CN1787755A - Puncture resistant textile structure, especially for shoe soles - Google Patents

Puncture resistant textile structure, especially for shoe soles Download PDF

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Publication number
CN1787755A
CN1787755A CNA2004800099577A CN200480009957A CN1787755A CN 1787755 A CN1787755 A CN 1787755A CN A2004800099577 A CNA2004800099577 A CN A2004800099577A CN 200480009957 A CN200480009957 A CN 200480009957A CN 1787755 A CN1787755 A CN 1787755A
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CN
China
Prior art keywords
fabric
layer
textile
textile structural
aramid fibre
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Pending
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CNA2004800099577A
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Chinese (zh)
Inventor
R·芬兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LENZI EGISTO Spa
LENZI EGISTO SpA
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LENZI EGISTO Spa
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Publication of CN1787755A publication Critical patent/CN1787755A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B7/00Footwear with health or hygienic arrangements
    • A43B7/32Footwear with health or hygienic arrangements with shock-absorbing means
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/026Composites, e.g. carbon fibre or aramid fibre; the sole, one or more sole layers or sole part being made of a composite
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/12Soles with several layers of different materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0471Layered armour containing fibre- or fabric-reinforced layers
    • F41H5/0485Layered armour containing fibre- or fabric-reinforced layers all the layers being only fibre- or fabric-reinforced layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Ceramic Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Laminated Bodies (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Bedding Items (AREA)
  • Knitting Of Fabric (AREA)

Abstract

A textile structure resistant to perforation, specifically for shoe soles, comprises one or more layers of woven fabric of aramidic fibers and one or more layers of woven fabric of high tenacity non-aramidic fibers; the layers are bonded together by means of thermoplastic film and each separate layer of fabric is treated, preferably in the right side, by coating with a polyester and/or acrylic resin enriched with powders of hard and abrasive materials, such as ceramic materials preferably micronized and in form of aluminum silicates.

