DE69028843D1 - Verfahren zur herstellung von methacrolein und methacrylsäure - Google Patents
Verfahren zur herstellung von methacrolein und methacrylsäureInfo
- Publication number
- DE69028843D1 DE69028843D1 DE69028843T DE69028843T DE69028843D1 DE 69028843 D1 DE69028843 D1 DE 69028843D1 DE 69028843 T DE69028843 T DE 69028843T DE 69028843 T DE69028843 T DE 69028843T DE 69028843 D1 DE69028843 D1 DE 69028843D1
- Authority
- DE
- Germany
- Prior art keywords
- methacrylic acid
- producing methacrolein
- methacrolein
- producing
- methacrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 title 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8873—Zinc, cadmium or mercury
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8875—Germanium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1315163A JP2934267B2 (ja) | 1989-12-06 | 1989-12-06 | メタクロレインおよびメタクリル酸の製造方法 |
JP1338471A JP2756160B2 (ja) | 1989-12-28 | 1989-12-28 | メタクロレインおよびメタクリル酸の製造方法 |
JP2007200A JP2638241B2 (ja) | 1990-01-18 | 1990-01-18 | メタクロレインおよびメタクリル酸の製造方法 |
JP2014815A JP2659839B2 (ja) | 1990-01-26 | 1990-01-26 | メタクロレインおよびメタクリル酸の製造方法 |
PCT/JP1990/001594 WO1991008185A1 (en) | 1989-12-06 | 1990-12-06 | Process for producing methacrolein and methacrylic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69028843D1 true DE69028843D1 (de) | 1996-11-14 |
DE69028843T2 DE69028843T2 (de) | 1997-02-27 |
Family
ID=27454664
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69028843T Expired - Lifetime DE69028843T2 (de) | 1989-12-06 | 1990-12-06 | Verfahren zur herstellung von methacrolein und methacrylsäure |
DE69033068T Expired - Lifetime DE69033068T2 (de) | 1989-12-06 | 1990-12-06 | Verfahren zur Herstellung von Methacrolein und Methacrylsäure |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69033068T Expired - Lifetime DE69033068T2 (de) | 1989-12-06 | 1990-12-06 | Verfahren zur Herstellung von Methacrolein und Methacrylsäure |
Country Status (7)
Country | Link |
---|---|
US (1) | US5276178A (de) |
EP (2) | EP0608917B1 (de) |
KR (1) | KR950006522B1 (de) |
DE (2) | DE69028843T2 (de) |
ES (2) | ES2130297T3 (de) |
SG (1) | SG50687A1 (de) |
WO (1) | WO1991008185A1 (de) |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3272745B2 (ja) * | 1991-06-06 | 2002-04-08 | 三菱レイヨン株式会社 | メタクロレイン及びメタクリル酸の製造法 |
JP2974826B2 (ja) * | 1991-07-17 | 1999-11-10 | 三菱レイヨン株式会社 | メタクロレイン及びメタクリル酸製造用触媒の調製法 |
KR100277241B1 (ko) * | 1993-06-25 | 2001-02-01 | 고오사이 아끼오 | 불포화 알데하이드 및 불포화 카복실산의 제조방법 |
KR100247525B1 (ko) * | 1994-05-31 | 2000-03-15 | 겐지 아이다 | 불포화 알데히드 및 불포화 카르복실산 제조용 촉매 및 이 촉매를 이용한 불포화 알데히드 및 불포화 카르복실산의 제조방법 |
CN1046499C (zh) * | 1994-06-22 | 1999-11-17 | 旭化成工业株式会社 | 制备异丁烯醛的方法 |
US6136998A (en) * | 1996-10-15 | 2000-10-24 | Mitsubishi Rayon Co., Ltd. | Retention of activity of molybdenum-containing metallic oxide catalyst |
JP3775872B2 (ja) * | 1996-12-03 | 2006-05-17 | 日本化薬株式会社 | アクロレイン及びアクリル酸の製造方法 |
US5864051A (en) * | 1997-11-10 | 1999-01-26 | Uop | Selective oxidation catalyst process for preparing the catalyst and process using the catalyst |
JP4045693B2 (ja) * | 1999-04-27 | 2008-02-13 | 住友化学株式会社 | メタクリル酸の製造方法 |
KR100569632B1 (ko) * | 1999-05-13 | 2006-04-10 | 가부시키가이샤 닛폰 쇼쿠바이 | 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법 |
