CN108863444A - A kind of antifouling anti-skidding treatment process of ceramic tile - Google Patents
A kind of antifouling anti-skidding treatment process of ceramic tile Download PDFInfo
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- CN108863444A CN108863444A CN201810889760.0A CN201810889760A CN108863444A CN 108863444 A CN108863444 A CN 108863444A CN 201810889760 A CN201810889760 A CN 201810889760A CN 108863444 A CN108863444 A CN 108863444A
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- Prior art keywords
- ceramic tile
- antifouling
- skidding
- oiliness
- fouling agent
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- 239000000919 ceramic Substances 0.000 title claims abstract description 196
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 126
- 238000000034 method Methods 0.000 title claims abstract description 84
- 238000005498 polishing Methods 0.000 claims abstract description 60
- 239000002519 antifouling agent Substances 0.000 claims abstract description 53
- 238000012545 processing Methods 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000004140 cleaning Methods 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims description 24
- 239000002253 acid Substances 0.000 claims description 13
- 239000002105 nanoparticle Substances 0.000 claims description 9
- -1 Alcohol ethers Chemical class 0.000 claims description 3
- 239000003082 abrasive agent Substances 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 45
- 239000000243 solution Substances 0.000 description 30
- 239000000377 silicon dioxide Substances 0.000 description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 19
- 239000010703 silicon Substances 0.000 description 19
- 229910052710 silicon Inorganic materials 0.000 description 19
- 239000011449 brick Substances 0.000 description 16
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 239000002086 nanomaterial Substances 0.000 description 10
- 229910052573 porcelain Inorganic materials 0.000 description 10
- 239000004677 Nylon Substances 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 9
- 229940008099 dimethicone Drugs 0.000 description 9
- 239000004205 dimethyl polysiloxane Substances 0.000 description 9
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 9
- 229920001778 nylon Polymers 0.000 description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 9
- 230000003068 static effect Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910011255 B2O3 Inorganic materials 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B1/00—Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Detergent Compositions (AREA)
- Laminated Bodies (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
A kind of antifouling anti-skidding treatment process of ceramic tile of the present invention, the technique include the following steps：Antifouling process step：Super clean bright anti-fouling agent is uniformly coated on ceramic tile surface to be processed, surface to the glossiness for ceramic tile of polishing is greater than 85 degree, obtains the ceramic tile of antifouling process；The antifouling curing process step of oiliness：Oiliness anti-fouling agent is uniformly coated on the ceramic tile surface of antifouling process, polishes, obtains the antifouling cured ceramic tile of oiliness；Anti-skidding processing step：Antilubricant is uniformly coated on the antifouling cured ceramic tile surface of oiliness, polishes, obtains anti-skidding antifouling ceramic tile；Cleaning treatment step：It is rinsed with water the surface of anti-skidding antifouling ceramic tile, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.The present invention solve it is super it is clean it is bright it is antifouling with it is anti-skidding between there is technical issues that very big, obtain with the anti-skidding and fabulous ceramic tile of anti-fouling effect.
Description
Technical field
The present invention relates to a kind of antifouling anti-skidding treatment process of ceramic tile.
Background technique
With economic continuous development and the raising of domestic level, people for interior decoration visual effect and
The requirement of properties of product is more stringent.And it is required that safety first, thus antiskid function has attracted much attention.Super clean bright antifouling ceramic tile by
To liking for more and more consumers, super clean bright antifouling ceramic tile is prepared using super clean bright anti-fouling material polishing, super clean bright
Technology is currently widely used a kind of high-precision ceramic tile surface processing method, it applies ceramic tile by grinding head for polishing repeatedly
Pressure, polishing, polishing, the nanometer silicon dioxide particle in nano fluid are preferably penetrated into inside the pore of polished bricks, are plugged
The pore and micro-crack of ceramic tile form a kind of special, continuous nanometer film, thus make ceramic tile that there is beautiful surface, and
The surface can effectively prevent the invasion of pollutant, have preferable anti-pollution.The anti-skidding of ceramic tile is also an important technology
Index, so, the super clean bright antifouling ceramic tile with antiskid function is a great problem of the prior art.