Description

Be particularly useful for the puncture resistant textile structure of sole
Technical field
The present invention relates to a kind of particularly textile structural of safety shoe hosiery of footwear that is suitable for, these footwear require to possess high level prevent by as nail or the similar sharp weapon puncture ability of particularly passing sole.
Background technology
Known many composite construction systems that are used for safe footwear sole, they are used to protect pin not to be subjected to the infringement of sharp or sharp objects.Some systems like this adopt metallic plate, yet its weight that has increased footwear has reduced the flexibility of footwear.The high heat conductance of metallic plate makes that also wearing footwear under hot environment understands uncomfortable.In addition, when wearing in the place that is limited by the metal detector monitoring, these footwear have further problem.
The tissue layer that some other system's employing is made by the coherent aramid fibre of thermoplastic polymer film (for example, referring to, patent US6368989).The problem of this class protectiveness panel is owing to only adopting aramid fibre to cost an arm and a leg.
Summary of the invention
Therefore; main purpose of the present invention is to provide a kind of particularly protectiveness textile structural of sole of footwear that is used in; this structure height prevents piercing through and penetrating of sharp or sharp objects, and possesses limited thickness and weight, the pliability of abundance and the cost of reduction simultaneously.
Further aim of the present invention is to provide a kind of textile structural of penetrating of preventing, this structure is antistatic and/or high temperature resistant also.
These purposes realize by the anti-penetration textile structural that claim 1 limited.Advantageous forms of implementation of the present invention such as dependent claims limit.
Advantage of the present invention and technical characteristic will be by becoming clear to following two non-limiting detailed descriptions of giving an example.
Description of drawings
-Fig. 1 is the schematic diagram according to first textile structural of the present invention;
-shown in Figure 2 is the polyester textile that is used in structure shown in Figure 1;
-Fig. 3 and Fig. 4 shown in respectively are the warp thread of fabric among Fig. 2 and the sectional drawing of weft yarn;
-Fig. 5 is the schematic diagram according to second textile structural of the present invention.
The specific embodiment
With reference to figure 1 and 5, according to a plurality of woven fabric layers 12,14,12 that are bonded together by thermoplastic film of puncture resistant textile structure 10,10 of the present invention ' consist essentially of ', 14 '.Particularly, described structure comprises one or more woven aramid fibre layers 12,12 ' and the non-aramid fibre of high strength (for example, polyamide, polyester, polyolefin and liquid crystal fiber) of one or more woven one-tenth fabric constructions layer.Each tissue layer preferably has the treated side 16 that has applied polyurethane and/or acrylic resin in the front, described resin is strengthened with hard, attrition resistant materials powder, and this powder is preferably micronized ceramic material, and described pottery is for example silicate form of aluminium.
In described structure, the aramid fibre layer is arranged alternately with non-layer of aramidic fabric respectively.
Two kinds of textile structurals as more detailed description hereinafter, have been found especially effectively and have been easy to produce.
Referring to figs. 1 through 4, puncture-proof first kind of textile structural is made of sandwich construction 10, and structure 10 comprises the woven fabric layer 12 of aramid fibre and is stacked on three the h woven fabric layer 14 of layer on 12.These layers bond together by thermoplastic film.At least one side of each layer is provided with ceramic treatment surface 16.
Advantageously, tissue layer 12,14 is handled in the front, and described layer of aramidic fabric 12 and contiguous dacron fabric layer 14 are with described treated side 16 contacts, and the treated side of remaining dacron fabric layer contacts with the face of being untreated of adjacent layer.Like this, be untreated in two of sandwich construction 10 outsides.Described aramid fibre layer is in and steps on ground one side when equally, more advantageously adopting above-mentioned structure in sole.
Because the ceramic coated materials on each tissue layer, structure according to the present invention possess the anti-mechanical penetration performance of the height of sharp metal thing and stop the sharp metal thing to pass this structure.
In addition, advantageously, this structure possesses following feature, and promptly by being no more than the aramid fibre that accounts for the textile fabric gross weight 15% of using, remainder then constitutes for h.This point relatively all greatly reduces production cost by the structure that aramid fibre constitutes, and keeps the suitable production cost with the structure that is made of metallic plate, but possesses the advantage of high flexibility than it.
In the embodiment according to protective structures of the present invention, found to select in the following manner to form the fabric the 12, the 14th of sandwich construction 10, very favourable.
Fabric in aramidic fibers:
-plain weave;
-warp yams in aramidic fibers, Kevlar  730dtex particularly, every centimetre 19 ± 2% of density;
-weft yarn aramid fibre, Kevlar  730dtex particularly, every centimetre 15 ± 2% of density;
-ceramic blankets realizes by the compound that applies 90~120gr/sq.mt., and this compound is made up of 50% polyurethane resin, 25% acrylic resin and 25% alumina silicate.
The final weight of the fabric of Xing Chenging is 340~350 ± 5%gr/sq.mt. like this, and its weight consists of about 80% Kevlar , 10% polyurethane, 5% acrylic acid and 5% alumina silicate.
Dacron fabric:
-united organization (shown in Fig. 2 to 4) is made up of two simple 3X3;
The warp thread of-high strength (H.T.) polyester fiber 1100dtex, every centimetre 22 ± 2% of density;
The weft yarn of-h 1100dtex, every centimetre 29 ± 2% of density;
-ceramic blankets realizes by applying 90~120gr/sq.mt..
The final weight of the fabric of Xing Chenging is 690~720 ± 5%gr/sq.mt. by this way, and its weight consists of about 86% polyester fiber, 7% polyurethane, 3.5% acrylic acid and 3.5% alumina silicate.
