DE60033436D1 - Verfahren zur herstellung von vergrösserten latexteilchen - Google Patents

Verfahren zur herstellung von vergrösserten latexteilchen

Info

Publication number
DE60033436D1
DE60033436D1 DE60033436T DE60033436T DE60033436D1 DE 60033436 D1 DE60033436 D1 DE 60033436D1 DE 60033436 T DE60033436 T DE 60033436T DE 60033436 T DE60033436 T DE 60033436T DE 60033436 D1 DE60033436 D1 DE 60033436D1
Authority
DE
Germany
Prior art keywords
latex
acid
surfactant
enlarged
enlarged latex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60033436T
Other languages
English (en)
Other versions
DE60033436T2 (de
Inventor
Hiroshi Sakabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Denmark Finance AS
Original Assignee
Rohm and Haas Denmark Finance AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Denmark Finance AS filed Critical Rohm and Haas Denmark Finance AS
Application granted granted Critical
Publication of DE60033436D1 publication Critical patent/DE60033436D1/de
Publication of DE60033436T2 publication Critical patent/DE60033436T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C1/00Treatment of rubber latex
    • C08C1/02Chemical or physical treatment of rubber latex before or during concentration
    • C08C1/065Increasing the size of dispersed rubber particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C1/00Treatment of rubber latex
    • C08C1/02Chemical or physical treatment of rubber latex before or during concentration
    • C08C1/065Increasing the size of dispersed rubber particles
    • C08C1/07Increasing the size of dispersed rubber particles characterised by the agglomerating agents used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06Hydrocarbons
    • C08F12/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/06Vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/08Vinylidene chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04Acids, Metal salts or ammonium salts thereof
    • C08F20/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/42Nitriles
    • C08F20/44Acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/14Treatment of polymer emulsions
    • C08F6/18Increasing the size of the dispersed particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • C08L9/04Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • C08L9/08Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/10Latex

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
DE60033436T 1999-12-20 2000-12-14 Verfahren zur herstellung von vergrössertem latex Expired - Lifetime DE60033436T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP36071099 1999-12-20
JP36071099A JP4817403B2 (ja) 1999-12-20 1999-12-20 肥大化ラテックスの製造方法
PCT/JP2000/008843 WO2001046267A1 (fr) 1999-12-20 2000-12-14 Procede de production de latex a particules agrandies

Publications (2)

Publication Number Publication Date
DE60033436D1 true DE60033436D1 (de) 2007-03-29
DE60033436T2 DE60033436T2 (de) 2007-10-31

Family

ID=18470587

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60033436T Expired - Lifetime DE60033436T2 (de) 1999-12-20 2000-12-14 Verfahren zur herstellung von vergrössertem latex

Country Status (10)

Country Link
US (1) US6723764B2 (de)
EP (1) EP1245584B1 (de)
JP (1) JP4817403B2 (de)
KR (1) KR100477162B1 (de)
CN (1) CN1196715C (de)
AT (1) ATE353922T1 (de)
DE (1) DE60033436T2 (de)
MY (1) MY120866A (de)
TW (1) TWI228133B (de)
WO (1) WO2001046267A1 (de)