Solving the anti-skidding method of ceramic tile has；1, the texture of overstriking ceramic tile surface reaches antiskid effect, this slip-proof way, only
It is anti-skidding when can solve dry, it, will be without any antiskid effect when encountering water or grease stain.This anti-skidding method seriously affects
The aesthetics of ceramic tile.2, a kind of acidic liquid is blent, is brushed in ceramic tile surface, is corroded tile floor, ceramic tile is allowed to reach anti-skidding
Effect, this slip-proof way is simultaneously imperfect, and disadvantage ceramic tile is destroyed, and confficient of static friction is relatively low after meeting water, it is easy to dirt is formed,
Time, which has been grown, loses antiskid effect, greatly destroys the antifouling and glossiness of ceramic tile.But the above method be not available in
Super clean bright antifouling ceramic tile.
Chinese patent 201610880415.1 discloses a kind of preparation process of antifouling brick, by molten in brick face coating colloid
Liquid forms one layer of waterproof membrane after its drying to play anti-fouling effect.Anti-dirtying liquid ingredient used in the patent is containing hydrogen silicone oil,
Alkali resistance is very poor, is easy to be corroded in cleaning by alkaline cleaner；Silica gel solution is also easy to be worn after being immersed in water,
Cause antifouling capacity not lasting.
Chinese patent 201410185232.9 discloses a kind of clean bright technique of coloured polished brick, antifouling by coating in brick face
Liquid and silicone oil carry out sealed porosity and reach antifouling purpose.Anti-dirtying liquid used in the patent is by silicon dioxide gel and water-soluble mill base mixing
It forms, water-soluble mill base, which adjusts formula according to ceramic tile color, keeps its color consistent with ceramic tile, produces the porcelain of different colours every time
Brick will replace mill base and cleaning container, complex process；Simultaneously when producing the ceramic tile of color complexity, the configuration of water-soluble mill base and
Coating will be the insurmountable problem of this method, be unfavorable for producing the glaze paint polished bricks of multiple color.
In the prior art, realize ceramic tile it is super it is clean it is bright it is antifouling contradicted with anti-skidding, now in industry only first use
Super clean bright anti-fouling agent is polished anti-slip material again.Or first polishing anti-slip material reuses super clean bright anti-fouling agent.But due to super clean
Bright anti-fouling material be it is alkaline, anti-slip material be it is acid, it is unqualified that anti-fouling effect is caused in practice.
Summary of the invention
In order to solve the above-mentioned technical problems, the present invention provides a kind of antifouling anti-skidding treatment process of ceramic tile, the technique packets
Include following steps：
Antifouling process step：Super clean bright anti-fouling agent is uniformly coated on ceramic tile surface to be processed, the surface for ceramic tile of polishing
It is greater than 85 degree to glossiness, obtains the ceramic tile of antifouling process；
The antifouling curing process step of oiliness：Oiliness anti-fouling agent is uniformly coated on the ceramic tile surface of antifouling process, polishes, obtains
To the antifouling cured ceramic tile of oiliness；
Anti-skidding processing step：Antilubricant is uniformly coated on the antifouling cured ceramic tile surface of oiliness, is polished, is obtained anti-skidding anti-
Dirty ceramic tile；
Cleaning treatment step：It is rinsed with water the surface of anti-skidding antifouling ceramic tile, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed；
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 0.5-5 minutes.
The temperature of ceramic tile surface is 45-80 degrees Celsius when the polishing of the antifouling process step.
The abrasive material of the anti-skidding processing step is wool pad.
The super clean bright anti-fouling agent is the super clean bright anti-fouling agent of alkalinity containing nanoparticle.
The oiliness anti-fouling agent is solvent type oiliness anti-fouling agent.
The oiliness anti-fouling agent is the organosilicon oily solution containing 1-30wt%
The oiliness anti-fouling agent is alcohol ethers oiliness anti-fouling agent.
The antilubricant is neutral, faintly acid antilubricant.
A kind of ceramic tile, the ceramic tile are prepared using antifouling anti-skidding treatment process above-mentioned.
