) | 1994-10-13 |
ATE159276T1 (de) | 1997-11-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: PPG INDUSTRIES OHIO, INC., CLEVELAND, OHIO, US |
|
8366 | Restricted maintained after opposition proceedings | ||
8339 | Ceased/non-payment of the annual fee |