CN1482857A - 农药增效剂 - Google Patents
农药增效剂 Download PDFInfo
- Publication number
- CN1482857A CN1482857A CNA018210856A CN01821085A CN1482857A CN 1482857 A CN1482857 A CN 1482857A CN A018210856 A CNA018210856 A CN A018210856A CN 01821085 A CN01821085 A CN 01821085A CN 1482857 A CN1482857 A CN 1482857A
- Authority
- CN
- China
- Prior art keywords
- pesticide
- alkyl
- formula
- acid
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004009 herbicide Substances 0.000 title description 44
- 230000002363 herbicidal effect Effects 0.000 title description 26
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 239000003905 agrochemical Substances 0.000 claims abstract description 25
- 239000000575 pesticide Substances 0.000 claims description 82
- 150000001875 compounds Chemical class 0.000 claims description 57
- 239000012747 synergistic agent Substances 0.000 claims description 46
- 239000004094 surface-active agent Substances 0.000 claims description 31
- 239000002738 chelating agent Substances 0.000 claims description 22
- 239000003814 drug Substances 0.000 claims description 14
- 239000004480 active ingredient Substances 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 125000003368 amide group Chemical group 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- -1 alcohol compound Chemical class 0.000 abstract description 69
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 36
- 230000012010 growth Effects 0.000 abstract description 5
- 230000002708 enhancing effect Effects 0.000 abstract description 2
- 239000003623 enhancer Substances 0.000 abstract 2
- 231100000674 Phytotoxicity Toxicity 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 20
- 239000000194 fatty acid Substances 0.000 description 20
- 229930195729 fatty acid Natural products 0.000 description 20
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 19
- 241000196324 Embryophyta Species 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 14
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 125000003342 alkenyl group Chemical group 0.000 description 11
- 239000003899 bactericide agent Substances 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 125000001118 alkylidene group Chemical group 0.000 description 10
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 150000001721 carbon Chemical group 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000417 fungicide Substances 0.000 description 7
- 239000002917 insecticide Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 230000000361 pesticidal effect Effects 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- GINJFDRNADDBIN-FXQIFTODSA-N bilanafos Chemical compound OC(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O GINJFDRNADDBIN-FXQIFTODSA-N 0.000 description 6
- 239000004359 castor oil Substances 0.000 description 6
- 229960001777 castor oil Drugs 0.000 description 6
- 235000019438 castor oil Nutrition 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N n-hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- 150000005846 sugar alcohols Chemical class 0.000 description 6
- 239000004563 wettable powder Substances 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000000855 fungicidal effect Effects 0.000 description 5
- 239000005648 plant growth regulator Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 4
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 235000021314 Palmitic acid Nutrition 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 230000000895 acaricidal effect Effects 0.000 description 4
- 125000005466 alkylenyl group Chemical group 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- 235000015165 citric acid Nutrition 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- RHEVFAMQJMWLFS-UHFFFAOYSA-N icosan-2-ol Chemical compound CCCCCCCCCCCCCCCCCCC(C)O RHEVFAMQJMWLFS-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 4
- 150000002825 nitriles Chemical class 0.000 description 4
- OXGBCSQEKCRCHN-UHFFFAOYSA-N octadecan-2-ol Chemical compound CCCCCCCCCCCCCCCCC(C)O OXGBCSQEKCRCHN-UHFFFAOYSA-N 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- TYWMIZZBOVGFOV-UHFFFAOYSA-N tetracosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCO TYWMIZZBOVGFOV-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 239000005885 Buprofezin Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000000642 acaricide Substances 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 150000003851 azoles Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 3
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000001630 malic acid Substances 0.000 description 3
- 235000011090 malic acid Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 229940055577 oleyl alcohol Drugs 0.000 description 3
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 3
- XAMUDJHXFNRLCY-UHFFFAOYSA-N phenthoate Chemical compound CCOC(=O)C(SP(=S)(OC)OC)C1=CC=CC=C1 XAMUDJHXFNRLCY-UHFFFAOYSA-N 0.000 description 3
- 229920001515 polyalkylene glycol Polymers 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- SEEPANYCNGTZFQ-UHFFFAOYSA-N sulfadiazine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)NC1=NC=CC=N1 SEEPANYCNGTZFQ-UHFFFAOYSA-N 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000009333 weeding Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 2
