CN110055643A - A kind of zinc oxide yarn and preparation method thereof and application - Google Patents
A kind of zinc oxide yarn and preparation method thereof and application Download PDFInfo
- Publication number
- CN110055643A CN110055643A CN201910433195.1A CN201910433195A CN110055643A CN 110055643 A CN110055643 A CN 110055643A CN 201910433195 A CN201910433195 A CN 201910433195A CN 110055643 A CN110055643 A CN 110055643A
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- Prior art keywords
- zinc oxide
- yarn
- container
- distilled water
- production method
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of zinc oxide yarn, component is Fypro, zinc oxide, interfacial agents, dispersing agent and plastic lubricating agent.The invention also discloses a kind of production methods of zinc oxide yarn, including (1) tentatively to be cleaned by ethyl alcohol to zinc oxide；(2) zinc oxide after ethyl alcohol cleaning is dried；(3) by distilled water to zinc oxide progress secondary cleaning.The present invention discloses a kind of application of zinc oxide yarn again, and textile is made by the zinc oxide yarn；The textile includes underwear, underpants, shirt, socks and cap.The present invention provides a kind of zinc oxide yarn and preparation method thereof and application, it can be good at completing the production and manufacture of zinc oxide yarn, become a kind of novel antimicrobial yarn instead of oxidation silver yarn well, to reduce the production and use cost of antimicrobial yarn, antimicrobial yarn preferably has been popularized, while also having reduced influence of the antimicrobial yarn to human body well.
Description
Technical field
The invention belongs to antibacterial yarn field, in particular to a kind of zinc oxide yarn and preparation method thereof and answer
With.
Background technique
In life, people inevitably touch the microorganisms such as various bacteriums, fungi, these microorganisms
It can breed rapidly at suitable external condition (such as temperature, humidity) and be spread the disease by the contact of people, to influence
The health and normal work, study and life of people.And all kinds of textiles are often well dwelling for these microorganisms
Breath ground, and become the important propagating source of disease, pathogenic bacteria can not only generate strange taste after mass propagation on the textile, but will pass through
Direct or indirect mode completes the propagation to disease, as intersected caused by the public places such as hospital, hotel, restaurant, park
Infection.Therefore, just seem increasingly important to the research and development of antibacterial textile function.
Anti-bacterial fibre and fabric refer to the fiber for have killing or inhibiting effect to microorganisms such as bacterium, fungi and viruses or knitting
Object, purpose are damaged not only for preventing textile from being stained by microorganism, it is often more important that are infected disease in order to prevent, protected
Witness's body health and it is comfortable and easy to wear, reduce the cross-infection rate of public environment, anti-bacterial fibre makes textile obtain hygienic guarantor
Strong new function.
Metallic silver and its oxide are that one kind commonly uses effective antibacterial agent.It is answered by addition metallic silver and its oxide
It closes spinning and prepares anti-bacterial fibre simple process, fibrous mechanical property obtained is good, antibacterial effect is good.But silver ion have it is weak
Toxicity, long-time service has a certain impact to human body, and the stability of silver ion is not high, and it is molten that part is had after washing
Out, the effect of product, and the higher cost of metallic silver or its oxide can be greatly reduced after being cleaned multiple times, greatly improve
The production and use cost of product.
Summary of the invention
It is an object of the invention to overcome the above problem, a kind of zinc oxide yarn and preparation method thereof and application are provided,
It can be good at completing the production and manufacture of zinc oxide yarn, become a kind of novel antibacterial instead of oxidation silver yarn well
Yarn has preferably popularized antimicrobial yarn, while also reducing well to reduce the production and use cost of antimicrobial yarn
Influence of the antimicrobial yarn to human body.
The purpose of the invention is achieved by the following technical solution:
A kind of zinc oxide yarn, component and its number are as follows:
A kind of production method of zinc oxide yarn, comprising the following steps:
(1) zinc oxide is tentatively cleaned by ethyl alcohol；
(2) zinc oxide after ethyl alcohol cleaning is dried；
(3) secondary cleaning is carried out to zinc oxide by distilled water；
(4) zinc oxide after distilled water cleaning is dried and is smashed rear spare；
(5) by Fypro particle grinding at powder；
(6) it is uniformly mixed Fypro powder to obtain mixture with zinc oxide；
(7) mixture mixing is made into zinc oxide nylon master batch；
(8) zinc oxide nylon master batch is reeled off raw silk from cocoons by zinc oxide just line processed by wire drawing machine；
(9) final zinc oxide yarn just is obtained after line processed toasts to zinc oxide.
