CN110073458B - 褶皱状石墨烯复合体的制备方法、由此制备的复合体及包含复合体的超级电容器 - Google Patents

褶皱状石墨烯复合体的制备方法、由此制备的复合体及包含复合体的超级电容器 Download PDF

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CN110073458B
CN110073458B CN201780076905.9A CN201780076905A CN110073458B CN 110073458 B CN110073458 B CN 110073458B CN 201780076905 A CN201780076905 A CN 201780076905A CN 110073458 B CN110073458 B CN 110073458B
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graphene
composite
carbon nanotube
prepared
electrode
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CN110073458A (zh
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张喜栋
蒋韩权
崔志赫
吉大燮
金亨锡
裵仁国
徐宙范
赵恩姬
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Korea Institute of Geoscience and Mineral Resources KIGAM
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Korea Institute of Geoscience and Mineral Resources KIGAM
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Priority claimed from KR1020160169022A external-priority patent/KR101744122B1/ko
Priority claimed from KR1020160174818A external-priority patent/KR101742593B1/ko
Priority claimed from KR1020170001353A external-priority patent/KR101753129B1/ko
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • H01G11/36Nanostructures, e.g. nanofibres, nanotubes or fullerenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/52Separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54Electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66Current collectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/84Processes for the manufacture of hybrid or EDL capacitors, or components thereof
    • H01G11/86Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors
CN201780076905.9A 2016-12-12 2017-03-29 褶皱状石墨烯复合体的制备方法、由此制备的复合体及包含复合体的超级电容器 Active CN110073458B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
KR10-2016-0169022 2016-12-12
KR1020160169022A KR101744122B1 (ko) 2016-12-12 2016-12-12 구겨진 형상의 그래핀-탄소나노튜브 복합체 제조방법, 이에 따라 제조된 그래핀-탄소나노튜브 복합체 및 이를 포함하는 슈퍼커패시터
KR1020160174818A KR101742593B1 (ko) 2016-12-20 2016-12-20 구겨진 형상의 그래핀-탄소나노튜브-고분자 복합체 제조방법, 이에 따라 제조된 복합체 및 이를 포함하는 슈퍼커패시터
KR10-2016-0174818 2016-12-20
KR1020170001353A KR101753129B1 (ko) 2017-01-04 2017-01-04 구겨진 형상의 그래핀 복합체를 포함하는 슈퍼커패시터 전극의 제조방법, 이에 따라 제조되는 전극 및 이를 포함하는 슈퍼커패시터
KR10-2017-0001353 2017-01-04
PCT/KR2017/003433 WO2018110776A1 (ko) 2016-12-12 2017-03-29 구겨진 형상의 그래핀 복합체 제조방법, 이에 따라 제조되는 복합체 및 복합체를 포함하는 슈퍼커패시터

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CN110073458B true CN110073458B (zh) 2022-07-08

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Families Citing this family (8)

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Publication number Priority date Publication date Assignee Title
US11081684B2 (en) * 2017-05-24 2021-08-03 Honda Motor Co., Ltd. Production of carbon nanotube modified battery electrode powders via single step dispersion
CN111285336B (zh) * 2018-12-10 2023-02-03 北京清正泰科技术有限公司 一种消除二维材料褶皱的方法
WO2020231150A1 (ko) * 2019-05-15 2020-11-19 주식회사 엘지화학 도전재, 상기 도전재를 포함하는 전극, 및 상기 전극을 포함하는 이차 전지
CN110544771B (zh) * 2019-08-23 2021-02-05 暨南大学 低电压、高载量的自支撑钾离子电池负极及其制备与应用
CN111739740B (zh) * 2020-06-29 2021-12-07 清华大学深圳国际研究生院 多孔碳基复合材料及其制备方法
CN114171325A (zh) * 2021-11-17 2022-03-11 中北大学南通智能光机电研究院 一种三维石墨烯/聚苯胺负载的导电织物复合电极材料的制备方法
CN115172066B (zh) * 2022-06-16 2023-04-25 宁德师范学院 一种Fe3+诱导的褶皱石墨烯基电容复合材料及其制备方法
CN116836421B (zh) * 2023-04-11 2024-02-06 湖北中一科技股份有限公司 一种导电膜及其制备方法

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110018735A (ko) * 2009-08-18 2011-02-24 한국전기연구원 탄소나노튜브 마이크로볼의 제조방법, 이에 의해 제조된 탄소나노튜브 마이크로볼 및 이를 이용한 전극의 제조방법
CN101993065A (zh) * 2010-12-17 2011-03-30 中国科学院上海微***与信息技术研究所 一种制备石墨烯粉体的方法
CN102515145A (zh) * 2011-12-27 2012-06-27 常州第六元素材料科技股份有限公司 一种高比表面多孔炭材料的制备工艺
CN102530913A (zh) * 2010-12-30 2012-07-04 海洋王照明科技股份有限公司 石墨烯-碳纳米管复合材料的制备方法
KR101211949B1 (ko) * 2010-11-17 2012-12-18 성균관대학교산학협력단 하이브리드 복합체 및 이의 제조방법
CN102832050A (zh) * 2012-08-29 2012-12-19 华东理工大学 分级结构石墨烯/碳纳米管杂化物的制备方法
CN102850543A (zh) * 2012-09-28 2013-01-02 中国科学院宁波材料技术与工程研究所 一种石墨烯/导电聚合物复合材料及其制备方法
CN103204497A (zh) * 2013-04-16 2013-07-17 中国科学院福建物质结构研究所 一种制备石墨烯材料的方法及其在化学储能和/或转化中的用途
CN103308574A (zh) * 2013-05-21 2013-09-18 上海师范大学 一种碳纳米管-石墨烯复合膜修饰的电化学传感器及其制备方法和应用
CN103346022A (zh) * 2013-07-03 2013-10-09 中国科学院福建物质结构研究所 一种石墨烯/纳米碳颗粒复合材料的制备方法
CN103366971A (zh) * 2013-07-09 2013-10-23 武汉国墨新材料技术有限公司 石墨烯-聚苯胺-碳纳米管立体三维复合物的制备方法
CN104993170A (zh) * 2015-05-25 2015-10-21 天津巴莫科技股份有限公司 锂硫二次电池正极材料的制备方法
KR101623346B1 (ko) * 2015-10-27 2016-05-23 한국지질자원연구원 3차원 산화철-그래핀 나노복합체의 제조방법 및 이를 이용한 슈퍼커패시터

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101036164B1 (ko) * 2009-04-24 2011-05-23 성균관대학교산학협력단 복합전극 및 이의 제조방법
US20140205841A1 (en) * 2013-01-18 2014-07-24 Hongwei Qiu Granules of graphene oxide by spray drying
CN106463699B (zh) * 2014-05-09 2019-08-27 株式会社半导体能源研究所 锂离子二次电池及电子装置
CN104009205B (zh) * 2014-06-12 2016-08-24 上海中聚佳华电池科技有限公司 一种中空石墨烯球及其制备方法和用途
CN105304882A (zh) * 2014-07-25 2016-02-03 中国科学院物理研究所 锂硫电池正极材料的制备方法、锂硫电池正极材料和电池
CN105742590B (zh) * 2016-03-02 2019-01-08 合肥国轩高科动力能源有限公司 一种低电阻率的磷酸铁锂/碳复合材料的制备方法

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110018735A (ko) * 2009-08-18 2011-02-24 한국전기연구원 탄소나노튜브 마이크로볼의 제조방법, 이에 의해 제조된 탄소나노튜브 마이크로볼 및 이를 이용한 전극의 제조방법
KR101211949B1 (ko) * 2010-11-17 2012-12-18 성균관대학교산학협력단 하이브리드 복합체 및 이의 제조방법
CN101993065A (zh) * 2010-12-17 2011-03-30 中国科学院上海微***与信息技术研究所 一种制备石墨烯粉体的方法
CN102530913A (zh) * 2010-12-30 2012-07-04 海洋王照明科技股份有限公司 石墨烯-碳纳米管复合材料的制备方法
CN102515145A (zh) * 2011-12-27 2012-06-27 常州第六元素材料科技股份有限公司 一种高比表面多孔炭材料的制备工艺
CN102832050A (zh) * 2012-08-29 2012-12-19 华东理工大学 分级结构石墨烯/碳纳米管杂化物的制备方法
CN102850543A (zh) * 2012-09-28 2013-01-02 中国科学院宁波材料技术与工程研究所 一种石墨烯/导电聚合物复合材料及其制备方法
CN103204497A (zh) * 2013-04-16 2013-07-17 中国科学院福建物质结构研究所 一种制备石墨烯材料的方法及其在化学储能和/或转化中的用途
CN103308574A (zh) * 2013-05-21 2013-09-18 上海师范大学 一种碳纳米管-石墨烯复合膜修饰的电化学传感器及其制备方法和应用
CN103346022A (zh) * 2013-07-03 2013-10-09 中国科学院福建物质结构研究所 一种石墨烯/纳米碳颗粒复合材料的制备方法
CN103366971A (zh) * 2013-07-09 2013-10-23 武汉国墨新材料技术有限公司 石墨烯-聚苯胺-碳纳米管立体三维复合物的制备方法
CN104993170A (zh) * 2015-05-25 2015-10-21 天津巴莫科技股份有限公司 锂硫二次电池正极材料的制备方法
KR101623346B1 (ko) * 2015-10-27 2016-05-23 한국지질자원연구원 3차원 산화철-그래핀 나노복합체의 제조방법 및 이를 이용한 슈퍼커패시터

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Preparation of graphene nanosheetcarbon nanotubepolyaniline composite as electrode material for supercapacitors;Jun Yan;《Journal of Power Sources》;20091111;第195卷;第3041-3045页 *
Synthesis of microspherical polyaniline/graphene composites and their application in supercapacitors;Tao Yu等;《Electrochimica Acta》;20161108;第222卷;第12-19页论文摘要及正文部分 *

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