DE60017467D1 - Carbenium-aktivierte polymerisationskatalysatoren mit hoher aktivität - Google Patents

Carbenium-aktivierte polymerisationskatalysatoren mit hoher aktivität

Info

Publication number
DE60017467D1
DE60017467D1 DE60017467T DE60017467T DE60017467D1 DE 60017467 D1 DE60017467 D1 DE 60017467D1 DE 60017467 T DE60017467 T DE 60017467T DE 60017467 T DE60017467 T DE 60017467T DE 60017467 D1 DE60017467 D1 DE 60017467D1
Authority
DE
Germany
Prior art keywords
cyclopentadienyl ligand
polymerization
olefin
aromatic fused
ring substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60017467T
Other languages
English (en)
Other versions
DE60017467T2 (de
Inventor
J Crowther
George Rodriguez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE60017467D1 publication Critical patent/DE60017467D1/de
Application granted granted Critical
Publication of DE60017467T2 publication Critical patent/DE60017467T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE60017467T 1999-10-21 2000-10-23 Carbenium-aktivierte polymerisationskatalysatoren mit hoher aktivität Expired - Lifetime DE60017467T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US422533 1999-10-21
US09/422,533 US6300433B1 (en) 1998-10-23 1999-10-21 Olefin copolymerization process with bridged hafnocenes
PCT/US2000/029197 WO2001029096A1 (en) 1999-10-21 2000-10-23 High activity carbenium-activated polymerization catalysts

Publications (2)

Publication Number Publication Date
DE60017467D1 true DE60017467D1 (de) 2005-02-17
DE60017467T2 DE60017467T2 (de) 2006-02-16

Family

ID=23675314

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60017467T Expired - Lifetime DE60017467T2 (de) 1999-10-21 2000-10-23 Carbenium-aktivierte polymerisationskatalysatoren mit hoher aktivität

Country Status (12)

Country Link
US (1) US6300433B1 (de)
EP (1) EP1259553B1 (de)
JP (1) JP2003518146A (de)
KR (1) KR20020040905A (de)
CN (1) CN1376168A (de)
AT (1) ATE286921T1 (de)
BR (1) BR0014119A (de)
CA (1) CA2397818A1 (de)
DE (1) DE60017467T2 (de)
ES (1) ES2233471T3 (de)
MX (1) MXPA02003940A (de)
WO (1) WO2001029096A1 (de)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
EP1196464B9 (de) * 1998-10-23 2005-03-23 ExxonMobil Chemical Patents Inc. Verbrückte metallocene zur olefincopolymerisation
US6825295B2 (en) * 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
US20020107343A1 (en) * 2001-02-08 2002-08-08 Mitsui Chemicals, Inc. Ethylene polymer, preparation process thereof and molded articles of the same
EP1390417B1 (de) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
CN100595202C (zh) * 2002-09-27 2010-03-24 三井化学株式会社 烯烃聚合用交联金属茂化合物及使用该化合物的烯烃聚合方法
EP1620479B1 (de) 2002-10-15 2013-07-24 ExxonMobil Chemical Patents Inc. Polyolefinklebstoffzusammensetzungen und daraus hergestellte gegenstände
JP5255833B2 (ja) * 2004-03-24 2013-08-07 エクソンモービル・ケミカル・パテンツ・インク エチレン・インターポリマーの製造方法、該方法により製造されたインターポリマー、組成物、および該インターポリマーを含む電気デバイス
KR101141359B1 (ko) * 2005-09-09 2012-05-03 에스케이이노베이션 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계
WO2007029986A1 (en) * 2005-09-09 2007-03-15 Sk Energy Co., Ltd. Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins
CN101395188A (zh) 2006-03-02 2009-03-25 埃克森美孚化学专利公司 制备丙烯共聚物的方法
JP4714088B2 (ja) * 2006-06-16 2011-06-29 株式会社小糸製作所 車両用前照灯
US7872086B2 (en) 2008-01-17 2011-01-18 Tonen Chemical Corporation Polymeric material and its manufacture and use
EP2287145A1 (de) 2009-08-12 2011-02-23 BP p.l.c. Verfahren zur Reinigung von Ethylen
BR112016016396B1 (pt) 2014-02-13 2021-08-10 Mitsui Chemicals, Inc. Processo para a produção de copolímero de etileno/a-olefina
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties
KR20240005309A (ko) 2022-07-05 2024-01-12 한화토탈에너지스 주식회사 신규한 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물 및 이를 이용한 에틸렌 및 α-올레핀의 공중합체의 제조방법

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5408017A (en) 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
DE69026679T3 (de) * 1989-10-30 2005-10-06 Fina Technology, Inc., Houston Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
EP0708117B1 (de) * 1994-10-03 1999-08-11 Sumitomo Chemical Company Limited Verfahren zur Herstellung eines Copolymerkautschuks
US5834393A (en) 1995-03-10 1998-11-10 The Dow Chemical Company Adduct of an organometal compound and a compatible anion, supported catalyst component supported catalyst processes for the preparation thereof
JPH08208736A (ja) * 1994-11-28 1996-08-13 Chisso Corp 塩化ビニル系樹脂の製造方法
US5696213A (en) 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
WO1997022639A1 (en) * 1995-12-19 1997-06-26 Exxon Chemical Patents Inc. High temperature solution polymerization process
EP0786466B1 (de) 1996-01-25 2003-04-16 Tosoh Corporation Verfahren zur Olefinpolymerisierung unter Verwendung eines Übergangsmetallkatalysators.
US5856256A (en) 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
DE59703850D1 (de) 1996-08-13 2001-07-26 Basell Polyolefine Gmbh Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE69904449T2 (de) 1998-03-03 2003-09-25 Aquasol Ltd Chelmsford Wasserlösliche folien
CA2319067A1 (en) * 1998-03-04 1999-09-10 Exxon Chemical Patents, Inc. High temperature olefin polymerization process

Also Published As

Publication number Publication date
EP1259553B1 (de) 2005-01-12
CN1376168A (zh) 2002-10-23
ES2233471T3 (es) 2005-06-16
ATE286921T1 (de) 2005-01-15
CA2397818A1 (en) 2001-04-26
JP2003518146A (ja) 2003-06-03
BR0014119A (pt) 2002-05-14
WO2001029096A1 (en) 2001-04-26
US6300433B1 (en) 2001-10-09
DE60017467T2 (de) 2006-02-16
MXPA02003940A (es) 2002-10-23
EP1259553A1 (de) 2002-11-27
KR20020040905A (ko) 2002-05-30

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