The detailed process tentatively cleaned described in step (1) are as follows:
(11) zinc oxide is held in a reservoir, and ethyl alcohol is added until ethyl alcohol liquid level does not have table on zinc peroxide into container
The 10-15cm in face；
(12) in container zinc oxide and ethyl alcohol be stirred, mixing speed 30r/min, when stirring a length of 5min；
(13) it completes that the alcohol suspension of zinc oxide is stood 30min in a reservoir after stirring, so that zinc oxide sinks；
(14) supernatant is discharged, and guarantee be discharged supernatant after ethyl alcohol upper surface and the zinc oxide upper surface after precipitating
Between spacing be 2-4cm；
(15) step (12)-(14) are repeated, and number of repetition is 3-5 times, so just completes preliminary cleaning.
The drying of step (2) be container is heated with 200-300 DEG C of temperature, and while heating container to zinc oxide into
Row stirring, mixing speed 15-20r/min, until the liquid in container all volatilizees.
The detailed process of secondary cleaning described in step (3) are as follows:
(31) distilled water is added into the container for the zinc oxide being contained with after tentatively cleaning until the liquid level of distilled water did not had
The 20-25cm of zinc oxide upper surface；
(32) in container zinc oxide and distilled water be stirred, mixing speed 30r/min, when stirring is a length of
15min；
(33) it completes that the distillation water slurry of zinc oxide is stood 90-120min in a reservoir after stirring, so that oxidation
Zinc sinks；
(34) supernatant is discharged, and guarantees to be discharged after supernatant table on the upper surface of distilled water and the zinc oxide after precipitating
Spacing between face is 5-8cm；
(35) step (32)-(34) are repeated, and number of repetition is 1-2 times, so just completes secondary cleaning.
The drying of step (4) be container is heated with 160-280 DEG C of temperature, and while heating container to zinc oxide into
Row stirring, mixing speed 5-10r/min, until the distilled water in container all volatilizees, being tapped or milled later makes
Zinc oxide keeps powdered, and the diameter of Zinc oxide powder is made to be no more than 200nm.
Step (5) is the powder that Fypro particle grinding is no more than to 200nm by grinding mill at diameter；Step
(6) component and its number mixed in are as follows:
Mixture is made by zinc oxide nylon master batch by kneading machine in step (7)；Step is reeled off raw silk from cocoons in (8) by wire drawing machine
Made of zinc oxide just line processed Denier: number 80:48, breaking strength 4.8gf/d, extension at break 39.8%.
Baking described in step (9) is completed in vacuum dryer, and drying temperature is 80-95 DEG C, drying time 3-5
Hour.
Textile is made by the zinc oxide yarn in the application of zinc oxide yarn；The textile include underwear, underpants, shirt,
Socks and cap.
Compared with prior art, the present invention have the following advantages that and the utility model has the advantages that
(1) present invention reduces the impurity content in zinc oxide by cleaning twice well, preferably ensures production
Product quality.
(2) present invention first mixes each substance, and is kneaded again upon mixing, and so much the better improves production
The uniformity after product mixing, further ensures the antibacterial validity of product.
(3) present invention utilizes the positive electricity (Zn of zinc oxide+2) inhibit breeding, the decomposition smell of bacterium, to reach thin
Bacterium growth resists smelly and other effects, which is mainly to pass through the physical antibacterial of the non-chemical property of zinc oxide, and then avoid well
Influence to human body greatly improves the safety in utilization of product.
(4) present invention has filled up the blank in antibacterial yarn field, becomes a kind of novel instead of oxidation silver yarn well
Low cost antimicrobial yarn, while possessing safer, more economical, more effective feature compared to the prior art, promote well
Into the development of enterprise and industry.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto.
Embodiment 1
A kind of zinc oxide yarn, component include Fypro, zinc oxide, interfacial agents, dispersing agent and plastics lubrication
Agent.
Embodiment 2
A kind of production method of zinc oxide yarn, comprising the following steps:
(1) zinc oxide is tentatively cleaned by ethyl alcohol；
The detailed process tentatively cleaned are as follows:
(11) zinc oxide is held in a reservoir, and ethyl alcohol is added until ethyl alcohol liquid level does not have table on zinc peroxide into container
The 10-15cm in face；
(12) in container zinc oxide and ethyl alcohol be stirred, mixing speed 30r/min, when stirring a length of 5min；
(13) it completes that the alcohol suspension of zinc oxide is stood 30min in a reservoir after stirring, so that zinc oxide sinks；
(14) supernatant is discharged, and guarantee be discharged supernatant after ethyl alcohol upper surface and the zinc oxide upper surface after precipitating
Between spacing be 2-4cm；
(15) step (12)-(14) are repeated, and number of repetition is 3-5 times, so just completes preliminary cleaning.
