CN1458951A - 轮胎胎面用橡胶组合物 - Google Patents
轮胎胎面用橡胶组合物 Download PDFInfo
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- CN1458951A CN1458951A CN02800616.XA CN02800616A CN1458951A CN 1458951 A CN1458951 A CN 1458951A CN 02800616 A CN02800616 A CN 02800616A CN 1458951 A CN1458951 A CN 1458951A
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- Prior art keywords
- rubber composition
- oil
- crosslinkable
- crosslinked rubber
- softening agent
- Prior art date
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000004665 trialkylsilyl group Chemical group 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical class CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
T1 | NC1 | NC2 | NC3 | NC4 | I1 | |
配方(phr) | ||||||
弹性基S-SBRABRA | 5842 | 7723 | 7228 | 8020 | 7228 | 8515 |
补强填料:氧化硅“Zeosil 160MP炭黑N234 | 806 | 806 | 806 | 806 | 806 | 806 |
耦联剂:TESPT(“Si69”) | 6.4 | 6.4 | 6.4 | 6.4 | 6.4 | 6.4 |
硬脂酸/ZnO | 2/2.5 | 2/2.5 | 2/2.5 | 2/2.5 | 2/2.5 | 2/2.5 |
DPG(二苯胍) | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
抗氧化剂(6PPD) | 2 | 2 | 2 | 2 | 2 | 2 |
硫磺/促进剂(CBS) | 1.1/2 | 1.1/2 | 1.1/2 | 1.1/2 | 1.1/2 | 1.1/2 |
“高粘性”芳香油 | 39.5 | 25 | 24 | 22 | 23 | 11 |
甘油三油酸酯(合成物) | - | - | - | - | 14 | 22 |
磷酸三辛酯 | - | 15 | - | - | - | - |
偏苯三酸酯 | - | - | 16 | - | - | - |
油酸辛酯 | - | - | - | 16 | - | - |
总增塑剂 | 39.5 | 40 | 40 | 38 | 37 | 33 |
性质 | ||||||
100℃时的ML(1+4) | 102 | 95 | 98 | 93 | 100 | 80 |
肖氏A | 66 | 66 | 66 | 66 | 66 | 66 |
23℃时的ME10 | 6 | 5.5 | 5.6 | 6 | 5.7 | 5.9 |
60℃时的HL(%) | 30 | 28 | 30 | 33 | 31 | 33 |
扯断强度(Mpa) | 50 | 60 | 65 | 80 | 70 | 85 |
扯断伸长率(%) | 220 | 260 | 285 | 350 | 310 | 410 |
轮胎性能(175/70 R14“MXT”) | ||||||
附着性(雷诺拉古娜21在23℃时)-干路面刹车ABS-湿路面刹车ABS-湿路面刹车锁定车轮 | 100100100 | 9910799 | 10110299 | 100103100 | 102104106 | 102108107 |
压缩(性能上) | 100 | 93 | 95 | 96 | 106 | 115 |
T2 | T3 | I2 | I3 | I4 | I5 | I6 | I7 | |
配方(phr) | ||||||||
弹性基S-SBRAE-SBRABR A | -8020 | 75-25 | -8020 | -100- | -100- | -100- | 85-15 | 90-10 |
补强填料:N234N134 | -80 | 60- | -80 | -80 | -80 | -80 | 60- | 60- |
硬脂酸/ZnO | 0.5/2.5 | 0.5/2.5 | 0.5/2.5 | 0.5/2.5 | 0.5/2.5 | 0.5/2.5 | 0.5/2.5 | 0.5/2.5 |
抗氧化剂(6PPD) | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 |
硫磺/促进剂(CBS) | 1.5/1.4 | 1.4/1.4 | 1.5/1.4 | 1.5/1.4 | 1.5/1.4 | 1.5/1.4 | 1.4/1.4 | 1.4/1.4 |
“高粘性”芳香油 | 46 | 25 | 30 | 6 | 6 | 6 | 8 | - |