- 229940094997 1-tetracosanol Drugs 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- KWMLJOLKUYYJFJ-UHFFFAOYSA-N 2,3,4,5,6,7-Hexahydroxyheptanoic acid Chemical compound OCC(O)C(O)C(O)C(O)C(O)C(O)=O KWMLJOLKUYYJFJ-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 241000123650 Botrytis cinerea Species 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 235000007516 Chrysanthemum Nutrition 0.000 description 2
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- FCKYPQBAHLOOJQ-UHFFFAOYSA-N Cyclohexane-1,2-diaminetetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)C1CCCCC1N(CC(O)=O)CC(O)=O FCKYPQBAHLOOJQ-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 229930191978 Gibberellin Natural products 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- UWIULCYKVGIOPW-UHFFFAOYSA-N Glycolone Natural products CCOC1=C(CC=CC)C(=O)N(C)c2c(O)cccc12 UWIULCYKVGIOPW-UHFFFAOYSA-N 0.000 description 2
- 239000005562 Glyphosate Substances 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 150000001720 carbohydrates Chemical group 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- JGUQDUKBUKFFRO-CIIODKQPSA-N dimethylglyoxime Chemical compound O/N=C(/C)\C(\C)=N\O JGUQDUKBUKFFRO-CIIODKQPSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000009313 farming Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 235000011087 fumaric acid Nutrition 0.000 description 2
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 2
- 239000003448 gibberellin Substances 0.000 description 2
- 239000000174 gluconic acid Substances 0.000 description 2
- 235000012208 gluconic acid Nutrition 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 229940097068 glyphosate Drugs 0.000 description 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- FVDRFBGMOWJEOR-UHFFFAOYSA-N hexadecan-2-ol Chemical compound CCCCCCCCCCCCCCC(C)O FVDRFBGMOWJEOR-UHFFFAOYSA-N 0.000 description 2
- BILPUZXRUDPOOF-UHFFFAOYSA-N hexadecanoic acid octadecyl ester Natural products CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC BILPUZXRUDPOOF-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 2
- LZGUHMNOBNWABZ-UHFFFAOYSA-N n-nitro-n-phenylnitramide Chemical compound [O-][N+](=O)N([N+]([O-])=O)C1=CC=CC=C1 LZGUHMNOBNWABZ-UHFFFAOYSA-N 0.000 description 2
- XGFDHKJUZCCPKQ-UHFFFAOYSA-N nonadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCO XGFDHKJUZCCPKQ-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- ALVGHPMGQNBJRC-UHFFFAOYSA-N pentadecan-2-ol Chemical compound CCCCCCCCCCCCCC(C)O ALVGHPMGQNBJRC-UHFFFAOYSA-N 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229940083466 soybean lecithin Drugs 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- FPLNRAYTBIFSFW-UHFFFAOYSA-N tricosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCO FPLNRAYTBIFSFW-UHFFFAOYSA-N 0.000 description 2
- HKOLRKVMHVYNGG-UHFFFAOYSA-N tridecan-2-ol Natural products CCCCCCCCCCCC(C)O HKOLRKVMHVYNGG-UHFFFAOYSA-N 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical compound OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 description 1
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 1
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- LDDMACCNBZAMSG-BDVNFPICSA-N (2r,3r,4s,5r)-3,4,5,6-tetrahydroxy-2-(methylamino)hexanal Chemical compound CN[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO LDDMACCNBZAMSG-BDVNFPICSA-N 0.000 description 1
- CXNPLSGKWMLZPZ-GIFSMMMISA-N (2r,3r,6s)-3-[[(3s)-3-amino-5-[carbamimidoyl(methyl)amino]pentanoyl]amino]-6-(4-amino-2-oxopyrimidin-1-yl)-3,6-dihydro-2h-pyran-2-carboxylic acid Chemical compound O1[C@@H](C(O)=O)[C@H](NC(=O)C[C@@H](N)CCN(C)C(N)=N)C=C[C@H]1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-GIFSMMMISA-N 0.000 description 1
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
- SODPIMGUZLOIPE-UHFFFAOYSA-N (4-chlorophenoxy)acetic acid Chemical compound OC(=O)COC1=CC=C(Cl)C=C1 SODPIMGUZLOIPE-UHFFFAOYSA-N 0.000 description 1
- XUNYDVLIZWUPAW-UHFFFAOYSA-N (4-chlorophenyl) n-(4-methylphenyl)sulfonylcarbamate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)OC1=CC=C(Cl)C=C1 XUNYDVLIZWUPAW-UHFFFAOYSA-N 0.000 description 1
- IKYKEVDKGZYRMQ-PDBXOOCHSA-N (9Z,12Z,15Z)-octadecatrien-1-ol Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCCO IKYKEVDKGZYRMQ-PDBXOOCHSA-N 0.000 description 1
- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 description 1
- CKPCAYZTYMHQEX-NBVRZTHBSA-N (e)-1-(2,4-dichlorophenyl)-n-methoxy-2-pyridin-3-ylethanimine Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=N/OC)/CC1=CC=CN=C1 CKPCAYZTYMHQEX-NBVRZTHBSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- FOWAVPREFGTTQS-UPHRSURJSA-N (z)-4-hydrazinyl-4-oxobut-2-enoic acid Chemical class NNC(=O)\C=C/C(O)=O FOWAVPREFGTTQS-UPHRSURJSA-N 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- LQWHPYPUHPQSRX-UHFFFAOYSA-N 1,1'-biphenyl;pyridine Chemical class C1=CC=NC=C1.C1=CC=CC=C1C1=CC=CC=C1 LQWHPYPUHPQSRX-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical compound C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 1
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- LAYAKLSFVAPMEL-UHFFFAOYSA-N 1-ethenoxydodecane Chemical compound CCCCCCCCCCCCOC=C LAYAKLSFVAPMEL-UHFFFAOYSA-N 0.000 description 1
- UKDKWYQGLUUPBF-UHFFFAOYSA-N 1-ethenoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOC=C UKDKWYQGLUUPBF-UHFFFAOYSA-N 0.000 description 1
- QJJDJWUCRAPCOL-UHFFFAOYSA-N 1-ethenoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOC=C QJJDJWUCRAPCOL-UHFFFAOYSA-N 0.000 description 1
- LPYHXIHXJREIMY-UHFFFAOYSA-N 1-ethenoxytetradecane Chemical compound CCCCCCCCCCCCCCOC=C LPYHXIHXJREIMY-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- XFNJVKMNNVCYEK-UHFFFAOYSA-N 1-naphthaleneacetamide Chemical compound C1=CC=C2C(CC(=O)N)=CC=CC2=C1 XFNJVKMNNVCYEK-UHFFFAOYSA-N 0.000 description 1
