CN1257951A - Polyester staple fiber spinning oil and manufacturing method thereof - Google Patents
Polyester staple fiber spinning oil and manufacturing method thereof Download PDFInfo
- Publication number
- CN1257951A CN1257951A CN 99124281 CN99124281A CN1257951A CN 1257951 A CN1257951 A CN 1257951A CN 99124281 CN99124281 CN 99124281 CN 99124281 A CN99124281 A CN 99124281A CN 1257951 A CN1257951 A CN 1257951A
- Authority
- CN
- China
- Prior art keywords
- spinning oil
- agent
- phosphate
- antistatic additive
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009987 spinning Methods 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000000835 fiber Substances 0.000 title abstract description 22
- 229920000728 polyester Polymers 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- -1 alcohol ester Chemical class 0.000 claims description 17
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 14
- 229920004933 Terylene® Polymers 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 13
- 230000000996 additive effect Effects 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- 239000010452 phosphate Substances 0.000 claims description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 9
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 229920000570 polyether Polymers 0.000 claims description 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000001103 potassium chloride Substances 0.000 claims description 7
- 235000011164 potassium chloride Nutrition 0.000 claims description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- 229940070765 laurate Drugs 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000005259 measurement Methods 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 238000009499 grossing Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 2
- 229920004934 Dacron® Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000008340 white lotion Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A polyester staple fiber spinning oil agent and a manufacturing method thereof are disclosed, wherein the weight percentage of each component is 10-20% of a smoothing agent, 5-15% of a bundling agent and 70-80% of an antistatic agent.
Description
The present invention relates to a kind of spinning oil for terylene staple and manufacture method thereof, belong to the auxiliary agent manufacturing technology field in the synthetic fiber process technology.
Will pass through spinning when polyester staple fiber is produced in the chemical fibre factory, drawing-off is curled, and operations such as cut-out add man-hour again through operations such as blowing, comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarns behind the cotton mill.All there is friction between fiber and fiber, fiber and metallic weapon between each procedure and produces a large amount of electrostatic charges, and along with the quickening electrostatic problem of draw speed is more outstanding, thereby to the antistatic behaviour of short-staple Dacron oil solution, overall balance requires very high between flatness and the convergence.
The purpose of this invention is to provide a kind of stable performance, good spinnability can satisfy the polyester staple fiber spinning process requirement, effectively improves the short-staple Dacron oil solution and the manufacture method thereof of polyester staple fiber spinning quality.
The present invention is a spinning oil for terylene staple, mainly by smooth agent, and collecting agent, compositions such as antistatic additive is characterized in that the percentage by weight of each component is: smooth agent 10～20%, collecting agent 5～15%, antistatic additive 70～80%,
Described smooth agent can be mineral oil, double base alcohol ester, triol ester, quaternary alcohol ester, the mixture of one or more in the high molecular weight polyether.The effect of smooth agent can keep between fiber and the fiber, the suitable coefficient of friction between fiber and other contact components, improves level and smooth performance, helps carrying out smoothly of spin-drawing.
Described collecting agent can be the polyethylene glycol Glycol Oleic Acid Ester, aliphatic acid polyethenoxy ether, polyethylene glycol laurate dibasic acid esters, castor oil polyoxyethylene ether, the mixture of one or more in the octanol high-molecular weight atactic polyethers.The adding of collecting agent can improve the convergence of finish, makes fiber not fluffy, at random in process, and fiber is played the obvolvent effect.
Described antistatic additive can be lauryl alcohol phosphate polyoxyethylene ether sylvite, hexadecanol phosphate kalium salt, octadecanol phosphate kalium salt, lauryl alcohol polyoxyethylene ether phosphate sylvite, the mixture of one or more in the amphoteric phosphate ammonium salt.The effect of antistatic additive is can be adsorbed on fiber surface in the high speed spinning process, increases the hygroscopicity of fiber, improves electric conductivity, reduces the accumulation of static.
