CN105231565B - A kind of anti-stab protective fabric containing ice-cold material - Google Patents
A kind of anti-stab protective fabric containing ice-cold material Download PDFInfo
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- CN105231565B CN105231565B CN201510684194.6A CN201510684194A CN105231565B CN 105231565 B CN105231565 B CN 105231565B CN 201510684194 A CN201510684194 A CN 201510684194A CN 105231565 B CN105231565 B CN 105231565B
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Abstract
The invention discloses a kind of anti-stab protective fabric containing ice-cold material, its drip irrigation device is, the protective materials using superhigh molecular weight polyethylene fibers, aromatic polyamide fibre, it is poly- to penylene benzo-dioxazole fiber, carbon fiber, high-strength polyester fibers, imitative spider silk fiber any of which plain cloth as basic unit, and basic unit's multilayer is set；Blending has the Coolking fibers or Coolplus fibers of energy moisture absorbing and sweat releasing in fiber in the basic unit；Shear thickening fluid is uniformly attached with the basic unit, it is by using static dipping method that shear thickening fluid is compound with basic unit.The anti-stab protective fabric has the advantages that soft, ventilative, comfortable, in the state of usual use, close to the comfort level of common fabric, with enough intensity when by external impacts, meet police or the routine office work activity need of other staff for using anti-stabbing lining.
Description
Technical field
The present invention relates to protective materials technical field, more specifically, it relates to a kind of anti-stab protection containing ice-cold material
Fabric.
Background technology
Along with the process of global economic integration, various exchange activities are increasingly frequent, particularly current terrorism and
When violence has come back, the gradually enhancing of people's self-protection consciousness.It is standby that anti-terrorism turns into international especially developed country
Concerned event, therefore the exploitation of individual protection product is also able to fast development.
For many countries including China, the use management of firearms is strict, and army and police, law enforcement officer etc. face an ancient type of spoon
The threat of the sharp instrument such as head, cone, pin is relatively more so that the research and development of stab-resistant material is increasingly taken seriously.Tradition is anti-stab
Material is thick and heavy, volume is big, dumb, is only capable of protecting the metastomium of limbs, and can not be to some joint parts such as knee
Lid etc. is effectively protected, and is faced with barrier propterty and flexibility is difficult to the contradiction taken into account, recent years with Kevlar,
The appearance of the high performance synthetic fibers such as UHMWPE, PBO, carbon fiber, also lightweight flexible can be made using high-performance fiber, be easy to
The stab-resistant material of dress, but compared to common cloth, gas permeability, the comfortableness of this kind of stab-resistant material are poor, especially exist
It can seem abnormal sultry under the condition of high temperature in summer, if reducing the content of high-performance synthetic fibers, can cause under anti-stab performance
Drop.
The content of the invention
Well have the anti-stab protective materials of good anti-stab performance concurrently simultaneously it is an object of the invention to provide a kind of comfortableness.
To achieve the above object, the invention provides following technical scheme：
A kind of anti-stab protective fabric containing ice-cold material, the protective materials are knitted with the plain weave of superhigh molecular weight polyethylene fibers
Thing is basic unit, and basic unit's multilayer is set；
Blending has the Coolking fibers of energy moisture absorbing and sweat releasing in fiber in the basic unit；
Uniformly be attached with shear thickening fluid in the basic unit, by using static dipping method by shear thickening fluid with
Basic unit is compound.
Further set：There are modified nanoparticles in the shear thickening fluid, the nano particle is different-grain diameter
SiO2Particle, the SiO2The mass fraction of particle is between 40%-45%.
Further set：The SiO2The particle diameter of particle is 160-380nm.
Further set：The basic unit is made up of netted pilotaxitic texture, basic unit 20-500g/m2Surface density knot containing micropore
Structure, has 0.01-0.3mm aperture, and porosity is not less than 10%.
Further set：Resin matrix is compounded between the multilayer basic unit, the resin matrix is selected from high-density polyethylene
Alkene.