- 229960002666 1-octacosanol Drugs 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-N 1H-imidazole Chemical compound C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 1
- NFTOEHBFQROATQ-UHFFFAOYSA-N 2,3-dihydrofuran-5-carboxylic acid Chemical compound OC(=O)C1=CCCO1 NFTOEHBFQROATQ-UHFFFAOYSA-N 0.000 description 1
- YOYAIZYFCNQIRF-UHFFFAOYSA-N 2,6-dichlorobenzonitrile Chemical compound ClC1=CC=CC(Cl)=C1C#N YOYAIZYFCNQIRF-UHFFFAOYSA-N 0.000 description 1
- PWVUXRBUUYZMKM-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCO PWVUXRBUUYZMKM-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- AOKOVPYLILXXJR-UHFFFAOYSA-N 2-[2-(2-hydroxyethyl)-1H-imidazol-5-yl]acetic acid Chemical compound C(=O)(O)CC=1N=C(NC=1)CCO AOKOVPYLILXXJR-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 1
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- NMWKWBPNKPGATC-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-benzofuran-1(3H)-one Chemical compound ClC1=C(Cl)C(Cl)=C2COC(=O)C2=C1Cl NMWKWBPNKPGATC-UHFFFAOYSA-N 0.000 description 1
- CTSLUCNDVMMDHG-UHFFFAOYSA-N 5-bromo-3-(butan-2-yl)-6-methylpyrimidine-2,4(1H,3H)-dione Chemical compound CCC(C)N1C(=O)NC(C)=C(Br)C1=O CTSLUCNDVMMDHG-UHFFFAOYSA-N 0.000 description 1
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 239000005472 Bensulfuron methyl Substances 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- WTEJQBARPJSNLZ-UHFFFAOYSA-N C(C(=O)N)(=O)O.P Chemical compound C(C(=O)N)(=O)O.P WTEJQBARPJSNLZ-UHFFFAOYSA-N 0.000 description 1
- 239000005745 Captan Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000195649 Chlorella <Chlorellales> Species 0.000 description 1
- 239000005497 Clethodim Substances 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- NDUPDOJHUQKPAG-UHFFFAOYSA-N Dalapon Chemical compound CC(Cl)(Cl)C(O)=O NDUPDOJHUQKPAG-UHFFFAOYSA-N 0.000 description 1
- 239000005975 Daminozide Substances 0.000 description 1
- NOQGZXFMHARMLW-UHFFFAOYSA-N Daminozide Chemical compound CN(C)NC(=O)CCC(O)=O NOQGZXFMHARMLW-UHFFFAOYSA-N 0.000 description 1
- 239000005644 Dazomet Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000005504 Dicamba Substances 0.000 description 1
- 239000005893 Diflubenzuron Substances 0.000 description 1
- 239000005630 Diquat Substances 0.000 description 1
- 239000005510 Diuron Substances 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 1
- AIGRXSNSLVJMEA-UHFFFAOYSA-N EPN Chemical compound C=1C=CC=CC=1P(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 AIGRXSNSLVJMEA-UHFFFAOYSA-N 0.000 description 1
- 241000360590 Erythrites Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005784 Fluoxastrobin Substances 0.000 description 1
- 239000005979 Forchlorfenuron Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 102000018997 Growth Hormone Human genes 0.000 description 1
- 108010051696 Growth Hormone Proteins 0.000 description 1
- 229940122853 Growth hormone antagonist Drugs 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000005661 Hexythiazox Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 239000005867 Iprodione Substances 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- GGLZPLKKBSSKCX-YFKPBYRVSA-N L-ethionine Chemical compound CCSCC[C@H](N)C(O)=O GGLZPLKKBSSKCX-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 239000005572 Lenacil Substances 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000005949 Malathion Substances 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000005805 Mepanipyrim Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000005916 Methomyl Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- AYDQIZKZTQHYIY-UHFFFAOYSA-N OC(=O)C1(C)CC(C(O)=O)=CC=C1 Chemical compound OC(=O)C1(C)CC(C(O)=O)=CC=C1 AYDQIZKZTQHYIY-UHFFFAOYSA-N 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 239000005591 Pendimethalin Substances 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- UNLYSVIDNRIVFJ-UHFFFAOYSA-N Piperophos Chemical compound CCCOP(=S)(OCCC)SCC(=O)N1CCCCC1C UNLYSVIDNRIVFJ-UHFFFAOYSA-N 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000005823 Propineb Substances 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 240000000528 Ricinus communis Species 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- CSPPKDPQLUUTND-NBVRZTHBSA-N Sethoxydim Chemical compound CCO\N=C(/CCC)C1=C(O)CC(CC(C)SCC)CC1=O CSPPKDPQLUUTND-NBVRZTHBSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229940100389 Sulfonylurea Drugs 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000008931 Tadenan Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000005658 Tebufenpyrad Substances 0.000 description 1
- 241001454294 Tetranychus Species 0.000 description 1
- QHTQREMOGMZHJV-UHFFFAOYSA-N Thiobencarb Chemical compound CCN(CC)C(=O)SCC1=CC=C(Cl)C=C1 QHTQREMOGMZHJV-UHFFFAOYSA-N 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- 239000005846 Triadimenol Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 description 1
- KIPLYOUQVMMOHB-MXWBXKMOSA-L [Ca++].CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O.CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O Chemical compound [Ca++].CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O.CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O KIPLYOUQVMMOHB-MXWBXKMOSA-L 0.000 description 1