The manufacture method of spinning oil for terylene staple of the present invention is: the percentage by weight of pressing each component, elder generation is with the antistatic additive suction reactor of accurate measurement, being heated to 40-80 ℃ stirs, with in the collecting agent suction reactor, after stirring, add smooth agent again, after stirring 30-50min, cooling is filtered, packing.
The present invention compared with prior art has following distinguishing feature and good effect:
1, has good antistatic effect, can reduce interfibrous friction, guarantee that terylene front and back procedure carries out smoothly;
2, have good coherent and opening character, feel is abundant;
3, have good flatness, can reduce the card nailing neps in the wool top production, the generation of workprint improves the fiber feel greatly, improves fiber quality;
4, good with the fiber affinity, fuel consumption is low;
Spinning oil for terylene staple of the present invention is applicable to each end production process such as spinning, drawing-off, wool top processing and back processing of polyester staple fiber, uses through the Duo Jia chemical fibre factory, and spinning, the production that stretches run well, and the fiber quality index reaches customer requirements.
Below in conjunction with embodiment the present invention is further described:
By weight percentage, determine the ratio of each component:
Embodiment 1:
Collecting agent 10%, wherein aliphatic acid polyethenoxy ether (LAE-9 class) 2%, octanol high-molecular weight atactic polyethers 8%;
Antistatic additive 75%, wherein hexadecanol phosphate kalium salt (PK class) 45%, amphoteric phosphate ammonium salt 30%;
Smooth agent 15% is high molecular weight polyether.
Embodiment 2:
Collecting agent 12%, wherein the polyethylene glycol Glycol Oleic Acid Ester 5%, castor oil polyoxyethylene ether (EL class) 7%;
Antistatic additive 72%, lauryl alcohol phosphate polyoxyethylene ether sylvite (EP class) 50% wherein, lauryl alcohol polyoxyethylene phosphate sylvite (MPK class) 22%;
Smooth agent 16%, wherein triol ester 4%, high molecular weight polyether 10%, mineral oil 2%.
Embodiment 3:
Collecting agent 9%, polyethylene glycol laurate dibasic acid esters 5% wherein, aliphatic acid polyethenoxy ether (LAE-9 class) 4%;
Antistatic additive 78%, octadecanol phosphate kalium salt (PK class) 54% wherein, lauryl alcohol polyoxyethylene ether phosphate sylvite 24%;
Smooth agent 13%, wherein binary alcohol esters 30%, end capped polyether 15%, polybutene class 16%.
After the described ratio batching of above-mentioned three embodiment, the manufacture method of its spinning oil for terylene staple is:
With antistatic additive suction reactor, open and stir earlier, be warming up to about 50 ℃, stir, with collecting agent suction reactor, stir again, add smooth agent at last, keep about 50 ℃ of temperature, stir 30min, stir and finish, be cooled to about 40 ℃, blowing, filtration, packing are promptly.
The spinning oil for terylene staple of producing according to proportioning of the present invention and manufacture method can reach following quality index:
1, the white lotion of outward appearance (25 ℃)
2, pH value (10% aqueous solution, 20 ℃) 6.0-8.0
3, effective component content (%, 〉=) 30.0
4, stable one week of 2% aqueous solution is not stratified
Claims (5)
1, a kind of spinning oil for terylene staple, by flatness, collecting agent, antistatic additive is formed, and it is characterized in that the percentage by weight of each component is: smooth agent 10～20%, collecting agent 5～15%, antistatic additive 70～80%.
2, by the described spinning oil for terylene staple of claim 1, it is characterized in that described smooth agent can be mineral oil, double base alcohol ester, triol ester, quaternary alcohol ester, the mixture of one or more of high molecular weight polyether.
