CS220799B2 - Method of preparation of the cyclohexanole or cyclohexanone - Google Patents

Method of preparation of the cyclohexanole or cyclohexanone Download PDF

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Publication number
CS220799B2
CS220799B2 CS805261A CS526180A CS220799B2 CS 220799 B2 CS220799 B2 CS 220799B2 CS 805261 A CS805261 A CS 805261A CS 526180 A CS526180 A CS 526180A CS 220799 B2 CS220799 B2 CS 220799B2
Authority
CS
Czechoslovakia
Prior art keywords
cyclohexene
benzene
cyclohexanol
cyclohexanone
oxidation
Prior art date
Application number
CS805261A
Other languages
Czech (cs)
English (en)
Inventor
Greem Paul Ch Van
Graff Theodorus F De
Dirk Knol
Otto G Plantema
Original Assignee
Stamicarbon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stamicarbon filed Critical Stamicarbon
Publication of CS220799B2 publication Critical patent/CS220799B2/cs

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C07C29/05—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C07C29/05—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis
    • C07C29/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis the acid being sulfuric acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C07C29/05—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis
    • C07C29/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis the acid being phosphoric acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CS805261A 1979-07-26 1980-07-25 Method of preparation of the cyclohexanole or cyclohexanone CS220799B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7905781A NL7905781A (nl) 1979-07-26 1979-07-26 Werkwijze voor het bereiden van cyclohexanol.

Publications (1)

Publication Number Publication Date
CS220799B2 true CS220799B2 (en) 1983-04-29

Family

ID=19833597

Family Applications (1)

Application Number Title Priority Date Filing Date
CS805261A CS220799B2 (en) 1979-07-26 1980-07-25 Method of preparation of the cyclohexanole or cyclohexanone

Country Status (13)

Country Link
US (1) US4339604A (pt)
EP (1) EP0023379B1 (pt)
JP (1) JPS5643227A (pt)
BR (1) BR8004692A (pt)
CA (1) CA1140594A (pt)
CS (1) CS220799B2 (pt)
DD (1) DD152534A5 (pt)
DE (1) DE3064406D1 (pt)
ES (1) ES8104169A1 (pt)
IN (1) IN152656B (pt)
NL (1) NL7905781A (pt)
PL (1) PL126971B1 (pt)
YU (1) YU184380A (pt)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1146164B (it) * 1980-07-16 1986-11-12 Selenia Ind Elettroniche Dispositivo di filtraggio doppler adattivo alla situazione di clutter ed ecm esterna per impianti radar
NL8006602A (nl) * 1980-12-04 1982-07-01 Stamicarbon Werkwijze voor het bereiden van cyclohexanol en/of cyclohexanon.
DE3583818D1 (de) * 1984-05-25 1991-09-26 Asahi Chemical Ind Verfahren zur herstellung eines cyclischen alkohols.
JPH07108863B2 (ja) * 1987-04-07 1995-11-22 住友化学工業株式会社 シクロヘキサノ−ルの分離方法
NL8801036A (nl) * 1988-04-21 1989-11-16 Stamicarbon Werkwijze voor de bereiding van cyclohexanol en/of cyclohexanon.
KR950010785B1 (ko) * 1992-03-13 1995-09-23 재단법인한국화학연구소 시클로헥산올 및 시클로헥산온의 제조방법과 그에 사용되는 촉매
DE10209701A1 (de) * 2002-03-06 2003-09-18 Basf Ag Verfahren zur Herstellung von Cyclohexanol aus Benzol
RU2205819C1 (ru) * 2002-03-20 2003-06-10 Институт катализа им. Г.К.Борескова СО РАН Способ получения циклогексанона из бензола
UA95064C2 (en) * 2004-10-27 2011-07-11 ДСМ АйПи АСЕТС Б.В. Process for the preparation of cyclohexanol and cyclohexanone
TWI612031B (zh) * 2012-09-18 2018-01-21 China Petrochemical Technology Co Ltd 一種聯產環己醇和鏈烷醇的方法和裝置
US20160368844A1 (en) * 2013-07-24 2016-12-22 Exxonmobil Chemical Patents Inc. Process for Producing Mixtures of Cyclohexanone and Cyclohexanol
CN111559958A (zh) * 2020-06-19 2020-08-21 凯瑞环保科技股份有限公司 一种环己烯制备环己醇的工艺装置和工艺方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3682883A (en) * 1970-02-12 1972-08-08 Searle & Co Process for extraction of solanum alkaloids
US3682838A (en) * 1970-06-26 1972-08-08 Universal Oil Prod Co Multicomponent dehydrogenation catalyst
US3752776A (en) * 1970-11-16 1973-08-14 Mobil Oil Corp Multimetalite catalysts
US4067915A (en) * 1974-06-05 1978-01-10 Toray Industries, Inc. Method for producing cyclohexane derivatives directly from aromatic hydrocarbons
JPS5359649A (en) * 1976-11-11 1978-05-29 Toray Ind Inc Improved process for preparation of cyclohexane derivatives
JPS5390242A (en) * 1977-01-18 1978-08-08 Toray Ind Inc Preparation of cyclohexanol
JPS53144544A (en) * 1977-05-23 1978-12-15 Toray Ind Inc Production of cyclohexanols
JPS53144543A (en) * 1977-05-23 1978-12-15 Toray Ind Inc Improved method of producing cylcohexane derivative

Also Published As

Publication number Publication date
US4339604A (en) 1982-07-13
EP0023379A2 (en) 1981-02-04
ES493740A0 (es) 1981-04-16
EP0023379B1 (en) 1983-07-27
YU184380A (en) 1982-10-31
DD152534A5 (de) 1981-12-02
PL126971B1 (en) 1983-09-30
EP0023379A3 (en) 1981-02-11
PL225869A1 (pt) 1981-04-24
IN152656B (pt) 1984-03-03
BR8004692A (pt) 1981-02-10
CA1140594A (en) 1983-02-01
DE3064406D1 (en) 1983-09-01
NL7905781A (nl) 1981-01-28
ES8104169A1 (es) 1981-04-16
JPS5643227A (en) 1981-04-21

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