- BDKZHNJTLHOSDW-UHFFFAOYSA-N [Na].CC(O)=O Chemical compound [Na].CC(O)=O BDKZHNJTLHOSDW-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005189 alkyl hydroxy group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229960002587 amitraz Drugs 0.000 description 1
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- XQMIGRUKENWSIJ-UHFFFAOYSA-N aniline;pyrimidine Chemical class C1=CN=CN=C1.NC1=CC=CC=C1 XQMIGRUKENWSIJ-UHFFFAOYSA-N 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- OIPMQULDKWSNGX-UHFFFAOYSA-N bis[[ethoxy(oxo)phosphaniumyl]oxy]alumanyloxy-ethoxy-oxophosphanium Chemical compound [Al+3].CCO[P+]([O-])=O.CCO[P+]([O-])=O.CCO[P+]([O-])=O OIPMQULDKWSNGX-UHFFFAOYSA-N 0.000 description 1
- CXNPLSGKWMLZPZ-UHFFFAOYSA-N blasticidin-S Natural products O1C(C(O)=O)C(NC(=O)CC(N)CCN(C)C(N)=N)C=CC1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- RXDMAYSSBPYBFW-PKFCDNJMSA-N carpropamide Chemical compound N([C@@H](C)C=1C=CC(Cl)=CC=1)C(=O)[C@@]1(CC)[C@H](C)C1(Cl)Cl RXDMAYSSBPYBFW-PKFCDNJMSA-N 0.000 description 1
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- CWJSHJJYOPWUGX-UHFFFAOYSA-N chlorpropham Chemical compound CC(C)OC(=O)NC1=CC=CC(Cl)=C1 CWJSHJJYOPWUGX-UHFFFAOYSA-N 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- SILSDTWXNBZOGF-JWGBMQLESA-N clethodim Chemical compound CCSC(C)CC1CC(O)=C(C(CC)=NOC\C=C\Cl)C(=O)C1 SILSDTWXNBZOGF-JWGBMQLESA-N 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- QAYICIQNSGETAS-UHFFFAOYSA-N dazomet Chemical compound CN1CSC(=S)N(C)C1 QAYICIQNSGETAS-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- UOAMTSKGCBMZTC-UHFFFAOYSA-N dicofol Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)(Cl)Cl)(O)C1=CC=C(Cl)C=C1 UOAMTSKGCBMZTC-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- 229940031768 diglycol stearate Drugs 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- XSWSEQPWKOWORN-UHFFFAOYSA-N dodecan-2-ol Chemical compound CCCCCCCCCCC(C)O XSWSEQPWKOWORN-UHFFFAOYSA-N 0.000 description 1
- ZITKDVFRMRXIJQ-UHFFFAOYSA-N dodecane-1,2-diol Chemical compound CCCCCCCCCCC(O)CO ZITKDVFRMRXIJQ-UHFFFAOYSA-N 0.000 description 1
- JRTVEUGOGWTHTR-UHFFFAOYSA-N dodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCC JRTVEUGOGWTHTR-UHFFFAOYSA-N 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 206010016165 failure to thrive Diseases 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- GBIHOLCMZGAKNG-CGAIIQECSA-N flucythrinate Chemical compound O=C([C@@H](C(C)C)C=1C=CC(OC(F)F)=CC=1)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 GBIHOLCMZGAKNG-CGAIIQECSA-N 0.000 description 1
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- IRRZXISJLIZVRT-UHFFFAOYSA-N fluorobenzene urea Chemical compound C(N)(=O)N.FC1=CC=CC=C1 IRRZXISJLIZVRT-UHFFFAOYSA-N 0.000 description 1
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 description 1
- GPXLRLUVLMHHIK-UHFFFAOYSA-N forchlorfenuron Chemical compound C1=NC(Cl)=CC(NC(=O)NC=2C=CC=CC=2)=C1 GPXLRLUVLMHHIK-UHFFFAOYSA-N 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 description 1
- 239000000122 growth hormone Substances 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- ZNYQHFLBAPNPRC-UHFFFAOYSA-N heptadecan-2-ol Chemical compound CCCCCCCCCCCCCCCC(C)O ZNYQHFLBAPNPRC-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- JTEDVYBZBROSJT-UHFFFAOYSA-N indole-3-butyric acid Chemical compound C1=CC=C2C(CCCC(=O)O)=CNC2=C1 JTEDVYBZBROSJT-UHFFFAOYSA-N 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- FCOAHACKGGIURQ-UHFFFAOYSA-N iprobenfos Chemical compound CC(C)OP(=O)(OC(C)C)SCC1=CC=CC=C1 FCOAHACKGGIURQ-UHFFFAOYSA-N 0.000 description 1
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- ZTMKADLOSYKWCA-UHFFFAOYSA-N lenacil Chemical compound O=C1NC=2CCCC=2C(=O)N1C1CCCCC1 ZTMKADLOSYKWCA-UHFFFAOYSA-N 0.000 description 1
- 229960000453 malathion Drugs 0.000 description 1
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 1
- 229920000940 maneb Polymers 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 description 1
- BCTQJXQXJVLSIG-UHFFFAOYSA-N mepronil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C)=C1 BCTQJXQXJVLSIG-UHFFFAOYSA-N 0.000 description 1
- LGRLWUINFJPLSH-UHFFFAOYSA-N methanide Chemical compound [CH3-] LGRLWUINFJPLSH-UHFFFAOYSA-N 0.000 description 1
- MEBQXILRKZHVCX-UHFFFAOYSA-N methidathion Chemical compound COC1=NN(CSP(=S)(OC)OC)C(=O)S1 MEBQXILRKZHVCX-UHFFFAOYSA-N 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- CUYDUAXYJJPSRK-UHFFFAOYSA-N n-[4-methyl-3-(trifluoromethylsulfonylamino)phenyl]acetamide Chemical compound CC(=O)NC1=CC=C(C)C(NS(=O)(=O)C(F)(F)F)=C1 CUYDUAXYJJPSRK-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- QXYWIOWTBOREMG-UHFFFAOYSA-N nonadecan-2-ol Chemical compound CCCCCCCCCCCCCCCCCC(C)O QXYWIOWTBOREMG-UHFFFAOYSA-N 0.000 description 1
- SFRQGTJCXIVSEM-UHFFFAOYSA-N octacosan-2-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCC(C)O SFRQGTJCXIVSEM-UHFFFAOYSA-N 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- 229960000321 oxolinic acid Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- FURYAADUZGZUGQ-UHFFFAOYSA-N phenoxybenzene;sulfuric acid Chemical compound OS(O)(=O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 FURYAADUZGZUGQ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- BRFMYUCUGXFMIO-UHFFFAOYSA-N phosphono dihydrogen phosphate phosphoric acid Chemical compound OP(O)(O)=O.OP(O)(=O)OP(O)(O)=O BRFMYUCUGXFMIO-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 235000021251 pulses Nutrition 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- 229940070846 pyrethrins Drugs 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229940080817 rotenone Drugs 0.000 description 1
