CN1578795A - 具有良好耐化学性和透明度的丙烯腈-丁二烯-苯乙烯共聚物透明树脂及其制备方法 - Google Patents
具有良好耐化学性和透明度的丙烯腈-丁二烯-苯乙烯共聚物透明树脂及其制备方法 Download PDFInfo
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- CN1578795A CN1578795A CNA028215052A CN02821505A CN1578795A CN 1578795 A CN1578795 A CN 1578795A CN A028215052 A CNA028215052 A CN A028215052A CN 02821505 A CN02821505 A CN 02821505A CN 1578795 A CN1578795 A CN 1578795A
- Authority
- CN
- China
- Prior art keywords
- acrylonitrile
- butadiene
- transparent resin
- styrene copolymer
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000011347 resin Substances 0.000 title claims abstract description 56
- 229920005989 resin Polymers 0.000 title claims abstract description 56
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title claims abstract description 46
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 42
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000000126 substance Substances 0.000 title abstract description 35
- -1 acrylate alkylester compound Chemical class 0.000 claims abstract description 63
- 229920000126 latex Polymers 0.000 claims abstract description 29
- 239000004816 latex Substances 0.000 claims abstract description 29
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 14
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 150000008360 acrylonitriles Chemical class 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- GTBGXKPAKVYEKJ-UHFFFAOYSA-N decyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C(C)=C GTBGXKPAKVYEKJ-UHFFFAOYSA-N 0.000 claims description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 2
- 229920003244 diene elastomer Polymers 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 230000035939 shock Effects 0.000 description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 235000010469 Glycine max Nutrition 0.000 description 3
- 244000068988 Glycine max Species 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- AWFYPPSBLUWMFQ-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(1,4,6,7-tetrahydropyrazolo[4,3-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=C2 AWFYPPSBLUWMFQ-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例 | 对比实施例 | ||||||
1 | 2 | 1 | 2 | 3 | 4 | 5 | |
聚丁二烯 | 25 | 20 | 25 | 25 | 25 | 25 | 10 |
甲基丙烯酸甲酯 | 49.74 | 54.16 | 48.34 | 54.06 | 37.5 | 28.5 | 61.56 |
苯乙烯 | 17.26 | 18.84 | 18.76 | 18.94 | 12.5 | 21.5 | 21.44 |
丙烯腈 | 8 | 7 | 8 | 2 | 25 | 8 | 7 |
叔-十二烷基硫醇 | 0.5 | 0.5 | 0.8 | 0.5 | 0.5 | 0.5 | 0.5 |
雾度值 | 1.9 | 1.8 | 2 | 1.8 | - | 25 | 2.1 |
重量平均分子量 | 140,000 | 130,000 | 40,000 | 140,000 | - | 140,000 | 80,000 |
其他 | - | - | - | - | 稳定性降低 | 透明度降低 | - |
实施例 | 对比实施例 | |||||||||
3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | |||
ABS透明树脂 | 实施例 | 1 | 100 | 95 | - | - | - | - | - | - |
2 | - | - | 90 | 90 | - | - | - | - | ||
