CN110241500B - Production process of antibacterial wool textile - Google Patents
Production process of antibacterial wool textile Download PDFInfo
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- CN110241500B CN110241500B CN201910413267.6A CN201910413267A CN110241500B CN 110241500 B CN110241500 B CN 110241500B CN 201910413267 A CN201910413267 A CN 201910413267A CN 110241500 B CN110241500 B CN 110241500B
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- 210000002268 wool Anatomy 0.000 title claims abstract description 159
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 29
- 239000004753 textile Substances 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000835 fiber Substances 0.000 claims abstract description 20
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 16
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 16
- 241001330002 Bambuseae Species 0.000 claims abstract description 16
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 16
- 239000011425 bamboo Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000009941 weaving Methods 0.000 claims abstract description 8
- 238000004043 dyeing Methods 0.000 claims abstract description 7
- 238000004140 cleaning Methods 0.000 claims abstract description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
- 238000002791 soaking Methods 0.000 claims description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 10
- 239000004332 silver Substances 0.000 claims description 10
- 238000007747 plating Methods 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000010779 crude oil Substances 0.000 claims description 6
- 230000001954 sterilising effect Effects 0.000 claims description 6
- 238000004659 sterilization and disinfection Methods 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 241000347389 Serranus cabrilla Species 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 238000009940 knitting Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000004544 sputter deposition Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000004804 winding Methods 0.000 claims description 3
- 208000005156 Dehydration Diseases 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- 239000001117 sulphuric acid Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 6
- 230000001580 bacterial effect Effects 0.000 abstract description 3
- 239000003242 anti bacterial agent Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 229940123208 Biguanide Drugs 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 235000019687 Lamb Nutrition 0.000 description 1
- AZFKQCNGMSSWDS-UHFFFAOYSA-N MCPA-thioethyl Chemical compound CCSC(=O)COC1=CC=C(Cl)C=C1C AZFKQCNGMSSWDS-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000004283 biguanides Chemical class 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/042—Blended or other yarns or threads containing components made from different materials all components being made from natural material
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/10—Bamboo
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a production process of an antibacterial wool textile, which comprises the following steps: firstly, cleaning wool with water, spin-drying, treating the wool with a first finishing liquid and a second finishing liquid, mixing and weaving the treated wool with treated bamboo fiber filaments, dyeing and finishing the woven mixed wire, and finally obtaining a finished product, namely weaving; the invention provides a production process of an antibacterial wool textile, which is characterized in that wool is treated in the early-stage wool weaving process to be clean and soft, then the antibacterial effect of a wool product is further improved by the later-stage weaving and other operations and by mixing bamboo fiber filaments, the bacterial growth can be greatly resisted or reduced in the later-stage using process, and the antibacterial effect is kept for a long time after washing.
Description
Technical Field
The invention relates to the technical field of fabric weaving, in particular to a production process of an antibacterial wool textile.
Background
The importance of antibacterial finishing of textiles as a necessity in the daily life of people is self-evident. The wool fiber fabric has the advantages of smooth hand feeling, good moisture absorption and heat retention and the like, but the microporous structure and keratin components of the wool fiber provide moisture and nutrition for bacterial breeding. People put higher demands on the sanitary finishing of wool fabrics while wearing comfortable.
In recent years, the antibacterial finishing of wool is mature day by day, and the development of antibacterial wool has great significance for meeting daily requirements, widening application space and promoting the progress of the textile industry. The antibacterial finishing of the wool fibers mainly adopts an after-finishing process, namely, the fabric is endowed with special functions by loading various antibacterial agents. The antibacterial wool finishing mainly comprises inorganic metal ion antibacterial finishing, organic antibacterial finishing, natural antibacterial finishing and nano material antibacterial finishing. In the organic antibacterial finishing, various organic antibacterial agents represented by quaternary ammonium salts are dominant in the market. Medicinal antibacterial agents such as quaternary ammonium salts, biguanides and imidazoles are gradually applied to antibacterial finishing of wool products. However, the common quaternary ammonium salt has a poor binding force with the fiber, and has a certain limitation as a dissolution-type antibacterial agent, which is easily eluted and accumulated in the human body. Therefore, a production process of antibacterial wool textiles is provided.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides a production process of an antibacterial wool textile, which has the characteristics of health, no toxicity and long service life and solves the problems that the antibacterial agent is easy to elute and accumulates in a human body in the prior art.