- JUVIOZPCNVVQFO-UHFFFAOYSA-N rotenone Natural products O1C2=C3CC(C(C)=C)OC3=CC=C2C(=O)C2C1COC1=C2C=C(OC)C(OC)=C1 JUVIOZPCNVVQFO-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
- MGLWZSOBALDPEK-UHFFFAOYSA-N simetryn Chemical compound CCNC1=NC(NCC)=NC(SC)=N1 MGLWZSOBALDPEK-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 244000000000 soil microbiome Species 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 229960005322 streptomycin Drugs 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229960004306 sulfadiazine Drugs 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000006273 synthetic pesticide Substances 0.000 description 1
- 229940014903 tadenan Drugs 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- 229940063650 terramycin Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- BRGJIIMZXMWMCC-UHFFFAOYSA-N tetradecan-2-ol Chemical compound CCCCCCCCCCCCC(C)O BRGJIIMZXMWMCC-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明提供了对作物无药害,可以安全使用,而且对各种农药具有优异的增效作用,并能促进以生长为目的植物体生长的农药增效剂和农药组合物。该农药增效剂含有特定的醇化合物、醚化合物和酯化合物中的至少一种作为有效成分。
Description
技术领域
本发明涉及新的农药增效剂和农药组合物。
背景技术
以杀虫剂、杀菌剂、除草剂、杀螨剂、植物生长调节剂为代表的农药以乳剂、水和剂、颗粒剂、粉剂、混悬(flowable)剂等剂型使用。此时,为了充分发挥农药原药的效果,可对制剂的物理性质进行多种设计,但目前的现状是通过在制剂上的设计很难进一步增强农药的效果。而且,由于新农药的开发难度增加,因此进一步增强现有农药的活性在工业上具有重要意义。
US-A 5385750(对应于JP-A 7-508024和WO93/22917)公开了用烷基糖苷和C7~C20脂肪族醇改善水性混合物的润湿性的方法,但其中没有记载进一步增强现有农药的活性和促进作为目的的植物生长。
发明内容
本发明提供了一种农药增效剂,其含有式(I)代表的化合物、式(II)代表的化合物和式(III)代表的化合物中的至少一种作为有效成分:
R4-O-(AO)m-R5 (II)
R6-COO-(AO)n-R7 (III)式中,R1为C10~C22的烃基,R2为氢原子、羟基或C1~C24的烃基,R3为氢原子或C1~C24的烃基,R4为C12~C24的烃基,R5为C1~C24的烃基,AO为C2~C4的烯化氧基,m为0~50的数字,n为0~50的数字,R6为C11~C23的烃基,R7为C12~C24的烃基或-COR8,R8为C11~C23的烃基。
而且,本发明提供了一种农药增效剂组合物,其含有上述的式(I)、式(II)和式(III)代表的化合物,以及这些化合物以外的表面活性剂和螯合剂中的至少一种。表面活性剂优选为:(1)具有酯键、醚键和酰胺键中的至少一种的非离子表面活性剂,(2)阴离子表面活性剂,(3)阳离子表面活性剂,以及(4)两性表面活性剂中的至少一种。特别地,表面活性剂优选为:(1)具有酯键和醚键中的至少一种的非离子表面活性剂。
而且,本发明提供了一种农药组合物,其含有上述农药增效剂或组合物,以及农药原药。本发明还提供了上述农药增效剂或组合物增强农药效力并且促进植物生长的用途,以及通过将上述农药增效剂或组合物和农药一起施用于植物而增强农药效力并且促进植物生长的方法。
具体实施方式
在本发明中,在具有进一步增强农药活性,并且促进以生长为目的的植物体生长的效果的农药增效剂中,用上述式(I)~(III)代表的化合物中的至少一种作为有效成分。其中式(I)代表的化合物和式(II)代表的化合物是优选的,特别优选的是式(I)代表的化合物。
在式(I)~(III)中,R1、R2、R3、R4、R5、R6、R7、R8的烃基分别可以为饱和或不饱和的,优选是饱和的;而且可以为直链、支链或环状的,优选是直链或支链的,特别优选为直链的。
而且,R1、R2、R3的碳原子的总数,R4、R5的碳原子的总数,R6、R7、R8的碳原子的总数优选都在50以下,更优选为12~48,更加优选为16~44。
在式(I)中,R1的碳原子数优选为14~22,更优选为14~20,更加优选为14~18。而且,式(I)代表的化合物的总碳原子数优选为12~48,更优选为16~28,特别优选为16~24。而且,优选总碳原子数为12~24并具有1个羟基,特别优选总碳原子数为16~22并具有1个羟基。式(I)代表的化合物的具体实例如下所列。
(I-1)
例如CH3(CH2)o-1OH(o为12~24,优选为16~24,更优选为16~20的整数)代表的1-链烷醇。具体的实例包括1-十二烷醇、1-十三烷醇、1-十四烷醇、1-十五烷醇、1-十六烷醇、1-十七烷醇、1-十八烷醇、1-十九烷醇、1-二十烷醇、1-二十一烷醇、1-二十二烷醇、1-二十三烷醇、1-二十四烷醇。
(I-2)
例如CH3CH(OH)(CH2)p-3CH3(p为12~24,优选为16~24,更优选为16~20的整数)代表的2-链烷醇。具体的实例包括2-十二烷醇、2-十三烷醇、2-十四烷醇、2-十五烷醇、2-十六烷醇、2-十七烷醇、2-十八烷醇、2-十九烷醇、2-二十烷醇等。
(I-3)
例如CH2=CH(CH2)q-2OH(q为12~24,优选为16~24,更优选为16~20的整数)代表的末端不饱和醇。具体的实例包括11-十二碳烯-1-醇、12-十三碳烯-1-醇、15-十六碳烯-1-醇等。
(I-4)
其它不饱和长链醇的实例包括油醇、反式十八烯醇、亚油醇、亚麻醇、桐醇(α或β)、蓖麻醇等。
(I-5)
例如HOCH2CH(OH)(CH2)r-2H(r为12~24,优选为16~24,更优选为16~20的整数)代表的1,2-二醇。具体的实例包括1,2-十二烷二醇、1,2-十四烷二醇、1,2-十六烷二醇、1,2-十八烷二醇等。
上述(I-1)~(I-5)中,(I-1)、(I-2)、(I-4)、(I-5)是优选的,更优选为(I-1)、(I-2)、(I-4),更加优选为(I-1)、(I-4),特别优选为(I-1)。
式(II)代表的化合物的总碳原子数优选为13~48,更优选为24~48,特别优选为32~40。式(II)中的m优选为0~30,更优选为0~10,特别优选为0~5。式(II)代表的化合物的具体实例如下所列。
(II-1)
例如CH3(CH2)s-1-O-(CH2)s-1CH3(s为12~24,优选为16~24,更优选为16~20的整数)代表的二正烷基醚。具体的实例包括二-十二烷基醚、二-十三烷基醚、二-十四烷基醚、二-十五烷基醚、二-十六烷基醚、二-十八烷基醚等。
(II-2)
例如CH2=CH-OR5(R5为C12~C24,优选为C16~C24的烷基或链烯基)代表的乙烯基醚。具体的实例包括乙烯基月桂基醚、乙烯基肉豆蔻基醚、乙烯基十六烷基醚、乙烯基十八烷基醚、乙烯基油基醚、乙烯基亚油基醚等。
在上述(II-1)、(II-2)中,(II-1)是优选的。
式(III)代表的化合物的总碳原子数优选为24~48,更优选为28~48,特别优选为32~44。式(III)中的n优选为0~30,更优选为0~10,特别优选为0~5。而且,式(III)中的R6、R7、R8优选为直链型或饱和型,特别优选为饱和直链型。式(III)代表的化合物根据Griffin公式的HLB优选为小于7,更优选为6或6以下,更加优选为5或5以下,特别优选为4或4以下。该Griffin公式是,HLB=(亲水基部分的分子量/表面活性剂的分子量)×(100/5)(《新·表面活性剂入门》三洋化成工业株式会社,1985年11月1日发行,第128页)。式(III)代表的化合物的具体实例如下所列。
(III-1)
例如R6’-COO-CH2CH2OCOR8’(R6’和R8’可以相同或不同,是C11~C23,优选是C15~C23,特别优选是C15~C19的烷基或链烯基)代表的乙二醇脂肪酸二酯。具体的实例包括二月桂酸乙二醇酯、二肉豆蔻酸乙二醇酯、二棕榈酸乙二醇酯、二硬脂酸乙二醇酯等。
(III-2)
例如R6’-COO-R7’(R6’为C11~C23,优选为C15~C23,特别优选为C15~C19的烷基或链烯基,R7’为C12~C24,优选为C16~C24,特别优选为C16~C20的烷基或链烯基)代表的脂肪酸酯。具体的实例包括棕榈酸月桂酯、棕榈酸棕榈酯、棕榈酸十八酯、硬脂酸月桂酯、硬脂酸棕榈酯、硬脂酸十八酯等。
在上述(III-1)、(III-2)中,(III-2)是优选的。
本发明的农药增效剂表现与农药的结构种类无关的显著的增效作用的机理还不确定,一种可能是本发明的增效剂对农药的溶解性非常强,使得农药微粒子化而促进其向植物体内或虫体或菌体中渗透。本发明的农药增效剂的剂型可以是液体形式、粉末形式、颗粒形式中的任一种,但并不限于这些。
根据本发明的农药增效剂的使用方法包括,使用含有农药增效剂的农药组合物的方法,和使用农药(不含本发明的增效剂)在稀释使用时另外添加的农药增效剂的方法,使用上述任何方法都可获得作为本发明目的的增效作用。而且,根据本发明的农药增效剂对于各种作物都没有药害,可以安全地使用。
在本发明的农药增效剂中,通过将至少一种式(I)~(III)代表的化合物与除它们以外的表面活性剂并用,在保持式(I)~(III)代表的化合物的农药增效效果的同时,可以减少式(I)~(III)代表的化合物的使用量。表面活性剂根据上述Griffin公式的HLB优选大于等于7,更优选大于等于8,更加优选大于等于9,特别优选大于等于10。
表面活性剂优选为(1)具有酯键、醚键和酰胺键中的至少一种的非离子表面活性剂,(2)阴离子表面活性剂,(3)阳离子表面活性剂,以及(4)两性表面活性剂中的至少一种。
(1)的具有酯键、醚键和酰胺键中的至少一种的非离子表面活性剂包括酯类,如脱水山梨醇脂肪酸酯、聚氧亚烷基脱水山梨醇脂肪酸酯、蔗糖脂肪酸酯、山梨醇脂肪酸酯、聚氧亚烷基山梨醇脂肪酸酯、聚甘油脂肪酸酯、甘油脂肪酸酯、聚氧乙烯硬化蓖麻油等的聚氧亚烷基甘油脂肪酸酯、亚烷基二醇脂肪酸酯、聚亚烷基二醇脂肪酸酯等;醚类,如POE(20)月桂基醚等的聚氧亚烷基烷基醚、聚氧亚烷基烷基芳基醚、烷基甘油基醚、聚甘油和聚氧亚烷基嵌段共聚物(Pluronic型);酰胺类,如烷基链烷醇酰胺、糖类脂肪酸酰胺等。其中,糖类脂肪酸酰胺包括具有疏水基酰胺结合于糖或糖醇的结构,如葡萄糖或果糖的脂肪酸酰胺等糖类脂肪酸酰胺。具有疏水基酰胺结合于具有氨基的糖或糖醇的结构的糖类脂肪酸酰胺也可以用例如N-甲基葡糖胺的脂肪酸酰胺等的糖类脂肪酸酰胺。
作为糖类脂肪酸酰胺优选使用式(1)代表的化合物:
R11-CO-NR12X (1)
(式中:R11为C5~C17的直链或支链的烷基、链烯基或烷基苯基,R12为氢、C1~C18的直链或支链的烷基或链烯基、-(CH2CH(R13)O)c-H(其中,R13为氢或甲基,c为0~10的数字。)、-CH2CH2OH、-CH2CH(OH)CH3或-CH2CH2CH2OH,X为由C4~C30的糖残基组成的多羟基烷基。)
式(1)中作为R11的C5~C17的直链或支链的烷基、链烯基或烷基苯基中,例如可以为衍生自己酸、辛酸、月桂酸、肉豆蔻酸、棕榈酸、硬脂酸或异硬脂酸的R11CO,特别地,例如优选衍生自己酸、月桂酸的基团。
R12的具体实例可以是氢、甲基、乙基、正丙基、异丙基、正丁基、叔丁基、正己基、辛基、2-乙基己基、癸基、十二烷基、硬脂基、异硬脂基或聚合度为2~10的聚乙二醇基或聚丙二醇基、2-羟基乙基、2-羟基丙基、3-羟基丙基等。其中,优选为例如氢、甲基、乙基、2-羟基乙基、2-羟基丙基、3-羟基丙基。