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AUPO069996A0 (en) * 1996-06-27 1996-07-18 Australian National University, The Manipulation of plant cellulose
JP5185480B2 (ja) * 2001-05-23 2013-04-17 ユーエムジー・エービーエス株式会社 成形外観に優れた熱可塑性樹脂組成物及びその製造方法
JP4553610B2 (ja) * 2004-03-12 2010-09-29 住友ゴム工業株式会社 ゴムラテックスの濃縮法
US20060122327A1 (en) * 2004-10-13 2006-06-08 Christopher Lester Process for preparing enlarged latex particles
KR100789249B1 (ko) * 2005-10-31 2008-01-02 주식회사 엘지화학 낮은 점도를 갖는 플라스티졸을 제공할 수 있는 염화비닐계수지의 제조 방법 및 그로부터 제조된 염화비닐계 수지
WO2007052911A1 (en) 2005-10-31 2007-05-10 Lg Chem, Ltd. Method of preparing vinylchloride-based resin capable of producing plastisol with low viscosity, vinylchloride-based resin prepared using the method, method of preparing vinylchloride-based plastisol, and vinylchloride-based plastisol prepared using the method
JP4985922B2 (ja) * 2006-07-25 2012-07-25 日本ゼオン株式会社 高飽和ニトリルゴム、その製造方法およびゴム架橋物
EP2336235B1 (de) * 2009-12-18 2012-10-03 Actega Artistica S.A. Dispersion auf Wasserbasis auf einem thermoplastischen Polymer und nicht thermoplastisches Elastomer
CN101870778B (zh) * 2010-07-09 2012-08-29 中国热带农业科学院农产品加工研究所 一种预硫化天然胶乳/壳聚糖共混膜材料及其制备方法
JP5909880B2 (ja) * 2011-05-31 2016-04-27 三菱レイヨン株式会社 水性エマルションの製造方法
SG11201400763QA (en) * 2011-10-06 2014-08-28 Pmb Technologies Pty Ltd Surface stabiliser and uses thereof
CN103044580A (zh) * 2011-10-17 2013-04-17 中国石油天然气股份有限公司 一种附聚胶乳的制备方法
CN103897095B (zh) * 2012-12-27 2016-03-09 中国石油天然气股份有限公司 一种含醋酸的丙烯酸酯胶乳的制备方法
ES2688532T3 (es) 2013-01-18 2018-11-05 Basf Se Composiciones de recubrimiento a base de dispersión acrílica
JP5821159B2 (ja) * 2013-03-28 2015-11-24 エルジー・ケム・リミテッド 樹脂組成物及びこれを含む逆波長分散性を有する光学フィルム
CN103194129A (zh) * 2013-04-29 2013-07-10 十堰恐龙化工有限公司 负离子乳胶漆及其制备方法
KR101630015B1 (ko) * 2013-08-01 2016-06-13 주식회사 엘지화학 대구경 폴리머 입자의 제조방법
CN105601768B (zh) * 2016-03-14 2017-12-29 黄润燕 一种天然橡胶加工***及其加工方法
CN106280077A (zh) * 2016-08-05 2017-01-04 安徽蓝通科技股份有限公司 一种防开裂的pvc管材及其制备方法
WO2019151776A1 (ko) * 2018-02-02 2019-08-08 주식회사 엘지화학 그라프트 공중합체의 제조방법, 그라프트 공중합체 및 열가소성 수지 성형품
KR102111120B1 (ko) * 2018-02-02 2020-06-08 주식회사 엘지화학 그라프트 공중합체의 제조방법, 그라프트 공중합체 및 열가소성 수지 성형품
KR102212039B1 (ko) * 2018-05-16 2021-02-05 주식회사 엘지화학 공액 디엔계 중합체의 제조방법 및 이를 포함하는 그라프트 공중합체의 제조방법
US11286314B2 (en) 2018-05-16 2022-03-29 Lg Chem, Ltd. Method for preparing conjugated diene-based polymer and method for preparing graft copolymer including the same
KR20200077384A (ko) * 2018-12-20 2020-06-30 주식회사 엘지화학 디엔계 고무 라텍스, 이의 제조방법 및 이를 포함하는 코어-쉘 구조의 그라프트 공중합체
WO2020196919A1 (ja) * 2019-03-28 2020-10-01 株式会社カネカ 粉粒体およびその利用
KR102489409B1 (ko) * 2019-08-16 2023-01-17 주식회사 엘지화학 비닐시안 화합물-공액디엔 화합물-방향족 비닐 화합물 그라프트 공중합체의 제조방법 및 이 그라프트 공중합체를 포함하는 열가소성 수지 조성물
CN114402026A (zh) * 2020-05-21 2022-04-26 株式会社Lg化学 热塑性树脂组合物

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Also Published As

Publication number Publication date
EP1245584A4 (de) 2003-07-09
JP2001172303A (ja) 2001-06-26
TWI228133B (en) 2005-02-21
US6723764B2 (en) 2004-04-20
ATE353922T1 (de) 2007-03-15
EP1245584A1 (de) 2002-10-02
MY120866A (en) 2005-11-30
DE60033436T2 (de) 2007-10-31
KR20020058058A (ko) 2002-07-12
US20030040555A1 (en) 2003-02-27
EP1245584B1 (de) 2007-02-14
WO2001046267A1 (fr) 2001-06-28
KR100477162B1 (ko) 2005-03-18
JP4817403B2 (ja) 2011-11-16
CN1409727A (zh) 2003-04-09
CN1196715C (zh) 2005-04-13

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