ATE284421T1 - Verbrückte hafnocenen für die copolymerisation von olefinen - Google Patents

Verbrückte hafnocenen für die copolymerisation von olefinen

Info

Publication number
ATE284421T1
ATE284421T1 AT99971005T AT99971005T ATE284421T1 AT E284421 T1 ATE284421 T1 AT E284421T1 AT 99971005 T AT99971005 T AT 99971005T AT 99971005 T AT99971005 T AT 99971005T AT E284421 T1 ATE284421 T1 AT E284421T1
Authority
AT
Austria
Prior art keywords
polymerization
olefin
cyclopentadienyl
aromatic fused
ring substituted
Prior art date
Application number
AT99971005T
Other languages
English (en)
Inventor
George Rodriguez
Donna J Crowther
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE284421T1 publication Critical patent/ATE284421T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT99971005T 1998-10-23 1999-10-21 Verbrückte hafnocenen für die copolymerisation von olefinen ATE284421T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10532998P 1998-10-23 1998-10-23
PCT/US1999/024600 WO2000024792A1 (en) 1998-10-23 1999-10-21 Olefin copolymerization process with bridged hafnocenes

Publications (1)

Publication Number Publication Date
ATE284421T1 true ATE284421T1 (de) 2004-12-15

Family

ID=22305204

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99971005T ATE284421T1 (de) 1998-10-23 1999-10-21 Verbrückte hafnocenen für die copolymerisation von olefinen

Country Status (14)

Country Link
EP (1) EP1129115B1 (de)
JP (1) JP5255740B2 (de)
KR (1) KR100621299B1 (de)
CN (1) CN1125834C (de)
AT (1) ATE284421T1 (de)
AU (1) AU761531B2 (de)
BR (1) BR9914738A (de)
CA (1) CA2343768A1 (de)
DE (1) DE69922536T2 (de)
ES (1) ES2235549T3 (de)
MX (1) MXPA01003977A (de)
RU (1) RU2228937C2 (de)
TW (1) TW486489B (de)
WO (1) WO2000024792A1 (de)