甘油三油酸酯(合成物) | - | - | 16 | 30 | - | - | 14 | 18 |
“油酸”葵花油(油酸含量为85%) | - | - | - | - | 30 | - | - | - |
“标准”葵花油(油酸含量为50%) | - | - | - | - | - | 30 | - | - |
总增塑剂 | 46 | 25 | 46 | 36 | 36 | 36 | 22 | 18 |
性质 | ||||||||
100℃时的ML(1+4) | 80 | 87 | 80 | 65 | 67 | 70 | 72 | 70 |
肖氏A | 60.5 | 58 | 59 | 59 | 59 | 59.5 | 58 | 57 |
23℃时的ME10 | 4.65 | 4.5 | 4.6 | 4.7 | 4.6 | 4.8 | 4.4 | 4.5 |
23℃时的ME100 | 2.5 | 2.5 | 2.4 | 2.4 | 2.5 | 2.4 | 2.4 | 2.5 |
23℃时的ME300 | 4.3 | 4.3 | 4 | 3.9 | 4 | 3.6 | 4.2 | 4 |
60℃时的HL | 39.5 | 32 | 40.5 | 41 | 40 | 42.5 | 34 | 33 |
T4 | I8 | I9 | I10 | I11 | I12 | I13 | |
配方(phr) | |||||||
弹性基S-SBR ABR A | 57.542.5 | 8515 | 8515 | 8515 | 8515 | 8515 | 8515 |
补强填料:氧化硅“ZEOSIL 160MP”N234 | 8010.4 | 8010.4 | 8010.4 | 8010.4 | 8010.4 | 8010.4 | 8010.4 |
耦联剂:TESPT(“Si69”) | 6.4 | 6.4 | 6.4 | 6.4 | 6.4 | 6.4 | 6.4 |
硬脂酸/ZnO | 2/2.5 | 2/2.5 | 2/2.5 | 2/2.5 | 2/2.5 | 2/2.5 | 2/2.5 |
DPG(二苯胍) | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
抗氧化剂(6PPD) | 1.9 | 1.9 | 1.9 | 1.9 | 1.9 | 1.9 | 1.9 |
硫磺/促进剂(CBS) | 1.1/2 | 1.1/2 | 1.1/2 | 1.1/2 | 1.1/2 | 1.1/2 | 1.1/2 |
“高粘性”芳香油 | 39.5 | 15.3 | 15.3 | 15.3 | 15.3 | 15.3 | 15.3 |
甘油三油酸酯(合成物) | - | 22 | - | - | - | - | - |
“油酸”葵花籽油(油酸含量为85%) | - | - | 22 | - | - | - | - |
“标准”葵花籽油(油酸含量为50%) | - | - | - | 22 | - | - | - |
芥酸含量降低的菜籽油 | - | - | - | - | 22 | - | - |
亚麻子油 | - | - | - | - | - | 22 | - |
芥酸含量较高的菜籽油 | - | - | - | - | - | - | 22 |
总增塑剂 | 39.5 | 37.3 | 37.3 | 37.3 | 37.3 | 37.3 | 37.3 |
性质 | |||||||
100℃时的ML(1+4) | 96 | 80 | 80 | 84 | 70 | 85 | 88 |
肖氏A | 68 | 68 | 67.5 | 68 | 64 | 66 | 68.5 |
23℃时的ME10 | 6.8 | 7 | 6.7 | 7.1 | 5.7 | 6.7 | 7.2 |
23℃时的ME100 | 3.5 | 3.5 | 3.7 | 3.4 | 3 | 3 | 3.6 |
23℃时的ME300 | 6 | 5.3 | 5.6 | 5 | 4.8 | 4.4 | 5.5 |
60℃时的HL | 30 | 34 | 32 | 36 | 34 | 37 | 34 |
T5 | T6 | I14 | I15 | I16 | I17 | |
配方(phr) | ||||||
弹性基S-SBRBS-SBRC | 5050 | 8020 | 100- | 100 | 100 | 100 |
补强填料:氧化硅“ZEOSIL 160MP”N234N134 | 887.1- | 42.5-52.5 | 887.1- | 887.1- | 42.5-52.5 | 42.5-52.5 |
耦联剂:TESPT(“Si69”) | 7.1 | 3.5 | 7.1 | 7.1 | 3.5 | 3.5 |
硬脂酸/ZnO | 1/3.0 | 1/3.0 | 1/3.0 | 1/3.0 | 1/3.0 | 1/3.0 |
DPG(二苯胍) | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
抗氧化剂(6PPD) | 1.9 | 1.9 | 1.9 | 1.9 | 1.9 | 1.9 |
硫磺/促进剂(CBS) | 1.25/1.9 | 1.25/1.9 | 1.25/1.9 | 1.25/1.9 | 1.25/1.9 | 1.25/1.9 |
“高粘性”芳香油 | 37.5 | 45.5 | - | - | - | - |
甘油三油酸酯(合成物) | - | - | 20 | - | 20 | - |
“油酸”葵花籽油(油酸含量为85%) | - | - | - | 20 | - | 20 |
增塑树脂 | - | - | 12 | 12 | 17 | 17 |
总增塑剂 | 37.5 | 45.5 | 32 | 32 | 37 | 37 |
性质 | ||||||
100℃时的ML(1+4) | 116 | 109 | 72 | 75 | 80 | 82 |
肖氏A | 75.5 | 71 | 75.5 | 75 | 72 | 71.5 |
23℃时的ME10 | 9.9 | 7.2 | 9.9 | 9.7 | 7.5 | 7.3 |
23℃时的ME100 | 5.4 | 4.6 | 4.6 | 4.8 | 4.4 | 4.6 |
23℃时的ME300 | 9 | 7.5 | 6.6 | 7.5 | 6.3 | 6.9 |
60℃时的HL | 31 | 38 | 39 | 35 | 48 | 45 |
T7 | I18 | I19 | |
弹性基S-SBRAS-SBRDBR A | 70-30 | -8515 | -7030 |
补强填料:氧化硅“ZEOSIL 160MP”N234 | 806 | 806 | 806 |
耦联剂:TESPT(“Si69”) | 6.4 | 6.4 | 6.4 |
硬脂酸/ZnO | 2/2.5 | 2/2.5 | 2/2.5 |
DPG(二苯胍) | 1.5 | 9.5 | 12.5 |
抗氧化剂(6PPD) | 1.9 | 1.9 | 1.9 |
硫磺/促进剂(CBS) | 1.1/2 | 1.1/2 | 1.1/2 |
“高粘性”芳香油 | 33.25 | - | - |
“高粘性”石蜡油 | - | 13 | - |
甘油三油酸酯(合成物) | - | 15 | 17 |
实施例4的增塑树脂(“R2495”) | - | - | 15 |
轮胎(175/70 R14“MXT”)的抗冠带层脱层性 | |||
里程性能 | 100 | 119 | 116 |
平均开裂长度(mm) | 25 | 21 | 27 |
带束层中可溶性环己烷部分(%) | 10.7 | 8.9 | 8.5 |
Claims (27)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0103356 | 2001-03-12 | ||
FR01/03356 | 2001-03-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1458951A true CN1458951A (zh) | 2003-11-26 |
CN1271131C CN1271131C (zh) | 2006-08-23 |
Family
ID=8861024
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN02800616.XA Expired - Fee Related CN1271131C (zh) | 2001-03-12 | 2002-03-08 | 轮胎胎面用橡胶组合物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7335692B2 (zh) |
EP (1) | EP1379586B1 (zh) |
JP (1) | JP4209200B2 (zh) |
CN (1) | CN1271131C (zh) |
AT (1) | ATE355327T1 (zh) |
BR (1) | BR0204476B1 (zh) |
CA (1) | CA2410156C (zh) |
DE (1) | DE60218446T2 (zh) |
MX (1) | MXPA02011982A (zh) |
WO (1) | WO2002088238A1 (zh) |
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DE2712866C3 (de) | 1977-03-24 | 1980-04-30 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Verfahren zum Herstellen von schwefelhaltigen Organosiliciumverbindungen |
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JPH01215838A (ja) | 1988-02-24 | 1989-08-29 | Toyo Tire & Rubber Co Ltd | タイヤトレッド用ゴム組成物 |
JP2652795B2 (ja) | 1988-03-31 | 1997-09-10 | 日本ゼオン株式会社 | ジエン系重合体ゴムの製造方法及びゴム組成物 |
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AT397372B (de) * | 1992-03-17 | 1994-03-25 | Semperit Ag | Fahrzeugreifen |
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AT406683B (de) * | 1994-04-14 | 2000-07-25 | Semperit Ag | Kautschukmischung |
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RO121599B1 (ro) | 1995-05-22 | 2007-12-28 | Cabot Corporation | Compusi elastomerici care contin negru de fum tratat cu siliciu |
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US5708053A (en) | 1996-08-15 | 1998-01-13 | The Goodyear Tire & Rubber Company | Silica-filled rubber compositions and the processing thereof |
US5663396A (en) | 1996-10-31 | 1997-09-02 | The Goodyear Tire & Rubber Company | Preparation of sulfur-containing organosilicon compounds |
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DE19734295C1 (de) | 1997-08-08 | 1999-02-25 | Degussa | Verfahren zur Herstellung von Organosiliciumdisulfanen hoher Reinheit |
WO1999028376A2 (fr) | 1997-11-28 | 1999-06-10 | Compagnie Generale Des Etablissements Michelin - Michelin & Cie | Charge alumineuse renforcante et composition de caoutchouc comportant une telle charge |
DE19754059A1 (de) * | 1997-12-05 | 1999-06-24 | Continental Ag | Kautschukmischung für Laufstreifen von Fahrzeugreifen |
DE19915281A1 (de) | 1999-04-03 | 2000-10-05 | Degussa | Kautschukmischungen |
US6448318B1 (en) * | 2000-03-10 | 2002-09-10 | The Goodyear Tire & Rubber Company | Method of processing rubber compositions containing soya fatty acids, sunflower fatty acids and mixtures thereof |
-
2002
- 2002-03-08 MX MXPA02011982A patent/MXPA02011982A/es active IP Right Grant
- 2002-03-08 EP EP02732466A patent/EP1379586B1/fr not_active Expired - Lifetime
- 2002-03-08 BR BRPI0204476-5A patent/BR0204476B1/pt not_active IP Right Cessation
- 2002-03-08 AT AT02732466T patent/ATE355327T1/de active
- 2002-03-08 CA CA2410156A patent/CA2410156C/fr not_active Expired - Fee Related
- 2002-03-08 CN CN02800616.XA patent/CN1271131C/zh not_active Expired - Fee Related
- 2002-03-08 WO PCT/EP2002/002558 patent/WO2002088238A1/fr active IP Right Grant
- 2002-03-08 DE DE60218446T patent/DE60218446T2/de not_active Expired - Lifetime
- 2002-03-08 JP JP2002585532A patent/JP4209200B2/ja not_active Expired - Fee Related
-
2003
- 2003-09-05 US US10/656,435 patent/US7335692B2/en not_active Expired - Fee Related
Cited By (17)
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CN100465218C (zh) * | 2004-02-11 | 2009-03-04 | 米其林技术公司 | 用于橡胶组合物的增塑体系 |
CN1993416B (zh) * | 2004-07-29 | 2010-10-13 | 米其林技术公司 | 不含或基本上不含锌的橡胶组合物 |
CN101084267B (zh) * | 2004-10-28 | 2011-09-14 | 米其林技术公司 | 橡胶组合物的增塑体系 |
CN102971349A (zh) * | 2010-06-30 | 2013-03-13 | 米其林集团总公司 | 用于高性能轮胎的轮胎胎面 |
CN103328586A (zh) * | 2010-12-13 | 2013-09-25 | 埃迪亚贝拉努沃有限公司 | 用于橡胶加工的改进炭黑 |
CN103270100B (zh) * | 2010-12-23 | 2016-05-18 | 米其林企业总公司 | 胎面包含热塑性聚氨酯嵌段共聚物的轮胎 |
CN103270100A (zh) * | 2010-12-23 | 2013-08-28 | 米其林企业总公司 | 胎面包含热塑性聚氨酯嵌段共聚物的轮胎 |
CN103502346A (zh) * | 2011-05-06 | 2014-01-08 | 米其林集团总公司 | 具有包含高反式含量的sbr乳液的胎面的轮胎 |
CN103502347A (zh) * | 2011-05-06 | 2014-01-08 | 米其林集团总公司 | 具有包含高反式含量的乳液sbr的胎面的轮胎 |
CN103502347B (zh) * | 2011-05-06 | 2016-04-06 | 米其林集团总公司 | 具有包含高反式含量的乳液sbr的胎面的轮胎 |
CN103502346B (zh) * | 2011-05-06 | 2016-04-06 | 米其林集团总公司 | 具有包含高反式含量的sbr乳液的胎面的轮胎 |
CN103889736B (zh) * | 2011-09-14 | 2018-01-19 | 米其林集团总公司 | 轮胎胎面 |
CN104379693A (zh) * | 2012-06-13 | 2015-02-25 | 汉高股份有限及两合公司 | 热固化反应性体系 |
CN111433047A (zh) * | 2017-11-30 | 2020-07-17 | 米其林集团总公司 | 包含有效硫交联体系的高模量橡胶组合物 |
CN110511457A (zh) * | 2018-05-21 | 2019-11-29 | 韩国轮胎株式会社 | 轮胎胎面用橡胶组合物及利用该组合物制造的轮胎 |
CN110511457B (zh) * | 2018-05-21 | 2022-03-08 | 韩国轮胎株式会社 | 轮胎胎面用橡胶组合物及利用该组合物制造的轮胎 |
WO2022268106A1 (zh) * | 2021-06-22 | 2022-12-29 | 丰益油脂科技有限公司 | 生物基聚合油及其应用 |
Also Published As
Publication number | Publication date |
---|---|
MXPA02011982A (es) | 2003-05-27 |
US20040127617A1 (en) | 2004-07-01 |
BR0204476A (pt) | 2003-05-13 |
EP1379586A1 (fr) | 2004-01-14 |
BR0204476B1 (pt) | 2011-08-09 |
CN1271131C (zh) | 2006-08-23 |
JP2004519551A (ja) | 2004-07-02 |
CA2410156A1 (fr) | 2002-11-07 |
EP1379586B1 (fr) | 2007-02-28 |
DE60218446D1 (de) | 2007-04-12 |
DE60218446T2 (de) | 2007-11-29 |
WO2002088238A1 (fr) | 2002-11-07 |
JP4209200B2 (ja) | 2009-01-14 |
CA2410156C (fr) | 2011-08-23 |
US7335692B2 (en) | 2008-02-26 |
ATE355327T1 (de) | 2006-03-15 |
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Assignee: Shanghai Michelin tire Limited by Share Ltd Assignor: Michelin Research & Technology Co., Ltd.|Michelin Co., Ltd. Contract fulfillment period: The duration of the contract is from 2007.01.31 to 2026.12.13 Contract record no.: Contract filing No. 2007990000027 Denomination of invention: Rubber composition for tire tread Granted publication date: 20060823 License type: Common License Record date: 20070813 |
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