3, by the described spinning oil for terylene staple of claim 1, it is characterized in that described collecting agent can be the polyethylene glycol Glycol Oleic Acid Ester, aliphatic acid polyethenoxy ether, polyethylene glycol laurate dibasic acid esters, castor oil polyoxyethylene ether, the mixture of one or more in the octanol high-molecular weight atactic polyethers.
4, by the described spinning oil for terylene staple of claim 1, it is characterized in that described antistatic additive can be lauryl alcohol phosphate polyoxyethylene ether sylvite, the hexadecanol phosphate kalium salt, the octadecanol phosphate kalium salt, lauryl alcohol polyoxyethylene ether phosphate sylvite, the mixture of one or more in the amphoteric phosphate ammonium salt.
5, by claim 1 or 2,3, the manufacture method of 4 described spinning oil for terylene staple, it is characterized in that percentage by weight by each component, with the antistatic additive suction reactor of accurate measurement, be heated to 40～80 ℃ and stir, earlier again with in the collecting agent suction reactor, after stirring, add smooth agent, behind the stirring 30-50min, cooling, filter packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99124281 CN1257951A (en) | 1999-12-21 | 1999-12-21 | Polyester staple fiber spinning oil and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99124281 CN1257951A (en) | 1999-12-21 | 1999-12-21 | Polyester staple fiber spinning oil and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1257951A true CN1257951A (en) | 2000-06-28 |
Family
ID=5283365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99124281 Pending CN1257951A (en) | 1999-12-21 | 1999-12-21 | Polyester staple fiber spinning oil and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1257951A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101307564B (en) * | 2008-04-09 | 2011-04-20 | 张金惠 | Polyester staple fiber double-component assembled oil solution and preparation method |
| CN102321975A (en) * | 2011-07-26 | 2012-01-18 | 苏州晟德竹科技发展有限公司 | Oil agent for chopped polyester fiber |
| CN102851956A (en) * | 2012-08-30 | 2013-01-02 | 四川得阳特种新材料有限公司 | Method for improving production stability of polyphenylene sulfide short fibers |
| CN106939514A (en) * | 2017-04-25 | 2017-07-11 | 上海新浦特种助剂有限公司 | A kind of terylene FDY spinning oil |
| CN110528284A (en) * | 2019-09-19 | 2019-12-03 | 宁波民光新材料有限公司 | A kind of low-melting point polyester staple fiber finish and preparation method thereof |
| CN112647284A (en) * | 2020-12-17 | 2021-04-13 | 太仓旭云特种纤维科技有限公司 | PBO fiber carding oil |
-
1999
- 1999-12-21 CN CN 99124281 patent/CN1257951A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101307564B (en) * | 2008-04-09 | 2011-04-20 | 张金惠 | Polyester staple fiber double-component assembled oil solution and preparation method |
| CN102321975A (en) * | 2011-07-26 | 2012-01-18 | 苏州晟德竹科技发展有限公司 | Oil agent for chopped polyester fiber |
| CN102321975B (en) * | 2011-07-26 | 2012-10-10 | 苏州晟德竹科技发展有限公司 | Oil agent for chopped polyester fiber |
| CN102851956A (en) * | 2012-08-30 | 2013-01-02 | 四川得阳特种新材料有限公司 | Method for improving production stability of polyphenylene sulfide short fibers |
| CN102851956B (en) * | 2012-08-30 | 2024-02-13 | 四川得阳特种新材料有限公司 | Method for improving production stability of polyphenylene sulfide short fibers |
| CN106939514A (en) * | 2017-04-25 | 2017-07-11 | 上海新浦特种助剂有限公司 | A kind of terylene FDY spinning oil |
| CN110528284A (en) * | 2019-09-19 | 2019-12-03 | 宁波民光新材料有限公司 | A kind of low-melting point polyester staple fiber finish and preparation method thereof |
| CN112647284A (en) * | 2020-12-17 | 2021-04-13 | 太仓旭云特种纤维科技有限公司 | PBO fiber carding oil |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |