CN111655650A - 夹层玻璃用中间膜和夹层玻璃 - Google Patents
夹层玻璃用中间膜和夹层玻璃 Download PDFInfo
- Publication number
- CN111655650A CN111655650A CN201980010737.2A CN201980010737A CN111655650A CN 111655650 A CN111655650 A CN 111655650A CN 201980010737 A CN201980010737 A CN 201980010737A CN 111655650 A CN111655650 A CN 111655650A
- Authority
- CN
- China
- Prior art keywords
- layer
- laminated glass
- interlayer film
- cured product
- meth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005340 laminated glass Substances 0.000 title claims abstract description 177
- 239000011229 interlayer Substances 0.000 title claims abstract description 162
- 239000010410 layer Substances 0.000 claims abstract description 316
- 150000001875 compounds Chemical class 0.000 claims abstract description 55
- 238000005259 measurement Methods 0.000 claims abstract description 37
- 229920005989 resin Polymers 0.000 claims description 97
- 239000011347 resin Substances 0.000 claims description 97
- 238000003860 storage Methods 0.000 claims description 19
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims description 16
- 238000009413 insulation Methods 0.000 abstract description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 79
- -1 5-hydroxypentyl Chemical group 0.000 description 54
- 239000002245 particle Substances 0.000 description 49
- 239000000203 mixture Substances 0.000 description 44
- 239000003795 chemical substances by application Substances 0.000 description 42
- 239000011521 glass Substances 0.000 description 37
- 239000004014 plasticizer Substances 0.000 description 36
- 239000003963 antioxidant agent Substances 0.000 description 30
- 230000003078 antioxidant effect Effects 0.000 description 28
- 229920002554 vinyl polymer Polymers 0.000 description 28
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 27
- 239000011354 acetal resin Substances 0.000 description 25
- 229910052751 metal Inorganic materials 0.000 description 25
- 239000002184 metal Substances 0.000 description 25
- 229920006324 polyoxymethylene Polymers 0.000 description 25
- 239000000126 substance Substances 0.000 description 24
- 150000003839 salts Chemical class 0.000 description 21
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 20
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 15
- 238000012216 screening Methods 0.000 description 14
- 229920005992 thermoplastic resin Polymers 0.000 description 14
- 229920000058 polyacrylate Polymers 0.000 description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- 230000021736 acetylation Effects 0.000 description 11
- 238000006640 acetylation reaction Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 description 11
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 239000004372 Polyvinyl alcohol Substances 0.000 description 10
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
- 229910044991 metal oxide Inorganic materials 0.000 description 10
- 150000004706 metal oxides Chemical class 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- 238000006359 acetalization reaction Methods 0.000 description 9
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 description 9
- 239000005020 polyethylene terephthalate Substances 0.000 description 9
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 8
- 229920000535 Tan II Polymers 0.000 description 8
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000011342 resin composition Substances 0.000 description 7
- 238000010998 test method Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 6
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 150000001299 aldehydes Chemical class 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 6
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 description 5
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- LKKPNUDVOYAOBB-UHFFFAOYSA-N naphthalocyanine Chemical class N1C(N=C2C3=CC4=CC=CC=C4C=C3C(N=C3C4=CC5=CC=CC=C5C=C4C(=N4)N3)=N2)=C(C=C2C(C=CC=C2)=C2)C2=C1N=C1C2=CC3=CC=CC=C3C=C2C4=N1 LKKPNUDVOYAOBB-UHFFFAOYSA-N 0.000 description 5
- 150000002895 organic esters Chemical class 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 229920001187 thermosetting polymer Polymers 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 4
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 4
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 4
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000010734 process oil Substances 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
- 229910001930 tungsten oxide Inorganic materials 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 229940042596 viscoat Drugs 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- JEYLQCXBYFQJRO-UHFFFAOYSA-N 2-[2-[2-(2-ethylbutanoyloxy)ethoxy]ethoxy]ethyl 2-ethylbutanoate Chemical compound CCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CC JEYLQCXBYFQJRO-UHFFFAOYSA-N 0.000 description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical group OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 125000004036 acetal group Chemical group 0.000 description 3
- 150000001241 acetals Chemical class 0.000 description 3
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Natural products C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 238000004049 embossing Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000005329 float glass Substances 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 229920002725 thermoplastic elastomer Polymers 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 2
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 2
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 2
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- LEVFXWNQQSSNAC-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexoxyphenol Chemical compound OC1=CC(OCCCCCC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 LEVFXWNQQSSNAC-UHFFFAOYSA-N 0.000 description 2
- NQXNYVAALXGLQT-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)phenyl]fluoren-9-yl]phenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1C1(C=2C=CC(OCCO)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 NQXNYVAALXGLQT-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 2
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 2
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 2
- UZDMJPAQQFSMMV-UHFFFAOYSA-N 4-oxo-4-(2-prop-2-enoyloxyethoxy)butanoic acid Chemical compound OC(=O)CCC(=O)OCCOC(=O)C=C UZDMJPAQQFSMMV-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 2
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 2
- ZEFSGHVBJCEKAZ-UHFFFAOYSA-N bis(2,4-ditert-butyl-6-methylphenyl) ethyl phosphite Chemical compound CC=1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1OP(OCC)OC1=C(C)C=C(C(C)(C)C)C=C1C(C)(C)C ZEFSGHVBJCEKAZ-UHFFFAOYSA-N 0.000 description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 150000004292 cyclic ethers Chemical group 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 2
- 239000011654 magnesium acetate Substances 0.000 description 2
- 229940069446 magnesium acetate Drugs 0.000 description 2