The fabric that the tissue that is adopted makes it possible to produce possesses and weaves yarn very closely, and makes its structure have the height adhesion, thereby owing to its structure provides high anti-penetration performance, keeps higher flexibility simultaneously.
Particularly, found to use the woven united organization of polyester fiber very effective on production sandwich construction 10.
By carrying out hot calender and can obtain bonding between each tissue layer embedding thermoplastic film (polyolefin and/or polyurethane and/or polyester) between each layer; By heat handle described combining structure make ceramic material not only with thermoplastic film bonding and but also merge with the superficial layer of adjacent tissue layer, thereby produce the integral unit that gross thickness is no more than 3mm and limited weight.
Advantageously, adopt the thermoplastic film of making by resistant to elevated temperatures polyester, can obtain being particularly suitable for designing the footwear structure when being used in high temperature source and existing.
The main assembly that above-mentioned textile structural has is:
The aramid fibre of-percentage by weight about 12%;
The h of-percentage by weight about 73%;
The ceramic treatment surface of-percentage by weight about 15%;
-gross weight 2435~2555 ± 5%gr/sq.mt..
The evidence that described structure is carried out its can prevent the power of the 1100N at least that nail applies effectively, as standard EN ISO 20344, EN344/92 and EN12568/98 predict.
By conductor wire is inserted in the aromatic polyamide fiber fabric and non-aromatic polyamide fiber fabric that constitutes described sandwich construction, can obtain antistatic structure, can be used in the footwear that require antistatic property.
Particularly, it is favourable producing aromatic polyamide fiber fabric in the following manner:
-warp thread constitutes per 74 warps, repeat once (therefore, the second warp thread composition is 82% polyamide and 18% stainless steel) with Kevlar  730dtex as second warp thread that first warp thread repeats to constitute with the stainless steel long filament sth. made by twisting that with two gangs of high strength polyamide 180dtex and diameter is 60 microns for 73 times together.
-weft yarn constitutes per 56 parallels, repeats once as first weft yarn repetition 55 times and such as mentioned above second weft yarn that constitutes with polyamide and steel wire with Kevlar  730dtex.
Dacron fabric is preferably made again like this:
-every centimetre 23 ± 2% warp thread, warp thread consists of per 24 yarns, is repeated 23 times and is added that with polyester H.T.1100dtex second warp thread that 24dtex carbon (or steel) silk of a twisting constitutes repeats once (finally consisting of 95% polyester and 5% carbon) by first warp thread that constitutes with polyester H.T.1100dtex.
-every centimetre 25.5 ± 2% weft yarns, weft yarn consist of per 30 yarns, second weft yarn repetition secondary that is repeated 28 times and be made of polyester H.T. and carbon in the above described manner by first weft yarn that constitutes with polyester H.T.1100dtex.
Prevent that according to of the present invention textile structural second embodiment that penetrates as shown in Figure 5.
In this situation, two coherent sandwich constructions 120,140 of structure 10 ' comprise, this two sandwich construction comprises first group three layer and second group of three layer that are stacked of being stacked, first group of stack layer be by the aramid fibre woven fabric 12 that is provided with ceramic treatment surface 16 ' constitute, and second group of stack layer is by the high strength polyamide woven fabric 14 that is provided with ceramic treatment surface ' constitute.Advantageously, the adjacent layer 12 of at least two aromatic polyamide fiber fabrics ' or two polyamide fabrics 14 ' two adjacent layers or two adjacent layers of sandwich construction 120,140 have treatment surface 16 and be in contact with one another, thereby described structure 10 ' two outer surfaces (end face and bottom surface) be do not have treated.
In actual embodiment, found to select the fabric of the above-mentioned sandwich construction 120,140 of formation very effective according to following method.
Aromatic polyamide fiber fabric: as among above-mentioned first embodiment.
Polyamide fabric:
-weft yarn rib tissue (weft rep weave);
The warp thread that-polyamide 66 high strength fibre constitutes, 200dtex, Taslanization (taslanized) and density are every centimetre 62;
The weft yarn that-high-strength nylon 66 constitutes, 636dtex, Taslanization (taslanized) and density are every centimetre 16.5;
-by applying the ceramic blankets that 60gr/sq.mt. compound same as described above obtains.
The final weight of the fabric of Chan Shenging is about 300gr/sq.mt. like this, and is made up of following weight: 80% Fypro, 10% polyurethane, 5% acrylic acid and 5% alumina silicate.
The structure of being made up of three layers of layer of aramidic fabric and three high strength polyamide fabric layers as indicated above possesses following main assembly:
-components by weight percent accounts for 38% aramid fibre;
-components by weight percent accounts for 34% high strength Fypro;
-components by weight percent accounts for 18% ceramic treatment surface;
The about 2200gr/sq.mt. of-gross weight
Its thickness is less than 3mm (after bonding described layer and insertion thermoplastic film by hot calender).
Described in top each embodiment, can puncture-proof textile structural also adiabatic and can be in a conventional manner as the protectiveness insert that is embedded in the sole, this be by making or bonding being applied on the shoes.
Described structure also can be advantageously by sole is directly formed in the production that sole is used in footwear in the above by injection molding.For example, in Strobel class footwear, this structure can constitute the end in the footwear, and the end at first is sewn into top injection molding formation afterwards sole in these footwear.In fact,, determined, effectively prevented the perforation of nail and pierce through not hinder and utilize suitable suture needle that described structure is sewed on top according to the clause of standard EN 344/92.
The present invention can carry out multiple change and variation, and all these all fall within the scope of the present invention.And all available means that are equal to of all ins and outs are replaced.