The invention provides the following technical scheme: a production process of antibacterial wool textiles comprises the following steps:
s1: firstly, soaking wool in clear water, adding a cleaning agent into the wool, stirring, and standing for 15-30 minutes;
s2: after the wool soaking time reaches a preset time, rubbing and cleaning the wool to remove impurities or grease on the wool, after the wool is cleaned, rinsing the wool in deionized water until no foam exists, performing dehydration treatment, and putting the dehydrated wool into a container;
s3: putting the wool cleaned in the step S2 into a drying machine, and further draining and drying;
s4: putting the dried wool in the S3 into a dryer for drying;
s5: adding the wool material dried in the S4 into the crude oil, mixing, and making the wool added with the crude oil into strips and threads through a wool comber and finishing the strips and threads into balls;
s6: putting the knitted wool wires into a pre-prepared first finishing liquid for pre-treatment soaking, then putting the wool wires into a pre-prepared second finishing liquid for soaking, and carrying out airing or drying treatment at room temperature or in a dryer;
s7: placing the bamboo fiber filament in a winding type vacuum machine and carrying out plasma sterilization treatment twice, then carrying out vacuum sputtering silver treatment on the bamboo fiber filament subjected to the plasma sterilization treatment, and finally taking out the bamboo fiber filament subjected to silver plating processing for later use;
s8: mixing the wool wires processed in the step S6 with the bamboo fiber filaments subjected to silver plating processing in the step S7 to weave a thread, and finishing the woven wool mixed wires for later use;
s9: the wool mixed wire is dyed and finished, and the dyeing and finishing comprises two steps: pre-treating and dyeing;
s10: and finishing the dyed wool mixed wire, and knitting the finished wool mixed wire into a wool product.
Preferably, in the drying process in the step S4, the temperature inside the dryer needs to be kept at 50-60 ℃, the pre-drying time is 30-40 minutes, then the temperature of the dryer is adjusted to 160 ℃ of 140-.
Preferably, the finishing liquid I in the S6 comprises a surfactant, and the bath ratio of the surfactant to water is 40: 1.
Preferably, the No. two finishing solution in S6 includes a sodium sulfate solution, and the bath ratio of the sodium sulfate solution to water is 50: 1, and the pH of the solution needs to be adjusted to about 8.
Preferably, in the step S6, the wool reacts with the first finishing liquid at room temperature for 15-30 minutes, the reacted wool strands are rinsed clean with clean water, the wool reacts with the second finishing liquid at room temperature for 20-40 minutes, the reacted wool strands are rinsed clean with clean water again, and the temperature of the drying or baking process is controlled to be 80-100 ℃.
Preferably, the first step of the step S9 is to pre-treat, put the wool mixed wire into a sealed container, make the wool mixed wire react with the first treatment liquid at 80-100 ℃ for 60 minutes, then take the wool mixed wire out, clean the wool mixed wire for 10 minutes by using hot water at 60-80 ℃, drain, wash the wool mixed wire for 20-40 minutes at 40 ℃ by using 5 grams per liter of sulfuric acid solution, and finally treat the wool mixed wire for 20 minutes at normal temperature by using the deoxidizer with the mass fraction of zero one percent.
Preferably, the first treatment solution comprises 3 grams of sodium hydroxide solution per liter, 0.6 grams of defoaming agent per liter and 12 grams of hydrogen peroxide per liter.
The invention provides a production process of antibacterial wool textiles, which is characterized in that wool is treated in the early-stage wool weaving process to be clean and soft, and then later-stage weaving and other operations are performed, bamboo fiber filaments are mixed, compared with the existing process, the comfort and the structural force of wool products are greatly improved, and the bamboo fiber filaments are used to improve the antibacterial performance of the wool products when the wool products are used, increase the air permeability of the wool products, enable the wool products to have good water absorption and flexibility, increase the wear resistance of the wool products, prolong the service life of the wool products, further improve the antibacterial effect of the wool products through silver plating operation, and greatly reduce the bacterial breeding degree in the later-stage use process, and the antibacterial effect is maintained for a long time after washing.
Drawings
The accompanying drawings, which are included to provide a further understanding of the application and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the application and together with the description serve to explain the application and not to limit the application. In the drawings:
FIG. 1 is a block diagram of the operational flow of the present invention.
Detailed Description
The technical solution of the present invention will be described in detail below with reference to specific examples.
Example 1
The invention discloses a production process of an antibacterial wool textile, which comprises the following steps:
the method comprises the following steps: firstly, soaking wool in clear water, adding a cleaning agent into the wool, stirring, and standing for 15 minutes;
step two: after standing, rubbing and cleaning wool to remove impurities or grease on the wool, after the wool is cleaned, rinsing the wool in deionized water until no foam exists, dewatering, and putting the dewatered wool into a container;
step three: putting the wool cleaned in the step S2 into a drying machine, and further draining and drying;
step four: putting the dried wool in the S3 into a dryer for drying; in the drying process, the temperature in the dryer needs to be kept at 50 ℃, the pre-drying time is 30 minutes, the temperature is adjusted to 140 ℃, and the drying is carried out for 10 minutes;
step five: adding the wool material dried in the S4 into the crude oil, mixing, and making the wool added with the crude oil into strips and threads through a wool comber and finishing the strips and threads into balls;
step six: putting the knitted wool wires into a pre-prepared first finishing liquid for pre-treatment soaking, reacting for 15 minutes at room temperature, rinsing the reacted wool wires with clear water, putting the wool wires into a pre-prepared second finishing liquid for soaking, reacting for 20 minutes at room temperature, rinsing, and airing or drying at 80 ℃ in a room temperature or a dryer;
step seven: placing the bamboo fiber filament in a winding type vacuum machine and carrying out plasma sterilization treatment twice, then carrying out vacuum sputtering silver treatment on the bamboo fiber filament subjected to the plasma sterilization treatment, and finally taking out the bamboo fiber filament subjected to silver plating processing for later use;
step eight: mixing the wool wires processed in the step S6 with the bamboo fiber filaments subjected to silver plating processing in the step S7 to weave a thread, and finishing the woven wool mixed wires for later use;
step nine: the wool mixed wire is dyed and finished, and the dyeing and finishing comprises two steps: pre-treating and dyeing; the first step is pretreatment, the wool mixed wire is treated for 60 minutes at the temperature of 100 ℃ by using the first treatment solution, then the wool mixed wire is cleaned for 10 minutes by using hot water at the temperature of 60 ℃, then 5 grams of sulfuric acid solution per liter is used for washing for 20 minutes at the temperature of 40 ℃, and finally, the wool mixed wire is treated for 10 minutes at normal temperature by using deoxyenzyme with the mass fraction of one-tenth of zero percent;
step ten: and (3) finishing the dyed wool mixed wire, and knitting the finished wool mixed wire into wool products according to the requirements.
This embodiment is fit for processing comparatively high-quality wool (like lamb cashmere), and the predrying temperature who adopts is 50 degrees centigrade, it is long 30 minutes, all-round stoving 140 degrees centigrade, it is long 10 minutes, it directly adopts full stoving to compare current technology, it is inhomogeneous to make the inside and outside moisture evaporation of wool easily, water content produces great difference in the short time, make outside wool take place to warp or burnt, the wool stoving quality that obtains is poor, and adopt predrying processing back, can obtain the preheating effect before the high temperature drying inside and outside the wool, also can make the inside moisture of wool obtain partial evaporation simultaneously, make the inside and outside moisture content difference of wool too big after avoiding follow-up temperature to heighten, produce the damage when effectual wool of avoiding is dried.
The first finishing liquid is adopted for 15 minutes of treatment, the second finishing liquid is adopted for 20 minutes of treatment, the temperature after rinsing is 80 ℃, and the wool is made to be more flexible through rinsing after treatment by adopting a separate treatment method.
The reaction temperature of the wool mixed wire and the first treatment liquid is 100 ℃, the duration is 60 minutes, the wool mixed wire is cleaned by hot water at 60 ℃ for 10 minutes, then 5 grams of sulfuric acid solution per liter is used for washing at 40 ℃ for 20 minutes, and finally residual substances on wool are neutralized through the low-concentration sulfuric acid solution, so that the quality of wool products can be effectively improved.
Example 2:
example 2 differs from example 1 in that this example is suitable for processing normal quality wool, the wool soaking time is 30 minutes, the pre-drying temperature used for wool drying is 60 degrees centigrade, the duration is 40 minutes, the all-round drying time is 20 minutes, the temperature is 160 degrees centigrade, the wool strand is treated with the first finishing liquid for 30 minutes, the reaction time with the second finishing liquid is 40 minutes, after rinsing, the softness of the wool strand after rinsing meets the standard, the temperature for rinsing clean and drying is 100 degrees centigrade, the reaction temperature of the wool mixed strand with the first treating liquid is 100 degrees centigrade for 60 minutes, the wool mixed strand is cleaned with hot water at 80 degrees centigrade for 10 minutes, then 5 grams per liter of sulfuric acid solution is used for washing at 60 degrees centigrade for 40 minutes, and finally the residual substances on the wool are neutralized by the low-concentration sulfuric acid solution, can effectively improve the quality of wool products.
Example 3:
example 3 differs from example 2 in that this example is suitable for processing quality-doubled wool, the wool soaking time is 22 minutes, the wool drying and drying temperature and time are 55 ℃ and 35 minutes, the all-round drying time is 15 minutes and 150 ℃, the moisture content in the wool is slightly greater than that in example 2 after the all-round drying temperature is raised to 150 ℃, although the all-round drying temperature is moderate, the drying strength of the wool is general, the internal humidity is also general, the wool strand is treated with the first finishing liquid for 22 minutes and reacted with the second finishing liquid for 30 minutes, the softness of the wool strand after rinsing meets the standard, the temperature for rinsing and drying is 90 ℃, the reaction temperature of the wool mixed strand with the first treating liquid is 90 ℃ and treated for 60 minutes, the mixed wool wire is cleaned by hot water at 70 ℃ for 10 minutes, then 5 grams per liter of sulfuric acid solution is used for washing at 60 ℃ for 30 minutes, and finally residual substances on the wool are neutralized through the low-concentration sulfuric acid solution, so that the quality of wool products can be effectively improved.
By comparing example 1, example 2 and example 3, it can be concluded that wool processed on the method of example 1 will result in a better quality of wool than processed using the methods of example 2 and example 3.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (3)
1. A production process of antibacterial wool textiles is characterized by comprising the following steps: the method comprises the following steps:
s1: firstly, soaking wool in clear water, adding a cleaning agent into the wool, stirring, and standing for 15-30 minutes;
s2: after the wool soaking time reaches a preset time, rubbing and cleaning the wool to remove impurities or grease on the wool, after the wool is cleaned, rinsing the wool in deionized water until no foam exists, performing dehydration treatment, and putting the dehydrated wool into a container;
s3: putting the wool cleaned in the step S2 into a drying machine, and further draining and drying;
s4: putting the dried wool in the S3 into a dryer for drying;
s5: adding the wool material dried in the S4 into the crude oil, mixing, making strips of the wool added with the crude oil by a wool comber, weaving the strips into lines, and finishing the lines into balls;
s6: putting the knitted wool wire into a first finishing liquid prepared in advance for pretreatment soaking, then putting the wool wire into a second finishing liquid prepared in advance for soaking, and carrying out airing or drying treatment in room temperature or a dryer, wherein the first finishing liquid comprises a surfactant, the bath ratio of the surfactant to water is 40:1, the second finishing liquid comprises a sodium sulfate solution, and the bath ratio of the sodium sulfate solution to the water is 50: 1, adjusting the pH value of the solution to about 8, reacting wool with a first finishing liquid for 15-30 minutes at room temperature, rinsing the reacted wool wires with clear water, reacting the wool with a second finishing liquid for 20-40 minutes at room temperature, rinsing the reacted wool wires with clear water again, and controlling the temperature of the dried or dried wool wires to be 80-100 ℃ during processing;
s7: placing the bamboo fiber filament in a winding type vacuum machine and carrying out plasma sterilization treatment twice, then carrying out vacuum sputtering silver plating treatment on the bamboo fiber filament subjected to the plasma sterilization treatment, and finally taking out the bamboo fiber filament subjected to the silver plating treatment for later use;
s8: mixing the wool wires processed in the step S6 with the bamboo fiber filaments subjected to silver plating processing in the step S7 to weave a thread, and finishing the woven wool mixed wires for later use;
s9: the wool mixed wire is dyed and finished, and the dyeing and finishing comprises two steps: pre-treating and dyeing;
s10: and finishing the dyed wool mixed wire, and knitting the finished wool mixed wire into a wool product.
2. The process for producing an antibacterial wool textile according to claim 1, wherein the process comprises the following steps: in the drying process in the step S4, the temperature inside the dryer needs to be kept at 50-60 ℃, the pre-drying time is 30-40 minutes, then the temperature of the dryer is adjusted to 140-.
3. The process for producing an antibacterial wool textile according to claim 1, wherein the process comprises the following steps: the first step of pretreatment in step S9 is to put the wool mixed wire into a sealed container, to make the wool mixed wire react with the first treatment liquid at 80-100 ℃ for 60 minutes, then take the wool mixed wire out, to clean the wool mixed wire for 10 minutes by using hot water at 60-80 ℃, after draining, to wash the wool mixed wire for 20-40 minutes by using 5 g/L sulphuric acid solution at 40 ℃, finally to treat the wool mixed wire for 20 minutes at normal temperature by using the deoxidizer with the mass fraction of one hundredth, and the first treatment liquid comprises 3 g/L sodium hydroxide solution, 0.6 g/L defoamer and 12 g/L hydrogen peroxide.
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