- 235000011285 magnesium acetate Nutrition 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- JOADGALWHMAAKM-UHFFFAOYSA-L magnesium;2-ethylbutanoate Chemical compound [Mg+2].CCC(CC)C([O-])=O.CCC(CC)C([O-])=O JOADGALWHMAAKM-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- YIMHRDBSVCPJOV-UHFFFAOYSA-N n'-(2-ethoxyphenyl)-n-(2-ethylphenyl)oxamide Chemical compound CCOC1=CC=CC=C1NC(=O)C(=O)NC1=CC=CC=C1CC YIMHRDBSVCPJOV-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229940059574 pentaerithrityl Drugs 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- KJYSXRBJOSZLEL-UHFFFAOYSA-N (2,4-ditert-butylphenyl) 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 KJYSXRBJOSZLEL-UHFFFAOYSA-N 0.000 description 1
- LMODBTYAMBSWQE-UHFFFAOYSA-N (2-hydroxyphenyl)methanetriol Chemical compound OC1=CC=CC=C1C(O)(O)O LMODBTYAMBSWQE-UHFFFAOYSA-N 0.000 description 1
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- JKXUAKAQFISCCT-UHFFFAOYSA-M (4-benzoylphenyl)methyl-dimethyl-(2-prop-2-enoyloxyethyl)azanium;bromide Chemical compound [Br-].C1=CC(C[N+](C)(CCOC(=O)C=C)C)=CC=C1C(=O)C1=CC=CC=C1 JKXUAKAQFISCCT-UHFFFAOYSA-M 0.000 description 1
- UROHSXQUJQQUOO-UHFFFAOYSA-M (4-benzoylphenyl)methyl-trimethylazanium;chloride Chemical compound [Cl-].C1=CC(C[N+](C)(C)C)=CC=C1C(=O)C1=CC=CC=C1 UROHSXQUJQQUOO-UHFFFAOYSA-M 0.000 description 1
- ZXHDVRATSGZISC-UHFFFAOYSA-N 1,2-bis(ethenoxy)ethane Chemical compound C=COCCOC=C ZXHDVRATSGZISC-UHFFFAOYSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 229940035437 1,3-propanediol Drugs 0.000 description 1
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- KZVBBTZJMSWGTK-UHFFFAOYSA-N 1-[2-(2-butoxyethoxy)ethoxy]butane Chemical compound CCCCOCCOCCOCCCC KZVBBTZJMSWGTK-UHFFFAOYSA-N 0.000 description 1
- VKQJCUYEEABXNK-UHFFFAOYSA-N 1-chloro-4-propoxythioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C(OCCC)=CC=C2Cl VKQJCUYEEABXNK-UHFFFAOYSA-N 0.000 description 1
- DLZBUNUDESZERL-UHFFFAOYSA-N 1-o-heptyl 6-o-nonyl hexanedioate Chemical compound CCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCC DLZBUNUDESZERL-UHFFFAOYSA-N 0.000 description 1
- STFXXRRQKFUYEU-UHFFFAOYSA-N 16-methylheptadecyl prop-2-enoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C=C STFXXRRQKFUYEU-UHFFFAOYSA-N 0.000 description 1
- XCTNDJAFNBCVOM-UHFFFAOYSA-N 1h-imidazo[4,5-b]pyridin-2-ylmethanamine Chemical compound C1=CC=C2NC(CN)=NC2=N1 XCTNDJAFNBCVOM-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- BRXKVEIJEXJBFF-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)-3-methylbutane-1,4-diol Chemical compound OCC(C)C(CO)(CO)CO BRXKVEIJEXJBFF-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- BRKORVYTKKLNKX-UHFFFAOYSA-N 2,4-di(propan-2-yl)thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC(C(C)C)=C3SC2=C1 BRKORVYTKKLNKX-UHFFFAOYSA-N 0.000 description 1
- UXCIJKOCUAQMKD-UHFFFAOYSA-N 2,4-dichlorothioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(Cl)=CC(Cl)=C3SC2=C1 UXCIJKOCUAQMKD-UHFFFAOYSA-N 0.000 description 1
- LZHUBCULTHIFNO-UHFFFAOYSA-N 2,4-dihydroxy-1,5-bis[4-(2-hydroxyethoxy)phenyl]-2,4-dimethylpentan-3-one Chemical compound C=1C=C(OCCO)C=CC=1CC(C)(O)C(=O)C(O)(C)CC1=CC=C(OCCO)C=C1 LZHUBCULTHIFNO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- CKQNDABUGIXFCL-UHFFFAOYSA-N 2-(2-octanoyloxyethoxy)ethyl octanoate Chemical compound CCCCCCCC(=O)OCCOCCOC(=O)CCCCCCC CKQNDABUGIXFCL-UHFFFAOYSA-N 0.000 description 1
- IEJVNEXYOQXMNG-UHFFFAOYSA-N 2-(4-propylphenoxy)ethyl prop-2-enoate Chemical compound CCCC1=CC=C(OCCOC(=O)C=C)C=C1 IEJVNEXYOQXMNG-UHFFFAOYSA-N 0.000 description 1
- CYCYSJGJOIJFEP-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-dipentylphenol Chemical compound CCCCCC1=CC(CCCCC)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 CYCYSJGJOIJFEP-UHFFFAOYSA-N 0.000 description 1
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 1
- PUBNJSZGANKUGX-UHFFFAOYSA-N 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=C(C)C=C1 PUBNJSZGANKUGX-UHFFFAOYSA-N 0.000 description 1
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 description 1
- UNNGUFMVYQJGTD-UHFFFAOYSA-N 2-Ethylbutanal Chemical compound CCC(CC)C=O UNNGUFMVYQJGTD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- GCDUWJFWXVRGSM-UHFFFAOYSA-N 2-[2-(2-heptanoyloxyethoxy)ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCC GCDUWJFWXVRGSM-UHFFFAOYSA-N 0.000 description 1
- YJGHMLJGPSVSLF-UHFFFAOYSA-N 2-[2-(2-octanoyloxyethoxy)ethoxy]ethyl octanoate Chemical compound CCCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCCC YJGHMLJGPSVSLF-UHFFFAOYSA-N 0.000 description 1
- NBBXSWKUFZWAMU-UHFFFAOYSA-N 2-[2-(dimethylamino)ethyl]benzoic acid Chemical compound CN(C)CCC1=CC=CC=C1C(O)=O NBBXSWKUFZWAMU-UHFFFAOYSA-N 0.000 description 1
- SSKNCQWPZQCABD-UHFFFAOYSA-N 2-[2-[2-(2-heptanoyloxyethoxy)ethoxy]ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOCCOC(=O)CCCCCC SSKNCQWPZQCABD-UHFFFAOYSA-N 0.000 description 1
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 1
- YQZZHMXSIYMFDK-UHFFFAOYSA-N 2-[bis(2-prop-2-enoyloxyethoxy)phosphoryloxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOP(=O)(OCCOC(=O)C=C)OCCOC(=O)C=C YQZZHMXSIYMFDK-UHFFFAOYSA-N 0.000 description 1
- PQJZHMCWDKOPQG-UHFFFAOYSA-N 2-anilino-2-oxoacetic acid Chemical group OC(=O)C(=O)NC1=CC=CC=C1 PQJZHMCWDKOPQG-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 description 1
- LZHCVNIARUXHAL-UHFFFAOYSA-N 2-tert-butyl-4-ethylphenol Chemical compound CCC1=CC=C(O)C(C(C)(C)C)=C1 LZHCVNIARUXHAL-UHFFFAOYSA-N 0.000 description 1
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 1
- ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- NCAVPEPBIJTYSO-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate;2-(oxiran-2-ylmethoxymethyl)oxirane Chemical compound C1OC1COCC1CO1.OCCCCOC(=O)C=C NCAVPEPBIJTYSO-UHFFFAOYSA-N 0.000 description 1
- IKVYHNPVKUNCJM-UHFFFAOYSA-N 4-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C(C(C)C)=CC=C2 IKVYHNPVKUNCJM-UHFFFAOYSA-N 0.000 description 1
- 125000004864 4-thiomethylphenyl group Chemical group 0.000 description 1
- ZUDPXPYGTYNSCK-UHFFFAOYSA-N 6-(1-hexylcyclohexyl)oxy-6-oxohexanoic acid Chemical compound OC(=O)CCCCC(=O)OC1(CCCCCC)CCCCC1 ZUDPXPYGTYNSCK-UHFFFAOYSA-N 0.000 description 1
- GPZYYYGYCRFPBU-UHFFFAOYSA-N 6-Hydroxyflavone Chemical compound C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 GPZYYYGYCRFPBU-UHFFFAOYSA-N 0.000 description 1
- KEOUIRVJRXECRC-UHFFFAOYSA-N 6-[2-(2-butoxyethoxy)ethoxy]-6-oxohexanoic acid Chemical compound CCCCOCCOCCOC(=O)CCCCC(O)=O KEOUIRVJRXECRC-UHFFFAOYSA-N 0.000 description 1
- OIUGWVWLEGLAGH-UHFFFAOYSA-N 6-nonoxy-6-oxohexanoic acid Chemical class CCCCCCCCCOC(=O)CCCCC(O)=O OIUGWVWLEGLAGH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- ONOVRUOVXNSEDQ-UHFFFAOYSA-N C(C)(C)(C)C1=CC=C(C(=C1)C(C)(C)C)OC(C(CCCC)CC)O[P] Chemical compound C(C)(C)(C)C1=CC=C(C(=C1)C(C)(C)C)OC(C(CCCC)CC)O[P] ONOVRUOVXNSEDQ-UHFFFAOYSA-N 0.000 description 1
- GCYAYYOWQIFPNL-UHFFFAOYSA-N C(CCC)(=O)O.C(C)(C)(C)C1=C(C=CC=C1)O.C(C)(C)(C)C1=C(C=CC=C1)O.C(CO)O Chemical compound C(CCC)(=O)O.C(C)(C)(C)C1=C(C=CC=C1)O.C(C)(C)(C)C1=C(C=CC=C1)O.C(CO)O GCYAYYOWQIFPNL-UHFFFAOYSA-N 0.000 description 1