It is arranged such, using basic unit made of high-performance synthetic fibers, there is very high tensile property, modulus of elasticity and energy
Absorbent properties are measured, but cost is higher, and do not possess the comfortableness of common fabric, the blending simultaneously in the fiber for be made into basic unit
Enter Coolking fibers, Coolking fibers dimension belongs to new function fiber, and fibre section is "+" type, and surface is micro-grooves, tool
Have countless trickle cavities, by capillarity caused by these micro-grooves, by the moisture of skin surface discharge and sweat via
Effect, Quick diffusing moisture and the sweat such as wicking diffusion, transmission, human body surface is kept dry and comfortable, refrigerant, comfortable, there is regulation
The effect of body temperature.
In addition, be also attached with shear thickening fluid in the basic unit, shear thickening fluid can enter in fiber and fiber it
Between micro-grooves in either in microcellular structure, the inside of shear thickening fluid has nano particle, is being hit or is compressing
When, shear thickening fluid reforms into hard solid, absorbs and consumes impact energy, makes fabric stronger and be difficult to be pierced, have
Effect improves barrier propterty, on the other hand, is filled into nano particle increase of the micro-grooves of fiber either in microcellular structure
Frictional force between fiber, further stop and eliminate external impacts, so as to play a part of improving protection effect.
When not by external impacts, shear thickening fluid keeps not changing state, under the state, in basic unit
Fiber between micro-grooves in either microcellular structure not by solid-state shear thickening fluid fill, keep original work(
Can, produce capillarity and carry out moisture absorbing and sweat releasing.
Using high-performance synthetic fibers and new function fiber blend, the relative high-performance that reduces synthesizes under equal unit
The use of fiber, and then cost is reduced, meanwhile, resin matrix is compounded with basic unit, is entered to reducing high-performance synthetic fibers
One supplement of row, reaches corresponding anti-stab requirement.
Further, the nano particle in shear thickening fluid is preferably SiO2, it is modified, modified SiO2
For mass fraction at 40%~45%, anti-stab ability can improve 1.66 times.
A kind of preparation method of the anti-stab protective fabric containing ice-cold material of the present invention is realized, is comprised the following steps：(1) mix
Spin：Spun yarn is made using preferable superhigh molecular weight polyethylene fibers and the preferable advance blending of Coolking fibers, wherein, institute
The superhigh molecular weight polyethylene fibers fineness stated is 1-150tex, and described Coolking fibre finenesses are 1-85tex；
(2) weave：By the spun yarn plain weave after blending into weaving cotton cloth, and it is with close well word weaving that this, which is weaved cotton cloth,
Mode weaves, yarn linear density 420-1400D；Mechanical strength is not less than 30cN/dtex；Woven fabric specification is through close and filling density
For 65-150 roots/10cm；Fabric surface density is 60-200g/m2；Fabric thickness is 0.1-0.35mm；
(3) impregnate：Shear thickening fluid is prepared using ball-milling method, modified nanoparticles are dispersed to shear thickening stream
In body, then scattered mixed liquor impregnated into plain cloth；
(4) dry：The plain cloth impregnated is dried, encapsulated.
Further set：Described basic unit is compound using hot pressing with resin matrix, comprises the following steps, (1) pretreatment：Will
Plain cloth is dried, time 1h, 105 DEG C of temperature, resin matrix is dried, time 2h, temperature 60 C；
(2) lamination：Resin matrix and plain cloth are superimposed together in a certain order, different superposition order will obtain
The resin compounded layer of different structure, it is spaced apart with polytetrafluoroethylene (PTFE) release cloth between each composite bed；
(3) press：The resin matrix being superimposed and plain cloth are preheated, then pressed using press, heating one
Fix time, form composite bed；
Further set：The resin matrix and plain cloth have three kinds of complex methods：ABA, BAB, AB, wherein, A is
Resin matrix, B are plain cloth.
By using above-mentioned technical proposal, the present invention compares compared with the prior art to be had：The anti-stab protective fabric not only has
There is enough intensity, while have excellent pliability and gas permeability concurrently, in the state of usual use, close to common fabric
Comfort level, with enough intensity when by external impacts, meet police or other staff using anti-stabbing lining
Routine office work activity need.
Brief description of the drawings
Fig. 1 is a kind of pilotaxitic texture schematic diagram of the anti-stab protective fabric containing ice-cold material of the present invention；
Fig. 2 is a kind of yarn schematic diagram of the anti-stab protective fabric containing ice-cold material；
Fig. 3 is a kind of hierarchical structure schematic diagram of the anti-stab protective fabric containing ice-cold material.
In figure：1st, one layer of basic unit；2nd, yarn；21st, superhigh molecular weight polyethylene fibers；22nd, Coolking fibers；A, resin
Matrix；B, plain cloth.
Embodiment
A kind of anti-stab protective fabric embodiment containing ice-cold material of the present invention is described further referring to figs. 1 to Fig. 3.
In the present invention, high-performance synthetic fibers are preferably superhigh molecular weight polyethylene fibers, and new function fiber is preferably
Coolplus fibers, compound resin matrix, preferably high-density polyethylene material between multilayer basic unit, by high density polyethylene (HDPE) system
Into thin film.
In the present invention, the nano particle in shear thickening fluid is preferably SiO2, the present invention in SiO2Preparation method it is specific
It is as follows：Tetraethyl orthosilicate, ethanol, deionized water are configured to solution by volume at 1: 2: 2, solution is warming up to 70 DEG C of stirrings
1.5h, then add appropriate catalyst in the solution, continue to stir that milk white gel is formed after 1h, pH controls are 5~6, reaction
After the completion of, it is aged, dries, grind to obtain gel powder, through Muffle furnace after 600 DEG C of 1~2h of high-temperature roasting, obtain SiO2Powder.
Further, the SiO to obtaining2Powder is modified, and modified method is specific as follows：By volume fraction 95%
Absolute ethyl alcohol and the mixing of 5% deionized water, add the KH570 surfactants of volume fraction 6%, and reaction 40-50min promotes
Hydrolysis and formation hydroxyl, add the single dispersing SiO prepared2Nano particle, continue to react 60- at 78 DEG C after stirring
80min, treat that particle sinks to bottom and pours out liquid portion, rinsed 3 times with absolute ethyl alcohol.By modified SiO2Nano particle point
It is scattered in the PEG, absolute ethyl alcohol mixed liquor that volume ratio is 1: 5, is washed 3 times with absolute ethyl alcohol after reacting 4-5h, 80 DEG C of dryings
12h.Modified SiO2Mass fraction is controlled between 40%~45%, and particle diameter is between 160-380nm.
Embodiment one
Container equipped with PEG200 is fixed on miniature whirlpool mixed instrument, quality is gradually added into during Vibratory Mixing
Fraction 40%, average particle size 160nm, by the SiO of surface graft modification2Nano particle, Vibratory Mixing 2-3h, makes
SiO2It is dispersed in decentralized medium PEG200 and forms shear thickening fluid.
Spun yarn is made using superhigh molecular weight polyethylene fibers and the advance blending of Coolking fibers, then carries out plain weave volume
Knit, the fabric of braiding is netted pilotaxitic texture, the fabric 16 layers of stacking jointly, forms basic unit, the fabric machinery as basic unit
Intensity is not less than 30cN/dtex, and it through close and filling density is 65-150 roots/10cm that specification of weaving cotton cloth, which is,；The surface density of basic unit is 197g/m2
Surface density contains microcellular structure, has 0.01-0.3mm aperture, porosity about 15%, fabric thickness 0.1-0.35mm.
Resin matrix film and plain weave cloth are separately dried, plain cloth：Time 1h, 105 DEG C of temperature, resin base
Body：Time 2h, temperature 60 C.Then resin matrix film and plain weave cloth are superimposed together in a certain order, Ke Yishi
The lamination in the way of ABA, BAB, AB, in this programme, preferably BAB mode is finally compound using press hot pressing.Wherein, A
For resin matrix, B is plain cloth.
It is to be understood that it is the overlay order for referring to monolithic for orderly superposition to be superimposed together in a certain order
The overlay order that can not be destroyed before compacting, otherwise its anti-stab ability will decline.To be peeled off in order in order after why emphasizing compacting
Superposition is just to can guarantee that the carry out face contact of most " abundant " is capable of in the face of base material with face because doing so, and has avoided " cavity " from going out
It is existing.
Plain weave cloth is cut into 42mm × 38mm sample, using absolute ethyl alcohol to the fluid prepared by 1: 1 (matter
Amount ratio) it is diluted, the plain weave cloth after drying process is immersed and is immersed in diluted system, after standing a period of time
Take out, remove the solution of excess surface, place into 70 DEG C of air dry ovens and dry 20min to remove alcohol solvent.
Comparative example one, the preparation method of embodiment one is taken, but the step that blending enters Coolking fibers is subtracted in example one
Suddenly, other conditions are constant, and the stab-resistant material of identical surface density, the number of plies is made.
Comparative example two, the preparation method of embodiment one is taken, but the step of adding resin matrix film is subtracted in example one,
Other conditions are constant.
Comparative example three, the preparation method of embodiment one is taken, but when example one prepares basic unit, fabric is laminated jointly
24 layers.
By the cloth prepared by embodiment one, comparative example one, comparative example two, comparative example three, carry out gas permeability detection and prevent
The detection of thorn property.
Carry out gas permeability detection：Using the detection device in the Chinese patent of Application No. 201120091799.1 and side
Method, cloth is placed on the upper orifice of down tube, then puts connection sleeve pipe, observe the air penetration in down tube into upper tube
Amount, forms obvious bubble in the water of upper tube, immediately arrives at the gas permeability of cloth.
Anti prick function detection part：Sample is fixed on fixed mount, uses quality of dropping hammer to be dropped hammer for 2.40kg by electromagnet
On height-adjustable crossbeam, the distance dropped hammer by regulation between sample adjusts impact energy, falls when puncturing experiment for control
Hammer does the movement of falling object.The every kind of test of each sample is carried out 3 times, between each test point and between test point and sample edge away from
From not less than 5cm, the pierced number of plies of sample is observed after test.
Table 1 (embodiment one is compared with the properties of product of comparative example one to three)
| Sequence number | The number of plies | Pierce through the number of plies | Gas permeability | Comfortableness |
| Embodiment one | 16 | 12 | Preferably | It is soft |
| Comparative example one | 16 | 12 | Difference | It is soft |
| Comparative example two | 16 | 16 | It is good | It is soft |
| Comparative example three | 24 | 13 | Preferably | It is harder |
16 layers of compound fabric of the gained of embodiment one are placed in by the anti-stab standard NIJ0115.0 of U.S. NIJ and national standard
GA68-2008 testing standards, as a result meet standard requirement, also find out that the preparation method of embodiment one obtains one from above-mentioned table 1
Individual more suitable product, as presently preferred embodiments of the present invention.
Embodiment two
Container equipped with PEG200 is fixed on miniature whirlpool mixed instrument, quality is gradually added into during Vibratory Mixing
Fraction 40%, average particle size about 370nm, by the SiO of surface graft modification2Nano particle, Vibratory Mixing 2-3h, makes
SiO2It is dispersed in decentralized medium PEG200 and forms shear thickening fluid.
Spun yarn is made using superhigh molecular weight polyethylene fibers and the advance blending of Coolking fibers, then carries out plain weave volume
Knit, the fabric of braiding is netted pilotaxitic texture, the fabric 16 layers of stacking jointly, forms basic unit, the fabric machinery as basic unit
Intensity is not less than 30cN/dtex, and it through close and filling density is 65-150 roots/10cm that woven fabric specification, which is,；The surface density of basic unit is 197g/
m2Surface density contains microcellular structure, has 0.01-0.3mm aperture, porosity about 15%, fabric thickness 0.1-0.35mm.
Resin matrix film and plain weave cloth are separately dried, plain cloth：Time 1h, 105 DEG C of temperature, resin base
Body：Time 2h, temperature 60 C.Then resin matrix film and plain weave cloth are superimposed together in a certain order, Ke Yishi
The lamination in the way of ABA, BAB, AB, in this programme, preferably BAB mode is finally compound using press hot pressing.Wherein, A
For resin matrix, B is plain cloth.
Plain weave cloth is cut into 42mm × 38mm sample, using absolute ethyl alcohol to the fluid prepared by 1: 1 (matter
Amount ratio) it is diluted, the plain weave cloth after drying process is immersed and is immersed in diluted system, after standing a period of time
Take out, remove the solution of excess surface, place into 70 DEG C of air dry ovens and dry 20min to remove alcohol solvent.
Embodiment three
Container equipped with PEG200 is fixed on miniature whirlpool mixed instrument, quality is gradually added into during Vibratory Mixing
Fraction 40%, average particle size about 600nm, by the SiO of surface graft modification2Nano particle, Vibratory Mixing 2-3h, makes
SiO2It is dispersed in decentralized medium PEG200 and forms shear thickening fluid.
Spun yarn is made using superhigh molecular weight polyethylene fibers and the advance blending of Coolking fibers, then carries out plain weave volume
Knit, the fabric of braiding is netted pilotaxitic texture, the fabric 16 layers of stacking jointly, forms basic unit, the fabric machinery as basic unit
Intensity is not less than 30cN/dtex, and it through close and filling density is 65-150 roots/10cm that woven fabric specification, which is,；The surface density of basic unit is 197g/
m2Surface density contains microcellular structure, has 0.01-0.3mm aperture, porosity about 15%, fabric thickness 0.1-0.35mm.
Resin matrix film and plain weave cloth are separately dried, plain cloth：Time 1h, 105 DEG C of temperature, resin base
Body：Time 2h, temperature 60 C.Then resin matrix film and plain weave cloth are superimposed together in a certain order, Ke Yishi
The lamination in the way of ABA, BAB, AB, in this programme, preferably BAB mode is finally compound using press hot pressing.Wherein, A
For resin matrix, B is plain cloth.
Plain weave cloth is cut into 42mm × 38mm sample, using absolute ethyl alcohol to the fluid prepared by 1: 1 (matter
Amount ratio) it is diluted, the plain weave cloth after drying process is immersed and is immersed in diluted system, after standing a period of time
Take out, remove the solution of excess surface, place into 70 DEG C of air dry ovens and dry 20min to remove alcohol solvent.
Table 2 (embodiment one is compared with embodiment two, the properties of product of embodiment three)
| Sequence number | The particle diameters of SiO 2 | The number of plies | Pierce through the number of plies | Gas permeability |
| Embodiment one | 160 | 16 | 12 | Preferably |
| Embodiment two | 370 | 16 | 11 | Typically |
| Embodiment three | 600 | 16 | 10 | It is poor |
16 layers of compound fabric of embodiment one, embodiment two, the gained of embodiment three are placed in by the anti-stab standards of U.S. NIJ
NIJ0115.0 and national standard GA68-2008 testing standards, as a result meet standard requirement, also find out from above-mentioned table 2, with
The increase of particle diameter, the pierced number of plies of sample have been reduced, and when wherein particle diameter is 160nm, it is 12 layers that sample, which pierces through the number of plies,；Work as grain
When footpath is 370nm, it is 11 layers that sample, which pierces through the number of plies,；As particle diameter 600nm, pierce through the number of plies and reduce to 10 layers, but in reduction
Degree is not that the embodiment of the present invention one is preferred embodiment it is obvious that therefore, can from which further follow that.