JP4185217B2 (ja) * | 1999-05-25 | 2008-11-26 | 株式会社日本触媒 | 複合酸化物触媒、並びに(メタ)アクロレインおよび(メタ)アクリル酸の製造方法 |
JP3943291B2 (ja) | 1999-08-04 | 2007-07-11 | 株式会社日本触媒 | アクロレインおよびアクリル酸の製造方法 |
JP3943311B2 (ja) * | 2000-05-19 | 2007-07-11 | 株式会社日本触媒 | 不飽和アルデヒドおよび不飽和カルボン酸の製造方法 |
DE10046957A1 (de) * | 2000-09-21 | 2002-04-11 | Basf Ag | Verfahren zur Herstellung eines Multimetalloxid-Katalysators, Verfahren zur Herstellung ungesättigter Aldehyde und/oder Carbonsäuren und Bandcalziniervorrichtung |
DE10063162A1 (de) * | 2000-12-18 | 2002-06-20 | Basf Ag | Verfahren zur Herstellung einer Mo, Bi, Fe sowie Ni und/oder Co enthaltenden Multimetalloxidativmasse |
TW572885B (en) * | 2001-05-30 | 2004-01-21 | Mitsubishi Rayon Co | Method for producing (meth)acrolein and/or (meth)acrylic acid |
CN1599708A (zh) * | 2001-12-27 | 2005-03-23 | 三菱化学株式会社 | 气相催化氧化法及(甲基)丙烯醛或(甲基)丙烯酸的制造方法 |
AU2002357503A1 (en) * | 2001-12-28 | 2003-07-24 | Mitsubishi Chemical Corporation | Method for vapor phase catalytic oxidation |
JP3884967B2 (ja) * | 2002-02-07 | 2007-02-21 | 住友化学株式会社 | メタクリル酸の製造方法 |
US6960684B2 (en) | 2002-03-29 | 2005-11-01 | Nippon Shokubai Co., Ltd. | Production process for unsaturated aldehyde |
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US6946422B2 (en) * | 2002-12-12 | 2005-09-20 | Saudi Basic Industries Corporation | Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes |
US20040192973A1 (en) * | 2003-03-31 | 2004-09-30 | Saudi Basic Industries Corporation | Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
US7361791B2 (en) * | 2003-03-31 | 2008-04-22 | Saudi Basic Industries Corporation | Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
US7232788B2 (en) * | 2003-03-31 | 2007-06-19 | Saudi Basic Industries Corporation | Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
US7161044B2 (en) * | 2003-10-22 | 2007-01-09 | Nippon Shokubai Co., Ltd. | Catalytic gas phase oxidation reaction |
WO2005054166A1 (ja) * | 2003-12-03 | 2005-06-16 | Mitsubishi Chemical Corporation | 不飽和アルデヒド及び不飽和カルボン酸の製造方法 |
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DE102007017080A1 (de) | 2007-04-10 | 2008-10-16 | Basf Se | Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres |
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CN105801394B (zh) * | 2014-12-31 | 2018-10-02 | 上海华谊新材料有限公司 | 由叔丁醇制备甲基丙烯醛的方法 |
WO2017010159A1 (ja) * | 2015-07-10 | 2017-01-19 | 日本化薬株式会社 | 不飽和アルデヒドおよび/または不飽和カルボン酸の製造方法 |
CN115260015A (zh) * | 2021-04-29 | 2022-11-01 | 中国石油化工股份有限公司 | 制备甲基丙烯醛和甲基丙烯酸的方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2056614C3 (de) * | 1970-11-18 | 1981-04-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Acrylsäure aus Propylen |
JPS5541213B2 (de) * | 1972-07-21 | 1980-10-22 | ||
JPS5761011B2 (de) * | 1973-12-28 | 1982-12-22 | Nippon Shokubai Kagaku Kogyo Kk | |
US4001317A (en) * | 1974-07-22 | 1977-01-04 | Standard Oil Company | Process for the oxidation of olefins using catalysts containing various promoter elements |
IN142430B (de) * | 1975-04-21 | 1977-07-09 | Standard Oil Co | |
US4323520A (en) * | 1976-08-02 | 1982-04-06 | The Standard Oil Co. | Preparation of methacrylic derivatives from tertiary-butyl-containing compounds |
JPS543008A (en) * | 1977-06-09 | 1979-01-11 | Japan Synthetic Rubber Co Ltd | Preparation of methacrylic acid |
