CN1355350A - Oiling agent for acrylic staple fiber - Google Patents
Oiling agent for acrylic staple fiber Download PDFInfo
- Publication number
- CN1355350A CN1355350A CN 00133326 CN00133326A CN1355350A CN 1355350 A CN1355350 A CN 1355350A CN 00133326 CN00133326 CN 00133326 CN 00133326 A CN00133326 A CN 00133326A CN 1355350 A CN1355350 A CN 1355350A
- Authority
- CN
- China
- Prior art keywords
- general formula
- finish
- acrylic
- alkyl
- spinning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000000835 fiber Substances 0.000 title abstract description 23
- 239000008041 oiling agent Substances 0.000 title abstract 2
- -1 fatty acid polyol ester Chemical class 0.000 claims abstract description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 6
- 239000000194 fatty acid Substances 0.000 claims abstract description 6
- 229930195729 fatty acid Natural products 0.000 claims abstract description 6
- 229920005862 polyol Polymers 0.000 claims abstract description 6
- 239000004359 castor oil Substances 0.000 claims abstract description 5
- 235000019438 castor oil Nutrition 0.000 claims abstract description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 3
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Chemical group 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 238000009987 spinning Methods 0.000 abstract description 12
- 229910019142 PO4 Chemical group 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000010452 phosphate Chemical group 0.000 abstract description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 4
- 239000002932 luster Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 210000002268 wool Anatomy 0.000 description 6
- 229920002972 Acrylic fiber Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 230000001427 coherent effect Effects 0.000 description 3
- 230000002079 cooperative effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 206010009866 Cold sweat Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XGKPLOKHSA-N [2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XGKPLOKHSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an oiling agent for spinning and spinning acrylic staple fibers, which is 10-25% of open-chain quaternary ammonium salt cationic surfactant and has a general formula of R110-25% of fatty acid polyol ester type nonionic surfactant of COOQ, and the general formula is PO (CH)2CH2O) nH, 0-8 percent of fatty alcohol-polyoxyethylene ether, and the balance of water, wherein R represents alkyl, X represents sulfate or phosphate, P represents castor oil, and Q represents polyalcohol (the weight percentage is the weight percentage)The tow has soft hand feeling, smoothness, bright luster and good spinnability. As a result, the quality and production efficiency of acrylic staple fiber can be improved.
Description
The present invention relates to a kind of finish of acrylic staples spinning, spinning usefulness.
Acrylic fiber is a kind of important chemical fibre, is one of synthetic fiber three big kinds.Copolymer by polyacrylonitrile or acrylonitrile and a small amount of other monomers makes.Because its hygroscopicity is little, poorly conductive, coefficient of friction is big, therefore must use finish to eliminate because of fricative static, adjusts coefficient of friction, guarantees carrying out smoothly of acrylic spinning and back processing.
Acrylic staples generally divides cotton type and two kinds of specifications of wool type, short-staple adopts cotton spinning apparatus processing, wool type fiber uses the wool spinning processing technology, the former has relatively high expectations to the spinnability of finish weaving processing, if the oil performance imperfection just can not pass through each manufacturing procedure such as blowing, comb and parallel cotton fibers prior to spinning, spun yarn smoothly, cause many, the easy broken ends of yarn fault, consume height, weaving efficient is low.And wool spinning processing is low relatively to the spinnability requirement of finish.Usually the acrylic staple fibre finish is made up of antistatic additive, lubricant and other surfactants, and the kinds of surface activating agent is together composite, learns from other's strong points to offset one's weaknesses the performance cooperative effect mutually.Present domestic acrylic staples finish is mostly with alkyl phosphate salt, alkyl polyoxyethylene phosphate salt and trihydroxyethyl methyl quaternary ammonium Methylsulfate makes antistatic host and other single agent are composited, as domestic TZ-48, YQM-3001 etc., Tai Lun-A280, the Tai Lun-A330 etc. of Japan also belong to this type of.U.S. Pat 4072617 discloses a kind of polyacrylic fibre oil, and it is made up of alkylphenol polyoxyethylene, fatty alcohol phosphate, mineral oil, fatty alcohol-polyoxyethylene ether, aliphatic alcohol polyethenoxy phosphate.With regard to present homemade polyacrylic fibre oil, because the component that finish adopted lacks characteristic, the cooperative effect shortcoming, most of finishes are used for wool type fiber and still can, but be used for short-staple, especially the wet spinning short-staple then can not satisfy the requirement of each manufacturing procedure of spinning.The finish of making antistatic host with the phosphate anion surfactant has hygroscopicity owing to phosphate, and its use is subjected to the influence of operating environment humiture bigger, and under the high humidity situation, this oil performance is not good, and the fiber that oils is clamminess.The quality of acrylic staple fibre is except the inherent quality of fiber itself, and the good and used finish of its spinnability also is inseparable, and therefore domestic part acrylic fiber production process factory still uses expensive import finish.
The object of the present invention is to provide a kind of cotton type, wool type acrylic staples Wesy of being applicable to, have excellent anti static behaviour, flexibility, suitable flatness, an oil for acrylic staples of coherent.
The object of the present invention is achieved like this:
Acrylic staples finish of the present invention is to be by structural formula:
Open chain quaternary ammonium salt cationic surfactant 10～25%, its general formula is R
1The polyol esters of fatty acids type non-ionic surface active agent 10～25% of COOQ, its general formula is PO (CH
2CH
2O) fatty alcohol-polyoxyethylene ether 0～8% of nH, surplus are the finish that water is formed, and R represents alkyl, and X represents sulfuric acid ester or phosphoric acid fat, and P represents castor oil, and Q represents polyalcohol, and above-mentioned percentage is weight percentage.
R in the open chain quaternary ammonium salt structure formula
1, R
2, R
3, R
4Be C
nH
2n+1Alkyl 1, R wherein
1Middle n=12～18, R
2, R
3, R
4Be methyl or ethyl, X is a sulfuric acid ester.
Its general formula is R
1The polyol esters of fatty acids of COOQ, R in the formula
1Be C
12～C
18Alkyl, Q can be sorbierite, glycerine, polyethylene glycol.
General formula is PO (CH
2CH
2O)
nThe Emulsifier EL-60 of H, P represents castor oil, n=90～200.
General formula is RO (CH
2CH
2O)
nThe polyoxyethylene ether of H, R represents C
12～C
18Alkyl, n=10～25.
The open chain quaternary cationics that uses can make acrylic fiber have excellent antistatic and flexibility.Use polyol esters of fatty acids type non-ionic surface active agent can make acrylic staple fibre have good flatness.Use can make acrylic staple fibre have good antistatic behaviour and coherent, uses fatty alcohol-polyoxyethylene ether can make the acrylic staple fibre coefficient of friction moderate and make the mutual compatibility of several components, and cooperative effect is strengthened.
Acrylic staple fibre finish of the present invention, excellent performance oils evenly the film strength height.This finish can be given acrylic staple fibre excellent antistatic, flexibility, suitable flatness, coherent, soft, smooth with the acrylic staple fibre of its production, gloss is bright, moderate, the good spinnability of frictional coefficient of fiber can be passed through each procedure of textile mills smoothly.Finish of the present invention can improve the product quality of acrylic staple fibre greatly.
Embodiment 1
13 parts of octadecyl dimethyl ethyl ethyl-sulfate quaternary ammonium salts, 12 parts of sorbitan monostearates, 8 parts of Emulsifier EL-60s (100), 2 parts of ethoxylated dodecyl alcohols (15) and 65 parts of water are added in the container, be warming up to about 70 ℃, stir about got final product in 40 minutes.
Several oil performance item compared of table 1 embodiment 1 comparative example 1 comparative example 2PH value 6.3 6.5 7.1 ionic sun/non-sun/non-the moon/non-stability of emulsion＞240h＞240h＞72h fiber is than resistance/Ω 5.44 * 10
71.72 * 10
81.88 * 10
9Friction mu
s0.3138 0.3241 0.3628
F/F μ
d0.2487 0.2542 0.2768 coefficient μ
s0.4168 0.4052 0.4413
F/M μ
d0.4288 it is less than multi-fibre rate/% 0.25～0.35 0.25～0.35 0.35～0.55 that oils that 0.4238 0.4671 finishing bathtray temperature/℃ 82 ± 2 82 ± 2 90 ± 3 surpass double-length
Annotate: comparative example 1 is a U.S. XF-2B finish, and comparative example 2 is homemade HT-1063.
Finish YH-202 excellent performance of the present invention as can be seen from Table 1, it is lower than resistance, and antistatic behaviour is particularly outstanding.
Embodiment 2
According to embodiment 1 described method, prepare finish in following component ratio.
Composition weight
Hexadecyldimethyl benzyl ammonium ethyl sulfuric acid ethyl ester quaternary ammonium salt 15
Sorbitan monooleate 15
Emulsifier EL-60 (100) 10
Fatty alcohol-polyoxyethylene ether (20) 5
Water 55
Qualitative data project implementation example 2 comparative examples 2 intensity CN/dtex 2.86 2.64 faults of the different finish producd fibers of table 2/mg/100g 8 12 oil-containings/% 0.30 0.39 directly stretches/% 38 44 curling several/10cm 43 39 yellow degree 10 10.7 weight are irregular/% 2.2 2.8 length variations/% 1-4 undercoat coefficient/% 1.6 2.6 card nailing neps/only/rice 0.2 0.6 soft astringent gloss are bright dim
As can be seen from Table 2, use the every performance of acrylic fiber of embodiment 2 finish YH-202 productions of the present invention significantly better than the acrylic fiber that adopts comparative example 2 homemade HT-1063 finishes to produce.
Embodiment 3
According to embodiment 1 described method, prepare finish in following component ratio.
Composition weight
Octadecyl dimethyl ethyl ethyl-sulfate quaternary ammonium salt 23
Sorbitan monostearate 20
Emulsifier EL-60 (150) 22
Water 35
The dim finished product of the 62.5 70.0 percentage of A-class goods % bright gloss of the 450 370 row yielding % of 97.5 93.5 classes of output Kg/ classes, 98.0 94.0 finished product gloss appearances is soft smooth astringent during the different finish results of use of table 3 contrast project embodiment 3 comparative examples 2 silver mixing irregularity % 2.0 2.5 grilling irregularity % 1.0 1.7 spinning end breaking rate roots/thousand ingots
Embodiment 4
According to embodiment 1 described method, prepare finish in following component ratio.
Composition weight
Octadecyl dimethyl ethyl ethyl-sulfate quaternary ammonium salt 20
Span60 16
Emulsifier EL-60 (150) 10
Fatty alcohol-polyoxyethylene ether (15) 8
Water 46
The different finish results of use of table 4 contrast project embodiment 4 comparative examples 2 silver mixing irregularity % 1.6 2.5 grilling card nailing neps only/the dim finished product of the 63.0 70.0 percentage of A-class goods % bright gloss of 96.0 93.5 row yielding %, 97.0 94.0 finished product gloss appearances is soft smooth astringent during gram 1.5 1.9 grilling irregularity % 1.2 1.7 spinning end breaking rate roots/thousand ingots
Claims (5)
1. acrylic staples finish is characterized in that by structural formula being:
Open chain quaternary ammonium salt cationic surfactant 10～25%, its general formula is R
1The polyol esters of fatty acids type non-ionic surface active agent 10～25% of COOQ, its general formula is PO (CH
2CH
2O) fatty alcohol-polyoxyethylene ether 0～8% of nH, surplus are the finish that water is formed, and R represents alkyl, and X represents sulfuric acid ester or phosphoric acid fat, and P represents castor oil, and Q represents polyalcohol, and above-mentioned percentage is weight percentage.
2. a kind of acrylic staples finish according to claim 1 is characterized in that R in the open chain quaternary ammonium salt structure formula
1, R
2, R
3, R
4Be C
nH
2n+1Alkyl 1, R wherein
1Middle n=12～18, R
2, R
3, R
4Be methyl or ethyl, X is a sulfuric acid ester.
3. a kind of acrylic staples finish according to claim 1 is characterized in that its general formula is R
1The polyol esters of fatty acids of COOQ, R in the formula
1Be C
12～C
18Alkyl, Q can be sorbierite, glycerine, polyethylene glycol.
4. a kind of acrylic staples finish according to claim 1 is characterized in that general formula is PO (CH
2CH
2O)
nThe Emulsifier EL-60 of H, P represents castor oil, n=90～200.
5. a kind of acrylic staples finish according to claim 1 is characterized in that general formula is RO (CH
2CH
2O)
nThe polyoxyethylene ether of H, R represents C
12～C
18Alkyl, n=10～25.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001333267A CN1150364C (en) | 2000-11-24 | 2000-11-24 | Oiling agent for acrylic staple fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB001333267A CN1150364C (en) | 2000-11-24 | 2000-11-24 | Oiling agent for acrylic staple fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1355350A true CN1355350A (en) | 2002-06-26 |
| CN1150364C CN1150364C (en) | 2004-05-19 |
Family
ID=4595655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB001333267A Expired - Lifetime CN1150364C (en) | 2000-11-24 | 2000-11-24 | Oiling agent for acrylic staple fiber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1150364C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101569821B (en) * | 2009-05-31 | 2011-08-31 | 中国矿业大学(北京) | Gas absorbent for reducing gas concentration |
| CN102619084A (en) * | 2011-01-30 | 2012-08-01 | 大亚科技股份有限公司 | Polypropylene spinning oil composition for cigarette and preparation method thereof |
| CN101802295B (en) * | 2007-09-10 | 2013-03-06 | 松本油脂制药株式会社 | Oil for friction false twisting of synthetic fiber and use of the same |
| CN102978910A (en) * | 2012-12-03 | 2013-03-20 | 吴江市鼎佳纺织有限公司 | Acrylic fiber oiling agent |
| CN103614909A (en) * | 2013-11-22 | 2014-03-05 | 张家港市健华针纺织品有限公司 | Special oiling agent for acrylic yarn knitting spinning and preparation method thereof |
| CN103882547A (en) * | 2014-02-27 | 2014-06-25 | 宁波中新腈纶有限公司 | Flat acrylic fiber and production method thereof |
| CN104562664A (en) * | 2015-01-27 | 2015-04-29 | 安庆五宁精细化工有限责任公司 | Environment-friendly acrylic spinning oil |
| CN104911915A (en) * | 2015-06-29 | 2015-09-16 | 宁波懋盛纺织助剂科技有限公司 | Polyester pre-orient yarn oiling agent |
-
2000
- 2000-11-24 CN CNB001333267A patent/CN1150364C/en not_active Expired - Lifetime
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101802295B (en) * | 2007-09-10 | 2013-03-06 | 松本油脂制药株式会社 | Oil for friction false twisting of synthetic fiber and use of the same |
| CN101569821B (en) * | 2009-05-31 | 2011-08-31 | 中国矿业大学(北京) | Gas absorbent for reducing gas concentration |
| CN102619084A (en) * | 2011-01-30 | 2012-08-01 | 大亚科技股份有限公司 | Polypropylene spinning oil composition for cigarette and preparation method thereof |
| CN102619084B (en) * | 2011-01-30 | 2013-11-20 | 大亚科技股份有限公司 | Polypropylene spinning oil composition for cigarette and preparation method thereof |
| CN102978910A (en) * | 2012-12-03 | 2013-03-20 | 吴江市鼎佳纺织有限公司 | Acrylic fiber oiling agent |
| CN103614909A (en) * | 2013-11-22 | 2014-03-05 | 张家港市健华针纺织品有限公司 | Special oiling agent for acrylic yarn knitting spinning and preparation method thereof |
| CN103882547A (en) * | 2014-02-27 | 2014-06-25 | 宁波中新腈纶有限公司 | Flat acrylic fiber and production method thereof |
| CN104562664A (en) * | 2015-01-27 | 2015-04-29 | 安庆五宁精细化工有限责任公司 | Environment-friendly acrylic spinning oil |
| CN104911915A (en) * | 2015-06-29 | 2015-09-16 | 宁波懋盛纺织助剂科技有限公司 | Polyester pre-orient yarn oiling agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1150364C (en) | 2004-05-19 |
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Granted publication date: 20040519 |