Claims (16)

1, a kind of puncture resistant textile structure, be particularly useful for sole, it is characterized in that comprising: woven layer of one or more aramid fibres and the woven layer of the non-aramid fibre of one or more high strength, described each layer is bonded together by thermoplastic film, each woven layer is preferably handled by applying polyurethane and/or acrylic resin in the front, and described resin is rich in hard and high-abrasive material.
2, textile structural as claimed in claim 1 is characterized in that described hard and high-abrasive material is a ceramic material, and preferred micronize also is the silicate form.
3, textile structural as claimed in claim 2 is characterized in that described micronize ceramic material is an alumina silicate.
4, as the described textile structural of one of claim 1 to 3, it is characterized in that a sandwich construction comprises the woven fabric ground floor of being made by aramid fibre, and be stacked on three woven fabric layers making by h on the described ground floor, described each layer is bonded together by thermoplastic film, and at least one side of each layer has ceramic treatment surface.
5, textile structural as claimed in claim 4, it is characterized in that described aromatic poly-amide fabric layer and adjacent dacron fabric layer contact with described treatment surface, remaining dacron fabric layer contacts with the untreatment surface of adjacent layer with described treatment surface.
6, textile structural as claimed in claim 4 is characterized in that the 15-20% that is no more than of the textile fabric gross weight that adopted is made of aramid fibre.
7, textile structural as claimed in claim 5, wherein:
-described aromatic polyamide fiber fabric is a plain weave, it uses the aramid fibre warp thread, be specially Kevlar ), 730dtex, every centimetre of 19 yarns, with use aramid fibre weft yarn, be specially Kevlar , 730dtex, every centimetre of 15 yarns, it is coated with following composition with 90-120gr/sq.mt. at this fabric face, and said composition is made up of 50% polyurethane resin, 25% acrylic resin and 25% alumina silicate;
-described dacron fabric is the united organization fabric, and this united organization singly organizes 3X3 to form by two, and warp thread and weft yarn are the H.T.1100dtex polyester yarn, and every centimetre be respectively 22 and 29, and is coated with described compound in this fabric one side.
8, as the described textile structural of one of claim 4 to 7, its thing is levied in the aromatic polyamide fiber fabric that is the described sandwich construction of conductive filament embedding formation and in the non-aromatic polyamide fiber fabric of high strength.
9,, it is characterized in that alternately layout of described layer of aramidic fabric and the non-layer of aramidic fabric of those high strength as the described textile structural of one of claim 1 to 3.
10, as the described textile structural of one of claim 1 to 3, it is characterized in that two fabric sandwich constructions are bonded together, one of them fabric sandwich construction is formed by three laminations that the aramid fibre woven fabric constitutes, and coated ceramic coating on woven face, and second sandwich construction formed by three laminations that the h woven fabric constitutes, and on this woven face the coated ceramic coating.
11, textile structural as claimed in claim 10, it is characterized in that two adjacent layer of aramidic fabric or two adjacent dacron fabric layers, the adjacent layer of perhaps described two sandwich constructions contacts with the ceramic coating surface, and that this textile structural is in two outsides of top or bottom is not processed.
12, textile structural as claimed in claim 10 is characterized in that the 50-60% that is no more than of the textile fabric gross weight that adopted is made of aramid fibre.
13, textile structural as claimed in claim 10, wherein:
-described aromatic polyamide fiber fabric is a plain weave, its warp thread is an aramid fibre, be specially Kevlar  730dtex, 19 every centimetre, with weft yarn be aramid fibre, be specially Kevlar  730dtex, 15 every centimetre, organizing the following composition of front surface coated 90-120gr/sq.mt., said composition is made up of 50% polyurethane resin, 25% acrylic resin and 25% alumina silicate;
-described polyamide fabric is weft yarn rib tissue, and warp thread is a high strength polyamide 66 fiber, 200dtex, Taslanization, 62 every centimetre, and weft yarn is high-strength nylon 66,636dtex, Taslanization, is being organized the described composition of front surface coated 60gr/sq.mt. by 16.5 every centimetre.
14, structure as claimed in claim 1, wherein the aforementioned hot plastic films is made by resistant to elevated temperatures polyester.
15, according to the purposes of the puncture resistant textile structure of one of front claim, it is as the protection thing that embeds sole.
16, according to the purposes of the puncture resistant textile structure of one of claim 1-14, it directly forms sole on top by injection molding in the manufacture process of footwear, and top at footwear is at first made at an interior end.
CNA2004800099577A 2003-04-14 2004-04-14 Puncture resistant textile structure, especially for shoe soles Pending CN1787755A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITPO20030005 ITPO20030005A1 (en) 2003-04-14 2003-04-14 PERFORATION RESISTANT TEXTILE STRUCTURE ESPECIALLY FOR SHOE SOLES
ITPO2003A000005 2003-04-14

Publications (1)

Publication Number Publication Date
CN1787755A true CN1787755A (en) 2006-06-14

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US (1) US20060211318A1 (en)
EP (1) EP1613185B1 (en)
CN (1) CN1787755A (en)
AT (1) ATE399483T1 (en)
CA (1) CA2521626A1 (en)
DE (1) DE602004014749D1 (en)
IT (1) ITPO20030005A1 (en)
WO (1) WO2004089143A2 (en)

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CN102493202A (en) * 2011-12-01 2012-06-13 山东三达科技发展公司 Composite puncture-proof sheet and bulletproof puncture-proof composite material
CN110177993A (en) * 2017-01-12 2019-08-27 安东尼奥莫伦德布拉斯公司 The Woven fabric and gained sole of nonmetallic sole for safety footwear
CN110868882A (en) * 2018-04-16 2020-03-06 耐克创新有限合伙公司 Shoe outer sole plate
CN111150172A (en) * 2019-12-24 2020-05-15 温州市巨伦鞋业有限公司 Anti-puncture sole of labor protection shoes and preparation method thereof
CN111890758A (en) * 2020-07-24 2020-11-06 江西棱志特种材料有限公司 Weaving process of three-dimensional anti-puncture cloth based on multi-layer binding

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WO2014200465A1 (en) * 2013-06-11 2014-12-18 Honeywell International Inc. Perforation-resistant flexible insert for garment or footwear
EP3089610B1 (en) * 2014-01-03 2020-05-27 Vibram S.p.A. Sole resistant to perforation and method of manufacturing thereof
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WO2017058419A1 (en) 2015-10-02 2017-04-06 Nike Innovate C.V. Plate with foam for footwear
JP7240876B2 (en) 2015-10-02 2023-03-16 ナイキ イノベイト シーブイ board for footwear
CN105231565B (en) * 2015-10-20 2018-01-16 杭州华水布艺有限公司 A kind of anti-stab protective fabric containing ice-cold material
EP3383638A1 (en) 2015-12-02 2018-10-10 Carbitex, Inc. Joined fiber-reinforced composite material assembly with tunable anisotropic properties
US10798992B2 (en) 2016-07-20 2020-10-13 Nike, Inc. Footwear plate
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IT201700051624A1 (en) * 2017-05-12 2018-11-12 U Invest S R L SAFETY SAFETY SHOE.
KR102247685B1 (en) * 2017-09-28 2021-04-30 코오롱인더스트리 주식회사 Puncture-resistant sole for shoe and method of manufacturing the same
US11344078B2 (en) 2018-04-16 2022-05-31 Nike, Inc. Outsole plate
US11109639B2 (en) 2018-05-23 2021-09-07 Carbitex, Inc. Footwear insert formed from a composite assembly having anti-puncture and anisotropic properties

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102493202A (en) * 2011-12-01 2012-06-13 山东三达科技发展公司 Composite puncture-proof sheet and bulletproof puncture-proof composite material
CN110177993A (en) * 2017-01-12 2019-08-27 安东尼奥莫伦德布拉斯公司 The Woven fabric and gained sole of nonmetallic sole for safety footwear
CN110868882A (en) * 2018-04-16 2020-03-06 耐克创新有限合伙公司 Shoe outer sole plate
CN110868882B (en) * 2018-04-16 2021-09-21 耐克创新有限合伙公司 Shoe outer sole plate
CN111150172A (en) * 2019-12-24 2020-05-15 温州市巨伦鞋业有限公司 Anti-puncture sole of labor protection shoes and preparation method thereof
CN111890758A (en) * 2020-07-24 2020-11-06 江西棱志特种材料有限公司 Weaving process of three-dimensional anti-puncture cloth based on multi-layer binding

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CA2521626A1 (en) 2004-10-21
WO2004089143A2 (en) 2004-10-21
ATE399483T1 (en) 2008-07-15
EP1613185A2 (en) 2006-01-11
US20060211318A1 (en) 2006-09-21
EP1613185B1 (en) 2008-07-02
ITPO20030005A1 (en) 2004-10-15
WO2004089143A3 (en) 2004-11-18
DE602004014749D1 (en) 2008-08-14

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