US4148757A (en) * | 1977-08-10 | 1979-04-10 | The Standard Oil Company | Process for forming multi-component oxide complex catalysts |
JPS5547144A (en) * | 1977-08-10 | 1980-04-03 | Standard Oil Co | Multiple component oxide complex catalyst forming technique |
US4267386A (en) * | 1978-11-13 | 1981-05-12 | Celanese Corporation | Olefin oxidation catalyst |
JPS55113730A (en) * | 1979-02-26 | 1980-09-02 | Mitsubishi Petrochem Co Ltd | Preparation of acrolein and acrylic acid |
JPS5673041A (en) * | 1979-11-19 | 1981-06-17 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
JPS5687530A (en) * | 1979-12-19 | 1981-07-16 | Asahi Chem Ind Co Ltd | Dehydrating method of gas containing unsaturated aldehyde |
JPS56166140A (en) * | 1980-05-24 | 1981-12-21 | Asahi Chem Ind Co Ltd | Preparation of methacrolein |
JPS58119346A (ja) * | 1982-01-06 | 1983-07-15 | Nippon Shokubai Kagaku Kogyo Co Ltd | プロピレン酸化用触媒 |
JPS58143843A (ja) * | 1982-02-17 | 1983-08-26 | ザ・スタンダ−ド・オイル・カンパニー | オレフインの酸化またはアンモ酸化に有用な触媒 |
JPS5946132A (ja) * | 1982-09-06 | 1984-03-15 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクロレイン合成用触媒 |
JPS59115750A (ja) * | 1982-12-22 | 1984-07-04 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒 |
DE3308625A1 (de) * | 1983-03-11 | 1984-09-13 | Basf Ag, 6700 Ludwigshafen | Verfahren und katalysator zur herstellung von methacrylsaeure |
JPS6122040A (ja) * | 1984-07-10 | 1986-01-30 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
EP0168826B1 (de) * | 1984-07-18 | 1988-05-04 | Mitsubishi Rayon Co., Ltd. | Verfahren zur Herstellung von Methacrolein und Methacrylsäure |
JPH0625085B2 (ja) * | 1984-07-24 | 1994-04-06 | 三菱レイヨン株式会社 | メタクロレイン及びメタクリル酸の製造法 |
US5208371A (en) * | 1986-11-11 | 1993-05-04 | Mitsubishi Rayon Co., Ltd. | Process for production of methacrolein and methacrylic acid |
-
1990
- 1990-12-06 ES ES94103673T patent/ES2130297T3/es not_active Expired - Lifetime
- 1990-12-06 WO PCT/JP1990/001594 patent/WO1991008185A1/ja active IP Right Grant
- 1990-12-06 ES ES91900057T patent/ES2092557T3/es not_active Expired - Lifetime
- 1990-12-06 SG SG1996008755A patent/SG50687A1/en unknown
- 1990-12-06 DE DE69028843T patent/DE69028843T2/de not_active Expired - Lifetime
- 1990-12-06 DE DE69033068T patent/DE69033068T2/de not_active Expired - Lifetime
- 1990-12-06 EP EP94103673A patent/EP0608917B1/de not_active Expired - Lifetime
- 1990-12-06 KR KR1019910700846A patent/KR950006522B1/ko not_active IP Right Cessation
- 1990-12-06 EP EP91900057A patent/EP0456837B1/de not_active Expired - Lifetime
- 1990-12-06 US US07/721,574 patent/US5276178A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0456837A4 (en) | 1992-01-15 |
KR920701099A (ko) | 1992-08-11 |
DE69033068D1 (de) | 1999-05-27 |
EP0608917B1 (de) | 1999-04-21 |
SG50687A1 (en) | 1998-07-20 |
DE69033068T2 (de) | 1999-08-19 |
EP0456837A1 (de) | 1991-11-21 |
EP0456837B1 (de) | 1996-10-09 |
WO1991008185A1 (en) | 1991-06-13 |
US5276178A (en) | 1994-01-04 |
EP0608917A1 (de) | 1994-08-03 |
KR950006522B1 (ko) | 1995-06-16 |
ES2130297T3 (es) | 1999-07-01 |
DE69028843T2 (de) | 1997-02-27 |
ES2092557T3 (es) | 1996-12-01 |
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Owner name: SUMITOMO CHEMICAL CO., LTD., TOKIO/TOKYO, JP |