In the prior art, anti-fouling agent is to contain nanoparticle（Such as silica etc.）Silicon sol solution, pass through polishing
The super clean bright effect on surface is obtained, antilubricant is the acid solution with erosiveness, such as with fluorine ion and ammonium ion
Acid solution, fluorine ion generates fluorine in formula under the action of ammonium ion, with the silicate component chemically reactive in ceramic tile
SiClx gas overflowing, the direct effect of chemical reaction is that ceramic tile surface forms many nanoscale microcellular structures, to reach anti-
Sliding effect.Ceramic tile through anti-skidding processing, by the chemical action with antilubricant, after amplifying several times, the capillary channel of formation compared with
It is recessed to form hole on the original pore upper layer of ceramic tile, greatly increases coefficient of friction for width, when meeting water or grease stain with plantar contact energy
The sucker effect for forming physics, greatly increases antiskid effect.Even if as time goes by, the surface portion abrasion of ceramic tile, but
Its internal existing structure changing section is stable and has certain depth, thus can keep permanent antiskid effect.As can be seen that super clean
It is bright with it is anti-skidding between there is very big contradiction, the present invention is by being arranged one of solvent between antifouling process and anti-skidding processing
Oiliness antifouling process, solve it is super it is clean it is bright it is antifouling with it is anti-skidding between there is technical issues that very big, had
The anti-skidding and fabulous ceramic tile of anti-fouling effect.
The above-mentioned of the application and other features, aspects and advantages are more readily understood with reference to following detailed description.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific term have and the common skill of fields of the present invention
The normally understood identical meaning of art personnel.When there is a conflict, the definition in this specification shall prevail.
Super clean bright anti-fouling agent
Super clean bright anti-fouling agent of the invention is made of nanoparticle, solvent, and super clean bright anti-fouling agent is alkalinity.
Nanoparticle is not construed as limiting, and can arbitrarily select following nanoparticle：
(1) tetravalent metal oxide of SiO2, TiO2 etc.；
(2) trivalent metal oxide of Al2O3, Fe2O3, B2O3 etc.；
(3) bivalent metal oxide of MgO, CaO, ZnO, BaO etc.；
(4) as the fluoride of other compositions, phosphorus containg substances, Mo compound, V compound, Sb compound, W compound etc..
Nanoparticle as one preferred can choose in order to steadily be filled in the micropore of ceramic tile surface
Nano silica or silica solution, under alkaline condition, silica and silica solution can be well and inside ceramic tile micropores
Chemical reaction.Solvent is not construed as limiting, and solvent can choose water or other organic solvents.From environmental angle, preferably water
Or environment-friendly type solvent.
Organic silicon solvent type oiliness anti-fouling agent, including No. 120 solvent naphthas（Solvent）And dimethicone, dimethicone
Content is 1-30wt%.
Organosilicon Alcohol in Organic ethers anti-fouling agent, including alcohols solvent and dimethicone, the content of dimethicone are 1-
30wt%。
Specific ceramic tile treatment process：
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of nanoparticle）, warp
The polishing of 15 or 20 bistriques of two super clean bright machines is crossed, so that the nanomaterial-filled object on ceramic tile surface penetrates into porcelain
In the micropore of brick, it is polishing to the glossiness 85-95 degree of ceramic tile surface；Then it is rinsed with water ceramic tile surface and polishes；Bruting process
Middle ceramic tile surface temperature is maintained at 45-80 degrees Celsius, obtains the ceramic tile of antifouling process；
By oiliness anti-fouling agent（Oiliness anti-fouling agent is made of organic solvent and nano material）It is uniformly coated to the porcelain of antifouling process
On brick surface, polishes 1-10 minutes, obtain the antifouling cured ceramic tile of oiliness；
Antilubricant (acid solution containing fluorine ion and nanoparticle) is uniformly coated to the antifouling cured ceramic tile table of oiliness
On face, polish 1-10 minutes, the anti-slip material polishing of 2 to 3 mill infusion tube types of use.Obtain anti-skidding antifouling ceramic tile；
The surface of anti-skidding antifouling ceramic tile is rinsed with water in 1-10 minutes, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Hereinafter, the present invention is explained in more detail by embodiment, it should be appreciated that these embodiments are only
Illustrate and not restrictive.If raw materials used to be all commercially available without other explanations.
Referring to several example the present invention is described in detail.
Following percentage compositions be mass percentage.
Organic silicon solvent type oiliness anti-fouling agent, including No. 120 solvent naphthas（Solvent）And dimethicone, dimethicone
Content is 1-30wt%.
Organosilicon Alcohol in Organic ethers anti-fouling agent, including alcohols solvent and dimethicone, the content of dimethicone are 1-
30wt%。
Embodiment 1
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution, silicon are molten
Glue content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that on ceramic tile surface
Nanomaterial-filled object penetrate into the micropore of ceramic tile, be polishing to 90 degree of glossiness of ceramic tile surface；Then it is rinsed with water porcelain
It simultaneously polishes on brick surface；Ceramic tile surface temperature is maintained between 45-80 degrees Celsius in bruting process, obtains the ceramic tile of antifouling process；
By oiliness anti-fouling agent（Organic silicon solvent type oiliness anti-fouling agent, solvent are No. 120 solvent naphthas, the dimethyl-silicon containing 2wt%
Oil）It is uniformly coated on the ceramic tile surface of antifouling process, to obtain oiliness antifouling cured for polishing 1-10 minutes or drying and processing
Ceramic tile；
Equably by antilubricant (acid solution containing fluorine ion and citric acid, fluorinion concentration 0.1mol/L, pH value 6)
It is coated on the antifouling cured ceramic tile surface of oiliness, polishes 1-10 minutes, obtain anti-skidding antifouling ceramic tile；
The surface of anti-skidding antifouling ceramic tile is rinsed with water in 1 minute, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.60 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 5 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Embodiment 2
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution, silicon are molten
Glue content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that on ceramic tile surface
Nanomaterial-filled object penetrate into the micropore of ceramic tile, be polishing to 90 degree of glossiness of ceramic tile surface；Then it is rinsed with water porcelain
It simultaneously polishes on brick surface；Ceramic tile surface temperature is maintained at 45-80 degrees Celsius in bruting process, obtains the ceramic tile of antifouling process；
By oiliness anti-fouling agent（Organic silicon solvent type oiliness anti-fouling agent, solvent are No. 120 solvent naphthas, the dimethyl-silicon containing 8wt%
Oil）It is uniformly coated on the ceramic tile surface of antifouling process, polishes 1-10 minutes, obtain the antifouling cured ceramic tile of oiliness；
Equably by antilubricant (acid solution containing fluorine ion and citric acid, fluorinion concentration 0.1mol/L, pH value 6)
It is coated on the antifouling cured ceramic tile surface of oiliness, polishes 1-10 minutes, obtain anti-skidding antifouling ceramic tile；
The surface of anti-skidding antifouling ceramic tile is rinsed with water in 2 minutes, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.63 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 5 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Embodiment 3
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution, silicon are molten
Glue content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that on ceramic tile surface
Nanomaterial-filled object penetrate into the micropore of ceramic tile, be polishing to the glossiness 85-95 degree of ceramic tile surface；Then it is rinsed with water
Ceramic tile surface is simultaneously polished；Ceramic tile surface temperature is maintained at 45-80 degrees Celsius in bruting process, obtains the ceramic tile of antifouling process；
By oiliness anti-fouling agent（Alcohol ethers oiliness anti-fouling agent, isopropanol are solvent, the dimethicone containing 2wt%）Equably apply
Cloth polishes 1-10 minutes on the ceramic tile surface of antifouling process, obtains the antifouling cured ceramic tile of oiliness；
Equably by antilubricant (acid solution containing fluorine ion and citric acid, fluorinion concentration 0.1mol/L, pH value 6)
It is coated on the antifouling cured ceramic tile surface of oiliness, polishes 1-10 minutes, obtain anti-skidding antifouling ceramic tile；
It is rinsed with water the surface of anti-skidding antifouling ceramic tile in 5 minutes, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.69 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 5 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Comparative example 1
It is same as Example 1, do not contain the antifouling curing schedule of oiliness.
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution,
Silica solution content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that ceramic tile table
Nanomaterial-filled object on face penetrates into the micropore of ceramic tile, is polishing to 90 degree of glossiness of ceramic tile surface；Then it is rushed with water
It washes ceramic tile surface and polishes；Ceramic tile surface temperature is maintained between 45-80 degrees Celsius in bruting process, obtains the porcelain of antifouling process
Brick；
Equably by antilubricant (acid solution containing fluorine ion and citric acid, fluorinion concentration 0.1mol/L, pH value 6)
It is coated on the ceramic tile surface of antifouling process, polishes 1-10 minutes, obtain anti-skidding antifouling ceramic tile；
The surface of anti-skidding antifouling ceramic tile is rinsed with water in 1 minute, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.42 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 3 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Comparative example 2
It is same as Example 1, using aqueous anti-fouling agent.
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution,
Silica solution content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that ceramic tile table
Nanomaterial-filled object on face penetrates into the micropore of ceramic tile, is polishing to 90 degree of glossiness of ceramic tile surface；Then it is rushed with water
It washes ceramic tile surface and polishes；Ceramic tile surface temperature is maintained between 45-80 degrees Celsius in bruting process, obtains the porcelain of antifouling process
Brick；
By aqueous anti-fouling agent（The solution of water and silica solution, mass ratio 100：3）It is uniformly coated to the ceramic tile table of antifouling process
On face, polishes 1-10 minutes, obtain aqueous antifouling cured ceramic tile；
Equably by antilubricant (acid solution containing fluorine ion and citric acid, fluorinion concentration 0.1mol/L, pH value 6)
It is coated on the antifouling cured ceramic tile surface of oiliness, polishes 1-10 minutes, obtain anti-skidding antifouling ceramic tile；
The surface of anti-skidding antifouling ceramic tile is rinsed with water in 1 minute, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.43 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 3 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Comparative example 3
It is same as Example 1, without anti-skidding processing step.
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution,
Silica solution content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that ceramic tile table
Nanomaterial-filled object on face penetrates into the micropore of ceramic tile, is polishing to 90 degree of glossiness of ceramic tile surface；Then it is rushed with water
It washes ceramic tile surface and polishes；Ceramic tile surface temperature is maintained between 45-80 degrees Celsius in bruting process, obtains the porcelain of antifouling process
Brick；
By oiliness anti-fouling agent（Organic silicon solvent type oiliness anti-fouling agent）It is uniformly coated on the ceramic tile surface of antifouling process, polishes
1-10 minutes, obtain the antifouling cured ceramic tile of oiliness；
The surface of anti-skidding antifouling ceramic tile is rinsed with water in 1 minute, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.34 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 5 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Comparative example 4
It is same as Example 1, it is carried out after 30 minutes after the completion of cleaning step slip-preventing step.
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution,
Silica solution content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that ceramic tile table
Nanomaterial-filled object on face penetrates into the micropore of ceramic tile, is polishing to 90 degree of glossiness of ceramic tile surface；Then it is rushed with water
It washes ceramic tile surface and polishes；Ceramic tile surface temperature is maintained between 45-80 degrees Celsius in bruting process, obtains the porcelain of antifouling process
Brick；
By oiliness anti-fouling agent（Organic silicon solvent type oiliness anti-fouling agent）It is uniformly coated on the ceramic tile surface of antifouling process, polishes
1-10 minutes, obtain the antifouling cured ceramic tile of oiliness；
Equably by antilubricant (acid solution containing fluorine ion and citric acid, fluorinion concentration 0.1mol/L, pH value 6)
It is coated on the antifouling cured ceramic tile surface of oiliness, polishes 1-10 minutes, obtain anti-skidding antifouling ceramic tile；
The surface of anti-skidding antifouling ceramic tile is rinsed with water after 1-10 minutes, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.51 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 5 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Comparative example 5
It is same as Example 1, it is handled only with super clean bright anti-fouling agent.
With polished silicon wafer or the super clean bright anti-fouling agent of nylon wheel polishing on ceramic polishing machine（The alkaline aqueous solution of silica solution,
Silica solution content 12wt%, pH value 9）, by the polishing of 15 or 20 bistriques of two super clean bright machines, so that ceramic tile table
Nanomaterial-filled object on face penetrates into the micropore of ceramic tile, is polishing to 90 degree of glossiness of ceramic tile surface；Then it is rushed with water
It washes ceramic tile surface and polishes；Ceramic tile surface temperature is maintained between 45-80 degrees Celsius in bruting process, obtains the porcelain of antifouling process
Brick.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, it is 0.40 according to the sliding confficient of static friction of GB/T4100-2015 wet process, presses
It is 6 grades that the regulation of GB/T3810.14, which examines antifouling grade, and Mohs' hardness is 4 grades.
Comparative example 6
It is same as Example 1, only with antilubricant processing.
Antilubricant (acid solution containing fluorine ion and citric acid, fluorinion concentration 0.1mol/L, pH value 6) is equal
It is coated on the antifouling cured ceramic tile surface of oiliness evenly, polishes 1-10 minutes, obtain anti-skidding antifouling ceramic tile.
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 1 minute.
Using the ceramic tile after above-mentioned process, only with anti-skidding processing, quiet rub is slided according to GB/T4100-2015 wet process
Wiping coefficient is 0.7, and examining antifouling grade by the regulation of GB/T3810.14 is 2 grades, and Mohs' hardness is 4 grades.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the scope of the present invention.It is all
The equivalent changes and modifications that content is done according to the present invention are encompassed by the scope of the patents of the invention.
Claims (8)
1. a kind of antifouling anti-skidding treatment process of ceramic tile, which is characterized in that the technique includes the following steps：
Antifouling process step：Super clean bright anti-fouling agent is uniformly coated on ceramic tile surface to be processed, the surface for ceramic tile of polishing
It is greater than 85 degree to glossiness, obtains the ceramic tile of antifouling process；
The antifouling curing process step of oiliness：Oiliness anti-fouling agent is uniformly coated on the ceramic tile surface of antifouling process, polishes, obtains
To the antifouling cured ceramic tile of oiliness；
Anti-skidding processing step：Antilubricant is uniformly coated on the antifouling cured ceramic tile surface of oiliness, is polished, is obtained anti-skidding anti-
Dirty ceramic tile；
Cleaning treatment step：It is rinsed with water the surface of anti-skidding antifouling ceramic tile, polishing obtains the ceramic tile that antifouling anti-skidding processing is completed；
Baking step：By the complete ceramic tile of cleaning treatment 150-350 degrees Celsius at a temperature of drying and processing 0.5-5 minutes.
2. the antifouling anti-skidding treatment process of a kind of ceramic tile according to claim 1, which is characterized in that the antifouling process step
Polishing when ceramic tile surface temperature be 45-80 degrees Celsius.
3. the antifouling anti-skidding treatment process of a kind of ceramic tile according to claim 1, which is characterized in that the anti-skidding processing step
Abrasive material be wool pad.
4. the antifouling anti-skidding treatment process of a kind of ceramic tile according to claim 1, which is characterized in that the super clean bright anti-fouling agent
For the super clean bright anti-fouling agent of alkalinity containing nanoparticle.
5. the antifouling anti-skidding treatment process of a kind of ceramic tile according to claim 1, which is characterized in that the oiliness anti-fouling agent is
Solvent type oiliness anti-fouling agent.
6. the antifouling anti-skidding treatment process of a kind of ceramic tile according to claim 1, which is characterized in that the oiliness anti-fouling agent is
Alcohol ethers oiliness anti-fouling agent.
7. the antifouling anti-skidding treatment process of a kind of ceramic tile according to claim 1, which is characterized in that during the antilubricant is
Property, faintly acid antilubricant.
8. a kind of ceramic tile, the ceramic tile is using antifouling anti-skidding processing work described in any one of claim 1-7 claim
Skill is prepared.
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| CN116731578A (en) * | 2023-06-07 | 2023-09-12 | 佛山市安塔邦新材料有限公司 | Hard crystal face wear-resistant anti-slip agent |
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