对比实施例 | 1 | - | - | - | - | 100 | - | - | - | |
2 | - | - | - | - | - | 90 | - | - | ||
4 | - | - | - | - | - | - | 100 | - | ||
5 | - | - | - | - | - | - | - | 95 | ||
聚酰胺 | P-6321 | - | 5 | 10 | - | - | 10 | - | 5 | |
P-7530 | - | - | - | 10 | - | - | - | - | ||
雾度值 | 2.1 | 3.4 | 4.5 | 15 | 2 | 4.8 | 25 | 5.1 | ||
耐化学性 | 豆油 | OK | OK | OK | OK | B(4小时) | OK | OK | C | |
10%硫酸 | OK | OK | OK | OK | C | C | OK | C | ||
70%醋酸 | C | OK | C | C | B(30分钟) | B(4小时) | C | B(4小时) | ||
IPA | B(2小时) | C | B(4小时) | B(3小时) | B(1分钟) | B(20分钟) | B(3小时) | B(10分钟) | ||
P-6321:pellestat-6321,SANYO,R.I.=1.51P-7530:pellestat-7530,SANYO,R.I.=1.53 |
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR66856/2001 | 2001-10-29 | ||
KR10-2001-0066856A KR100442922B1 (ko) | 2001-10-29 | 2001-10-29 | 내화학성 및 투명성이 우수한아크릴로니트릴-부타디엔-스티렌계 공중합 투명수지 및그의 제조방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1578795A true CN1578795A (zh) | 2005-02-09 |
CN1297580C CN1297580C (zh) | 2007-01-31 |
Family
ID=19715483
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB028215052A Expired - Lifetime CN1297580C (zh) | 2001-10-29 | 2002-10-24 | 具有良好耐化学性和透明度的丙烯腈-丁二烯-苯乙烯共聚物透明树脂及其制备方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7217763B2 (zh) |
EP (1) | EP1448640B1 (zh) |
KR (1) | KR100442922B1 (zh) |
CN (1) | CN1297580C (zh) |
DE (1) | DE60228311D1 (zh) |
WO (1) | WO2003037977A2 (zh) |
Cited By (5)
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CN101148533B (zh) * | 2006-09-21 | 2011-04-13 | Lg化学株式会社 | 具有优异的物理属性的光散射性树脂聚合物组合物 |
CN103396617A (zh) * | 2008-08-19 | 2013-11-20 | Lg化学株式会社 | 具有优异的可脱模性和可着色性的热塑性丙烯腈-丁二烯-苯乙烯树脂组合物 |
CN105658725A (zh) * | 2014-10-02 | 2016-06-08 | Lg化学株式会社 | 具有优异耐化学性和透明性的热塑性树脂组合物、制备该组合物的方法以及包含该组合物的模制品 |
CN112457445A (zh) * | 2019-09-09 | 2021-03-09 | 青岛海尔电冰箱有限公司 | Abs板材的制备方法、内胆、门衬以及制冷设备 |
CN112876609A (zh) * | 2021-01-18 | 2021-06-01 | 万华化学(四川)有限公司 | 一种聚丁二烯胶乳的制备方法、聚丁二烯胶乳及abs |
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US7638559B2 (en) * | 2005-05-10 | 2009-12-29 | Nova Chemicals Inc. | Expandable resins |
WO2007023865A1 (ja) | 2005-08-25 | 2007-03-01 | Techno Polymer Co., Ltd. | ゴム強化樹脂、制電性樹脂組成物、成形体及び積層体 |
KR100779159B1 (ko) * | 2005-08-30 | 2007-11-28 | 주식회사 엘지화학 | 열가소성 수지 조성물 및 그 제조방법 |
KR100645260B1 (ko) | 2005-11-25 | 2006-11-14 | 제일모직주식회사 | 내화학성 및 전사성과 진공성형성이 우수한 냉장고용열가소성 수지 조성물 |
US7843560B2 (en) * | 2007-08-31 | 2010-11-30 | Dow Global Technologies Inc. | Stable turbidity calibration standards |
KR101443954B1 (ko) * | 2011-11-18 | 2014-09-23 | 주식회사 엘지화학 | 열가소성 투명수지 및 이의 제조방법 |
KR101769178B1 (ko) * | 2013-10-18 | 2017-08-30 | 주식회사 엘지화학 | 난연성 수지 조성물 |
CN103980428B (zh) * | 2014-04-30 | 2016-06-15 | 中国科学院化学研究所 | 一种用于3d打印的丙烯腈-丁二烯-苯乙烯(abs)粉料及其制备方法 |