(2) zinc oxide after ethyl alcohol cleaning is dried；
Drying is to heat container with 200-300 DEG C of temperature, and be stirred while heating container to zinc oxide,
Mixing speed is 15-20r/min, until the liquid in container all volatilizees.
(3) secondary cleaning is carried out to zinc oxide by distilled water；
The detailed process of secondary cleaning are as follows:
(31) distilled water is added into the container for the zinc oxide being contained with after tentatively cleaning until the liquid level of distilled water did not had
The 20-25cm of zinc oxide upper surface；
(32) in container zinc oxide and distilled water be stirred, mixing speed 30r/min, when stirring is a length of
15min；
(33) it completes that the distillation water slurry of zinc oxide is stood 90-120min in a reservoir after stirring, so that oxidation
Zinc sinks；
(34) supernatant is discharged, and guarantees to be discharged after supernatant table on the upper surface of distilled water and the zinc oxide after precipitating
Spacing between face is 5-8cm；
(35) step (32)-(34) are repeated, and number of repetition is 1-2 times, so just completes secondary cleaning.
(4) zinc oxide after distilled water cleaning is dried and is smashed rear spare；
Drying is to heat container with 160-280 DEG C of temperature, and be stirred while heating container to zinc oxide,
Mixing speed is 5-10r/min, until the distilled water in container all volatilizees, being tapped or milled later keeps zinc oxide
It is powdered, and the diameter of Zinc oxide powder is made to be no more than 200nm.
(5) by Fypro particle grinding at powder；
Fypro particle grinding is no more than to the powder of 200nm by grinding mill at diameter.
(6) it is uniformly mixed Fypro powder to obtain mixture with zinc oxide；
Mixed component and its number are as follows:
(7) mixture mixing is made into zinc oxide nylon master batch；
Mixture is made into zinc oxide nylon master batch by kneading machine.
(8) zinc oxide nylon master batch is reeled off raw silk from cocoons by zinc oxide just line processed by wire drawing machine；
The Denier of line processed at the beginning of zinc oxide made of being reeled off raw silk from cocoons by wire drawing machine: number 80:48, breaking strength 4.8gf/
D, extension at break 39.8%.
(9) final zinc oxide yarn just is obtained after line processed toasts to zinc oxide.
Baking is completed in vacuum dryer, and drying temperature is 80-95 DEG C, and drying time is 3-5 hours.
The application has filled up the blank in yarn field, becomes a kind of novel low cost instead of oxidation silver yarn well
Antimicrobial yarn.The product of the application and the comparison table of oxidation silver yarn enter shown in the following table 1:
Table 1
Positive electricity (the Zn of the product utilization zinc oxide of the application+2) inhibit breeding, the decomposition smell of bacterium, to reach
Bacterial growth, resist it is smelly and other effects.The function is mainly to pass through the physical antibacterial of the non-chemical property of zinc oxide, and then avoid well
Influence to human body, greatly improves the safety in utilization of product.
And the principle for aoxidizing silver yarn is that silver oxide dissolves out a large amount of silver ion (Ag+) thallus is surrounded, and then bring strong
Big sterilization capability, the principle also result in the reason of oxidation silver yarn when in use can have an impact human body.In addition, silver is very
It is easy vulcanization, so that yarn can black when in use, the long-time for being unfavorable for product is used.
The application possesses safer, more economical, more effective feature, promotes enterprise well compared with aoxidizing silver yarn
The development of industry and industry.
Embodiment 3
The present embodiment is with embodiment 1 the difference lies in that the component and its number mixed in step (6) are as follows:
Embodiment 4
The present embodiment is with embodiment 2 the difference lies in that the component and its number mixed in step (6) are as follows:
Embodiment 5
Textile is made by the zinc oxide yarn in the application of zinc oxide yarn；The textile include underwear, underpants, shirt,
Socks and cap etc..
As described above, the present invention can be realized well.
Claims (10)
1. a kind of zinc oxide yarn, it is characterised in that: its component and its number are as follows:
2. a kind of production method of zinc oxide yarn, it is characterised in that: the following steps are included:
(1) zinc oxide is tentatively cleaned by ethyl alcohol；
(2) zinc oxide after ethyl alcohol cleaning is dried；
(3) secondary cleaning is carried out to zinc oxide by distilled water；
(4) zinc oxide after distilled water cleaning is dried and is smashed rear spare；
(5) by Fypro particle grinding at powder；
(6) it is uniformly mixed Fypro powder to obtain mixture with zinc oxide；
(7) mixture mixing is made into zinc oxide nylon master batch；
(8) zinc oxide nylon master batch is reeled off raw silk from cocoons by zinc oxide just line processed by wire drawing machine；
(9) final zinc oxide yarn just is obtained after line processed toasts to zinc oxide.