- WMONOXOCMIPNNU-UHFFFAOYSA-N C=CC(=O)OCCCC(O)COC(=O)C1=CC=CC=C1C(O)=O Chemical compound C=CC(=O)OCCCC(O)COC(=O)C1=CC=CC=C1C(O)=O WMONOXOCMIPNNU-UHFFFAOYSA-N 0.000 description 1
- NJOHHIQDINJEMH-UHFFFAOYSA-N CC(C(CC)=O)C1=CC=C(C=C1)N1CCOCC1 Chemical compound CC(C(CC)=O)C1=CC=C(C=C1)N1CCOCC1 NJOHHIQDINJEMH-UHFFFAOYSA-N 0.000 description 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- ZGFPUTOTEJOSAY-UHFFFAOYSA-N FC1=C([Ti])C(F)=CC=C1N1C=CC=C1 Chemical compound FC1=C([Ti])C(F)=CC=C1N1C=CC=C1 ZGFPUTOTEJOSAY-UHFFFAOYSA-N 0.000 description 1
- FEXQDZTYJVXMOS-UHFFFAOYSA-N Isopropyl benzoate Chemical compound CC(C)OC(=O)C1=CC=CC=C1 FEXQDZTYJVXMOS-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NQSMEZJWJJVYOI-UHFFFAOYSA-N Methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 NQSMEZJWJJVYOI-UHFFFAOYSA-N 0.000 description 1
- BENNPBRBSFRLGP-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCC Chemical compound OP(O)OP(O)O.C(CCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCC BENNPBRBSFRLGP-UHFFFAOYSA-N 0.000 description 1
- MOABYHZDQQELLG-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCC Chemical compound OP(O)OP(O)O.C(CCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCC MOABYHZDQQELLG-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 1
- OFSAUHSCHWRZKM-UHFFFAOYSA-N Padimate A Chemical compound CC(C)CCOC(=O)C1=CC=C(N(C)C)C=C1 OFSAUHSCHWRZKM-UHFFFAOYSA-N 0.000 description 1
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- LFOXEOLGJPJZAA-UHFFFAOYSA-N [(2,6-dimethoxybenzoyl)-(2,4,4-trimethylpentyl)phosphoryl]-(2,6-dimethoxyphenyl)methanone Chemical compound COC1=CC=CC(OC)=C1C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)C1=C(OC)C=CC=C1OC LFOXEOLGJPJZAA-UHFFFAOYSA-N 0.000 description 1
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- DBHQYYNDKZDVTN-UHFFFAOYSA-N [4-(4-methylphenyl)sulfanylphenyl]-phenylmethanone Chemical compound C1=CC(C)=CC=C1SC1=CC=C(C(=O)C=2C=CC=CC=2)C=C1 DBHQYYNDKZDVTN-UHFFFAOYSA-N 0.000 description 1
- IDLJKTNBZKSHIY-UHFFFAOYSA-N [4-(diethylamino)phenyl]-phenylmethanone Chemical compound C1=CC(N(CC)CC)=CC=C1C(=O)C1=CC=CC=C1 IDLJKTNBZKSHIY-UHFFFAOYSA-N 0.000 description 1
- BEUGBYXJXMVRFO-UHFFFAOYSA-N [4-(dimethylamino)phenyl]-phenylmethanone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=CC=C1 BEUGBYXJXMVRFO-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 229920003054 adipate polyester Polymers 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- VQNRMLCRMNVBBP-UHFFFAOYSA-N aniline;oxalic acid Chemical group OC(=O)C(O)=O.NC1=CC=CC=C1 VQNRMLCRMNVBBP-UHFFFAOYSA-N 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- IHTSDBYPAZEUOP-UHFFFAOYSA-N bis(2-butoxyethyl) hexanedioate Chemical compound CCCCOCCOC(=O)CCCCC(=O)OCCOCCCC IHTSDBYPAZEUOP-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- KKPMZLPPEXRJOM-UHFFFAOYSA-N butane-1,3-diol;hexanedioic acid Chemical compound CC(O)CCO.OC(=O)CCCCC(O)=O KKPMZLPPEXRJOM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 229940100539 dibutyl adipate Drugs 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 229940031769 diisobutyl adipate Drugs 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- CQQJGTPWCKCEOQ-UHFFFAOYSA-L magnesium dipropionate Chemical compound [Mg+2].CCC([O-])=O.CCC([O-])=O CQQJGTPWCKCEOQ-UHFFFAOYSA-L 0.000 description 1
- OJXOOFXUHZAXLO-UHFFFAOYSA-M magnesium;1-bromo-3-methanidylbenzene;bromide Chemical compound [Mg+2].[Br-].[CH2-]C1=CC=CC(Br)=C1 OJXOOFXUHZAXLO-UHFFFAOYSA-M 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- ZBNMOUGFCKAGGQ-UHFFFAOYSA-N n'-(5-tert-butyl-2-ethoxyphenyl)-n-(2-ethylphenyl)oxamide Chemical compound CCOC1=CC=C(C(C)(C)C)C=C1NC(=O)C(=O)NC1=CC=CC=C1CC ZBNMOUGFCKAGGQ-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229950002083 octabenzone Drugs 0.000 description 1
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000005461 organic phosphorous group Chemical group 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- YNXCGLKMOXLBOD-UHFFFAOYSA-N oxolan-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CCCO1 YNXCGLKMOXLBOD-UHFFFAOYSA-N 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- LCDOENXNMQXGFS-UHFFFAOYSA-N phenoxybenzene;prop-2-enoic acid Chemical compound OC(=O)C=C.C=1C=CC=CC=1OC1=CC=CC=C1 LCDOENXNMQXGFS-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- BWILYWWHXDGKQA-UHFFFAOYSA-M potassium propanoate Chemical compound [K+].CCC([O-])=O BWILYWWHXDGKQA-UHFFFAOYSA-M 0.000 description 1
- 235000010332 potassium propionate Nutrition 0.000 description 1
- 239000004331 potassium propionate Substances 0.000 description 1
- LYWPJPGMDLOUDX-UHFFFAOYSA-M potassium;2-ethylbutanoate Chemical compound [K+].CCC(CC)C([O-])=O LYWPJPGMDLOUDX-UHFFFAOYSA-M 0.000 description 1
- UFUASNAHBMBJIX-UHFFFAOYSA-N propan-1-one Chemical compound CC[C]=O UFUASNAHBMBJIX-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000003329 sebacic acid derivatives Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- MXNUCYGENRZCBO-UHFFFAOYSA-M sodium;ethene;2-methylprop-2-enoate Chemical compound [Na+].C=C.CC(=C)C([O-])=O MXNUCYGENRZCBO-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- MVQLEZWPIWKLBY-UHFFFAOYSA-N tert-butyl 2-benzoylbenzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 MVQLEZWPIWKLBY-UHFFFAOYSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000001845 vibrational spectrum Methods 0.000 description 1
- 239000005322 wire mesh glass Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10559—Shape of the cross-section
- B32B17/10577—Surface roughness
- B32B17/10587—Surface roughness created by embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10678—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising UV absorbers or stabilizers, e.g. antioxidants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10688—Adjustment of the adherence to the glass layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10706—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer being photo-polymerized
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10743—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
- B32B7/022—Mechanical properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/066—Copolymers with monomers not covered by C08L33/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/162—Selection of materials
- G10K11/168—Plural layers of different materials, e.g. sandwiches
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/102—Oxide or hydroxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/10—Inorganic particles
- B32B2264/105—Metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/72—Cured, e.g. vulcanised, cross-linked
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/10—Properties of the layers or laminate having particular acoustical properties
- B32B2307/102—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
- B32B2315/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/10—Trains
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/12—Ships
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/18—Aircraft
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F120/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Multimedia (AREA)
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
Abstract
本发明提供能够在10℃~30℃的广温度范围提高隔音性的夹层玻璃用中间膜。本发明的夹层玻璃用中间膜为具有1层结构或2层以上结构的夹层玻璃用中间膜,并且具备包含固化物的层,所述固化物是使光固化性化合物或湿固化性化合物固化而得的固化物,所述包含固化物的层在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为‑50℃以上30℃以下,并且在所述tanδ的峰值温度下tanδ为2.0以上。
Description
技术领域
本发明涉及用于得到夹层玻璃的夹层玻璃用中间膜。此外,本发明涉及使用了所述夹层玻璃用中间膜的夹层玻璃。
背景技术
夹层玻璃,即使受到外部冲击而破损,玻璃的碎片的飞散量也较少,安全性优异。因此,所述夹层玻璃广泛使用于车辆、铁道车辆、航天器、船舶和建筑物等。所述夹层玻璃,通过在两个玻璃板间夹入夹层玻璃用中间膜而制造。
作为所述夹层玻璃用中间膜的一个实例,下述的专利文献1中,公开了:具备由包含选自热塑性树脂和热固化性树脂中的至少1种树脂(a1)的组合物(A)形成的隔音层的中间膜。所述组合物成形为厚度0.8mm的片材的动态粘弹性在频率0.3Hz和拉伸模式下进行测定时得到的tanδ在温度TA(℃)具有最大值。所述动态粘弹性的测定中,TA(℃)在-50~50℃的范围内,TA(℃)下的tanδ为2.5以上。
专利文献1中,作为所述热塑性树脂,举出了:聚乙烯醇缩醛、聚乙烯醇、聚氨酯、聚羧酸乙烯酯、烯烃-羧酸乙烯酯共聚物、聚氨酯弹性体、聚酯弹性体、苯乙烯-二烯嵌段共聚物和氯化聚烯烃。作为所述热固化性树脂,举出了:环氧类树脂、酚类树脂、氨基甲酸酯类树脂、三聚氰胺树脂和不饱和聚酯类树脂。
此外,专利文献1中,公开了所述的中间膜的隔音性提高。专利文献1的实施例中,作为0℃、5℃、10℃、15℃、20℃、25℃、30℃、35℃和40℃的温度下的声音透过损失的测定结果,公开了声音透过损失的平均值最大的温度和声音透过损失的平均值最大的温度下的声音透过损失(多个频率下的平均值)。
此外,在下述的专利文献2中,公开了夹层玻璃中间膜用光固化性树脂组合物。该光固化性树脂组合物含有(甲基)丙烯酸类聚合物、甲基丙烯酸单体和光聚合引发剂。专利文献2中,公开了能够得到从外部施加冲击时不易破裂的夹层玻璃。
现有技术文献
专利文献
专利文献1:WO2017/170259A1
专利文献2:WO2017/209013A1
发明内容
发明所解决的技术问题
使用了中间膜的夹层玻璃用于各种温度环境下。在使用了以往的中间膜的夹层玻璃中,有时无法在广温度范围内提高隔音性。即使在特定的一个温度中隔音性较高的夹层玻璃的情况下,在与该温度不同的温度下使用夹层玻璃时,有时隔音性降低。
此外,专利文献1中,公开了所述的中间膜的隔音性提高。然而,专利文献1中,评价了0℃、5℃、10℃、15℃、20℃、25℃、30℃、35℃和40℃的温度下的声音透过损失,但未公开所有温度下的声音透过损失的结果。专利文献1中,未公开在广温度范围内提高隔音性的实施例。
此外,专利文献2中,在所述的光固化性树脂组合物中,公开了能够得到从外部施加冲击时不易破裂的夹层玻璃,但是对于隔音性未给出记载。
本发明的目的在于,提供能够在10℃~30℃的广温度范围提高隔音性的夹层玻璃用中间膜。此外,本发明的目的在于,提供使用了所述夹层玻璃用中间膜的夹层玻璃。
解决问题的技术手段
根据本发明的广泛方案,提供夹层玻璃用中间膜(以下,有时记载为中间膜),其为具有1层结构或2层以上结构的夹层玻璃用中间膜,所述中间膜具备包含固化物的层,所述固化物是使光固化性化合物或者湿固化性化合物固化而得的固化物,或,使具有(甲基)丙烯酰基的固化性化合物固化而得的固化物,所述包含固化物的层在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为-50℃以上30℃以下,并且在所述tanδ的峰值温度下tanδ为2.0以上。
本发明的中间膜的一个特定方案中,所述固化物是使光固化性化合物固化而得的固化物。
本发明的中间膜的一个特定方案中,所述包含固化物的层在100℃下的储能模量G’为5.0×103Pa以上。
本发明的中间膜的一个特定方案中,所述包含固化物的层在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为-30℃以上20℃以下。
本发明的中间膜的一个特定方案中,该中间膜为具有2层以上结构的夹层玻璃用中间膜,所述中间膜具备所述包含与固化物不同的树脂的层。
本发明的中间膜的一个特定方案中,为具有2层以上结构的夹层玻璃用中间膜,所述中间膜具备所述包含与固化物不同的树脂的层,所述中间膜在频率为1Hz并且基于剪切模式的粘弹性测定中,所述包含与固化物不同的树脂的层的tanδ的峰值温度为-100℃以上100℃以下,所述中间膜在频率为1Hz并且基于剪切模式的粘弹性测定中的所述包含固化物的层在tanδ的峰值温度下的tanδ相对于所述包含与固化物不同的树脂的层在tanδ的峰值温度下的tanδ的比为2.0以上10.0以下。
根据本发明的广泛方案,提供夹层玻璃,其具备第1夹层玻璃部件、第2夹层玻璃部件以及所述夹层玻璃用中间膜,在所述第1夹层玻璃部件和所述第2夹层玻璃部件之间配置有所述夹层玻璃用中间膜。
发明的效果
本发明的夹层玻璃用中间膜具有1层结构或2层以上结构。本发明的夹层玻璃用中间膜具备包含固化物的层。本发明的夹层玻璃用中间膜中,所述固化物是使光固化性化合物或者湿固化性化合物固化而得的固化物,或,使具有(甲基)丙烯酰基的固化性化合物固化而得的固化物。本发明的夹层玻璃用中间膜中,所述固化物在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为-50℃以上30℃以下,并且在所述tanδ的峰值温度下tanδ为2.0以上。本发明的夹层玻璃用中间膜中,由于具备所述的构成,因此能够在10℃~30℃的广温度范围提高隔音性。
附图说明
[图1]图1为示意性地表示本发明的第1实施方式的夹层玻璃用中间膜的截面图。
[图2]图2为示意性地表示本发明的第2实施方式的夹层玻璃用中间膜的截面图。
[图3]图3为示意性地表示使用了图1表示的夹层玻璃用中间膜的夹层玻璃的一个实例的截面图。
[图4]图4为示意性地表示使用了图2表示的夹层玻璃用中间膜的夹层玻璃的一个实例的截面图。
本发明的具体实施方式
以下,对于本发明详细地进行说明。
(夹层玻璃用中间膜)
本发明的夹层玻璃用中间膜(以下,有时记载为中间膜)具有1层结构或2层以上结构。
本发明的中间膜具备包含固化物的层。本发明的中间膜中,所述固化物是使光固化性化合物或者湿固化性化合物固化而得的固化物,或,使具有(甲基)丙烯酰基的固化性化合物固化而得的固化物。
本发明的中间膜中,所述固化性化合物可以为光固化性化合物或湿固化性化合物或具有(甲基)丙烯酰基的固化性化合物。此外,具有(甲基)丙烯酰基的固化性化合物可以为光固化性化合物、湿固化性化合物、或与光固化性化合物和湿固化性化合物这两者不同的固化性化合物。通常而言,具有(甲基)丙烯酰基的固化性化合物,由于具有(甲基)丙烯酰基,因此通过光的照射而固化。
所述包含固化物的层中包含的所述固化物通常为树脂。因此,有时将所述包含固化物的层记载为第1树脂层。
本发明的中间膜中,所述包含固化物的层在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为-50℃以上30℃以下,并且在所述tanδ的峰值温度下tanδ(1)为2.0以上。
本发明的中间膜中,由于具备所述的构成,因此能够在10℃~30℃的广温度范围提高隔音性。例如,不仅在10℃、20℃和30℃中一个温度下,而能够在全部三个温度下提高隔音性。因此,本发明的中间膜的情况下,使用了该中间膜的夹层玻璃即使用于各种温度环境,也能够发挥高隔音性。
此外,本发明的中间膜中,增塑剂、其它的添加物的迁移变少,并且即使这些成分发生迁移也具有良好的相溶性,因此不易因保管而使得透明性降低,即使保管中间膜,雾度也不易发生变化。
从在广温度范围进一步提高隔音性的观点出发,所述包含固化物的层的所述tanδ的峰值温度优选为-45℃以上,更优选为-40℃以上,进一步优选为-35℃以上,进一步优选为-30℃以上,更进一步优选为-25℃以上,特别优选为-20℃以上,最优选为-10℃以上。
从在广温度范围进一步提高隔音性的观点出发,所述包含固化物的层的所述tanδ的峰值温度优选为25℃以下,更优选为20℃以下,进一步优选为15℃以下,特别优选为10℃以下。
从在广温度范围进一步提高隔音性的观点出发,所述包含固化物的层在所述tanδ的峰值温度下tanδ(1)优选为2.2以上,更优选为2.4以上,进一步优选为2.5以上,特别优选为2.6以上,进一步优选为2.8以上,更进一步优选为3.0以上。在所述tanδ的峰值温度下tanδ(1)的上限没有限定。在所述tanδ的峰值温度下tanδ(1)可以为6以下。在所述tanδ(1)为所述下限以上时,进一步提高250Hz~1000Hz的低频率区域以下的隔音性,使得将该中间膜用于车辆等时发动机噪音得到减轻。
所述包含固化物的层在100℃下的储能模量G’优选为5.0×103Pa以上,更优选为1.0×104Pa以上,进一步优选为2.0×104Pa以上,进一步优选为3.0×104Pa以上,更进一步优选为4.0×104Pa以上,特别优选为5.0×104Pa以上。所述包含固化物的层在100℃下的储能模量G’在所述下限以上时,在广温度范围进一步提高隔音性。此外,所述包含固化物的层在100℃下的储能模量G’在所述下限以上时,进一步提高5000Hz~10000Hz的高频率区域的隔音性,使得将该中间膜用于车辆等时道路噪音得到减轻。
从提高所述包含固化物的层的固化均匀性,在广温度范围进一步提高隔音性的观点出发,所述固化性化合物优选为光固化性化合物,更优选为具有(甲基)丙烯酰基的固化性化合物。从提高所述包含固化物的层的固化均匀性,在广温度范围进一步提高隔音性的观点出发,所述固化物优选为(甲基)丙烯酸类聚合物。
从在广温度范围进一步提高隔音性的观点出发,所述中间膜优选具备所述包含与固化物不同的树脂的层。所述包含树脂的层中包含的树脂,优选为热固化性化合物的固化物或热塑性树脂。在所述树脂为固化性化合物的固化物的情况下,所述固化性化合物优选为热固化性化合物。
所述包含与固化物不同的树脂的层有时记载为第2树脂层。
从在广温度范围进一步提高隔音性的观点出发,所述包含树脂的层(第2树脂层)在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度优选为-100℃以上,并且优选为100℃以下。
从在广温度范围进一步提高隔音性的观点出发,所述包含树脂的层(第2树脂层)的所述tanδ的峰值温度优选为-90℃以上,更优选为-80℃以上,优选为90℃以下,更优选为80℃以下。
进行具备包含与固化物不同的树脂的层并且具有2层以上结构的中间膜的粘弹性测定。所述中间膜在频率为1Hz并且基于剪切模式的粘弹性测定中的所述包含固化物的层(第1树脂层)在tanδ的峰值温度下的tanδ(1)相对于所述包含与固化物不同的树脂的层(第2树脂层)在tanδ的峰值温度下的tanδ(2)的比设为比(tanδ(1)/tanδ(2))。
从在广温度范围进一步提高隔音性的观点出发,所述比(tanδ(1)/tanδ(2))优选为2.0以上,优选为10.0以下。
所述比(tanδ(1)/tanδ(2))优选为2.2以上,更优选为2.3以上,进一步优选为2.4以上,进一步优选为2.5以上,更进一步优选为2.6以上,更进一步优选为2.7以上,特别优选为2.8以上,特别进一步优选为2.9以上,最优选为3.0以上。所述比(tanδ(1)/tanδ(2))优选为9.0以下,更优选为8.0以下,进一步优选为7.0以下,进一步优选为6.0以下,最优选为5.0以下。所述比(tanδ(1)/tanδ(2))在所述下限以上和所述上限以下时,能够在广温度范围进一步提高隔音性。
所述粘弹性测定,具体而言,通过下述方式进行测定。
将试验片在室温23±2℃、湿度25±5%的环境下保管12小时后,立即使用动态粘弹性测定装置,测定粘弹性。在基于剪切模式,以3℃/分钟的升温速度从-50℃升温至200℃的条件,以及频率1Hz和应变1%的条件下进行测定。
作为所述动态粘弹性测定装置,可举出IT计测制御株式会社制的粘弹性测定装置“DVA-200”等。
可以使用中间膜本身进行粘弹性测定。在这种情况下,可以根据测定结果,读取源自所述包含固化物的层的tanδ的峰、源自所述包含树脂的层的tanδ的峰等。此外,在中间膜是具有2层以上结构的多层中间膜的情况下,可以将各层剥离而进行粘弹性测定。此外,在夹层玻璃的情况下,可以通过液氮等将夹层玻璃冷却后将夹层玻璃部件和中间膜剥离,使用剥离得到的中间膜进行粘弹性测定。
此外,例如,如果所述包含固化物的层的厚度为0.3mm以上2mm以下,则可以使用所述包含固化物的层作为直接试验片,容易地进行粘弹性测定。在所述包含固化物的层的厚度低于0.3mm的情况下,可以重叠多个所述包含固化物的层,或另行制备仅调整了厚度并且包含固化物的层,而使用厚度为0.3mm以上2mm以下的试验片,进行粘弹性测定。在所述包含固化物的层的厚度大于2mm的情况下,可以将所述包含固化物的层切片,或进行压制,或另行制备仅调整了厚度并且包含固化物的层,而使用厚度为0.3mm以上2mm以下的试验片,进行粘弹性测定。
所述包含树脂的层的粘弹性测定中,可以变更试验片,以与所述包含固化物的层的粘弹性测定同样的方式进行测定。
所述包含固化物的层在100℃下的储能模量G’可以通过所述包含固化物的层的粘弹性测定而测定。
本发明的中间膜可以具有1层结构或2层以上结构。本发明的中间膜可以具有2层结构或3层以上结构。
本发明的中间膜可以具有仅第1层的1层结构。在这种情况下,第1层为所述包含固化物的层。
从有效提高隔音性和各层间的粘接性的观点出发,本发明的中间膜可以具备第1层、和配置在所述第1层的第1表面侧的第2层。在这种情况下,所述第1层优选为所述包含固化物的层。
从有效提高隔音性和各层间的粘接性的观点出发,本发明的中间膜可以具备第1层和配置在所述第1层的第1表面侧的第2层,可以进一步具备配置在所述第1层的与所述第1表面侧相反的第2表面侧的第3层。在这种情况下,所述第1层优选为所述包含固化物的层。
从有效提高隔音性和中间膜与玻璃之间的粘接性的观点出发,所述包含固化物的层优选不是中间膜中的表面层,优选为中间膜中的中间层。但是,所述包含固化物的层也可以为中间膜中的表面层。
从提高夹层玻璃的透明性的观点出发,所述中间膜的可见光线透射率优选为70%以上,更优选为80%以上,进一步优选为85%以上。
所述可见光线透射率,使用分光光度计(HITACHI HIGH-TECH公司制“U-4100”),基于JIS R3211:1998,以波长380~780nm进行测定。
所述中间膜的可见光线透射率,可以在2片透明玻璃之间配置中间膜而进行测定。所述透明玻璃的厚度优选为2.0mm。
以下,参照附图,同时对本发明的具体的实施方式进行说明。
图1为示意性地表示本发明的第1实施方式的夹层玻璃用中间膜的截面图。
图1表示的中间膜11为具有2层以上结构的多层中间膜。具体而言,中间膜11具有3层结构。中间膜11用于得到夹层玻璃。中间膜11为夹层玻璃用中间膜。中间膜11具备第1层1、第2层2以及第3层3。第1层1的第1表面1a侧配置并叠层有第2层2。第1层1的与第1表面1a相反的第2表面1b侧配置并叠层有第3层3。第1层1为中间层。第2层2和第3层3分别为保护层,本实施方式中为表面层。第1层1配置并夹入第2层2和第3层3之间。因此,中间膜11具有第2层2、第1层1以及第3层3依次叠层而成的多层结构(第2层2/第1层1/第3层3)。
中间膜11中,第1层1优选为所述包含固化物的层。第2层2也可以为所述包含固化物的层,第3层3也可以为所述包含固化物的层。
需要说明的是,第2层2和第1层1之间和第1层1和第3层3之间分别可以配置有其他层。优选第2层2与第1层1、和第1层1与第3层3分别直接叠层。作为其他层,可举出粘接层。
图2为示意性地表示本发明的第2实施方式的夹层玻璃用中间膜的截面图。
图2表示的中间膜11A为具有1层结构的单层中间膜。中间膜11A为第1层。中间膜11A用于得到夹层玻璃。中间膜11A为夹层玻璃用中间膜。
中间膜11A中,中间膜11A本身为所述包含固化物的层。
以下,对于本发明的中间膜、所述包含固化物的层、所述包含树脂的层、所述第1层、所述第2层和所述第3层的详细内容以及中间膜中使用的各成分的详细内容进行说明。
(用于形成包含固化物的层(第1树脂层)中的固化物的固化性化合物和固化物)
所述中间膜具备所述包含固化物的层。用于形成所述包含固化物的层中的所述固化物的固化性化合物为光固化性化合物或者湿固化性化合物。
所述固化性化合物优选为具有(甲基)丙烯酰基的固化性化合物,更优选为(甲基)丙烯酸类聚合物。
所述(甲基)丙烯酸类聚合物优选为包含具有(甲基)丙烯酰基的固化性化合物的聚合性组合物的聚合物。所述聚合性组合物包含聚合成分。为了有效形成所述包含固化物的层中的所述固化物,所述聚合性组合物可以包含光反应引发剂。所述聚合性组合物中,可以与光反应引发剂一同,包含用于促进固化反应的助剂。作为所述具有(甲基)丙烯酰基的固化性化合物的代表例,可举出(甲基)丙烯酸酯。所述(甲基)丙烯酸类聚合物优选为聚(甲基)丙烯酸酯。
为了有效得到本发明的效果,所述聚合成分优选包含:具有脂环结构的(甲基)丙烯酸酯、具有环状醚结构的(甲基)丙烯酸酯、具有芳香环的(甲基)丙烯酸酯、具有极性基团的(甲基)丙烯酸酯、或侧链的碳原子数为6以下的非环式(甲基)丙烯酸酯。通过使用这些优选的(甲基)丙烯酸酯,能够平衡性良好地提高隔音性和起泡抑制性能这两者。
作为所述具有脂环结构的(甲基)丙烯酸酯,可举出(甲基)丙烯酸异冰片酯、(甲基)丙烯酸环己酯、丙烯酸二环戊酯等。
作为所述具有环状醚结构的(甲基)丙烯酸酯,可举出:(甲基)丙烯酸缩水甘油酯、(甲基)丙烯酸2-羟基乙酯缩水甘油基醚、(甲基)丙烯酸3-羟基丙酯缩水甘油基醚、丙烯酸4-羟基丁酯缩水甘油基醚、(甲基)丙烯酸5-羟基戊酯缩水甘油基醚、(甲基)丙烯酸6-羟基己酯缩水甘油基醚;(甲基)丙烯酸(3-甲基氧杂环丁烷-3-基)甲酯、(甲基)丙烯酸(3-丙基氧杂环丁烷-3-基)甲酯、(甲基)丙烯酸(3-乙基氧杂环丁烷-3-基)甲酯、(甲基)丙烯酸(3-丁基氧杂环丁烷-3-基)甲酯、(甲基)丙烯酸(3-乙基氧杂环丁烷-3-基)乙酯、(甲基)丙烯酸(3-乙基氧杂环丁烷-3-基)丙酯、(甲基)丙烯酸(3-乙基氧杂环丁烷-3-基)丁酯、(甲基)丙烯酸(3-乙基氧杂环丁烷-3-基)戊酯、(甲基)丙烯酸(3-乙基氧杂环丁烷-3-基)己酯;(甲基)丙烯酸四氢糠酯、(甲基)丙烯酸(2,2-二甲基-1,3-二氧戊环-4-基)甲酯、(甲基)丙烯酸(2-甲基-2-乙基-1,3-二氧戊环-4-基)甲酯、(甲基)丙烯酸(2-甲基-2-异丁基-1,3-二氧戊环-4-基)甲酯、(甲基)丙烯酸(2-环己基-1,3-二氧戊环-4-基)甲酯、四氢糠醇丙烯酸多聚体酯;四氢-2H-吡喃-2-基-(甲基)丙烯酸酯、2-{1-[(四氢-2H-吡喃-2-基)氧基]-2-甲基丙基}(甲基)丙烯酸酯、环状三羟甲基丙烷甲缩醛丙烯酸酯、(甲基)丙烯酰基吗啉等。从有效得到本发明的效果的观点出发,特别优选(甲基)丙烯酸四氢糠酯、环状三羟甲基丙烷甲缩醛丙烯酸酯。
作为所述具有芳香环的(甲基)丙烯酸酯,可举出丙烯酸苄酯、聚(乙二醇)苯基醚丙烯酸酯等。
作为所述具有极性基团的(甲基)丙烯酸酯,可举出:具有羟基、酰胺基、氨基、异氰酸酯基、羧基等作为极性基团的(甲基)丙烯酸酯。
作为具有羟基的(甲基)丙烯酸酯,例如可举出(甲基)丙烯酸2-羟基乙酯、(甲基)丙烯酸羟基丙酯、(甲基)丙烯酸4-羟基丁酯、(甲基)丙烯酸2-羟基丁酯等。
作为具有酰胺基的(甲基)丙烯酸酯,例如可举出N,N-二甲基氨基丙基(甲基)丙烯酰胺、N,N-二甲基(甲基)丙烯酰胺、(甲基)丙烯酰基吗啉、N-异丙基(甲基)丙烯酰胺、N-羟基乙基(甲基)丙烯酰胺等。
作为具有酰胺基或氨基的(甲基)丙烯酸酯,例如可举出N-二烷基氨基烷基(甲基)丙烯酰胺、N,N-二烷基氨基烷基(甲基)丙烯酰胺等。
作为具有异氰酸酯基的(甲基)丙烯酸酯,可举出三烯丙基异氰脲酸酯和其衍生物等。
作为具有羧基的(甲基)丙烯酸酯,可举出丙烯酸、ω-羧基-聚己内酯单丙烯酸酯、琥珀酸2-丙烯酰氧基乙酯等。
所述(甲基)丙烯酸酯可以为具有(甲基)丙烯酰基的多元羧酸酯。作为该具有(甲基)丙烯酰基的多元羧酸酯,可举出琥珀酸2-丙烯酰氧基乙酯等。
从有效得到本发明的效果观点出发,优选具有羟基的(甲基)丙烯酸酯,特别优选(甲基)丙烯酸2-羟基乙酯、(甲基)丙烯酸羟基丙酯、或(甲基)丙烯酸4-羟基丁酯。
作为所述侧链的碳原子数为6以下的非环式(甲基)丙烯酸酯,例如可举出(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸丙酯、(甲基)丙烯酸丁酯。
为了有效得到本发明的效果,所述聚合成分100重量%中,侧链的碳原子数为8以上的非环式(甲基)丙烯酸酯的含量优选低于20重量%。
作为所述(甲基)丙烯酸酯,除了所述化合物以外,例如可举出:二乙二醇单***(甲基)丙烯酸酯、(甲基)丙烯酸3-甲氧基丁酯、2-丙烯酰氧基乙基-2-羟基丙基邻苯二甲酸酯、2-丙烯酰氧基乙基-2-羟基丙基邻苯二甲酸酯;乙二醇二(甲基)丙烯酸酯、二乙二醇二(甲基)丙烯酸酯、四乙二醇二(甲基)丙烯酸酯、1,6-己烷二醇二(甲基)丙烯酸酯、1,9-壬二醇二(甲基)丙烯酸酯、聚四亚甲基二醇二(甲基)丙烯酸酯、新戊二醇二(甲基)丙烯酸酯、1,3-丁二醇二(甲基)丙烯酸酯、2,2-双[4-(丙烯酰氧基乙氧基)苯基]丙烷二(甲基)丙烯酸酯;三羟甲基丙烷三(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯酸酯、季戊四醇四(甲基)丙烯酸酯、二季戊四醇五(甲基)丙烯酸酯、二季戊四醇六(甲基)丙烯酸酯、三(2-丙烯酰氧基乙基)磷酸酯、四羟甲基甲烷三(甲基)丙烯酸酯、四羟甲基丙烷四(甲基)丙烯酸酯和其衍生物等。
所述(甲基)丙烯酸酯可以仅使用1种或组合使用2种以上。所述(甲基)丙烯酸类聚合物可以为所述的(甲基)丙烯酸酯的均聚物或包含所述的(甲基)丙烯酸酯的聚合成分的共聚物。
作为所述光反应引发剂,具体而言,可举出:2-甲基-1-(4-甲基噻吩基)-2-吗啉代丙烷-1-酮、2-苄基-2-二甲基氨基-1-(4-吗啉代苯基)-丁酮-1,2-(二甲基氨基)-2-[(4-甲基苯基)甲基]-1-[4-(4-吗啉基)苯基]-1-丁酮、2,4,6-三甲基苯甲酰-二苯基-膦氧化物、双(2,4,6-三甲基苯甲酰)-苯基膦氧化物、双(η5-2,4-环戊二烯-1-基)-双(2,6-二氟-3-(1H-吡咯-1-基)-苯基)钛、2-甲基-1-(4-甲基噻吩基)-2-吗啉代丙烷-1-酮、2-苄基-2-二甲基氨基-1-(4-吗啉代苯基)-丁酮-1,2-(二甲基氨基)-2-[(4-甲基苯基)甲基]-1-[4-(4-吗啉基)苯基]-1-丁酮、二乙氧基苯乙酮、2-羟基-2-甲基-1-苯基丙烷-1-酮、苄基二甲基缩酮、4-(2-羟基乙氧基)苯基-(2-羟基-2-丙基)酮、1-羟基环己基苯基酮、2-甲基-2-吗啉代(4-硫甲基苯基)丙烷-1-酮、2-苄基-2-二甲基氨基-1-(4-吗啉代苯基)丁酮、2-羟基-2-甲基-1-[4-(1-甲基乙烯基)苯基]丙酮低聚物、安息香、安息香甲醚、安息香***、安息香异丙醚、安息香异丁基醚、二苯甲酮、o-苯甲酰苯甲酸甲酯、4-苯基二苯甲酮、4-苯甲酰-4’-甲基-二苯基硫化物、3,3’,4,4’-四(叔丁基过氧化羰基)二苯甲酮、2,4,6-三甲基二苯甲酮、4-苯甲酰-N,N-二甲基-N-[2-(1-氧代-2-丙烯氧基)乙基]苯甲基溴化铵、(4-苯甲酰苄基)三甲基氯化铵、2-异丙基噻吨酮、4-异丙基噻吨酮、2,4-二乙基噻吨酮、2,4-二氯噻吨酮、1-氯-4-丙氧基噻吨酮、2-(3-二甲基氨基-2-羟基)-3,4-二甲基-9H-噻吨酮-9-酮Mesochloride、2,4,6-三甲基苯甲酰-二苯基膦氧化物、双(2,6-二甲氧基苯甲酰)-2,4,4-三甲基-戊基膦氧化物、双(2,4,6-三甲基苯甲酰)-苯基膦氧化物、四(五氟苯基)硼酸三苯基甲酯等。所述光反应引发剂可以仅使用1种或组合使用2种以上。
作为所述助剂,可举出:三乙醇胺、三异丙醇胺、4,4’-二甲基氨基二苯甲酮(米氏酮)、4,4’-二乙基氨基二苯甲酮、2-二甲基氨基乙基苯甲酸、4-二甲基氨基苯甲酸乙酯、4-二甲基氨基苯甲酸(正丁氧基)乙酯、4-二甲基氨基苯甲酸异戊酯、4-二甲基氨基苯甲酸2-乙基己酯、2,4-二乙基9-噻吨酮、2,4-二异丙基9-噻吨酮等。所述助剂可以仅使用1种或组合使用2种以上。
所述助剂,优选为:苄基二甲基缩酮、1-羟基环己基苯基酮、苯甲酰异丙醚、4-(2-羟基乙氧基)-苯基(2-羟基-2-丙基)酮、2-羟基-2-甲基-1-苯基丙烷-1-酮、或四(五氟苯基)硼酸三苯基甲酯。
所述聚合性组合物100重量%中,所述光反应引发剂的含量优选为0.01重量%以上,更优选为0.1重量%以上,优选为10重量%以下,更优选为5重量%以下。所述光反应引发剂的含量为所述下限以上和所述上限以下时,光固化性和保存稳定性进一步提高。
用于形成所述包含固化物的层的组合物100重量%中,所述固化物的含量优选为50重量%以上,更优选为60重量%以上,进一步优选为70重量%以上,特别优选为80重量%以上。所述固化物的含量为所述下限以上时,能够进一步发挥本发明的效果。需要说明的是,用于形成所述包含固化物的层的组合物100重量%中的所述固化物的含量可以为100重量%(总量)。
用于形成所述包含固化物的层中的所述固化物的固化性化合物为具有(甲基)丙烯酰基的光固化性化合物等的光固化性化合物时,为了使该光固化性化合物固化,优选使用紫外线照射装置等的光固化性装置。作为所述紫外线照射装置,可举出箱式、输送带式等。此外,作为设置在所述紫外线照射装置中的紫外线灯,可举出:超高压水银灯、高压水银灯、低压水银灯、化学灯、金属卤化物灯、准分子灯、UV-LED等。所述紫外线灯优选为化学灯、或UV-LED。
为了得到所述固化物,对所述光固化性化合物照射紫外线的情况下,紫外线照射量(累积照射量)优选为500mJ以上,更优选为1000mJ以上,进一步优选为1500mJ以上,特别优选为2000mJ以上。所述紫外线照射量(累积照射量)优选为20000mJ以下,更优选为10000mJ以下,进一步优选为8000mJ以下。所述紫外线照射量(累积照射量)为所述下限以上时,能够减少未反应单体。所述紫外线照射量(累积照射量)为所述上限以下时,能够提高树脂的保存稳定性。此外,所述紫外线照射的照射强度优选为0.1mW以上,更优选为0.5mW以上,进一步优选为1mW以上,特别优选为2mW以上。
(包含与固化物不同的树脂的层(第2树脂层)中的树脂)
所述中间膜优选具备所述包含与固化物不同的树脂的层。所述包含与固化物不同的树脂的层(第2树脂层)是包含与使光固化性化合物固化而得的固化物、使湿固化性化合物固化而得的固化物和使具有(甲基)丙烯酰基的固化性化合物固化而得的固化物都不相同的树脂的层。所述包含与固化物不同的树脂的层是与所述包含固化物的层(第1树脂层)不同的树脂层。需要说明的是,所述中间膜可以不具备所述第2树脂层。
作为所述第2树脂层中包含的树脂,可举出热固化性化合物的固化物和热塑性树脂等。所述热塑性树脂可以为热塑性弹性体。
需要说明的是,热塑性树脂是指,加热时发生软化而表现出可塑性,冷却至室温时发生固化的树脂。热塑性弹性体是指,热塑性树脂中特别是加热时发生软化而表现出可塑性,冷却至室温(25℃)时发生固化而表现出橡胶弹性的树脂。
作为所述热塑性树脂,可举出:聚乙烯醇缩醛树脂、聚酯树脂、脂肪族聚烯烃、聚苯乙烯、乙烯-乙酸乙烯酯共聚物树脂、乙烯-丙烯酸共聚物树脂、聚氨酯树脂、离聚物树脂、聚乙烯醇树脂和聚乙酸乙烯酯等。也可以使用这些以外的热塑性树脂。
所述例举的热塑性树脂可以通过树脂的分子结构、聚合度等的调整而成为热塑性弹性体。
所述中间膜中的表面层优选包含热塑性树脂。具有第2层/第1层/第3层结构的中间膜中的第2层和第3层,分别优选包含热塑性树脂。
从进一步提高夹层玻璃的刚性的观点出发,所述热塑性树脂优选为聚乙烯醇缩醛树脂、离聚物树脂或乙烯-乙酸乙烯酯共聚物树脂。从进一步提高夹层玻璃的耐冲击性和防裂纹性的观点出发,所述热塑性树脂更优选为聚乙烯醇缩醛树脂。
所述聚乙烯醇缩醛树脂,例如,可以通过使聚乙烯醇(PVA)通过醛而缩醛化而进行制造。所述聚乙烯醇缩醛树脂优选为聚乙烯醇的缩醛化物。所述聚乙烯醇,例如可以通过使聚乙酸乙烯酯皂化而得到。所述聚乙烯醇的皂化度通常在70~99.9摩尔%的范围内。
所述聚乙烯醇(PVA)的平均聚合度优选为200以上,更优选为500以上,进一步优选为1500以上,进一步优选为1600以上,优选为5000以下,更优选为4000以下,进一步优选为3500以下,特别优选为3000以下。所述平均聚合度为所述下限以上时,夹层玻璃的耐贯穿性进一步提高。所述平均聚合度为所述上限以下时,中间膜的成形变得容易。
所述聚乙烯醇的平均聚合度,通过基于JIS K6726“聚乙烯醇试验方法”的方法而求得。
所述聚乙烯醇缩醛树脂中包含的缩醛基的碳原子数没有特别限定。制造所述聚乙烯醇缩醛树脂时中使用的醛没有特别限定。所述聚乙烯醇缩醛树脂中的缩醛基的碳原子数优选为3~5,更优选为3或4。所述聚乙烯醇缩醛树脂中的缩醛基的碳原子数为3以上时,中间膜的玻璃化转变温度充分变低。
所述醛没有特别限定。通常,优选使用碳原子数为1~10的醛。作为所述碳原子数为1~10的醛,例如可举出甲醛、乙醛、丙醛、正丁醛、异丁醛、正戊醛、2-乙基丁醛、正己醛、正辛醛、正壬醛、正癸醛、甲醛、乙醛和苯甲醛等。优选丙醛、正丁醛、异丁醛、正己醛或正戊醛,更优选丙醛、正丁醛或异丁醛,进一步优选正丁醛。所述醛可以仅使用1种或组合使用2种以上。
所述聚乙烯醇缩醛树脂的羟基的含有率(羟基量)优选为15摩尔%以上,更优选为18摩尔%以上,优选为40摩尔%以下,更优选为35摩尔%以下。所述羟基的含有率为所述下限以上时,中间膜的粘接力进一步提高。此外,所述羟基的含有率为所述上限以下时,中间膜的柔软性提高,中间膜的处理变得容易。
所述聚乙烯醇缩醛树脂的羟基的含有率为,将键合有羟基的亚乙基量除以主链的总亚乙基量而求得的摩尔分数以百分率表示的值。所述键合有羟基的亚乙基量,例如可以通过基于JIS K6728“聚乙烯醇缩丁醛试验方法”而测定。
所述聚乙烯醇缩醛树脂的乙酰化度优选为0.01摩尔%以上,更优选为0.5摩尔%以上,优选为10摩尔%以下,更优选为2摩尔%以下。所述乙酰化度为所述下限以上时,聚乙烯醇缩醛树脂和增塑剂的相溶性提高。所述乙酰化度为所述上限以下时,中间膜和夹层玻璃的耐湿性提高。
所述乙酰化度为,将键合有乙酰基的亚乙基量除以主链的总亚乙基量而求得的摩尔分数以百分率表示的值。所述键合有乙酰基的亚乙基量,例如可以基于JIS K6728“聚乙烯醇缩丁醛试验方法”而测定。
所述聚乙烯醇缩醛树脂的缩醛化度(聚乙烯醇缩丁醛树脂的情况下为缩丁醛化度)优选为55摩尔%以上,更优选为60摩尔%以上,优选为75摩尔%以下,更优选为71摩尔%以下。所述缩醛化度为所述下限以上时,聚乙烯醇缩醛树脂和增塑剂的相溶性提高。所述缩醛化度为所述上限以下时,用于制造聚乙烯醇缩醛树脂的必要的反应时间变短。
所述缩醛化度以下述方式求得。首先,求得从主链的总亚乙基量减去键合有羟基的亚乙基量和键合有乙酰基的亚乙基量而得的值。将得到的值除以主链的总亚乙基量而求得摩尔分数。该摩尔分数以百分率表示的值为缩醛化度。
需要说明的是,所述羟基的含有率(羟基量)、缩醛化度(缩丁醛化度)和乙酰化度,优选根据通过基于JIS K6728“聚乙烯醇缩丁醛试验方法”的方法测定得到的结果而进行计算。但是,也可以使用基于ASTM D1396-92的测定。在聚乙烯醇缩醛树脂为聚乙烯醇缩丁醛树脂的情况下,所述羟基的含有率(羟基量)、所述缩醛化度(缩丁醛化度)和所述乙酰化度可以根据通过基于JIS K6728“聚乙烯醇缩丁醛试验方法”的方法测定得到的结果而计算。
(增粘树脂)
所述中间膜优选包含增粘树脂。所述包含固化物的层(第1树脂层)优选包含增粘树脂。所述包含树脂的层(第2树脂层)优选包含增粘树脂。所述第1层优选包含增粘树脂。所述增粘树脂可以仅使用1种或组合使用2种以上。
作为所述增粘树脂,可举出苯乙烯树脂、萜烯树脂和松香树脂等。从良好地保持雾度,同时在广温度范围内提高隔音性观点出发,所述增粘树脂优选为苯乙烯树脂。所述苯乙烯树脂优选为苯乙烯的低聚物。作为所述苯乙烯的低聚物的市售品,例如可举出YASUHARACHEMICAL公司制“YS树脂SX100”等。
在包含增粘树脂的树脂层中,增粘树脂相对于该树脂层中包含的除了该增粘树脂之外的树脂100重量份的含量优选为10重量份以上,更优选为20重量份以上,进一步优选为30重量份以上,优选为150重量份以下,更优选为100重量份以下。所述增粘树脂的含量为所述下限以上时,能够在良好地保持雾度的同时在广温度范围内提高隔音性。
(增塑剂)
所述中间膜优选包含增塑剂。从有效提高隔音性观点出发,所述包含固化物的层(第1树脂层)优选包含增塑剂。所述包含树脂的层(第2树脂层)优选包含增塑剂。所述第1层优选包含增塑剂。所述第2层优选包含增塑剂。所述第3层优选包含增塑剂。通过增塑剂的使用,存在进一步提高各层间的粘接力的倾向。所述增塑剂可以仅使用1种或组合使用2种以上。
作为所述增塑剂,可举出石蜡油、苯甲酸酯增塑剂、有机酯增塑剂、有机磷酸增塑剂等。作为所述有机酯增塑剂,可举出一元有机酸酯和多元有机酸酯等。作为所述磷酸增塑剂,可举出有机磷酸增塑剂和有机亚磷酸增塑剂等。所述增塑剂优选为液态增塑剂。
作为所述石蜡油,可举出环烷类的工艺用油、白色矿物油、矿物油、石蜡和流动石蜡等。
作为所述石蜡油的市售品,可举出:出光兴产公司制“DIANA PROCES S OIL PW-90”、出光兴产公司制“DIANA PROCESS OIL PW-100”和出光兴产公司制“DIANA PROCESSOIL PW-32”等。
作为所述有机酯增塑剂,可举出:三乙二醇二-2-乙基丙酸酯、三乙二醇二-2-乙基丁酸酯、三乙二醇二-2-乙基己酸酯、三乙二醇二辛酸酯、三乙二醇二正辛酸酯、三乙二醇二正庚酸酯、四乙二醇二正庚酸酯、癸二酸二丁酯、壬二酸二辛酯、二丁基卡必醇乙二酸酯、乙二醇二-2-乙基丁酸酯、1,3-丙二醇二-2-乙基丁酸酯、1,4-丁二醇二-2-乙基丁酸酯、二乙二醇二-2-乙基丁酸酯、二乙二醇二-2-乙基己酸酯、二丙二醇二-2-乙基丁酸酯、三乙二醇二-2-乙基戊酸酯、四乙二醇二-2-乙基丁酸酯、二乙二醇二辛酸酯、马来酸二丁酯、己二酸双(2-丁氧基乙基)酯、己二酸二丁酯、己二酸二异丁酯、己二酸2,2-丁氧基乙氧基乙酯、苯甲酸二醇酯、己二酸1,3-丁二醇聚酯、己二酸二己酯、己二酸二辛酯、己二酸己基环己酯、己二酸庚酯和己二酸壬酯的混合物、己二酸二异壬酯、己二酸二异癸酯、己二酸庚基壬酯、柠檬酸三丁酯、乙酰柠檬酸三丁酯、碳酸二乙酯、癸二酸二丁酯、油改性癸二酸醇酸、和磷酸酯和己二酸酯的混合物等。也可以使用这些以外的有机酯增塑剂。也可以使用上述的己二酸酯以外的其他己二酸酯。
在结构式表示的情况下,作为所述有机酯增塑剂,可举出下述式(1)表示的二酯增塑剂。
[化学式1]
所述式(1)中,R1和R2分别表示碳原子数2~10的有机基团,R3表示亚乙基、亚异丙基或亚正丙基,p表示3~10的整数。所述式(1)中的R1和R2分别优选为碳原子数5~10的有机基团,更优选为碳原子数6~10的有机基团。
所述增塑剂优选包含三乙二醇二-2-乙基己酸酯(3GO)、三乙二醇二-2-乙基丁酸酯(3GH)或三乙二醇二-2-乙基丙酸酯。所述增塑剂更优选包含三乙二醇二-2-乙基己酸酯或三乙二醇二-2-乙基丁酸酯,进一步优选包含三乙二醇二-2-乙基己酸酯。
所述包含固化物的层(第1树脂层)中,增塑剂相对于所述固化物100重量份的含量设为含量(1)。所述含量(1)优选为5重量份以上,更优选为10重量份以上,进一步优选为20重量份以上,特别优选为25重量份以上,优选为60重量份以下,更优选为50重量份以下。所述含量(1)为所述下限以上时,能够有效提高隔音性。所述含量(1)为所述上限以下时,夹层玻璃的耐贯穿性进一步提高。
所述包含树脂的层(第2树脂层)中,增塑剂相对于所述树脂100重量份的含量设为含量(2)。所述含量(2)优选为5重量份以上,更优选为10重量份以上,进一步优选为20重量份以上,优选为60重量份以下,更优选为55重量份以下,进一步优选为50重量份以下。所述含量(2)为所述下限以上时,能够有效提高隔音性。所述增塑剂的含量为所述上限以下时,夹层玻璃的耐贯穿性进一步提高。
(隔热性物质)
所述中间膜可以包含隔热性物质。所述包含固化物的层可以包含隔热性物质。所述包含树脂的层可以包含隔热性物质。所述第1层可以包含隔热性物质。所述第2层可以包含隔热性物质。所述第3层可以包含隔热性物质。所述隔热性物质可以仅使用1种或组合使用2种以上。
所述隔热性物质可以包含酞菁化合物、萘酞菁化合物和蒽酞菁化合物中的至少1种成分X或隔热粒子。在这种情况下,所述隔热性物质可以包含所述成分X和所述隔热粒子这两者。
所述中间膜可以包含酞菁化合物、萘酞菁化合物和蒽酞菁化合物中的至少1种成分X。所述包含固化物的层可以包含所述成分X。所述包含树脂的层可以包含所述成分X。所述第1层可以包含所述成分X。所述第2层可以包含所述成分X。所述第3层可以包含所述成分X。所述成分X为隔热性物质。所述成分X可以仅使用1种或组合使用2种以上。
所述成分X没有特别限定。作为成分X,可使用以往公知的酞菁化合物、萘酞菁化合物和蒽酞菁化合物。
作为所述成分X,可举出酞菁、酞菁的衍生物、萘酞菁、萘酞菁的衍生物、蒽酞菁和蒽酞菁的衍生物等。所述酞菁化合物和所述酞菁的衍生物分别优选具有酞菁骨架。所述萘酞菁化合物和所述萘酞菁的衍生物分别优选具有萘酞菁骨架。所述蒽酞菁化合物和所述蒽酞菁的衍生物分别优选具有蒽酞菁骨架。
所述成分X可以含有钒原子或铜原子。所述成分X可以含有钒原子,可以含有铜原子。所述成分X可以为含有钒原子或铜原子的酞菁、和含有钒原子或铜原子的酞菁的衍生物中的至少1种。
所述中间膜可以包含隔热粒子。所述包含固化物的层可以包含隔热粒子。所述包含树脂的层可以包含隔热粒子。所述第1层可以包含所述隔热粒子。所述第2层可以包含所述隔热粒子。所述第3层可以包含所述隔热粒子。所述隔热粒子为隔热性物质。通过隔热粒子的使用,能够有效隔断红外线(热线)。所述隔热粒子可以仅使用1种或组合使用2种以上。
作为所述隔热粒子,可以使用金属氧化物粒子。作为所述隔热粒子,可以使用由金属的氧化物形成而得的粒子(金属氧化物粒子)。
波长长于可见光的780nm以上的红外线,与紫外线比较,能量较小。然而,红外线的热作用较大,红外线被物质吸收时作为热而放出。因此,红外线通常被称为热线。通过所述隔热粒子的使用,能够有效隔断红外线(热线)。需要说明的是,隔热粒子是指,可吸收红外线的粒子。
作为所述隔热粒子的具体例,可举出:铝掺杂氧化锡粒子、铟掺杂氧化锡粒子、锑掺杂氧化锡粒子(ATO粒子)、镓掺杂氧化锌粒子(GZO粒子)、铟掺杂氧化锌粒子(IZO粒子)、铝掺杂氧化锌粒子(AZO粒子)、铌掺杂氧化钛粒子、钠掺杂氧化钨粒子、铯掺杂氧化钨粒子、铊掺杂氧化钨粒子、铷掺杂氧化钨粒子、锡掺杂氧化铟粒子(ITO粒子)、锡掺杂氧化锌粒子、硅掺杂氧化锌粒子等的金属氧化物粒子、六硼化镧(LaB6)粒子等。可以使用这些以外的隔热粒子。
(金属盐)
所述中间膜可以包含碱金属盐、碱土金属盐和镁盐中的至少1种金属盐(以下,有时记载为金属盐M)。所述包含固化物的层可以包含所述金属盐M。所述包含树脂的层可以包含所述金属盐M。所述第1层可以包含所述金属盐M。所述第2层可以包含所述金属盐M。所述第3层可以包含所述金属盐M。通过所述金属盐M的使用,使得控制中间膜和玻璃板等的夹层玻璃部件之间的粘接性或中间膜中的各层间的粘接性变得容易。所述金属盐M可以仅使用1种或组合使用2种以上。
所述金属盐M可以包含选自Li、Na、K、Rb、Cs、Mg、Ca、Sr和Ba中的至少1种金属。
此外,作为所述金属盐M,可以使用碳原子数2~16的有机酸的碱金属盐、碳原子数2~16的有机酸的碱土金属盐或碳原子数2~16的有机酸的镁盐。
作为所述碳原子数2~16的羧酸镁盐和所述碳原子数2~16的羧酸钾盐,可举出乙酸镁、乙酸钾、丙酸镁、丙酸钾、2-乙基丁酸镁、2-乙基丁酸钾、2-乙基己酸镁和2-乙基己酸钾等。
(紫外线屏蔽剂)
所述中间膜可以包含紫外线屏蔽剂。所述包含固化物的层可以包含紫外线屏蔽剂。所述包含树脂的层可以包含紫外线屏蔽剂。所述第1层可以包含紫外线屏蔽剂。所述第2层可以包含紫外线屏蔽剂。所述第3层可以包含紫外线屏蔽剂。通过紫外线屏蔽剂的使用,即使中间膜和夹层玻璃被长期间使用,也进一步使得可见光线透射率不易降低。所述紫外线屏蔽剂可以仅使用1种或组合使用2种以上。
所述紫外线屏蔽剂中包含紫外线吸收剂。所述紫外线屏蔽剂优选为紫外线吸收剂。
作为所述紫外线屏蔽剂,例如,可举出包含金属原子的紫外线屏蔽剂、包含金属氧化物的紫外线屏蔽剂、具有苯并***结构的紫外线屏蔽剂(苯并***化合物)、具有二苯甲酮结构的紫外线屏蔽剂(二苯甲酮化合物)、具有三嗪结构的紫外线屏蔽剂(三嗪化合物)、具有丙二酸酯结构的紫外线屏蔽剂(丙二酸酯化合物)、具有草酸苯胺结构的紫外线屏蔽剂(草酸苯胺化合物)和具有苯甲酸酯结构的紫外线屏蔽剂(苯甲酸酯化合物)等。
作为所述包含金属原子的紫外线屏蔽剂,例如可举出铂粒子、铂粒子的表面由二氧化硅包覆而成的粒子、钯粒子和钯粒子的表面由二氧化硅包覆而成的粒子等。紫外线屏蔽剂优选不是隔热粒子。
作为所述包含金属氧化物的紫外线屏蔽剂,例如可举出氧化锌、氧化钛和氧化铈等。此外,就所述包含金属氧化物的紫外线屏蔽剂而言,表面可以被包覆。作为所述包含金属氧化物的紫外线屏蔽剂的表面的包覆材料,可举出绝缘性金属氧化物、水解性有机硅化合物和聚硅氧烷化合物等。
作为所述绝缘性金属氧化物,可举出二氧化硅、氧化铝和氧化锆等。所述绝缘性金属氧化物,例如具有5.0eV以上的带隙能量。
作为所述具有苯并***结构的紫外线屏蔽剂,例如可举出:2-(2’-羟基-5’-甲基苯基)苯并***(BASF公司制“TinuvinP”)、2-(2’-羟基-3’,5’-二叔丁基苯基)苯并***(BASF公司制“Tinuvin320”)、2-(2’-羟基-3’-叔丁基-5-甲基苯基)-5-氯苯并***(BASF公司制“Tinuvin326”)、和2-(2’-羟基-3’,5’-二戊基苯基)苯并***(BASF公司制“Tinuvin328”)等。
作为所述具有二苯甲酮结构的紫外线屏蔽剂,例如,OCTABENZONE(BASF公司制“Chimassorb81”)等。
作为所述具有三嗪结构的紫外线屏蔽剂,例如可举出ADEKA公司制“LA-F70”和2-(4,6-二苯基-1,3,5-三嗪-2-基)-5-[(己基)氧基]-酚(BASF公司制“Tinuvin1577FF”)等。
作为所述具有丙二酸酯结构的紫外线屏蔽剂,可举出2-(对甲氧基亚苄基)丙二酸二甲酯、2,2-(1,4-亚苯基二亚甲基)双丙二酸四乙酯、2-(对甲氧基亚苄基)-双(1,2,2,6,6-五甲基4-哌啶基)丙二酸酯等。
作为所述具有丙二酸酯结构的紫外线屏蔽剂的市售品,可举出HostavinB-CAP、Hostavin PR-25、Hostavin PR-31(均为CLARIANT公司制)。
作为所述具有草酸苯胺结构的紫外线屏蔽剂,可举出:N-(2-乙基苯基)-N’-(2-乙氧基-5-叔丁基苯基)草酸二酰胺、N-(2-乙基苯基)-N’-(2-乙氧基-苯基)草酸二酰胺、2-乙基-2’-乙氧基-氧基苯胺(CLARIANT公司制“SanduvorVSU”)等具有取代在氮原子上的芳基等的草酸二酰胺类。
作为所述具有苯甲酸酯结构的紫外线屏蔽剂,例如可举出2,4-二叔丁基苯基-3,5-二叔丁基-4-羟基苯甲酸酯(BASF公司制“Tinuvin120”)等。
(抗氧化剂)
所述中间膜可以包含抗氧化剂。所述包含固化物的层可以包含抗氧化剂。所述包含树脂的层可以包含抗氧化剂。所述第1层可以包含抗氧化剂。所述第2层可以包含抗氧化剂。所述第3层可以包含抗氧化剂。所述抗氧化剂可以仅使用1种或组合使用2种以上。
作为所述抗氧化剂,可举出酚类抗氧化剂、硫类抗氧化剂和磷类抗氧化剂等。所述酚类抗氧化剂为具有酚骨架的抗氧化剂。所述硫类抗氧化剂为含有硫原子的抗氧化剂。所述磷类抗氧化剂为含有磷原子的抗氧化剂。
作为所述酚类抗氧化剂,可举出:2,6-二叔丁基-对甲酚(BHT)、丁基羟基苯甲醚(BHA)、2,6-二叔丁基-4-乙基酚、硬脂基-β-(3,5-二叔丁基-4-羟基苯基)丙酸酯、2,2’-亚甲基双-(4-甲基-6-丁基酚)、2,2’-亚甲基双-(4-乙基-6-叔丁基酚)、4,4’-亚丁基-双-(3-甲基-6-叔丁基酚)、1,1,3-三-(2-甲基-羟基-5-叔丁基苯基)丁烷、四[亚甲基-3-(3’,5’-丁基-4-羟基苯基)丙酸酯]甲烷、1,3,3-三-(2-甲基-4-羟基-5-叔丁基酚)丁烷、1,3,5-三甲基-2,4,6-三(3,5-二叔丁基-4-羟基苄基)苯、双(3,3’-叔丁基酚)丁酸乙二醇酯和双(3-叔丁基-4-羟基-5-甲基苯丙酸)乙烯双(氧乙烯)等。优选使用这些抗氧化剂中的1种或2种以上。
作为所述磷类抗氧化剂,可举出:亚磷酸十三烷酯、亚磷酸三(十三烷基)酯、亚磷酸三苯酯、亚磷酸三壬基苯酯、二亚磷酸双(十三烷基)季戊四醇酯、二亚磷酸双(癸基)季戊四醇酯、亚磷酸三(2,4-二叔丁基苯基)酯、亚磷酸双(2,4-二叔丁基-6-甲基苯基)乙酯和2,2’-亚甲基双(4,6-二叔丁基-1-苯氧基)(2-乙基己氧基)磷等。优选使用这些抗氧化剂中的1种或2种以上。
作为所述抗氧化剂的市售品,例如可举出:BASF公司制“IRGANOX 245”、BASF公司制“IRGAFOS 168”、BASF公司制“IRGAFOS 38”、住友化学工业公司制“SUMILIZERBHT”、堺化学工业公司制“H-BHT”、以及BASF公司制“IRGANOX 1010”等。
(其他成分)
所述中间膜、所述包含固化物的层、所述包含树脂的层、所述所述第1层、所述第2层以及所述第3层,分别根据需要可以包含偶联剂、分散剂、表面活性剂、阻燃剂、抗静电剂、颜料、染料、金属盐以外的粘接力调整剂、耐湿剂、荧光增白剂和红外线吸收剂等的添加剂。这些添加剂可以仅使用1种或组合使用2种以上。
(夹层玻璃用中间膜的其他详细)
所述中间膜的厚度没有特别限定。从实用面的观点、以及充分提高夹层玻璃的耐贯穿性和弯曲刚性的观点出发,中间膜的厚度优选为0.1mm以上,更优选为0.25mm以上,优选为3mm以下,更优选为1.5mm以下。中间膜的厚度为所述下限以上时,夹层玻璃的耐贯穿性和弯曲刚性进一步提高。中间膜的厚度为所述上限以下时,中间膜的透明性进一步变得良好。
将中间膜的厚度设为T。从在广温度范围进一步提高隔音性的观点出发,所述包含固化物的层的厚度(每一层的厚度)优选为0.03T以上,更优选为0.06T以上,进一步优选为0.1T以上,优选为1T以下,更优选为0.5T以下,进一步优选为0.2T以下。
从在广温度范围进一步提高隔音性的观点出发,所述包含树脂的层的厚度(每一层的厚度)优选为0.3T以上,更优选为0.35T以上,进一步优选为0.4T以上,优选为0.95T以下,更优选为0.9T以下。
从在广温度范围进一步提高隔音性的观点出发,所述包含固化物的层的厚度(每一层的厚度)优选为15μm以上,更优选为40μm以上,进一步优选为80μm以上,优选为600μm以下,更优选为300μm以下,进一步优选为150μm以下。
从在广温度范围进一步提高隔音性的观点出发,所述包含树脂的层的厚度(每一层的厚度)优选为200μm以上,更优选为400μm以上,进一步优选为600μm以上,优选为1200μm以下,更优选为1000μm以下,进一步优选为850μm以下。
所述中间膜可以为厚度均匀的中间膜或厚度发生变化的中间膜。所述中间膜的截面形状可以为矩形或楔形。
作为本发明的中间膜的制造方法,没有特别限定。作为本发明的中间膜的制造方法,在单层中间膜的情况下,可举出将树脂组合物使用挤出机而挤出的方法。作为本发明的中间膜的制造方法,在多层中间膜的情况下,可举出:使用用于形成各层的各树脂组合物而分别形成各层后,例如,将得到的各层进行叠层的方法;以及将用于形成各层的各树脂组合物使用挤出机进行共挤出,而叠层各层的方法等。由于适用于连续性的生产,因此优选挤出成形的制造方法。
从中间膜的制造效率优异的方面出发,优选所述第2层和所述第3层包含相同的聚乙烯醇缩醛树脂,更优选所述第2层和所述第3层包含相同的聚乙烯醇缩醛树脂和相同的增塑剂。从中间膜的制造效率优异的方面出发,更优选所述第2层和所述第3层由相同的树脂组合物形成。
所述中间膜优选在两侧的表面中的至少一个表面具有凹凸形状。所述中间膜更优选在两侧的表面具有凹凸形状。作为形成所述的凹凸形状的方法没有特别限定,例如,唇压纹法、压纹辊法、压延辊法和型材押出法等。从能够定量性地形成作为一定的凹凸模样的多个凹凸形状的雕花的方面出发,优选压纹辊法。
(夹层玻璃)
本发明的夹层玻璃具备第1夹层玻璃部件、第2夹层玻璃部件、以及所述夹层玻璃用中间膜。本发明的夹层玻璃中,所述夹层玻璃用中间膜配置在所述第1夹层玻璃部件和所述第2夹层玻璃部件之间。
图3为示意性地表示使用了图1表示的夹层玻璃用中间膜的夹层玻璃的一个实例的截面图。
图3表示的夹层玻璃31具备第1夹层玻璃部件21、第2夹层玻璃部件22以及中间膜11。中间膜11配置并夹入于第1夹层玻璃部件21和第2夹层玻璃部件22之间。
第1夹层玻璃部件21叠层在中间膜11的第1表面11a。第2夹层玻璃部件22叠层在中间膜11的与第1表面11a相反的第2表面11b。第1夹层玻璃部件21叠层在第2层2的外侧的表面2a。第2夹层玻璃部件22叠层在第3层3的外侧的表面3a。
图4为示意性地表示使用了图2表示的夹层玻璃用中间膜的夹层玻璃的一个实例的截面图。
图4表示的夹层玻璃31A具备第1夹层玻璃部件21、第2夹层玻璃部件22以及中间膜11A。中间膜11A配置并夹入于第1夹层玻璃部件21和第2夹层玻璃部件22之间。
第1夹层玻璃部件21叠层在中间膜11A的第1表面11a。第2夹层玻璃部件22叠层在中间膜11A的与第1表面11a相反的第2表面11b。
这样,本发明的夹层玻璃具备第1夹层玻璃部件、第2夹层玻璃部件、以及中间膜,该中间膜为本发明的夹层玻璃用中间膜。本发明的夹层玻璃中,所述中间膜配置在所述第1夹层玻璃部件和所述第2夹层玻璃部件之间。
所述第1夹层玻璃部件优选为第1玻璃板。所述第2夹层玻璃部件优选为第2玻璃板。
作为所述第1、第2夹层玻璃部件,可举出玻璃板和PET(聚对苯二甲酸乙二醇酯)膜等。所述夹层玻璃中,不只是在2片玻璃板之间夹入中间膜而得的夹层玻璃,还包含在玻璃板和PET膜等之间夹入中间膜而得的夹层玻璃。所述夹层玻璃为具备玻璃板的叠层体,优选使用了至少1片玻璃板。所述第1夹层玻璃部件和所述第2夹层玻璃部件分别为玻璃板或PET膜,并且所述夹层玻璃优选具备玻璃板作为所述第1夹层玻璃部件和所述第2夹层玻璃部件中的至少一者。特别优选所述第1、第2夹层玻璃部件这两者为玻璃板。
作为所述玻璃板,可举出无机玻璃和有机玻璃。作为所述无机玻璃,可举出浮法玻璃板、热线吸收玻璃板、热线反射玻璃板、抛光板玻璃、模板玻璃和夹丝玻璃等。所述有机玻璃为替代无机玻璃的合成树脂玻璃。作为所述有机玻璃,可举出聚碳酸酯板和聚(甲基)丙烯酸类树脂板等。作为所述聚(甲基)丙烯酸类树脂板,可举出聚(甲基)丙烯酸甲酯板等。
所述第1夹层玻璃部件和所述第2夹层玻璃部件的各厚度优选为1mm以上,优选为5mm以下,更优选为3mm以下。此外,所述夹层玻璃部件为玻璃板的情况下,该玻璃板的厚度优选为0.5mm以上,更优选为0.7mm以上,优选为5mm以下,更优选为3mm以下。所述夹层玻璃部件为PET膜的情况下,该PET膜的厚度优选为0.03mm以上,优选为0.5mm以下。
所述夹层玻璃的制造方法没有特别限定。例如,在所述第1夹层玻璃部件和所述第2夹层玻璃部件之间夹入中间膜,通过按压辊,或放入橡胶袋中进行减压抽吸,而将残留在所述第1夹层玻璃部件、所述第2夹层玻璃部件以及中间膜之间的空气进行脱气。然后,在约70~110℃下进行预压合而得到叠层体。接下来,将叠层体放入高压釜,或进行压制,而在约120~150℃和1~1.5MPa的压力下进行压合。由此,能够得到夹层玻璃。所述夹层玻璃的制造时,可以将中间膜中的各层进行叠层。
所述中间膜和所述夹层玻璃,能够用于车辆、铁道车辆、航天器、船舶和建筑物等。所述中间膜和所述夹层玻璃也可以用于这些用途以外。所述中间膜和所述夹层玻璃,优选为用于车辆或用于建筑物的中间膜和夹层玻璃,更优选为用于车辆的中间膜和夹层玻璃。所述中间膜和所述夹层玻璃,可以用于车辆的挡风玻璃、侧玻璃、后玻璃或顶玻璃等。所述中间膜和所述夹层玻璃优选用于车辆。所述中间膜用于得到车辆的夹层玻璃。
以下,举出实施例和比较例来对本发明更详细地进行说明。本发明不限于这些实施例。
准备以下的材料。
需要说明的是,就聚乙烯醇缩醛树脂而言,缩醛化度(缩丁醛化度)、乙酰化度和羟基的含有率通过基于JIS K6728“聚乙烯醇缩丁醛试验方法”的方法而测定。需要说明的是,在通过ASTM D1396-92进行测定的情况下,也显示出与基于JIS K6728“聚乙烯醇缩丁醛试验方法”的方法同样的数值。此外,在缩醛的种类为缩乙醛等的情况下,缩醛化度同样通过测定乙酰化度、羟基的含有率,根据得到的测定结果而计算摩尔分数,接着从100摩尔%减去乙酰化度和羟基的含有率,而进行计算。
(树脂)
聚乙烯醇缩醛树脂(1)(使用正丁醛,聚合度1700,羟基的含有率33.5摩尔%,乙酰化度1摩尔%,缩丁醛化度65.5摩尔%)
聚乙烯醇缩醛树脂(2)(使用正丁醛,聚合度3000,羟基的含有率24摩尔%,乙酰化度12摩尔%,缩丁醛化度64摩尔%)
聚乙酸乙烯酯(聚合度2400)
丙烯酸类(PMMA)聚合物(热塑性树脂,(MITSUBISHI RAYON公司制,MF001,维卡软化温度89℃(JIS K7206),熔融指数14.0g/10min(JIS K7210,230℃,37.3N))
(固化物)
(甲基)丙烯酸类聚合物(1)~(9)、(11)、(12)、(A)和(B):
将具有下述的表1、2表示的混合组成的聚合性组合物夹入2片进行了单面脱模处理的PET片(NIPPA公司制,厚度50μm)中,以设为厚度100μm的方式形成聚合性组合物层。需要说明的是,在2片PET片的周围设置了间隔物。使用高压水银UV灯,以照射量3000mJ/cm2对聚合性组合物层照射紫外线,使聚合性组合物反应而使其固化,得到(甲基)丙烯酸类聚合物(1)~(9)、(11)、(12)、(A)和(B)。
(甲基)丙烯酸类聚合物(10):
将具有下述的表2表示的混合组成的聚合性组合物夹入2片进行了单面脱模处理PET片(NIPPA公司制,厚度50μm)中,以设为厚度810μm的方式形成聚合性组合物层。需要说明的是,在2片PET片的周围配置了间隔物。使用化学灯(东芝公司制“FL20SBL”),以照射量5000mJ/cm2对聚合性组合物层照射紫外线,使聚合性组合物反应而使其固化。此外,将一个PET片脱模后,在100℃加热干燥30分钟,而得到(甲基)丙烯酸类聚合物(10)。
(增塑剂)
三乙二醇二-2-乙基己酸酯(3GO)
(金属盐M)
Mg混合物(2-乙基丁酸镁和乙酸镁的50:50(重量比)混合物)
(紫外线屏蔽剂)
Tinuvin326(2-(2’-羟基-3’-叔丁基-5-甲基苯基)-5-氯苯并***,BASF公司制“Tinuvin326”)
(抗氧化剂)
BHT(2,6-二-叔丁基-对甲酚)
(添加剂)
添加剂(1):9,9-双[4-(2-羟基乙氧基)苯基]芴
添加剂(2):YS树脂SX100(苯乙烯低聚物,YASUHARA CHEMICAL公司制)
(实施例1)
第1层的制备:
准备上述得到的(甲基)丙烯酸类聚合物(1)(包含固化物的层,厚度100μm)。
第2、第3层的制备:
将以下的混合成分进行混合,通过混合辊充分进行混炼,得到用于形成第2、第3层的组合物。
聚乙烯醇缩醛树脂(1)100重量份
增塑剂(3GO)35重量份
在得到的第2、第3层中成为70ppm的量的金属盐M(Mg混合物)
在得到的第2、第3层中成为0.2重量%的量的紫外线屏蔽剂(Tinuvin326)
在得到的第2、第3层中成为0.2重量%的量的抗氧化剂(BHT)
将得到的用于形成第2、第3层的组合物使用挤出机押出,得到第2、第3层(各层厚度380μm)。
中间膜的制备:
将叠层在第1层的经过了脱模处理的PET片剥离,使用辊式覆膜机贴合至第2层,将第1层和第2层进行压合,得到2层叠层体。接着将叠层在第1层的另一侧的经过了脱模处理的PET片剥离,所述同样地将第1层和第3层进行压合,而得到具有第2层/第1层/第3层结构的中间膜。
用于隔音性评价(初次损耗系数测定)的夹层玻璃的制备:
将得到的中间膜切断为宽度25mm和长度300mm的尺寸。准备两个玻璃板(透明浮法玻璃,宽度25mm,长度300mm和厚度2mm)作为第1夹层玻璃部件和第2夹层玻璃部件。在2片玻璃板之间夹入中间膜,得到叠层体。将该叠层体装入橡胶袋内,以2.6kPa的真空度进行20分钟脱气后,在脱气的状态下移至烘箱内,进一步在90℃下保持30分钟并真空压制,将叠层体进行预压合。在高压釜中在135℃和压力1.2MPa的条件下,将进行了预压合的叠层体压合20分钟,得到夹层玻璃。
用于雾度评价的夹层玻璃的制备:
将得到的中间膜切成宽度100mm、长度100mm的尺寸。作为第1夹层玻璃部件和第2夹层玻璃部件,准备两个玻璃板(透明浮法玻璃,宽度100mm、长度100mm和厚度2mm)。在2片玻璃板之间,夹入中间膜,得到叠层体。将该叠层体放入橡胶袋内,在2.6kPa的真空度下脱气20分钟后,在脱气的状态下移至烘箱内,进一步在90℃下保持30分钟而真空压制,将叠层体预压合。在高压釜中在135℃和压力1.2MPa的条件下,将进行了预压合的叠层体压合20分钟,得到夹层玻璃。
(实施例2~9)
除了将混合成分的种类和混合量如下述的表3、4表示地进行设定以外,以与实施例1同样的方式,而制备中间膜。需要说明的是,第2、第3层中,以与实施例1同样的种类和混合量而混合金属盐M、紫外线屏蔽剂和抗氧化剂(表3、4中省略)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(实施例10)
作为中间膜,准备所述得到的(甲基)丙烯酸类聚合物(10)(包含固化物的层,厚度810μm)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(实施例11~14)
第1层的制备:
混合表4的混合成分,通过混合辊充分进行混炼,得到用于形成第1层的组合物后,压制成型为厚度100μm,得到包含(甲基)丙烯酸类聚合物(11)或(12)的固化物的层。
第2、第3层的制备:
混合表4的混合成分,通过混合辊充分进行混炼,得到用于形成第2、第3层的组合物。
中间膜的制备:
除了将混合成分的种类和混合量如下述的表4表示的进行设定以外,以与实施例1同样的方式,而制备中间膜。需要说明的是,在第2、第3层中,混合与实施例1同样的种类和混合量的金属盐M、紫外线屏蔽剂和抗氧化剂(表4中省略)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(比较例1)
将聚乙烯醇缩醛树脂(2)100重量份、增塑剂(3GO)75重量份、在得到的中间膜中成为0.2重量%的量的紫外线屏蔽剂(Tinuvin326)、在得到的中间膜中成为0.2重量%的量的抗氧化剂(BHT)混合,通过混合辊充分进行混炼,得到用于形成第1层的组合物。
与实施例1相同,准备用于形成第2、第3层的组合物。
将得到的用于形成第1层的组合物和得到的用于形成第2、第3层的组合物使用共挤出机进行共挤出,得到具有第2层/第1层/第3层结构的中间膜(第1层的厚度100μm,第2、第3层的各层厚度380μm)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(比较例2、3)
除了将混合成分的种类和混合量如下述的表5表示的进行设定,并且将厚度如下述的表5表示的进行设定以外,以与比较例1同样的方式,而制备中间膜。需要说明的是,在第2、第3层中,以与比较例1同样的种类和混合量而混合金属盐M、紫外线屏蔽剂和抗氧化剂(表5中省略)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(比较例4)
混合以下的混合成分,通过混合辊充分进行混炼,得到用于形成中间膜的组合物。
聚乙烯醇缩醛树脂(2)100重量份
增塑剂(3GO)75重量份
在得到的中间膜中成为70ppm的量的金属盐M(Mg混合物)
在得到的中间膜中成为0.2重量%的量的紫外线屏蔽剂(Tinuvin326)
在得到的中间膜中成为0.2重量%的量的抗氧化剂(BHT)
添加剂(添加剂(1):9,9-双[4-(2-羟基乙氧基)苯基]芴)75重量份
将得到的用于形成中间膜的组合物使用挤出机而挤出,得到中间膜(厚度810μm)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(比较例5)
准备丙烯酸类(PMMA)聚合物作为用于形成第1层的组合物。
与实施例1相同,准备用于形成第2、第3层的组合物。
将得到的用于形成第1层的组合物和得到的用于形成第2、第3层的组合物使用共挤出机进行共挤出,得到具有第2层/第1层/第3层结构的中间膜(第1层的厚度100μm,第2、第3层的各层厚度380μm)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(比较例6、7)
除了将混合成分的种类和混合量如下述的表5表示的进行设定以外,以与实施例1同样的方式,而制备中间膜。需要说明的是,在第2、第3层中,以与实施例1同样的种类和混合量而混合金属盐M、紫外线屏蔽剂和抗氧化剂(表5中省略)。
除了使用了得到的中间膜以外,以与实施例1同样的方式,得到夹层玻璃。
(评价)
(1)动态粘弹性测定
对于得到的具有仅第1层结构的中间膜和得到的具有第2层/第1层/第3层结构的中间膜,进行动态粘弹性测定。使用动态粘弹性测定装置(IT计测制御株式会社制,DVA-200),在剪切模式,以3℃/分的升温速度从-50℃升温至200℃的条件并且频率1Hz和应变1%的条件下测定动态粘弹性,而对于以下的项目进行评价。
第1层的tanδ的峰值温度
第1层在tanδ的峰值温度下的tanδ(1)
第2、3层的tanδ的峰值温度
第2、3层在tanδ的峰值温度下的tanδ(2)
比(tanδ(1)/tanδ(2))
第1层在100℃下的第1层储能模量G’
(2)初次损耗系数(隔音性)
对于得到的夹层玻璃,通过用于阻尼试验的振动发生机(振研公司制“加振机G21-005D”)而施加振动。将由此得到的振动特性通过机械阻抗测定装置(RION公司制“XG-81”)进行增幅,通过FFT频谱分析仪(RION公司制“FFT Analyzer SA-01A2”)对振动频谱进行解析。
根据所述初次损耗系数,对于隔音性以以下的基准进行判定。
[隔音性的判定基准]
○○:初次损耗系数为0.35以上
○:初次损耗系数为0.2以上并且低于0.35
△:初次损耗系数为0.1以上并且低于0.2
×:初次损耗系数低于0.1
(3)雾度
测定刚制备后的夹层玻璃的雾度。此外,将刚制备后的夹层玻璃在23℃、50%RH下保管4周后,测定保管后的夹层玻璃的雾度。
[刚制备后的夹层玻璃的雾度的判定基准]
○:雾度为2.5%以下
×:雾度超过2.5%
[保管后的夹层玻璃的雾度的判定基准]
○:保管后的雾度相对于保管前的雾度的比为0.99以上1.01以下
△:保管后的雾度相对于保管前的雾度的比为0.5以上并且低于0.99,或,超过1.01并且为1.5以下
×:保管后的雾度相对于保管前的雾度的比低于0.5,或,超过1.5
详细内容和结果如下述的表1~5表示。需要说明的是,下述的表3~5中,省略了金属盐M、紫外线屏蔽剂和抗氧化剂的记载。需要说明的是,表3~5中,“E+03”表示“×103”,“E+04”表示“×104”,“E+05”表示“×105”。
[表1]
[表2]
表1、2表示的成分的详细内容如下所述。
EA:丙烯酸乙酯(NIPPON SHOKUBAI公司制)
HEA:丙烯酸2-羟基乙酯(大阪有机化学工业公司制)
BzA:丙烯酸苄酯(大阪有机化学工业公司制,VISCOAT#160)
BA:丙烯酸正丁酯(NIPPON SHOKUBAI公司制)
THF-A:丙烯酸四氢糠酯(大阪有机化学工业公司制,VISCOAT#150)
CHA:丙烯酸环己酯(大阪有机化学工业公司制,VISCOAT#155)
HPA:丙烯酸羟基丙酯(大阪有机化学工业公司制)
CTFA(#200):环状三羟甲基丙烷甲缩醛丙烯酸酯(大阪有机化学工业公司制,VISCOAT#200)
2-EHA:丙烯酸2-乙基己酯(NIPPON SHOKUBAI公司制)
ISTA:丙烯酸异硬脂酯(大阪有机化学工业公司制)
4HBA:丙烯酸4-羟基丁酯(大阪有机化学工业公司制)
IBOA:丙烯酸异冰片酯(NIPPON SHOKUBAI公司制)
IRGACURE 184:2,2-二甲氧基-1,2-二苯基乙烷-1-酮(BASF公司制)