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DE19527579A1 (de) | 1995-07-28 | 1997-01-30 | Basf Ag | Transparente spannungsrißbeständige Formmassen mit einem verbesserten Zähigkeits-Steifigkeits-Verhältnis |
KR100226671B1 (ko) | 1996-12-10 | 1999-10-15 | 정몽규 | 자동차의 프론트필러 밀림방지구조 |
JP3879204B2 (ja) | 1997-11-17 | 2007-02-07 | 石川島播磨重工業株式会社 | 排煙脱硫装置の吸収塔循環ポンプ起動・停止時における吸収剤スラリー流量制御方法及び装置 |
KR100387447B1 (ko) * | 1998-10-29 | 2003-09-29 | 주식회사 엘지화학 | 대전방지성이우수한투명수지조성물및그의제조방법 |
US6354965B1 (en) * | 2000-02-02 | 2002-03-12 | Acushnet Company | Golf balls including low water activity fluid and methods for making same |
KR20030009856A (ko) * | 2001-07-24 | 2003-02-05 | 주식회사 엘지화학 | 내충격성이 우수한 아크릴로니트릴-부타디엔-스티렌열가소성 수지의 제조방법 |
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2001
- 2001-10-29 KR KR10-2001-0066856A patent/KR100442922B1/ko active IP Right Grant
-
2002
- 2002-10-24 EP EP02781976A patent/EP1448640B1/en not_active Expired - Lifetime
- 2002-10-24 US US10/494,228 patent/US7217763B2/en not_active Expired - Lifetime
- 2002-10-24 WO PCT/KR2002/001985 patent/WO2003037977A2/en active Application Filing
- 2002-10-24 DE DE60228311T patent/DE60228311D1/de not_active Expired - Lifetime
- 2002-10-24 CN CNB028215052A patent/CN1297580C/zh not_active Expired - Lifetime
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CN101148533B (zh) * | 2006-09-21 | 2011-04-13 | Lg化学株式会社 | 具有优异的物理属性的光散射性树脂聚合物组合物 |
CN103396617A (zh) * | 2008-08-19 | 2013-11-20 | Lg化学株式会社 | 具有优异的可脱模性和可着色性的热塑性丙烯腈-丁二烯-苯乙烯树脂组合物 |
CN101665606B (zh) * | 2008-08-19 | 2014-07-16 | Lg化学株式会社 | 具有优异的可脱模性和可着色性的热塑性丙烯腈-丁二烯-苯乙烯树脂组合物 |
CN103396617B (zh) * | 2008-08-19 | 2015-07-22 | Lg化学株式会社 | 具有优异的可脱模性和可着色性的热塑性丙烯腈-丁二烯-苯乙烯树脂组合物 |
CN105658725A (zh) * | 2014-10-02 | 2016-06-08 | Lg化学株式会社 | 具有优异耐化学性和透明性的热塑性树脂组合物、制备该组合物的方法以及包含该组合物的模制品 |
US9840618B2 (en) | 2014-10-02 | 2017-12-12 | Lg Chem, Ltd. | Thermoplastic resin composition having superior chemical resistance and transparency, method of preparing the same and molded article including the same |
CN105658725B (zh) * | 2014-10-02 | 2018-01-19 | Lg化学株式会社 | 具有优异耐化学性和透明性的热塑性树脂组合物、制备该组合物的方法以及包含该组合物的模制品 |
CN112457445A (zh) * | 2019-09-09 | 2021-03-09 | 青岛海尔电冰箱有限公司 | Abs板材的制备方法、内胆、门衬以及制冷设备 |
CN112876609A (zh) * | 2021-01-18 | 2021-06-01 | 万华化学(四川)有限公司 | 一种聚丁二烯胶乳的制备方法、聚丁二烯胶乳及abs |
CN112876609B (zh) * | 2021-01-18 | 2023-04-07 | 万华化学(四川)有限公司 | 一种聚丁二烯胶乳的制备方法、聚丁二烯胶乳及abs |
Also Published As
Publication number | Publication date |
---|---|
US7217763B2 (en) | 2007-05-15 |
EP1448640A2 (en) | 2004-08-25 |
WO2003037977A3 (en) | 2003-12-18 |
WO2003037977A2 (en) | 2003-05-08 |
CN1297580C (zh) | 2007-01-31 |
EP1448640B1 (en) | 2008-08-13 |
KR20030034998A (ko) | 2003-05-09 |
KR100442922B1 (ko) | 2004-08-02 |
US20050032984A1 (en) | 2005-02-10 |
DE60228311D1 (de) | 2008-09-25 |
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