X的由C4~C30的糖残基组成的多羟基烷基中包括与一-、二-或寡糖基糖苷结合的C4~C7的多羟基烷基。
上述非离子表面活性剂可以单独使用,也可使用两种或两种以上上述表面活性剂的混合物形式。
作为(2)的阴离子表面活性剂,典型的是以水溶液或固体状态获得的,例如:一-和二-烷基萘磺酸钠、α-烯烃磺酸钠、烷基磺酸钠、烷基磺基琥珀酸盐、烷基硫酸盐、聚氧亚烷基烷基醚硫酸盐、聚氧亚烷基烷基芳基醚硫酸盐、聚氧亚烷基苯乙烯基苯基醚硫酸盐、一-和二-烷基苯磺酸盐、烷基萘磺酸盐、烷基萘磺酸盐的甲醛缩聚物、烷基二苯基醚磺酸盐、烯属磺酸盐、一-和二-烷基磷酸盐、聚氧亚烷基一-和二-烷基磷酸盐、聚氧亚烷基一-和二-苯基醚磷酸盐、聚氧亚烷基一-和二-烷基苯基醚磷酸盐、聚羧酸盐、脂肪酸盐、直链或支链烷基聚氧亚烷基醚乙酸或其盐、链烯基聚氧亚烷基醚乙酸或其盐、硬脂酸及其盐、油酸及其盐、N-甲基脂肪酸牛磺酸盐,两种或多种上述化合物的混合物等(包括钠、钾、铵及胺盐)。
(3)的阳离子表面活性剂的实例包括,烷基胺环氧乙烷加成物和烷基胺环氧丙烷加成物,例如牛脂胺环氧乙烷加成物、油胺环氧乙烷加成物、大豆胺环氧乙烷加成物、椰子胺(cocoamine)环氧乙烷加成物、合成烷基胺环氧乙烷加成物、辛胺环氧乙烷加成物、WO95/33379中记载的链烷醇胺烷基酯化物及其环氧乙烷加成物等,以及衍生自上述化合物的季铵化合物及其混合物。
(4)的两性表面活性剂的实例包括,十二烷基二甲基氨基乙酸甜菜碱、烷基二甲基胺氧化物、烷基羧甲基羟乙基咪唑鎓甜菜碱、烷基酰胺丙基甜菜碱和烷基羟基磺基甜菜碱和它们的混合物等。
在这些表面活性剂中,优选至少一种具有上述特定键的非离子型表面活性剂,以及阴离子表面活性剂,特别优选具有上述特定键的非离子型表面活性剂。
其中,优选酯类和醚类,特别优选酯类。在酯类表面活性剂中,优选PEO(20)脱水山梨醇一油酸酯等的脱水山梨醇脂肪酸酯、聚氧亚烷基脱水山梨醇脂肪酸酯、PEO(20)硬化蓖麻油等的聚氧乙烯硬化蓖麻油。
在以上述式(I)~(III)代表的化合物和除此以外的表面活性剂为有效成分的农药增效剂中,式(I)代表的化合物的总量和表面活性剂的优选并用比例为[式(I)代表的化合物的总量]/[除该化合物以外的表面活性剂]=0.01~100(重量比),更优选为0.05~50,特别优选为0.1~10。
在本发明的农药增效剂中,至少一种式(I)~(III)代表的化合物中,还可以配合有螯合剂。通过配合螯合剂,可以进一步提供对农药的增效效果。这些螯合剂包括,氨基聚羧酸类螯合剂、芳族或脂族羧酸类螯合剂、氨基酸类螯合剂、醚聚羧酸类螯合剂、膦酸类螯合剂(例如亚氨基二甲基膦酸(IDP)、烷基二膦酸(ADPA)等),或二甲基乙二肟(DG)等,它们可以是酸形式或钠、钾或铵等盐的形式。在本发明中,对1摩尔的式(I)~(III)代表的化合物,优选配合0.001~30倍摩尔,更优选0.01~20倍摩尔,特别优选0.05~15倍摩尔的螯合剂。
作为氨基多羧酸类螯合剂,可以使用下述各种化合物:
a)RNX2型化合物
b)NX3型化合物
c)R-NX-CH2CH2-NX-R型化合物
d)R-NX-CH2CH2-NX2型化合物和
e)X2N-R’-NX2型化合物,以及这种类型的化合物中包括4个或4个以上的X的化合物。上述式中,X代表-CH2COOH或-CH2CH2COOH,R代表氢原子、烷基、羟基、羟烷基或这种公知的螯合剂化合物代表的取代基,R’代表亚烷基、环亚烷基或这种公知的螯合剂化合物代表的取代基。它们的代表实例包括,EDTA·4Na等的乙二胺四乙酸(EDTA)、环己二胺四乙酸(CDTA)、次氮基三乙酸(NTA)、亚胺基二乙酸(IDA)、N-(2-羟基乙基)亚胺基二乙酸(HIMDA)、二亚乙基三胺五乙酸(DTPA)、N-(2-羟基乙基)乙二胺三乙酸(EDTA-OH)和乙二醇醚二胺四乙酸(GEDTA),以及它们的盐等。
芳族或脂族羧酸类螯合剂包括,柠檬酸、葡糖酸、苹果酸、庚糖酸、草酸、丙二酸、乳酸、酒石酸、琥珀酸、富马酸、马来酸、己二酸、戊二酸等的氧羧酸,多元羧酸,以及它们的钾、钠、链烷醇胺盐和脂族胺盐等。
氨基酸类螯合剂包括,甘氨酸、丝氨酸、丙氨酸、赖氨酸、胱氨酸、半胱氨酸、乙硫氨酸、酪氨酸或甲硫氨酸,以及它们的盐和衍生物。本发明中使用的醚多羧酸类螯合剂,例如下式代表的化合物,其类似化合物及其盐(特别是钠盐)。
[式中Y代表氢原子、式-CH2COOH代表的基团或式-COOH代表的基团,Z代表氢原子、式-CH2COOH代表的基团,或式
代表的基团]。
在本发明的农药增效剂中,可以并用溶剂或渗透助剂。溶剂或渗透助剂的实例如下所述:
1)包括离子交换水、有机或无机酸水溶液、碱水溶液的水。
2)乙醇、正己醇、2-庚醇、正辛醇、2-乙基己醇、正癸醇、环己醇、苄醇等C1~C11的一元醇。
3)乙二醇、丙二醇、二乙二醇、二丙二醇、三乙二醇、三丙二醇、1,3-丁二醇、1,4-丁二醇、1,5-戊二醇、2-甲基-2,4-戊二醇、3-甲基-1,5-戊二醇、1,6-己二醇、2-乙基-1,3-己二醇、甘油和二甘油等C2~C11的多元醇,上述多元醇的一烷基或链烯基(C1~C6)醚,上述多元醇的一烷基或链烯基(C1~C6)醚乙酸酯,上述多元醇的二乙酸酯和上述多元醇的二烷基或链烯基(C1~C6)醚;(常温下)液体的聚乙二醇、(常温下)液体的聚丙二醇、聚乙烯醇等的高分子量多元醇类及其一或二醚类。在上述3)中,优选聚亚烷基二醇一烷基醚和聚亚烷基二醇二烷基醚,更优选二乙二醇一烷基(C1~C6)醚、二乙二醇二烷基(C1~C6)醚、三乙二醇一烷基(C1~C6)醚和三乙二醇二烷基(C1~C6)醚。
4)C1~C11的一元醇的有机酸(C2~C18)一、二或三酯。有机酸例如,乙酸、丙酸、丁酸、硬脂酸、油酸、乳酸、苯甲酸、枞酸、草酸、丙二酸、苯二甲酸、苹果酸、琥珀酸、马来酸、富马酸、偏苯三酸、柠檬酸等。C1~C11的一元醇与上述2)中所述相同。其中优选苯二甲酸烷基酯和偏苯三酸烷基酯。
5)大豆油、棉籽油等植物油。
本发明的农药组合物含有本发明的农药增效剂和农药原药,所述农药增效剂含有至少一种式(I)~(III)代表的化合物。本文中,农药原药即农药的有效成分。在本发明的农药组合物中,式(I)~(III)代表的化合物和农药原药的重量比优选为[式(I)~(III)代表的化合物]/[农药原药]=0.001~100,更优选为0.05~50,特别优选为0.01~20。在此范围内可获得良好的农药增效效果。
而且,本发明的农药组合物的剂型没有限制,可以是乳剂、水和剂、颗粒剂、粉剂、混悬剂等。因此,该剂型中可含有其它添加剂,例如乳化剂、分散剂、载体等。
必要时,在本发明的农药组合物中可加入螯合剂、pH调节剂、无机盐类、增稠剂。
作为螯合剂,可以使用与农药增效剂中使用的螯合剂相同的物质。
本发明中使用的pH调节剂包括柠檬酸、磷酸(焦磷酸)、葡糖酸等或它们的盐。
本发明中使用的无机盐类包括无机矿物盐,例如无机盐粘土、滑石、膨润土、沸石、碳酸钙、高岭土和白碳黑等,无机铵盐,例如硫酸铵、硝酸铵、磷酸铵、硫氰酸铵、氯化铵、氨基磺酸铵等。
作为本发明中使用的增稠剂,可以使用任何天然、半合成及合成的水溶性增稠剂,天然粘性物质的实例包括,来自微生物的黄原胶、zanflow,来自植物的果胶、***胶、瓜耳胶等;半合成粘性物质的实例包括纤维素或淀粉衍生物的甲基化物、羧烷基化物、羟烷基化物(包括甲基纤维素、羧甲基纤维素、羟甲基纤维素等)、山梨醇等;合成粘性物质的实例包括聚丙烯酸盐、聚马来酸盐、聚乙烯吡咯烷酮和五赤藓醇环氧乙烷加成物。
本发明的农药组合物中使用的农药原药的实例包括《农药手册1998年版》(第10版,1998年12月15日,社团法人日本植物防疫协会发行)中记载的物质。其具体实例如下所示,但并不限于它们。
杀菌剂包括,有机硫杀菌剂,如代森锌、代森锰、福美双、代森锰锌、聚氨基甲酸酯、丙森锌等,苯并咪唑类杀菌剂,如苯菌灵、甲基硫菌灵等,二羧酸类杀菌剂,如异菌脲、腐霉利等,其它合成杀菌剂,如三嗪、双胍锌乙酸盐、稻瘟灵、百菌清、烯丙苯噻唑、克菌丹、增糖胺、敌螨普、双八胍盐等,甾醇生物合成抑制剂,如氟菌唑、联苯***醇、啶斑肟、氯苯嘧啶醇、嗪胺灵、***醇、腈菌唑(miclobutanil)、defenoconazole、亚胺唑等,酰胺类杀菌剂,如甲霜安和担菌宁,铜杀菌剂,如无机铜制剂、有机铜制剂等,抗生素杀菌剂,如链霉素、多抗霉素、灭瘟素、春雷霉素、有效霉素、土霉素等,土壤杀菌剂,如氯唑灵、土消菌等,三聚氰胺生物合成抑制剂,如四氯苯酞、氯环丙酰胺,有机磷类杀菌剂,如异稻瘟净、克瘟散、三乙膦酸铝等,无机杀菌剂,如无机硫磺、碳酸氢盐等,甲氧丙烯酸类杀菌剂,如腈嘧菌酯、亚胺菌等,苯胺嘧啶类杀菌剂,如嘧菌胺等,合成抗细菌剂,如噁喹酸等,天然杀菌剂,如大豆卵磷脂等,来自生物的杀菌剂,如对抗菌剂。
杀虫剂包括拟除虫菊酯杀虫剂,如氰戊菊酯、氟氯氰菊酯、氯菊酯、氟氰戊菊酯、醚菊酯等,有机磷杀虫剂,如DDVP,杀螟松、马拉硫磷、乐果、稻丰散、倍硫磷、杀扑磷、苯硫磷等,氨基甲酸酯类杀虫剂,如丁苯威、西维因、灭多威等,杀蚕毒素类杀虫剂,如杀螟丹等,天然物类杀虫剂,如来自除虫菊的除虫菊酯、胡椒基丁醚、来自豆科的鱼藤植物的鱼藤酮、烟碱、大豆卵磷脂、淀粉等。昆虫生长抑制剂(IGR剂)包括,除虫脲、氟苯脲、定虫隆、噻嗪酮、富士一号、氟虫脲等。
杀螨剂包括,开乐散、克螨特、杀螨锡、噻螨酮、双甲脒、唑螨酯、吡螨胺、苄螨酯、双丙氨膦等,氯代烟碱类杀菌剂,如吡虫啉等,其他合成杀虫剂,如油酸钠、油酸钾等,杀线虫剂,如滴滴混剂、棉隆、苯菌灵等,来自生物的杀虫剂如苏云菌杆菌等。
除草剂包括,酰胺类除草剂,如敌稗、甲草胺、磺草灵等,脲类除草剂,如敌草隆、利谷隆等,联苯吡啶鎓类除草剂,如百草枯、敌草快等,二嗪类除草剂,如除草定、环草定等,三嗪类除草剂,如西玛津、西草净等,其他有机除草剂,如敌草腈等的腈类除草剂,如稀禾定、烯草酮等,二硝基苯胺类除草剂,如氟乐灵、二甲戊灵等,氨基甲酸酯类除草剂,如禾草丹。芳香族羧酸类除草剂,如麦草畏等,苯氧基酸类除草剂,如2,4-PA、sihalofop-butyl等,有机磷除草剂,如哌草磷、草胺膦等,氨基酸类除草剂,如草甘膦、双丙氨酰膦、草铵膦等,脂肪酸类除草剂,如壬酸、茅草枯等,磺酰脲类除草剂,如噻黄隆、啶嘧黄隆、苄嘧磺隆等,嘧啶基氧苯甲酸类除草剂,如双嘧啶苯甲酸盐等,二唑类除草剂,如吡唑特等,
这些除草剂中,优选酰胺类除草剂、二嗪类除草剂、腈类除草剂、二硝基苯胺类除草剂、芳香族羧酸类除草剂和氨基酸类除草剂,特别优选酰胺类除草剂中的双丙氨膦、草铵膦或草甘膦。
植物生长调节剂包括生长素拮抗剂,如马来酸酰肼、烯效唑等,生长素,如吲哚丁酸、1-萘乙酰胺、促生灵等,细胞***素,如调吡脲等,赤霉素类,例如赤霉素等,其他生长减缓剂,如丁酰肼等,蒸发抑制剂,如石蜡等,其他的植物生长调节剂,如胆碱等,来自生物的植物生长调节剂,如小球藻提取物等,乙烯制剂,如乙烯利等。
本发明的农药组合物中还可以混合使用除上述以外的至少一种植物生长调节剂、肥料、防腐剂等。
本发明的农药组合物的剂型的更具体的实例包括:
(a)一种或一种以上上述式(I)~(III)代表的化合物的分包包装体和农药原药的分包包装体组成的农药制剂,
(b)一种或一种以上上述式(I)~(III)代表的化合物和除该化合物以外的一种或一种以上表面活性剂的混合物的分包包装体和农药原药的分包包装体组成的农药制剂,
(c)一种或一种以上上述式(I)~(III)代表的化合物的分包包装体,一种或一种以上该化合物以外的表面活性剂的分包包装体,以及农药原药的分包包装体组成的农药制剂,
(d)一种或一种以上上述式(I)~(III)代表的化合物和螯合剂组成的混合物的分包包装体和农药原药的分包包装体组成的农药制剂,
(e)一种或一种以上上述式(I)~(III)代表的化合物和螯合剂组成的混合物的分包包装体,一种或一种以上上述化合物以外的表面活性剂的分包包装体,以及农药原药的分包包装体组成的农药制剂,
(f)一种或一种以上上述式(I)~(III)代表的化合物和一种或一种以上该化合物以外的表面活性剂和螯合剂组成的混合物的分包包装体和农药原药的分包包装体组成的农药制剂。
对各分包包装体中的形态不作限定,可根据其用途和目的相应地调制。
本发明的农药增效剂,与常用的植物用或动物用农药配合成农药组合物使用,或农药增效剂与上述农药混合使用,可以大幅度地提高其防除效力。而且,本发明的农药增效剂的安全性高。通过如上述使用本发明的农药增效剂,既可以将现存农药的活性提高,而且可以促进以生长为目的的植物体生长,对生产者非常有意义。
实施例
实施例1
根据表1,用(A)式(I)~(III)代表的化合物,(B)表面活性剂,(C)螯合剂来制备各种农药增效剂。