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ATE485319T1 (de) * 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
WO2004039852A1 (en) * 2002-10-28 2004-05-13 Exxonmobil Chemical Patents, Inc. Low density ethylene copolymer, a process for making same and blends comprising such copolymer
JP5255833B2 (ja) * 2004-03-24 2013-08-07 エクソンモービル・ケミカル・パテンツ・インク エチレン・インターポリマーの製造方法、該方法により製造されたインターポリマー、組成物、および該インターポリマーを含む電気デバイス
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7576163B2 (en) 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
TWI404730B (zh) * 2007-02-05 2013-08-11 Univation Tech Llc 控制聚合物性質之方法
US9234093B2 (en) 2008-03-31 2016-01-12 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates
CN107268101B (zh) 2009-12-23 2021-08-24 英威达技术有限公司 聚烯烃弹性纤维
MX2012007401A (es) 2009-12-23 2012-07-17 Invista Tech Sarl Articulos elasticos que incluyen fibra elastica de poliolefina.
JP2013515871A (ja) 2009-12-23 2013-05-09 インビスタ テクノロジーズ エス エイ アール エル 抗粘着添加剤を含む弾性繊維
MX337858B (es) 2009-12-23 2016-03-18 INVISTA Technologies S à r l Tela que incluye fibra elastica de poliolefina.
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
WO2011087731A1 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
CN104428326A (zh) * 2012-09-27 2015-03-18 埃克森美孚化学专利公司 乙烯基封端聚合物及其制造方法
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
CN107075209B (zh) * 2014-09-30 2020-05-19 埃克森美孚化学专利公司 低乙烯的无定形丙烯-乙烯-二烯三元共聚物组合物
KR101975695B1 (ko) 2015-06-15 2019-05-07 엑손모빌 케미칼 패턴츠 인코포레이티드 연속 용액 중합 공정
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
KR102505086B1 (ko) 2016-11-18 2023-02-28 보레알리스 아게 촉매
US11530280B2 (en) 2016-12-15 2022-12-20 Borealis Ag Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
CN110234665B (zh) * 2016-12-15 2022-05-24 博里利斯股份公司 用于在高温溶液聚合方法中制备聚乙烯共聚物的催化剂体系
WO2018122134A1 (en) 2016-12-29 2018-07-05 Borealis Ag Catalysts
WO2018160300A1 (en) 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized epdm
US11560440B2 (en) 2017-03-30 2023-01-24 Borealis Ag Aluminoxane-activated metallocene catalysts
JP7221875B2 (ja) 2017-03-30 2023-02-14 ボレアリス エージー ホウ素で活性化されたメタロセン触媒
ES2905783T3 (es) 2018-03-19 2022-04-12 Borealis Ag Catalizadores para polimerización de olefinas
JP7440431B2 (ja) 2018-06-28 2024-02-28 ボレアリス エージー 触媒
JP7216184B2 (ja) 2018-07-23 2023-01-31 エクソンモービル・ケミカル・パテンツ・インク バイモーダルゴム、熱可塑性加硫物の調製およびそれから作られた物品
SG11202102663QA (en) 2018-09-19 2021-04-29 Exxonmobil Chemical Patents Inc Devolatilization processes
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
CA3037415A1 (en) * 2019-03-20 2020-09-20 Nova Chemicals Corporation Synthesis of metallocene polymerization catalyst
JP2022528937A (ja) 2019-04-12 2022-06-16 ボレアリス エージー 触媒系
WO2021126443A2 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Solution polymerization process for making high-density polyethylene long-chain branching
EP3845572A1 (de) * 2020-01-02 2021-07-07 Borealis AG Verfahren zur polymerisation von olefinen in lösung mit kontrollierter katalysatoraktivität im reaktoraustrittsstrom
JP2023532133A (ja) 2020-07-02 2023-07-26 セラニーズ・インターナショナル・コーポレーション メタロセン多峰性コポリマーゴムを含有する熱可塑性加硫物組成物およびその製造方法
CN118284630A (zh) 2021-11-23 2024-07-02 埃克森美孚化学专利公司 用于形成聚合物的设施和方法

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JP3392205B2 (ja) * 1994-03-11 2003-03-31 三井化学株式会社 新規遷移金属化合物およびこれを用いたオレフィンの重合方法
WO1996028480A1 (en) * 1995-03-10 1996-09-19 The Dow Chemical Company Supported catalyst component, supported catalyst, preparation process, polymerization process, complex compounds, and their preparation
DE69720823T2 (de) * 1996-01-25 2004-01-22 Tosoh Corp., Shinnanyo Verfahren zur Olefinpolymerisierung unter Verwendung eines Übergangsmetallkatalysators.
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
EP0824113B2 (de) * 1996-08-13 2012-06-27 Basell Polyolefine GmbH Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
KR20010041557A (ko) * 1998-03-04 2001-05-25 엑손 케미칼 패턴츠 인코포레이티드 고온 올레핀 중합방법

Also Published As

Publication number Publication date
RU2228937C2 (ru) 2004-05-20
BR9914738A (pt) 2001-07-03
KR20010075644A (ko) 2001-08-09
MXPA01003977A (es) 2003-06-06
TW486489B (en) 2002-05-11
JP2002528576A (ja) 2002-09-03
CN1125834C (zh) 2003-10-29
JP5255740B2 (ja) 2013-08-07
KR100621299B1 (ko) 2006-09-13
CN1324370A (zh) 2001-11-28
ES2235549T3 (es) 2005-07-01
EP1129115A1 (de) 2001-09-05
CA2343768A1 (en) 2000-05-04
DE69922536D1 (de) 2005-01-13
DE69922536T2 (de) 2005-12-15
AU1448400A (en) 2000-05-15
EP1129115B1 (de) 2004-12-08
AU761531B2 (en) 2003-06-05
WO2000024792A1 (en) 2000-05-04

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