Described above is only presently preferred embodiments of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, also do not limit the scope that the present invention is implemented.It should be pointed out that for those skilled in the art, not
Depart from some improvements and modifications under the premise of the principle of the invention, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (5)
1. a kind of anti-stab protective fabric containing ice-cold material, the protective materials is with the plain cloth of superhigh molecular weight polyethylene fibers
For basic unit, and basic unit's multilayer is set；
Shear thickening fluid is uniformly attached with the basic unit, by using static dipping method by shear thickening fluid and basic unit
It is compound, it is characterised in that：There are modified nanoparticles in the shear thickening fluid, modified nanoparticles are obtained using following technique
Arrive：The absolute ethyl alcohol of volume fraction 95% and 5% deionized water are mixed, add the KH570 surfaces of volume fraction 6%
Activating agent, reaction 40-50min promote hydrolysis and form hydroxyl, add the single dispersing SiO prepared 2 Nano particle, stirring
Continue to react 60-80min at 78 DEG C after uniformly, treat that particle sinks to bottom and pours out liquid portion, 3 are rinsed with absolute ethyl alcohol
It is secondary；By modified SiO 2 Nano particle is distributed to volume ratio as 1:In 5 PEG, absolute ethyl alcohol mixed liquor, 4- is reacted
Washed 3 times with absolute ethyl alcohol after 5h, 80 DEG C of dry 12h；Modified SiO 2 Mass fraction is controlled between 40% ~ 45%,
Particle diameter is 160-380nm；
Blending has the Coolking fibers of energy moisture absorbing and sweat releasing in fiber in the basic unit；
The described anti-stab protective fabric containing ice-cold material is prepared by following steps：（1）Blending：Using superhigh molecular weight polyethylene
Spun yarn is made with the advance blending of Coolking fibers in alkene fiber, wherein, described superhigh molecular weight polyethylene fibers fineness is 1-
150tex, described Coolking fibre finenesses are 1-85tex；
（2）Braiding：By the spun yarn plain weave after blending into weaving cotton cloth, and it is in a manner of close well word weaving that this, which is weaved cotton cloth,
Braiding, yarn linear density 420-1400D；Mechanical strength is not less than 30cN/dtex；Woven fabric specification is through close and filling density
For 65-150 roots/10cm；Fabric surface density is 60-200g/ ㎡；Fabric thickness is 0.1-0.35mm；
（3）Dipping：Shear thickening fluid is prepared using ball-milling method, by modified mass fraction between 40%-45%, SiO 2
The particle diameter of grain is 160-380nm SiO 2Even particulate dispersion impregnates into shear thickening fluid, then by scattered mixed liquor
Plain cloth；
Wherein, scattered technique is as follows：Mass fraction 40% is gradually added into during Vibratory Mixing, average particle size is
160nm, by the SiO of surface graft modification 2 Nano particle, Vibratory Mixing 2-3h, makes SiO 2It is dispersed in scattered Jie
Shear thickening fluid is formed in matter PEG200；
（4）Dry：The plain cloth impregnated is dried, encapsulated.
A kind of 2. anti-stab protective fabric containing ice-cold material according to claim 1, it is characterised in that：The basic unit is by net
Shape pilotaxitic texture is made, and basic unit is that 20-500g/ ㎡ surface densities contain microcellular structure, the aperture with 0.01-0.3mm, porosity
Not less than 10%.
A kind of 3. anti-stab protective fabric containing ice-cold material according to claim 1, it is characterised in that：The multilayer basic unit
Between be compounded with resin matrix, the resin matrix is selected from high density polyethylene (HDPE).
A kind of 4. anti-stab protective fabric containing ice-cold material according to claim 3, it is characterised in that：Described basic unit with
Resin matrix is compound using hot pressing, comprises the following steps,（1）Pretreatment：Plain cloth is dried, time 1h, temperature 105
DEG C, resin matrix is dried, time 2h, temperature 60 C；
（2）Lamination：Resin matrix and plain cloth are superimposed together in a certain order, different superposition order will obtain difference
The resin compounded layer of structure, it is spaced apart with polytetrafluoroethylene (PTFE) release cloth between each composite bed；
（3）Pressing：The resin matrix being superimposed and plain cloth are preheated, then pressed using press, the timing of heating one
Between, form composite bed.
A kind of 5. anti-stab protective fabric containing ice-cold material according to claim 3, it is characterised in that：The resin matrix
There are three kinds of complex methods with plain cloth：ABA, BAB, AB, wherein, A is resin matrix, and B is plain cloth.
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| CN114250629B (en) * | 2021-12-02 | 2023-07-25 | 西安工程大学 | Preparation method of intelligent stab-resistant fabric, product and application thereof |
| CN115583086A (en) * | 2022-09-29 | 2023-01-10 | 中山莱圃新材料有限公司 | Light puncture-resistant clamp mesh cloth |
| CN116254706B (en) * | 2023-03-03 | 2023-10-03 | 无锡威豪体育器材有限公司 | Puncture-resistant fabric for fencing clothes and preparation method thereof |
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