符号说明
1…第1层
1a…第1表面
1b…第2表面
2…第2层
2a…外侧的表面
3…第3层
3a…外侧的表面
11…中间膜
11A…中间膜(第1层)
11a…第1表面
11b…第2表面
21…第1夹层玻璃部件
22…第2夹层玻璃部件
31…夹层玻璃
31A…夹层玻璃
Claims (8)
1.一种夹层玻璃用中间膜,其为具有1层结构或2层以上结构的夹层玻璃用中间膜,其中,
所述中间膜具备包含固化物的层,
所述固化物是使光固化性化合物或湿固化性化合物固化而得的固化物,
所述包含固化物的层在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为-50℃以上30℃以下,并且在所述tanδ的峰值温度下tanδ为2.0以上。
2.根据权利要求1所述的夹层玻璃用中间膜,其中,
所述固化物是使光固化性化合物固化而得的固化物。
3.一种夹层玻璃用中间膜,其为具有1层结构或2层以上结构的夹层玻璃用中间膜,其中,
所述中间膜具备包含固化物的层,
所述固化物是使具有(甲基)丙烯酰基的固化性化合物固化而得的固化物,
所述包含固化物的层在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为-50℃以上30℃以下,并且在所述tanδ的峰值温度下tanδ为2以上。
4.根据权利要求1~3中任一项所述的夹层玻璃用中间膜,其中,
所述包含固化物的层在100℃下的储能模量G’为5.0×103Pa以上。
5.根据权利要求1~4中任一项所述的夹层玻璃用中间膜,其中,
所述包含固化物的层在频率为1Hz并且基于剪切模式的粘弹性测定中,tanδ的峰值温度为-30℃以上20℃以下。
6.根据权利要求1~5中任一项所述的夹层玻璃用中间膜,其为具有2层以上结构的夹层玻璃用中间膜,其中,
所述中间膜具备所述包含与固化物不同的树脂的层。
7.根据权利要求1~5中任一项所述的夹层玻璃用中间膜,其为具有2层以上结构的夹层玻璃用中间膜,其中,
所述中间膜具备所述包含与固化物不同的树脂的层,
所述中间膜在频率为1Hz并且基于剪切模式的粘弹性测定中,所述包含与固化物不同的树脂的层的tanδ的峰值温度为-100℃以上100℃以下,
所述中间膜在频率为1Hz并且基于剪切模式的粘弹性测定中,所述包含固化物的层在tanδ的峰值温度下的tanδ相对于所述包含与固化物不同的树脂的层在tanδ的峰值温度下的tanδ的比为2.0以上10.0以下。
8.一种夹层玻璃,其具备:
第1夹层玻璃部件、
第2夹层玻璃部件、以及
权利要求1~7中任一项所述的夹层玻璃用中间膜,其中,
在所述第1夹层玻璃部件和所述第2夹层玻璃部件之间配置有所述夹层玻璃用中间膜。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202211356788.0A CN115648751A (zh) | 2018-02-02 | 2019-01-30 | 夹层玻璃用中间膜和夹层玻璃 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018-017724 | 2018-02-02 | ||
JP2018017724 | 2018-02-02 | ||
PCT/JP2019/003181 WO2019151328A1 (ja) | 2018-02-02 | 2019-01-30 | 合わせガラス用中間膜及び合わせガラス |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202211356788.0A Division CN115648751A (zh) | 2018-02-02 | 2019-01-30 | 夹层玻璃用中间膜和夹层玻璃 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111655650A true CN111655650A (zh) | 2020-09-11 |
CN111655650B CN111655650B (zh) | 2022-11-18 |
Family
ID=67478805
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201980010737.2A Active CN111655650B (zh) | 2018-02-02 | 2019-01-30 | 夹层玻璃用中间膜和夹层玻璃 |
CN202211356788.0A Pending CN115648751A (zh) | 2018-02-02 | 2019-01-30 | 夹层玻璃用中间膜和夹层玻璃 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202211356788.0A Pending CN115648751A (zh) | 2018-02-02 | 2019-01-30 | 夹层玻璃用中间膜和夹层玻璃 |
Country Status (9)
Country | Link |
---|---|
US (1) | US20210060907A1 (zh) |
EP (1) | EP3747845A4 (zh) |
JP (1) | JP7316213B2 (zh) |
KR (1) | KR20200118018A (zh) |
CN (2) | CN111655650B (zh) |
BR (1) | BR112020014919A2 (zh) |
MX (1) | MX2020007937A (zh) |
TW (1) | TWI798349B (zh) |
WO (1) | WO2019151328A1 (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114072366B (zh) | 2019-07-02 | 2024-07-19 | 积水化学工业株式会社 | 夹层玻璃用中间膜和夹层玻璃 |
EP4269091A1 (en) * | 2020-12-28 | 2023-11-01 | Agc Inc. | Layered resin film, and laminate |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1176787A (en) * | 1980-05-26 | 1984-10-23 | Pierre Chevreux | Photosetting adhesive composition |
JP2009091434A (ja) * | 2007-10-05 | 2009-04-30 | Sekisui Chem Co Ltd | 中間膜用重合性組成物、中間膜及び透明積層体 |
CN102256910A (zh) * | 2008-12-22 | 2011-11-23 | 积水化学工业株式会社 | 夹层玻璃用层叠体及夹层玻璃用中间膜 |
WO2013051717A1 (ja) * | 2011-10-07 | 2013-04-11 | 旭硝子株式会社 | 積層体の製造方法 |
US20170028687A1 (en) * | 2015-07-31 | 2017-02-02 | Corning Incorporated | Laminate structures with enhanced damping properties |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8828634D0 (en) * | 1988-12-08 | 1989-01-11 | Glaverbel | Composite glazing panel |
US5464659A (en) * | 1991-05-23 | 1995-11-07 | Minnesota Mining And Manufacturing Company | Silicone/acrylate vibration dampers |
ES2183106T5 (es) * | 1996-11-26 | 2016-09-29 | Saint-Gobain Glass France | Utilización de un acristalamiento laminado para la amortiguación de vibraciones de origen sólido en un vehículo |
WO2005066094A1 (ja) * | 2003-12-26 | 2005-07-21 | Sekisui Chemical Co., Ltd. | 合わせガラス用中間膜及び合わせガラス |
US20070036956A1 (en) * | 2005-08-15 | 2007-02-15 | Solutia, Inc. | Interlayers comprising an ultraviolet curable layer |
JP2007070200A (ja) * | 2005-09-09 | 2007-03-22 | Asahi Glass Co Ltd | 合わせガラス |
JP5220956B2 (ja) * | 2010-08-24 | 2013-06-26 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
JP5827161B2 (ja) * | 2012-03-28 | 2015-12-02 | 富士フイルム株式会社 | コレステリック液晶性混合物、フィルム、赤外反射板、積層体および合わせガラス |
AU2016242392A1 (en) * | 2015-03-31 | 2017-06-08 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass, and laminated glass |
US11325354B2 (en) | 2016-03-28 | 2022-05-10 | Kuraray Co., Ltd. | Interlayer film for laminated glass |
JPWO2017204342A1 (ja) * | 2016-05-27 | 2019-03-28 | 日本化薬株式会社 | 合わせガラス用中間膜及びこれを用いた合わせガラス |
WO2017209013A1 (ja) | 2016-06-01 | 2017-12-07 | 日立化成株式会社 | 合わせガラスの中間膜用光硬化性樹脂組成物、合わせガラスの中間膜用フィルム材及び合わせガラスの製造方法 |
EP3578530A4 (en) * | 2017-02-03 | 2020-11-18 | Sekisui Chemical Co., Ltd. | INTERMEDIATE FILM FOR LAMINATED GLASS AND LAMINATED GLASS |
JP7060515B2 (ja) * | 2017-07-24 | 2022-04-26 | 積水化学工業株式会社 | 樹脂膜及びガラス板含有積層体 |
-
2019
- 2019-01-30 US US16/965,200 patent/US20210060907A1/en not_active Abandoned
- 2019-01-30 EP EP19747824.1A patent/EP3747845A4/en not_active Withdrawn
- 2019-01-30 MX MX2020007937A patent/MX2020007937A/es unknown
- 2019-01-30 JP JP2019516004A patent/JP7316213B2/ja active Active
- 2019-01-30 CN CN201980010737.2A patent/CN111655650B/zh active Active
- 2019-01-30 BR BR112020014919-5A patent/BR112020014919A2/pt not_active Application Discontinuation
- 2019-01-30 CN CN202211356788.0A patent/CN115648751A/zh active Pending
- 2019-01-30 WO PCT/JP2019/003181 patent/WO2019151328A1/ja unknown
- 2019-01-30 KR KR1020207022053A patent/KR20200118018A/ko not_active Application Discontinuation
- 2019-02-01 TW TW108104083A patent/TWI798349B/zh active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1176787A (en) * | 1980-05-26 | 1984-10-23 | Pierre Chevreux | Photosetting adhesive composition |
JP2009091434A (ja) * | 2007-10-05 | 2009-04-30 | Sekisui Chem Co Ltd | 中間膜用重合性組成物、中間膜及び透明積層体 |
CN102256910A (zh) * | 2008-12-22 | 2011-11-23 | 积水化学工业株式会社 | 夹层玻璃用层叠体及夹层玻璃用中间膜 |
WO2013051717A1 (ja) * | 2011-10-07 | 2013-04-11 | 旭硝子株式会社 | 積層体の製造方法 |
US20170028687A1 (en) * | 2015-07-31 | 2017-02-02 | Corning Incorporated | Laminate structures with enhanced damping properties |
Also Published As
Publication number | Publication date |
---|---|
WO2019151328A1 (ja) | 2019-08-08 |
TWI798349B (zh) | 2023-04-11 |
MX2020007937A (es) | 2020-09-03 |
CN111655650B (zh) | 2022-11-18 |
KR20200118018A (ko) | 2020-10-14 |
EP3747845A1 (en) | 2020-12-09 |
EP3747845A4 (en) | 2021-10-06 |
TW201936393A (zh) | 2019-09-16 |
JP7316213B2 (ja) | 2023-07-27 |
JPWO2019151328A1 (ja) | 2020-12-03 |
BR112020014919A2 (pt) | 2020-12-08 |
US20210060907A1 (en) | 2021-03-04 |
CN115648751A (zh) | 2023-01-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110536875B (zh) | 夹层玻璃用中间膜和夹层玻璃 | |
CN111655648B (zh) | 夹层玻璃用中间膜和夹层玻璃 | |
CN111655647B (zh) | 夹层玻璃用中间膜和夹层玻璃 | |
CN110621744B (zh) | 树脂膜以及包含玻璃板的叠层体 | |
CN114072367B (zh) | 夹层玻璃用中间膜以及夹层玻璃 | |
CN111655650B (zh) | 夹层玻璃用中间膜和夹层玻璃 | |
CN114072365A (zh) | 夹层玻璃用中间膜以及夹层玻璃 | |
CN111683911A (zh) | 夹层玻璃用中间膜、卷体和夹层玻璃 | |
CN112334426B (zh) | 夹层玻璃用中间膜及夹层玻璃 | |
CN114072366B (zh) | 夹层玻璃用中间膜和夹层玻璃 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |