CN109678561A - A kind of anti-skidding anti-fouling material of nano-hydrogel and its preparation method and application - Google Patents
A kind of anti-skidding anti-fouling material of nano-hydrogel and its preparation method and application Download PDFInfo
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- CN109678561A CN109678561A CN201811446316.8A CN201811446316A CN109678561A CN 109678561 A CN109678561 A CN 109678561A CN 201811446316 A CN201811446316 A CN 201811446316A CN 109678561 A CN109678561 A CN 109678561A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5007—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing
- C04B41/5015—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing containing phosphorus in the anion, e.g. phosphates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
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Abstract
The invention discloses anti-skidding anti-fouling materials of a kind of nano-hydrogel and its preparation method and application.The anti-skidding anti-fouling material of the nano-hydrogel, by weight percentage, including the following raw material: water-soluble organic acid 1~35%, synergist 0~5%, anion salt 0.001~10%, cationic polymer 0.001~10%, water surplus.After being surface-treated using the anti-skidding anti-fouling material of the nano-hydrogel to ceramic tile, the slight non-uniform corrosion ceramic tile surface of energy, keep ceramic tile surface uneven, it is formed again on the surface of ceramic tile and is as thin as nanoscale and transparent anti-skidding antifouling particle layer, there is no any organoleptic effects to the texture of ceramic tile, color saturation and pattern, and visually observes before processing less than significant difference；The anti-skidding antifouling persistent of the anti-skidding anti-fouling material of the nano-hydrogel, the quiet wiping coefficient of hygrometric state is up to 0.6 or more, and dry state confficient of static friction is up to 0.7 or more；The anti-skidding anti-fouling material of the nano-hydrogel is applied widely, can continuous mass production, easy industrialization promotion.
Description
Technical field
The present invention relates to technical field of ceramic production, in particular to the anti-skidding anti-fouling material of a kind of nano-hydrogel and its preparation
Methods and applications.
Background technique
Ceramic Tiles or ceramic wafer it is polished at after high gloss have it is well arranged, texture is full, rich in color, pattern can
Design, likes for people, becomes products of big industry.The prior art can also directly adopt anti-skidding glaze material production have anti-skidding function
Can ceramic tile, but this kind of ceramic tile only just has an anti-skidding effect in dry state, without anti-skidding effect when hygrometric state, therefore, existing ceramic tile
It is generally required in production process by antifouling and non skid matting treatment process.Existing ceramic tile surface treatment process is mainly as follows:
1. carrying out matte management to ceramic tile surface, although the ceramic tile that matte management is crossed has certain antiskid function, not only can be in certain journey
The original texture of ceramic tile, color and pattern, the ceramic tile after matte management are damaged on degree does not have anti-soil clean function, surface
It is easy to be dirty, and cleans difficult；2. spraying one layer of anti-skidding hyaline membrane in former polished bricks/plate face, but anti-skidding hyaline membrane is anti-
Dirty effect is poor, and still needs to carry out antifouling surface processing after spraying anti-skidding hyaline membrane, and anti-skidding hyaline membrane is at antifouling surface
It is easily removed in reason and subsequent use process, persistence is poor.
Summary of the invention
The purpose of the present invention is intended to provide a kind of anti-skidding anti-fouling material of nano-hydrogel and its preparation method and application, with solution
Certainly above-mentioned technical problem.
To achieve the goals above, the technical solution of the present invention is as follows:
In a first aspect, the anti-skidding anti-fouling material of a kind of nano-hydrogel provided by the invention, by weight percentage, including such as
Lower raw material: water-soluble organic acid 1~35%, synergist 0~5%, anion salt 0.001~10%, cationic polymer 0.001
~10%, water surplus.
Preferably, the water-soluble organic acid is selected from citric acid, oxalic acid, tartaric acid, malic acid, succinic acid, pyruvic acid, prolongs
One or more of fumarate.
Preferably, the synergist is selected from polyalcohol, water-soluble ether compound, water-soluble nonionic surface-active
One or both of agent, cationic surfactant.
Preferably, the cationic polymer is selected from one of chitin, chitosan, chitosan derivatives or a variety of.
Preferably, the anti-skidding anti-fouling material of the nano-hydrogel, by weight percentage, including the following raw material: it is water-soluble
Organic acid 1~15%, synergist 0~3%, anion salt 0.01~2%, cationic polymer 0.01~3%, water surplus.
Preferably, the anti-skidding anti-fouling material of the nano-hydrogel, by weight percentage, including the following raw material: it is water-soluble
Organic acid 2.5~5%, synergist 0.1~1%, anion salt 0.35~1%, cationic polymer 1.2~2%, water surplus.
Preferably, the average grain diameter of hydrogel particle is 50~250nm in the anti-skidding anti-fouling material of the nano-hydrogel.
Second aspect, a kind of preparation of the anti-skidding anti-fouling material of nano-hydrogel as described in relation to the first aspect provided by the invention
Method includes the following steps:
It is under stiring that organic acid is soluble in water, be added synergist, cationic polymer, after mixing evenly, be added dropwise yin from
The anti-skidding anti-fouling material of nano-hydrogel can be obtained in alite reaction.
A kind of third aspect, anti-skidding anti-fouling treatment method of ceramic brick surface provided by the invention, includes the following steps:
The anti-skidding anti-fouling material of nano-hydrogel using super clean brilliant polish equipment and as described in relation to the first aspect carries out ceramic tile
Surface treatment, the super clean brilliant polish equipment include 2~20 groups of grinding head for polishing, are equipped with 6 polishing emery wheels on every group of bistrique, will
The communicated band of ceramic tile is sent in super clean brilliant polish equipment, will be such as first aspect institute before ceramic tile is contacted with every group of grinding head for polishing
The anti-skidding anti-fouling material of the nano-hydrogel stated is added dropwise on ceramic tile surface with the dripping quantity of 10~100 drops, when the communicated band of ceramic tile
When the position being sent to below each group of bistrique, the polishing emery wheel on the bistrique is contacted with ceramic tile surface, the super clean bright throwing
The bistrique pair of light device is polished with ceramic tile surface, keeps ceramic tile surface dry.
In embodiments of the present invention, the anti-skidding anti-fouling treatment method of the ceramic brick surface further includes following steps: being used
Heating furnace carries out high temperature drying, the condition of high temperature drying to the ceramic tile after polishing are as follows: and 100~190 DEG C of temperature, the time 0.1~
5min。
Compared with prior art, the beneficial effects of the present invention are:
(1) after carrying out anti-skidding antifouling process to ceramic tile using the anti-skidding anti-fouling material of nano-hydrogel provided by the present invention,
The slight non-uniform corrosion ceramic tile surface of energy, keeps ceramic tile surface uneven, and is formed on the surface of ceramic tile and be as thin as nanoscale
And transparent anti-skidding antifouling particle layer, there is no any organoleptic effects to the texture of ceramic tile, color saturation and pattern, before processing
It visually observes less than significant difference；
(2) the anti-skidding persistent of the anti-skidding anti-fouling material of nano-hydrogel provided by the present invention, and hygrometric state and dry state are anti-
Sliding effect is significantly better than the anti-skidding anti-fouling effect of existing process of surface treatment, and the thickness of anti-skidding antifouling particle layer is bigger, anti-skidding
Effect is better, and the quiet wiping coefficient of hygrometric state is up to 0.6 or more, and dry state confficient of static friction is up to 0.7 or more；
(3) anti-skidding processing difficulty is easier than other techniques, and effect is good, can continuous mass production, easy industrialization promotion, and
The anti-skidding anti-fouling material of nano-hydrogel provided by the present invention is applied widely:
1. being suitable for Polished crystal tile, Buddha's warrior attendant glaze glazed tile, by super clean brilliant polish equipment, with nano-silicon aqueous dispersions by ceramic tile
High gloss (such as 90 degree or more) are thrown, are then surface-treated with the anti-skidding anti-fouling material of nano-hydrogel, washing is clean, blows
It is dry, it can be obtained the ceramic tile good with antiskid effect, and anti-fouling effect is also slightly better than not using the anti-skidding anti-fouling material of the present invention
Surface-treated Polished crystal tile and Buddha's warrior attendant glaze glazed tile；
2. being suitable for the general polished bricks of anti-fouling effect itself and glazed tile, this kind of ceramic tile is by super clean brilliant polish
Equipment bistrique throwing played the strong anti-fouling agent of rapid curing bonding force, using the anti-skidding anti-fouling material of nano-hydrogel of the invention into
After row surface treatment, the antiskid effect of ceramic tile is good, and anti-fouling effect be also better than it is only anti-with the processed ceramic tile of anti-fouling agent
Dirty effect；
3. being suitable for common Antique Imitation Tiles, half throwing Antique Imitation Tiles, soft throwing Antique Imitation Tiles and glazed tile.
Detailed description of the invention
Fig. 1 is the anti-pollution test result using the ceramic tile after the surface treatment of 1 products obtained therefrom of embodiment；
Fig. 2 is the anti-pollution test result using the ceramic tile after the surface treatment of 7 products obtained therefrom of embodiment；
Fig. 3 is the anti-pollution test result using the ceramic tile after the surface treatment of 8 products obtained therefrom of embodiment；
Fig. 4 is the anti-pollution test result using the ceramic tile after the surface treatment of 9 products obtained therefrom of embodiment；
Fig. 5 is the anti-pollution test result using the ceramic tile after the surface treatment of 10 products obtained therefrom of embodiment；
Fig. 6 is the anti-pollution test result using the ceramic tile after the surface treatment of 11 products obtained therefrom of embodiment；
Fig. 7 is the anti-pollution test result using the ceramic tile after the surface treatment of 12 products obtained therefrom of embodiment；
Fig. 8 is the anti-pollution test result using the ceramic tile after the surface treatment of 1 products obtained therefrom of comparative example；
Fig. 9 is the anti-pollution test result of not surface treated ceramic tile.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
In a first aspect, the anti-skidding anti-fouling material of a kind of nano-hydrogel provided by the invention, by weight percentage, including such as
Lower raw material: water-soluble organic acid 1~35%, synergist 0~5%, anion salt 0.001~10%, cationic polymer 0.001
~10%, water surplus.
In embodiments of the present invention, the water-soluble organic acid is selected from citric acid, oxalic acid, tartaric acid, malic acid, fourth two
One or more of acid, pyruvic acid, fumaric acid.
In embodiments of the present invention, the synergist is selected from polyalcohol, water-soluble ether compound, water-soluble nonionic
One or both of type surfactant, cationic surfactant.
Further, the polyalcohol is selected from one of glycerine, isopropanol, isobutanol or a variety of.
Further, the water-soluble nonionic surfactant is selected from polyethylene glycol, alkyl phenol polyoxyethylene ether phosphorus
One of acid esters, alkyl-glucoside, fatty alcohol polyoxyethylene ether are a variety of.
In the present invention, the synergist mainly plays humidification, is conducive to the anti-skidding anti-fouling material of nano-hydrogel in porcelain
The coating of brick surface uniformly, improves antiskid effect.In embodiments of the present invention, the anion salt be selected from phosphate, sulfate,
One of fluoride, alginate are a variety of.
In the present invention, the fluoride is used for the corrosiveness of the anti-skidding anti-fouling material of reinforced nano hydrogel, but most
It not be used alone well, it is more preferable with other high-valence anion salt (such as phosphate, alginate) composite effect.
In embodiments of the present invention, the cationic polymer is in chitin, chitosan, chitosan derivatives
It is one or more.
In the present invention, dosage of the cationic polymer in the anti-skidding anti-fouling material of nano-hydrogel be 0.01~
10% (further preferably 0.1~3%), the dosage of the cationic polymer is excessive, and it is anti-skidding anti-to will lead to nano-hydrogel
The water absorption of dirty material is excessive, and mechanical strength is poor, to influence the non-skid property of the anti-skidding anti-fouling material of nano-hydrogel；It is described
The dosage of cationic polymer is very few, and the water absorption that will lead to the anti-skidding anti-fouling material of nano-hydrogel is very few, high mechanical strength, prevents
Dirty persistence is high, but antiskid effect is poor.
In embodiments of the present invention, the anti-skidding anti-fouling material of the nano-hydrogel, by weight percentage, including it is as follows
Raw material: water-soluble organic acid 1~15%, synergist 0~3%, anion salt 0.01~2%, cationic polymer 0.01~
3%, water surplus.
In embodiments of the present invention, the anti-skidding anti-fouling material of the nano-hydrogel, by weight percentage, including it is as follows
Raw material: water-soluble organic acid 2.5~5%, synergist 0.1~1%, anion salt 0.35~1%, cationic polymer 1.2~
2%, water surplus.
In embodiments of the present invention, the average grain diameter of hydrogel particle is in the anti-skidding anti-fouling material of the nano-hydrogel
50~250nm.
Second aspect, a kind of preparation of the anti-skidding anti-fouling material of nano-hydrogel as described in relation to the first aspect provided by the invention
Method includes the following steps:
It is under stiring that organic acid is soluble in water, be added synergist, cationic polymer, after mixing evenly, be added dropwise yin from
The anti-skidding anti-fouling material of nano-hydrogel can be obtained in alite reaction.
A kind of third aspect, anti-skidding anti-fouling treatment method of ceramic brick surface provided by the invention, includes the following steps:
The anti-skidding anti-fouling material of nano-hydrogel using super clean brilliant polish equipment and as described in relation to the first aspect carries out ceramic tile
Surface treatment, the super clean brilliant polish equipment include 2~20 groups of grinding head for polishing, are equipped with 6 polishing emery wheels on every group of bistrique, will
The communicated band of ceramic tile is sent in super clean brilliant polish equipment, will be such as first aspect institute before ceramic tile is contacted with every group of grinding head for polishing
The anti-skidding anti-fouling material of the nano-hydrogel stated is added dropwise on ceramic tile surface with the dripping quantity of 10~100 drops, when the communicated band of ceramic tile
When the position being sent to below each group of bistrique, the polishing emery wheel on the bistrique is contacted with ceramic tile surface, the super clean bright throwing
The bistrique pair of light device is polished with ceramic tile surface, keeps ceramic tile surface dry.
In embodiments of the present invention, the anti-skidding anti-fouling treatment method of the ceramic brick surface further includes following steps: being used
Heating furnace carries out high temperature drying, the condition of high temperature drying to the ceramic tile after polishing are as follows: and 100~190 DEG C of temperature, the time 0.1~
5min.High temperature drying processing can be such that the moisture inside the gel particles of ceramic tile surface all releases, and be conducive to improve gel
The antifouling non-skid property of particle layer.
In embodiments of the present invention, the revolving speed of the bistrique of the super clean brilliant polish equipment is 60~120r/min.
In embodiments of the present invention, the operating condition of the polishing emery wheel are as follows: revolving speed is 500~2800r/min, pressure
For 0.5~3Kg/cm2。
The embodiment of the present invention is described further below.
Embodiment 1
Take following raw materials by weight percentage: citric acid 5.0%, glycerine 0.5%, sodium phosphate 0.5%, chitosan
2%, water surplus.It is under conditions of normal temperature and pressure and stirring, citric acid is soluble in water, glycerine, chitosan is added, stirring is equal
After even, sodium phosphate is added dropwise, it is reacted that the anti-skidding anti-fouling material of nano-hydrogel, the anti-skidding antifouling material of nano-hydrogel can be obtained
Material is the nanogel solution of organic polymer cladding.
Embodiment 2~6
Beneficial effect in order to further illustrate the present invention repeats above-mentioned step, by " the chitosan in above-mentioned steps
2% " is substituted for " chitosan 0.01% ", " chitosan 0.1% ", " chitosan 1% ", " chitosan 2.5% ", " chitosan 3% ",
Obtain the anti-skidding anti-fouling material of nano-hydrogel.
Application Example 1
Beneficial effect in order to further illustrate the present invention, using 1~6 gained of super clean brilliant polish equipment and above-described embodiment
Nano-hydrogel anti-skidding anti-fouling material ceramic tile is surface-treated, the super clean brilliant polish equipment include 6 groups of grinding head for polishing,
6 polishing emery wheels are installed on every group of bistrique, the communicated band of ceramic tile are sent in super clean brilliant polish equipment, in ceramic tile and every group
Before grinding head for polishing contact, the anti-skidding anti-fouling material of nano-hydrogel is added dropwise on ceramic tile surface with the dripping quantity of 20 drops, works as ceramic tile
When communicated band is sent to the position below each group of bistrique, the polishing emery wheel on the bistrique is contacted with ceramic tile surface, described
The bistrique pair of super clean brilliant polish equipment is polished with ceramic tile surface, keeps ceramic tile surface dry, then using heating furnace to polishing after
Ceramic tile carry out high temperature drying, wherein the bistrique of the super clean brilliant polish equipment is with the rotational speed of 100r/min, the polishing
Emery wheel is with the revolving speed of 1500r/min, 1.5Kg/cm2Pressure pair polish with ceramic tile surface；The condition of the high temperature drying
Are as follows: 185 DEG C of temperature, time 0.5min.
Performance test:
Beneficial effect in order to further illustrate the present invention, according to GB/T26542-2001 test method to above-mentioned processed
Tile product be tested for the property, shown in test result table 1.
1 non-skid property test result of table
Embodiment 7
Take following raw materials by weight percentage: citric acid 2.5%, glycerine 0.1%, ammonium acid fluoride 1%, chitosan
1.2%, water surplus.It is under conditions of normal temperature and pressure and stirring, citric acid is soluble in water, glycerine, chitosan, stirring is added
After uniformly, ammonium acid fluoride is added dropwise, it is reacted that the anti-skidding anti-fouling material of nano-hydrogel can be obtained, wherein hydrogel particle is put down
Equal partial size is 125nm.
Embodiment 8
Take following raw materials by weight percentage: citric acid 3.0%, glycerine 1.0%, sodium alginate 0.05%, fluorine
Change hydrogen ammonium 0.3%, chitosan 1.6%, water surplus.It is under conditions of normal temperature and pressure and stirring, citric acid is soluble in water, it is added
Sodium alginate and ammonium acid fluoride is added dropwise after mixing evenly in glycerine, chitosan, and reacted that nano-hydrogel can be obtained is anti-skidding
Anti-fouling material, wherein the average grain diameter of hydrogel particle is 143nm.
Embodiment 9
Take following raw materials by weight percentage: citric acid 5%, glycerine 3%, sodium alginate 1%, ammonium acid fluoride
1%, chitosan 2.5%, water surplus.It is under conditions of normal temperature and pressure and stirring, citric acid is soluble in water, addition glycerine,
Sodium alginate and ammonium acid fluoride is added dropwise after mixing evenly in chitosan, reacted that the anti-skidding antifouling material of nano-hydrogel can be obtained
Material, wherein the average grain diameter of hydrogel particle is 162nm.
Embodiment 10
Take following raw materials by weight percentage: citric acid 1%, glycerine 0.5%, sodium alginate 0.05%, fluorination
Hydrogen ammonium 0.05%, chitosan 0.1%, water surplus.It is under conditions of normal temperature and pressure and stirring, citric acid is soluble in water, it is added
Glycerine, chitosan, after mixing evenly, ammonium acid fluoride reaction, which is added dropwise, can be obtained the anti-skidding anti-fouling material of nano-hydrogel, wherein
The average grain diameter of hydrogel particle is 71nm.
Embodiment 11
Take following raw materials by weight percentage: oxalic acid 3.5%, isopropanol 0.6%, sodium alginate 0.1%, chitosan
0.1%, water surplus.It is under conditions of normal temperature and pressure and stirring, oxalic acid is soluble in water, isopropanol, chitosan is added, stirring is equal
After even, sodium alginate reaction, which is added dropwise, can be obtained the anti-skidding anti-fouling material of nano-hydrogel, wherein the average grain diameter of hydrogel particle
For 71nm.
Embodiment 12
Take following raw materials by weight percentage: tartaric acid 4%, polyethylene glycol 0.5%, sodium phosphate 0.8%, chitin
1.6%, water surplus.It is under conditions of normal temperature and pressure and stirring, citric acid is soluble in water, polyethylene glycol, chitin is added, stirs
After mixing uniformly, sodium phosphate reaction, which is added dropwise, can be obtained the anti-skidding anti-fouling material of nano-hydrogel, wherein the average grain of hydrogel particle
Diameter is 71nm.
Comparative example 1
Beneficial effect in order to further illustrate the present invention, according to real in the patent of invention of Publication No. CN108300414A
It applies example 10 and anti-skidding nano material is made.
Application Example 2
Beneficial effect in order to further illustrate the present invention, according to the method for Application Example 1, using above-described embodiment 1,
Embodiment 7~12 and 1 resulting product of comparative example are surface-treated ceramic tile.
Performance test:
(1) beneficial effect in order to further illustrate the present invention, using U.S.'s ASTMC1028-07 tester to above-mentioned reality
The performance for applying 1 resulting product of example 1, embodiment 7~12 and comparative example is tested, and anti-skidding classification standard is as shown in table 2.
The anti-skidding classification standard of table 2
| Anti-skidding grade | Slide angle | Wet friction coefficient | Slip risk |
| R9 | 6 °~10 ° | 0.11~0.18 | It is high |
| R10 | 10 °~19 ° | 0.18~0.34 | It is higher |
| R11 | 19 °~27 ° | 0.34~0.51 | It is lower |
| R12 | 27 °~35 ° | 0.51~0.70 | It is low |
| R13 | 35 ° of > | > 0.70 | It is low |
Through detecting, the embodiment of the present invention 1, the non-skid property test result of 7~12 products obtained therefrom of embodiment show wet friction
Coefficient is between 0.51~0.70, and anti-skidding grade is R12, and the non-skid property test result of 1 resulting product of comparative example
Show that anti-skidding grade is R11.
(2) beneficial effect in order to further illustrate the present invention, the present invention also use following methods to for the above-mentioned reality of progress
Apply the ceramic tile of 3h and the ceramic tile not being surface-treated after example 1, embodiment 7~12 and 1 products obtained therefrom of comparative example are surface-treated
Anti-pollution test is carried out, specific testing procedure is as follows:
It is smeared with oil pen in ceramic tile surface, is wiped after ten minutes with paper handkerchief, observe brick planar condition.Test result ginseng
See Fig. 1~9, wherein Fig. 1~7 are respectively the anti-of the ceramic tile after embodiment 1 and the surface treatment of 7~12 products obtained therefrom of embodiment
Dirty the performance test results, Fig. 8 are the anti-pollution test result of the ceramic tile after 1 products obtained therefrom of example surface treatment by contrast, and Fig. 9 is
The anti-pollution test result of not surface treated ceramic tile.
By Fig. 1~9 it is found that through 1,8,9,12 products obtained therefrom of the embodiment of the present invention surface treatment after ceramic tile anti-pollution most
Good, ink marks can remove easily, any surface finish of ceramic tile after wiping, without any stain；And through 7,10,11 institute of the embodiment of the present invention
Product surface treated that ceramic tile anti-pollution is preferable, after wiping, ceramic tile surface needs to be rinsed with water still there are a small amount of ink marks
Wiped clean；And the ceramic tile surface after 1 products obtained therefrom of comparative example of the present invention surface treatment has a large amount of ink markss to remain, and without table
The ink marks residual quantity of the ceramic tile surface of surface treatment does not have significant difference, and is required to be cleaned with detergent.Obviously, the present invention is implemented
The anti-pollution of the anti-skidding anti-fouling material of nano-hydrogel provided by example 1,7~12 is far superior to the anti-of 1 products obtained therefrom of comparative example
Dirty performance.
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (10)
1. a kind of anti-skidding anti-fouling material of nano-hydrogel, which is characterized in that by weight percentage, including the following raw material: it is water-soluble
Property organic acid 1~35%, synergist 0~5%, anion salt 0.001~10%, cationic polymer 0.001~10%, more than water
Amount.
2. the anti-skidding anti-fouling material of nano-hydrogel according to claim 1, which is characterized in that the water-soluble organic acid choosing
From one or more of citric acid, oxalic acid, tartaric acid, malic acid, succinic acid, pyruvic acid, fumaric acid.
3. the anti-skidding anti-fouling material of nano-hydrogel according to claim 1, which is characterized in that the synergist is selected from polynary
One or both of alcohol, water-soluble ether compound, water-soluble nonionic surfactant, cationic surfactant.
4. the anti-skidding anti-fouling material of nano-hydrogel according to claim 1, which is characterized in that the cationic polymer choosing
From one of chitin, chitosan, chitosan derivatives or a variety of.
5. the anti-skidding anti-fouling material of nano-hydrogel according to claim 1, which is characterized in that the nano-hydrogel is anti-skidding
Anti-fouling material, by weight percentage, including the following raw material: water-soluble organic acid 1~15%, synergist 0~3%, anion
Salt 0.01~2%, cationic polymer 0.01~3%, water surplus.
6. the anti-skidding anti-fouling material of nano-hydrogel according to claim 1, which is characterized in that the nano-hydrogel is anti-skidding
Anti-fouling material, by weight percentage, including the following raw material: water-soluble organic acid 2.5~5%, synergist 0.1~1%, yin from
Alite 0.35~1%, cationic polymer 1.2~2%, water surplus.
7. the anti-skidding anti-fouling material of nano-hydrogel according to claim 1, which is characterized in that the nano-hydrogel is anti-skidding
The average grain diameter of hydrogel particle is 50~250nm in anti-fouling material.
8. a kind of preparation method of such as anti-skidding anti-fouling material of nano-hydrogel according to any one of claims 1 to 7, feature
It is, includes the following steps:
It is under stiring that organic acid is soluble in water, synergist, cationic polymer is added, after mixing evenly, anion salt is added dropwise
The anti-skidding anti-fouling material of nano-hydrogel can be obtained in reaction.
9. a kind of anti-skidding processing method of ceramic brick surface, which comprises the steps of:
Using super clean brilliant polish equipment and such as the anti-skidding anti-fouling material pair of nano-hydrogel according to any one of claims 1 to 6
Ceramic tile is surface-treated, and the super clean brilliant polish equipment includes 2~20 groups of grinding head for polishing, is equipped with 6 throwings on every group of bistrique
The communicated band of ceramic tile is sent in super clean brilliant polish equipment by tarry matter wheel, will be such as before ceramic tile is contacted with every group of grinding head for polishing
The anti-skidding anti-fouling material of nano-hydrogel described in one side is added dropwise on ceramic tile surface with the dripping quantity of 10~100 drops, works as ceramic tile
When communicated band is sent to the position below each group of bistrique, the polishing emery wheel on the bistrique is contacted with ceramic tile surface, described
The bistrique pair of super clean brilliant polish equipment is polished with ceramic tile surface, keeps ceramic tile surface dry.
10. the anti-skidding processing method of ceramic brick surface according to claim 9, which is characterized in that further include following steps: adopting
High temperature drying, the condition of high temperature drying are carried out to the ceramic tile after polishing with heating furnace are as follows: 100~190 DEG C of temperature, the time 0.1~
5min。
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110587405A (en) * | 2019-08-06 | 2019-12-20 | 佛山欧神诺陶瓷有限公司 | Method for improving anti-slip performance of polished tile and polished tile |
| CN115612408A (en) * | 2022-09-05 | 2023-01-17 | 佛山市号亮科技有限公司 | Wear-resistant anti-slip crystal face agent for polishing ceramic tiles and using method thereof |
-
2018
- 2018-11-29 CN CN201811446316.8A patent/CN109678561A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110587405A (en) * | 2019-08-06 | 2019-12-20 | 佛山欧神诺陶瓷有限公司 | Method for improving anti-slip performance of polished tile and polished tile |
| CN110587405B (en) * | 2019-08-06 | 2021-06-18 | 佛山欧神诺陶瓷有限公司 | Method for improving anti-slip performance of polished tile and polished tile |
| CN115612408A (en) * | 2022-09-05 | 2023-01-17 | 佛山市号亮科技有限公司 | Wear-resistant anti-slip crystal face agent for polishing ceramic tiles and using method thereof |
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