将上述农药增效剂分别以0.02重量%的浓度溶解于离子交换水中。用所得的0.02重量%稀释液将市售的除草剂农达液剂(以41重量%的草甘膦异丙胺盐作为有效成分)、双丙氨膦水溶剂(以20重量%的双丙氨膦作为有效成分)分别稀释300倍,每种有效成分得到两种农药组合物。
将从温室试验水田采集的肥土及河砂和市售培养土以7∶2∶1(重量比)混合得到的土壤放入内径12cm的盆中,种植马唐草的种子,使之发芽。为了提高各盆间的个体的均一性,废弃生长异常的盆。将马唐草长到18cm高的盆用于试验。用喷雾枪(岩田图装机工业(株)制,RG型),将农药组合物以相当于10升/公亩的比例向盆中的所有马唐草均一地喷洒,评价除草效力。
除草效力的评价,是在喷雾处理后第10天称量地上部分的鲜重,以未处理区的地上部分的鲜重为基准表示除草百分率(参照下述式)。各农药组合物的除草率如表2所示。
实施例2
将神泽叶螨成虫,每区25只4个反复地接种在菜豆的叶片上,在25℃下培养14小时。使用直径4cm的圆形叶片。然后,将整个叶片在试验溶液中浸渍5秒钟。从试验溶液中取出,在25℃下放置48小时后观察,以未处理区的情况为基准求出杀螨率(参照下述式)。作为杀螨剂,使用杀螨锡水和剂25(以25重量%的杀螨锡作为有效成分)的2000倍稀释液,使用与实施例1相同的农药增效剂。使用的农药增效剂的有效成分在稀释液中的浓度调整为0.1重量%。而且,同样进行不使用农药增效剂的情况。按下式求出杀螨率。而且,用“ミノルタ叶绿素仪SPAD 502”(ミノルタ社制)测定叶片的绿色度,用SPAD值表示。在一个试验区测定30个点的SPAD值,取其平均值,以未处理区的SPAD值为100,将其平均值用相对值表示。结果如表3所示。
实施例3
将菜豆叶片整个在试验溶液中浸渍5秒钟,从试验溶液中取出,风干后,将10只叶蝉的三龄幼虫接种在叶片上,在25℃下培养10天,肉眼观察叶蝉的死亡数,对杀虫剂的效力进行检查。使用直径4cm的圆形叶片。而且,试验重复进行10次,与杀螨率相同地求出杀虫率。作为杀虫剂,使用噻嗪酮水和剂(以25重量%的噻嗪酮作为有效成分)的2000倍稀释液,使用与实施例1相同的农药增效剂,其在稀释液中的浓度调整为0.025重量%。同时,与实施例2相同地测定SPAD值。结果如表4所示。
实施例4
将杀菌剂抗性菌黄瓜灰霉病菌(Botrytis cinerea)的孢子悬浮液(107个/ml)以每盆10ml的量喷洒在黄瓜幼苗上(已发育三个真叶),在25℃,90%的相对湿度下静置1日。每个试验区的盆重复为10个。然后,用与实施例1相同的农药增效剂的0.025%稀释溶液将市售杀菌剂苯菌灵水和剂(以50重量%苯菌灵作为有效成分)稀释2000倍。1盆以5ml的量喷洒。然后在25℃、85%的相对湿度下静置,喷洒杀菌剂14天后,目测计数病斑数,通过下式求出相对未处理区的防除值。而且,同时测定植物体的高度和鲜重量(地上部和地下部的合计),以农药单独处理区为100以相对值表示。结果如表5所示。
实施例1~4显示本发明的农药增效剂的效力与一般的表面活性剂作为农药增效剂的情况(比较产品)比较的情况。从表2~5可以清楚地发现,本发明的农药增效剂发挥显著的效果,而且促进以生长为目的植物体的生长。
表1~5如下所示。
【表1】
化合物名 | (A)/(B)/(C)重量比 | ||
本发明的产品 | 1 | (A)1-十六烷醇 | 25/75/0 |
(B)POE(40)山梨醇四油酸酯 | |||
(C)- | |||
2 | (A)二硬脂酸乙二醇(花王(株)制エマノ-3201M) | 25/70/5 | |
(B)POE(20)月桂醚 | |||
(C)柠檬酸 | |||
3 | (A)1-十八烷醇 | 20/70/10 | |
(B)POE(20)脱水山梨醇一油酸酯 | |||
(C)EDTA·4Na | |||
4 | (A)1,2-十八烷二醇 | 20/80/0 | |
(B)POE(3)月桂醚硫酸钠 | |||
(C)- | |||
5 | (A)1-二十四烷醇 | 20/70/10 | |
(B)POE(20)脱水山梨醇一油酸酯 | |||
(C)苹果酸 | |||
6 | (A)二-十八烷基醚 | 25/70/5 | |
(B)POE(20)硬化蓖麻油 | |||
(C)庚糖酸 | |||
7 | (A)油醇 | 20/80/0 | |
(B)月桂基酰胺丙基甜菜碱 | |||
(C)- | |||
8 | (A)1-十八烷醇 | 25/75/0 | |
(B)POE(20)脱水山梨醇一油酸酯 | |||
(C)- | |||
9 | (A)C18H37O(EO)5C18H37 | 100/0/0 | |
(B)- | |||
(C)- | |||
10 | (A)2-十八烷醇 | 33/67/0 | |
(B)POE(13)十六烷基醚 | |||
(C)- | |||
11 | (A)2-二十烷醇 | 20/75/5 | |
(B)POE(4.5)月桂醚乙酸钠 | |||
(C)柠檬酸三钠 | |||
12 | (A)15-十六碳烯-1-醇 | 25/70/5 | |
(B)POE(40)山梨醇四油酸酯 | |||
(C)EDTA·2Na | |||
13 | (A)C18H37O(EO)5C18H37 | 70/0/30 | |
(B)- | |||
(C)EDTA·4Na | |||
14 | (A)1-十八烷醇 | 23/68/9 | |
(B)POE(80)硬化蓖麻油 | |||
(C)柠檬酸三钠 | |||
15 | (A)1-十八烷醇 | 25/75/0 | |
(B)POE(40)硬化蓖麻油 | |||
(C)- | |||
比较产品 | 16 | (A)- | 0/100/0 |
(B)POE(20)脱水山梨醇一油酸酯 | |||
(C)- | |||
17 | (A)- | 0/100/0 | |
(B)POE(3)月桂醚硫酸钠 | |||
(C)- |
【表2】
农药增效剂编号 | 除草率(%) | ||
农达液剂 | 双丙氨膦水和剂 | ||
本发明的产品 | 1 | 95.9 | 88.9 |
2 | 95.8 | 87.1 | |
3 | 98.9 | 91.0 | |
4 | 96.3 | 88.1 | |
5 | 97.0 | 88.2 | |
6 | 96.5 | 89.0 | |
7 | 96.0 | 87.0 | |
8 | 97.2 | 89.5 | |
9 | 95.2 | 87.3 | |
10 | 96.5 | 88.1 | |
11 | 96.0 | 87.9 | |
12 | 94.2 | 86.9 | |
13 | 96.3 | 88.1 | |
14 | 98.8 | 90.7 | |
15 | 97.2 | 89.6 | |
比较产品 | 16 | 74.2 | 69.9 |
17 | 72.7 | 67.5 | |
农药单独处理 | 70.3 | 65.4 |
【表3】
农药增效剂编号 | 杀螨率(%) | SPAD值 | |
本发明的产品 | 1 | 95 | 114 |
2 | 93 | 112 | |
3 | 98 | 120 | |
4 | 95 | 116 | |
5 | 94 | 114 | |
6 | 94 | 116 | |
7 | 95 | 113 | |
8 | 96 | 117 | |
9 | 94 | 113 | |
10 | 95 | 115 | |
11 | 93 | 112 | |
12 | 94 | 112 | |
13 | 95 | 114 | |
14 | 98 | 119 | |
15 | 96 | 117 | |
比较产品 | 16 | 61 | 102 |
17 | 60 | 101 | |
农药单独处理 | 58 | 100 |
【表4】
农药增效剂编号 | 杀虫率(%) | SPAD值 | |
本发明的产品 | 1 | 94 | 115 |
2 | 92 | 113 | |
3 | 97 | 121 | |
4 | 94 | 115 | |
5 | 94 | 114 | |
6 | 94 | 115 | |
7 | 92 | 111 | |
8 | 96 | 117 | |
9 | 93 | 114 | |
10 | 90 | 113 | |
11 | 89 | 110 | |
12 | 88 | 113 | |
13 | 94 | 116 | |
14 | 96 | 120 | |
15 | 95 | 116 | |
比较产品 | 16 | 60 | 102 |
17 | 58 | 101 | |
农药单独处理 | 55 | 100 |
【表5】
农药增效剂编号 | 防除值 | 草高 | 生重量 | |
本发明的产品 | 1 | 87 | 108 | 119 |
2 | 86 | 107 | 119 | |
3 | 92 | 117 | 128 | |
4 | 87 | 110 | 119 | |
5 | 87 | 109 | 120 | |
6 | 89 | 112 | 121 | |
7 | 88 | 111 | 120 | |
8 | 90 | 113 | 125 | |
9 | 87 | 109 | 116 | |
10 | 88 | 110 | 119 | |
11 | 86 | 108 | 114 | |
12 | 84 | 110 | 111 | |
13 | 89 | 110 | 118 | |
14 | 91 | 116 | 128 | |
15 | 89 | 113 | 124 | |
比较产品 | 16 | 70 | 102 | 102 |
17 | 68 | 100 | 101 | |
农药单独处理 | 58 | 100 | 100 |
Claims (7)
2.一种农药增效剂组合物,其含有上述权利要求1中记载的式(I)、式(II)和式(III)代表的化合物,以及这些化合物以外的表面活性剂和螯合剂中的至少一种。
3.权利要求2的农药增效剂组合物,其中表面活性剂为(1)具有酯键、醚键和酰胺键中的至少一种的非离子表面活性剂,(2)阴离子表面活性剂,(3)阳离子表面活性剂,以及(4)两性表面活性剂中的至少一种。
4.权利要求2的农药增效剂组合物,其中表面活性剂为(1)具有酯键和醚键中的至少一种的非离子表面活性剂。
5.含有权利要求1~4之任一项的农药增效剂或组合物,以及农药原药的农药组合物。
6.权利要求1~4之任一项的农药增效剂或组合物增强农药效力并且促进植物生长的用途。
7.通过将权利要求1~4之任一项的农药增效剂或组合物和农药一起施用于植物而增强农药效力并且促进植物生长的方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP386954/00 | 2000-12-20 | ||
JP386954/2000 | 2000-12-20 | ||
JP2000386954 | 2000-12-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1482857A true CN1482857A (zh) | 2004-03-17 |
CN1279816C CN1279816C (zh) | 2006-10-18 |
Family
ID=18853975
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB018210856A Expired - Lifetime CN1279816C (zh) | 2000-12-20 | 2001-12-19 | 农药增效剂 |
Country Status (7)
Country | Link |
---|---|
US (1) | US7056862B2 (zh) |
EP (1) | EP1344454B1 (zh) |
KR (3) | KR100878166B1 (zh) |
CN (1) | CN1279816C (zh) |
DE (1) | DE60138042D1 (zh) |
ES (1) | ES2323567T3 (zh) |
WO (1) | WO2002049429A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114885952A (zh) * | 2017-09-08 | 2022-08-12 | 马罗内生物创新公司 | 新型除草化合物 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040138176A1 (en) * | 2002-05-31 | 2004-07-15 | Cjb Industries, Inc. | Adjuvant for pesticides |