3. a kind of production method of zinc oxide yarn according to claim 2, it is characterised in that: described in step (1)
The detailed process tentatively cleaned are as follows:
(11) zinc oxide is held in a reservoir, and ethyl alcohol is added until ethyl alcohol liquid level does not have zinc peroxide upper surface into container
10-15cm；
(12) in container zinc oxide and ethyl alcohol be stirred, mixing speed 30r/min, when stirring a length of 5min；
(13) it completes that the alcohol suspension of zinc oxide is stood 30min in a reservoir after stirring, so that zinc oxide sinks；
(14) supernatant is discharged, and guaranteed to be discharged after supernatant between the upper surface of ethyl alcohol and the zinc oxide upper surface after precipitating
Spacing be 2-4cm；
(15) step (12)-(14) are repeated, and number of repetition is 3-5 times, so just completes preliminary cleaning.
4. a kind of production method of zinc oxide yarn according to claim 3, it is characterised in that: the drying of step (2) is
Container is heated with 200-300 DEG C of temperature, and zinc oxide is stirred while heating container, mixing speed 15-
20r/min, until the liquid in container all volatilizees.
5. a kind of production method of zinc oxide yarn according to claim 4, it is characterised in that: described in step (3)
The detailed process of secondary cleaning are as follows:
(31) distilled water is added into the container for the zinc oxide being contained with after tentatively cleaning until the liquid level of distilled water does not have peroxidating
The 20-25cm of zinc upper surface；
(32) in container zinc oxide and distilled water be stirred, mixing speed 30r/min, when stirring a length of 15min；
(33) it completes that the distillation water slurry of zinc oxide is stood 90-120min in a reservoir after stirring, so that under zinc oxide
It is heavy；
(34) supernatant is discharged, and guarantee to be discharged distilled water after supernatant upper surface and zinc oxide upper surface after precipitating it
Between spacing be 5-8cm；
(35) step (32)-(34) are repeated, and number of repetition is 1-2 times, so just completes secondary cleaning.
6. a kind of production method of zinc oxide yarn according to claim 5, it is characterised in that: the drying of step (4) is
Container is heated with 160-280 DEG C of temperature, and zinc oxide is stirred while heating container, mixing speed 5-
10r/min, until the distilled water in container all volatilizees, being tapped or milled later makes zinc oxide keep powdered, and makes
The diameter for obtaining Zinc oxide powder is no more than 200nm.
7. a kind of production method of zinc oxide yarn according to claim 6, it is characterised in that: step (5) is to pass through stone roller
Fypro particle grinding is no more than the powder of 200nm by grinding machine at diameter；The component and its number mixed in step (6)
Are as follows:
8. a kind of production method of zinc oxide yarn according to claim 7, it is characterised in that: by mixed in step (7)
Mixture is made into zinc oxide nylon master batch by mill；The pellet of line processed at the beginning of zinc oxide made of being reeled off raw silk from cocoons in step (8) by wire drawing machine
Neil: number 80:48, breaking strength 4.8gf/d, extension at break 39.8%.
9. a kind of production method of zinc oxide yarn according to claim 8, it is characterised in that: described in step (9)
Baking is completed in vacuum dryer, and drying temperature is 80-95 DEG C, and drying time is 3-5 hours.
10. the application based on the zinc oxide yarn that production method described in claim 2-9 is produced, it is characterised in that: by this
Textile is made in zinc oxide yarn；The textile includes underwear, underpants, shirt, socks and cap.
Time hour is 3-5 hours 3-5 hours.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910433195.1A CN110055643A (en) | 2019-05-23 | 2019-05-23 | A kind of zinc oxide yarn and preparation method thereof and application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910433195.1A CN110055643A (en) | 2019-05-23 | 2019-05-23 | A kind of zinc oxide yarn and preparation method thereof and application |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110522094A (en) * | 2019-08-28 | 2019-12-03 | 佳莱科技有限公司 | A kind of strong sufficient socks of composite fibre type |
| CN114990892A (en) * | 2022-07-11 | 2022-09-02 | 佳莱科技有限公司 | Manufacturing method of sleep-benefiting skin-beautifying fabric |
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| CN101238817A (en) * | 2008-03-06 | 2008-08-13 | 刘燕平 | Bacteriostat, far-infrared ray emitting agent, mother particle, fiber and manufacturing method thereof |
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Application publication date: 20190726 |
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