UA78326C2 (uk) | 2002-06-12 | 2007-03-15 | Сінгента Партісіпейшнс Аг | Гербіцидна синергетична композиція та спосіб боротьби з ростом небажаної рослинності |
MXPA06013561A (es) * | 2004-05-24 | 2007-02-08 | Valent Biosciences Corp | Composiciones liquidas estables y solubles en agua de regulador de crecimiento de plantas y metodos para el uso de las mismas. |
CA2619018A1 (en) * | 2005-09-05 | 2007-03-15 | Cheminova A/S | Concentrated liquid triazole-fungicide formulations |
JP5122841B2 (ja) * | 2006-03-24 | 2013-01-16 | 石原産業株式会社 | 除草組成物 |
CA2663248C (en) * | 2006-09-12 | 2011-11-22 | Nippon Soda Co., Ltd. | Pest control agent in form of stable suspension |
US7829513B2 (en) * | 2009-03-12 | 2010-11-09 | Greenology Products, Inc. | Organic cleaning composition |
FR2949643B1 (fr) * | 2009-09-08 | 2012-09-28 | Fonds De Dev Des Filieres Des Oleagineux Et Proteagineux Fidop | Utilisation d'ethers de glycerol comme activateurs des effets herbicides d'une substance herbicide |
US10188101B2 (en) | 2010-09-03 | 2019-01-29 | Kao Corporation | Method for producing an agricultural product |
GB201107040D0 (en) | 2011-04-26 | 2011-06-08 | Syngenta Ltd | Formulation component |
KR101131038B1 (ko) * | 2011-12-01 | 2012-03-29 | 주식회사 영일케미컬 | 글라이포세이트를 함유하는 안정한 수성현탁액 제초제 조성물 |
CA2879771A1 (en) * | 2012-07-25 | 2014-01-30 | Bayer Cropscience Ag | Emulsifiable concentrate (ec) formulation with herbicidal active fatty acids |
CN105722388B (zh) * | 2014-01-31 | 2019-09-03 | 花王株式会社 | 农药用固着剂组合物 |
US11457624B2 (en) | 2016-11-02 | 2022-10-04 | Corbet Scientific, Llc | Adjuvant compositions for plant treatment chemicals |
WO2018156457A1 (en) | 2017-02-24 | 2018-08-30 | Paramount Products 1 Llc | Treatment for plants in conjunction with harvesting |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5653521B2 (zh) * | 1973-01-17 | 1981-12-19 | ||
AU504108B2 (en) * | 1976-06-18 | 1979-10-04 | Gulf Oil Corporation | Barban formulation |
JPS5724303A (en) | 1980-07-21 | 1982-02-08 | Mitsui Toatsu Chem Inc | Insecticidal composition |
DE3247050A1 (de) * | 1982-12-20 | 1984-06-20 | Bayer Ag, 5090 Leverkusen | Herbizide mittel |
JPH0678201B2 (ja) * | 1985-09-06 | 1994-10-05 | ア−ス製薬株式会社 | ピレスロイド系殺虫組成物用効力増強剤 |
JPH0751481B2 (ja) * | 1986-04-13 | 1995-06-05 | アース製薬株式会社 | 害虫防除組成物および害虫防除方法 |
US5385750A (en) | 1992-05-14 | 1995-01-31 | Henkel Corporation | Alkyl glycoside compositions with improved wetting properties |
US5622911A (en) * | 1994-02-14 | 1997-04-22 | Kao Corporation | Method for enhancing the efficacy of agricultural chemical with alkoxylated fatty acid amides |
JPH08333204A (ja) * | 1995-04-06 | 1996-12-17 | Nippon Soda Co Ltd | 除草性組成物 |
JP2745008B2 (ja) * | 1996-10-21 | 1998-04-28 | アース製薬株式会社 | ピレスロイド系殺虫剤 |
EP0968649A1 (en) * | 1998-07-02 | 2000-01-05 | E.I. Du Pont De Nemours And Company | Adjuvants for novel dry herbicide formulations |
MY123201A (en) * | 1998-11-06 | 2006-05-31 | Kao Corp | Plant-activating agent |
JP3545661B2 (ja) * | 1998-11-06 | 2004-07-21 | 花王株式会社 | 植物活力剤 |
DE60111676T2 (de) | 2000-04-28 | 2006-05-18 | Kao Corp. | Pflanzenaktivierungsmittel |
-
2001
- 2001-12-19 CN CNB018210856A patent/CN1279816C/zh not_active Expired - Lifetime
- 2001-12-19 KR KR1020037007678A patent/KR100878166B1/ko not_active IP Right Cessation
- 2001-12-19 ES ES01271147T patent/ES2323567T3/es not_active Expired - Lifetime
- 2001-12-19 KR KR1020087016519A patent/KR100911645B1/ko not_active IP Right Cessation
- 2001-12-19 EP EP01271147A patent/EP1344454B1/en not_active Expired - Lifetime
- 2001-12-19 DE DE60138042T patent/DE60138042D1/de not_active Expired - Lifetime
- 2001-12-19 WO PCT/JP2001/011142 patent/WO2002049429A1/ja active Application Filing
- 2001-12-19 US US10/432,927 patent/US7056862B2/en not_active Expired - Lifetime
- 2001-12-19 KR KR1020087016520A patent/KR100898540B1/ko not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114885952A (zh) * | 2017-09-08 | 2022-08-12 | 马罗内生物创新公司 | 新型除草化合物 |
Also Published As
Publication number | Publication date |
---|---|
DE60138042D1 (de) | 2009-04-30 |
KR20080070777A (ko) | 2008-07-30 |
US7056862B2 (en) | 2006-06-06 |
EP1344454B1 (en) | 2009-03-18 |
KR100911645B1 (ko) | 2009-08-10 |
EP1344454A1 (en) | 2003-09-17 |
KR100878166B1 (ko) | 2009-01-12 |
EP1344454A4 (en) | 2006-06-07 |
KR100898540B1 (ko) | 2009-05-19 |
US20040053788A1 (en) | 2004-03-18 |
ES2323567T3 (es) | 2009-07-21 |
CN1279816C (zh) | 2006-10-18 |
WO2002049429A1 (fr) | 2002-06-27 |
KR20030060982A (ko) | 2003-07-16 |
KR20080070776A (ko) | 2008-07-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1279816C (zh) | 农药增效剂 | |
JP4987992B2 (ja) | 農薬組成物 | |
JP3853356B2 (ja) | 農薬用効力増強剤、農薬用効力増強剤組成物及び農薬の効力を増強する方法 | |
CN1138473C (zh) | 农药增效剂和农药组合物 | |
JP5826554B2 (ja) | 農薬用展着剤組成物 | |
JP5763370B2 (ja) | 農薬用効力増強剤組成物 | |
JP3776210B2 (ja) | 農薬用効力増強剤及び農薬製剤 | |
US5622911A (en) | Method for enhancing the efficacy of agricultural chemical with alkoxylated fatty acid amides | |
WO2012029893A1 (ja) | 農作物の生産方法 | |
JP4275338B2 (ja) | 農薬用効力増強剤 | |
JP5610811B2 (ja) | 農業用添着剤 | |
JPH0892021A (ja) | 農薬用効力増強剤組成物及び農薬組成物 | |
JP4476564B2 (ja) | 農薬組成物 | |
JPH0892023A (ja) | 農薬用効力増強剤組成物及び農薬組成物 | |
JP3339956B2 (ja) | 農薬用効力増強剤及び農薬組成物 | |
CN110461153A (zh) | 农药用效力增强剂组合物 | |
JP3923488B2 (ja) | 農薬用効力増強剤組成物及び農薬組成物 | |
JP3662270B2 (ja) | 農薬用効力増強剤及び農薬組成物 | |
JP2012051861A (ja) | 農薬用効力増強剤組成物 | |
CN110461154A (zh) | 农药用效力增强剂组合物 | |
JPH09291001A (ja) | 農薬用効力増強剤及び農薬組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term |
Granted publication date: 20061018 |
|
CX01 | Expiry of patent term |