CN108048804A - A kind of oil-stain-preventing lens coating method - Google Patents
A kind of oil-stain-preventing lens coating method Download PDFInfo
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- CN108048804A CN108048804A CN201711354745.8A CN201711354745A CN108048804A CN 108048804 A CN108048804 A CN 108048804A CN 201711354745 A CN201711354745 A CN 201711354745A CN 108048804 A CN108048804 A CN 108048804A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/28—Vacuum evaporation by wave energy or particle radiation
- C23C14/30—Vacuum evaporation by wave energy or particle radiation by electron bombardment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0688—Cermets, e.g. mixtures of metal and one or more of carbides, nitrides, oxides or borides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/10—Glass or silica
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
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- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
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- Ophthalmology & Optometry (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The present invention discloses a kind of oil-stain-preventing lens coating method, and manufacturing method is that membrane system is deposited respectively in the molding substrate outer surface of macromolecule resin material and inner surface to form anti-blue light optical mirror slip, and manufacturing method specifically includes following steps：1）Substrate is cleaned；2）Drying after substrate cleaning：3）Cleaning again before substrate coating in the vacuum chamber of vacuum evaporation plating machine：4）The plated film of substrate：The plated film of substrate is included in the outer surface plating membrane system of substrate and plates membrane system in the inner surface of substrate.With the injury of harmful blue light and ultraviolet light to human body is prevented, which also has the function of oil-stain-preventing and regulates and controls from main optical the anti-blue light optical mirror slip that the present invention manufactures simultaneously.
Description
Technical field
The present invention relates to a kind of oil-stain-preventing lens coating methods.
Background technology
People have known that ultraviolet light can damage eyes, and the irradiation of long-term ultraviolet light can trigger cataract.Equally,
Blue light is the high-energy visible ray that wavelength is 400-500nm, and blue light is can be directed through cornea, eyes crystal, through regard
Nethike embrane, blue light can stimulate retina to generate a large amount of radical ions so that the atrophy of retinal pigment epithelium, and cause light
The death of sensitive cells, retinal pigment epithelium are very strong to the light absorption effect of blue region, absorb blue light spoke
One of the main reason for retinal pigment epithelium atrophy can be made by penetrating, this is also generation maculopathy；Blue ray radiation ingredient is got over
Height is bigger to cellula visualis injury, and the atrophy of retinal pigment epithelium can make the image of retina thicken, to fuzzy
Image ciliary muscle can do continuous adjusting, aggravate the working strength of ciliary muscle, cause visual fatigue.In ultraviolet light and blue light
Under the action of can cause the visual fatigue of people, eyesight can be gradually reduced, and easily cause dry and astringent, photophobia, fatigue on ocular vision
Wait early onsets cataract, spontaneous macular diseases.
In addition, when the hand of people is touched in touch display screen, greasy dirt on hand and water stain it is easy in touch display screen
On leave a trace, these traces are not easy to wipe out very much again, can thus influence user observe things effect, to user
It makes troubles.And regular wiping touch display screen is easy to scratch touch display screen again.
The content of the invention
It is an object of the invention to provide a kind of oil-stain-preventing lens coating method, anti-blue light optics that this method manufactures
Eyeglass has the function of oil-stain-preventing and regulates and controls from main optical, while can also prevent the injury of harmful blue light and ultraviolet light to human body.
To achieve the above object, the present invention uses following technical scheme：
A kind of oil-stain-preventing lens coating method, the manufacturing method are that membrane system is deposited respectively in substrate outer surface and inner surface to be formed
Anti-blue light optical mirror slip, the manufacturing method specifically include following steps：
1）Substrate is cleaned；
2）Drying after substrate cleaning：Substrate after cleaning is taken off with isopropanol it is dry, it is de- it is dry after substrate drawn slowly using isopropanol
It is dry, then be placed in dustless plated film constant temperature roaster more than when 60 DEG C~75 DEG C bakings 8 are small；
3）Cleaning again before substrate coating in the vacuum chamber of vacuum evaporation plating machine：Slowly dried substrate is drawn to be placed in isopropanol
In the vacuum chamber of vacuum evaporation plating machine, the vacuum degree in vacuum chamber is adjusted to less than or equal to 9.5 × 10-3 pas, starts ion source
Icon bombardment cleaning is carried out to substrate, wherein, temperature is 60~68 DEG C in vacuum chamber, and ion bombardment rate is 180~190a/
Sec, time are 2~5min；
4）The plated film of substrate：The plated film of substrate is included in the outer surface plating membrane system of substrate and plates membrane system in the inner surface of substrate；
A, the outer surface plating membrane system of substrate sequentially include plating shock resistance strengthen film layer, plating uvioresistant film layer, plating anti-blue light film layer,
Plate optics regulation and control film layer, plating oil-stain-preventing film layer；
Film layer is strengthened in A1, plating shock resistance：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3 pas, using electricity
Sub- rifle, after the membrane material of shock resistance reinforcing film layer is evaporated, the membrane material is with nanoscale molecular shape under the action of ion source
Formula is deposited on substrate outer surface, forms shock resistance and strengthens film layer, the thickness that film layer is strengthened in shock resistance is 50-100 nanometers；It is described anti-
The membrane material of shock peening film layer is silica；
A2, plating uvioresistant film layer：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3 pas, using electronics
After the membrane material of uvioresistant film layer is evaporated by rifle, the membrane material is deposited in the form of nanoscale molecular under the action of ion source
In the surface of step A1 moderate resistance shock peening film layers, uvioresistant film layer is formed, the thickness of uvioresistant film layer is received for 10-50
Rice；The membrane material of the uvioresistant film layer includes the mixture of following weight ratio ingredient：Silica 20%-80%；Zirconium oxide 20%-
80%；
A3, plating anti-blue light film layer：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3 pas, using electron gun
After the membrane material of anti-blue light film layer is evaporated, the membrane material is deposited on step in the form of nanoscale molecular under the action of ion source
The surface of rapid A2 moderate resistance ultraviolet light film layers forms anti-blue light film layer, and the thickness of anti-blue light film layer is 5-20 nanometers；The anti-blue light
The membrane material of film layer includes the mixture of following weight ratio ingredient：Tin oxide 30%-60%；Rubidium 10%-40%；Platinum 10%-40%；
Repeat step A3 at least once more than, form more than the two layers anti-blue light film layer being stacked with；
A4, plating optics regulation and control film layer：After using electron gun, the membrane material of optics regulation and control film layer is evaporated, in the effect of ion source
Under the membrane material surface of anti-blue light film layer in step A3 is deposited in the form of nanoscale molecular, form optics regulation and control film layer, light
The thickness for learning regulation and control film layer is 20-100 nanometers；The membrane material of the optics regulation and control film layer includes the mixing of following weight ratio ingredient
Object：Aluminium 40%-60%；Silica 40%-60%；
A5, plating oil-stain-preventing film layer：After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source
The surface that membrane material is deposited on optics regulation and control film layer in step A4 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing
The thickness of film layer is 5-20 nanometers；The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient：Magnesium fluoride
60%-80%；Zirconium oxide 20%-40%；
Oil-stain-preventing film layer plated film is completed, and after the completion of the outer surface plating membrane system of substrate, is transferred to the inner surface plating membrane system of substrate；
B, the inner surface plating membrane system of substrate sequentially include plating shock resistance strengthen film layer, plating uvioresistant film layer, plating anti-blue light film layer,
Plate oil-stain-preventing film layer；
Film layer is strengthened in B1, plating shock resistance：Using electron gun, after the membrane material of shock resistance reinforcing film layer is evaporated, in ion source
Under the action of the membrane material be deposited on substrate interior surface in the form of nanoscale molecular, form shock resistance and strengthen film layer, shock resistance is strong
The thickness for changing film layer is 50-100 nanometers；The membrane material that film layer is strengthened in the shock resistance is silica；
B2, plating uvioresistant film layer：After using electron gun, the membrane material of uvioresistant film layer is evaporated, in the effect of ion source
Under the membrane material surfaces of step A1 moderate resistance shock peening film layers is deposited in the form of nanoscale molecular, form uvioresistant film
Layer, the thickness of uvioresistant film layer is 10-50 nanometers；The membrane material of the uvioresistant film layer includes the mixed of following weight ratio ingredient
Close object：Silica 20%-80%；Zirconium oxide 20-80%；
Repeat step B2 at least once more than, form more than the two layers uvioresistant film layer being stacked with；
B3, plating anti-blue light film layer：After using electron gun, the membrane material of anti-blue light film layer is evaporated, the institute under the action of ion source
The surface that membrane material is deposited on step B2 moderate resistance ultraviolet light film layers in the form of nanoscale molecular is stated, forms anti-blue light film layer, anti-blue light
The thickness of film layer is 5-20 nanometers；The membrane material of the anti-blue light film layer includes the mixture of following weight ratio ingredient：Tin oxide
30%-60%；Rubidium 10%-40%；Platinum 10%-40%；
Repeat step B3 at least once more than, form more than the two layers anti-blue light film layer being stacked with；
B4, plating oil-stain-preventing film layer：After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source
The surface that membrane material is deposited on anti-blue light film layer in step B3 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing film
The thickness of layer is 20-100 nanometers；The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient：Magnesium fluoride
60%-80%；Zirconium oxide 20%-40%.
The step 1）In, the cleaning of substrate is as follows：
A, substrate is cleaned using organic cleaning solvent, and aids in cleaning with ultrasonic wave；
B, the substrate cleaned through step a is cleaned using aqueous cleaning agent, and aids in cleaning with ultrasonic wave；
C, the substrate for handling step b sequentially carries out tap water rinse and distilled water rinsing.
The substrate is molded for macromolecule resin.
The effect of film layer is strengthened in the shock resistance of substrate outer surface and inner surface：The impact resistance of eyeglass can the 1st, improved,
Eyeglass do not allow it is broken avoid injury eyes；2nd, the adhesive force of eyeglass is improved, can be had as the medium for plating next tunic layer
Fine cementation to be not easy delamination between film layer.
The effect of the uvioresistant film layer of substrate outer surface and inner surface：Corrosion-resistant, anti-oxidant, stop ultraviolet light.
The effect of the anti-blue light film layer of substrate outer surface and inner surface：For the blue light absorption rate that wavelength is 380-500nm
Reach up to more than 33% and various harmful rays, make the visual field apparent bright, and can also effective protect eyes,
Extenuate visual fatigue.
The effect of substrate outer surface optics regulation and control film layer：It make use of the principle of zoom camera camera lens, rather dark or
In the too strong environment of light, optics regulation and control film layer have it is certain from main optical regulate and control, play the role of photo-equilibrium so that Yong Hugeng
It is fast to adapt to environment；Long depending on overtaxing one's nerves, for a long time against computer, LCD screen, eyes be present with ache, be dry and astringent, eye is swollen, sheds tears etc. regards
Feel fatigue phenomenon, the processing of film is regulated and controled by optics can alleviate visual fatigue.
The effect of the oil-stain-preventing film layer of substrate outer surface and inner surface：Oil-stain-preventing film layer will plate the film layer of substrate surface
Cover, and can Jiang Shui and oil reduced with the contact area of eyeglass, oil and water droplet is made to be not easy to be adhered to lens surface.
The present invention uses the principle of electron beam vacuum evaporation, has after being accelerated in the electric field using electrically charged particle certain
Ion is guided into and is intended to the electrode made of the substrate of plated film by the characteristics of kinetic energy, and by electron gun with high temperature bombardment that high-purity is golden
Belong to oxide component, the nano molecular being evaporated makes it move to substrate and finally in deposition on substrate along certain direction
The method of film forming.This invention technology is combined the trajectory of electron motion in the special distributed controll electric field in magnetic field, is changed with this
Into the technique of plated film so that coating film thickness and uniformity are controllable, and the film layer compactness prepared is good, cohesive force is strong and degree of purity
It is high.
Description of the drawings
The present invention is described in further details below in conjunction with the drawings and specific embodiments：
Fig. 1 is the whole exploded view of the present invention.
Specific embodiment
As shown in Figure 1, a kind of oil-stain-preventing lens coating method, the manufacturing method is in 11 outer surface of substrate and inner surface
Membrane system is deposited respectively and forms anti-blue light optical mirror slip, the manufacturing method specifically includes following steps：
1）Substrate 1 is cleaned；
2）Drying after the cleaning of substrate 1：Substrate 1 after cleaning is taken off with isopropanol it is dry, take off it is dry after substrate 1 it is slow using isopropanol
Drying is drawn, then is placed in dustless plated film constant temperature roaster more than when 60 DEG C~75 DEG C bakings 8 are small；
3）Cleaning again before 1 plated film of substrate in the vacuum chamber of vacuum evaporation plating machine：Isopropanol is drawn slowly dried substrate 1 put
In in the vacuum chamber of vacuum evaporation plating machine, the vacuum degree in vacuum chamber is adjusted to less than or equal to 9.5 × 10-3 pas, starts ion
Source carries out icon bombardment cleaning to substrate 1, wherein, temperature is 60~68 DEG C in vacuum chamber, ion bombardment rate for 180~
190a/sec, time are 2~5min；
4）The plated film of substrate 1：The outer surface plating membrane system and the inner surface plated film in substrate 1 that the plated film of substrate 1 is included in substrate 1
System；
A, the outer surface plating membrane system of substrate 1 sequentially includes plating shock resistance reinforcing film layer, plating uvioresistant film layer, plating anti-blue light film layer
4th, optics regulation and control film layer 5, plating oil-stain-preventing film layer 6 are plated；
Film layer 2 is strengthened in A1, plating shock resistance：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3 pas, using electricity
Sub- rifle, after the membrane material of shock resistance reinforcing film layer 2 is evaporated, the membrane material is with nanoscale molecular shape under the action of ion source
Formula is deposited on 1 outer surface of substrate, forms shock resistance and strengthens film layer 2, the thickness that film layer 2 is strengthened in shock resistance is 50-100 nanometers；Institute
It states shock resistance and strengthens the membrane material of film layer 2 as silica；
A2, plating uvioresistant film layer 3：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3 pas, using electronics
After the membrane material of uvioresistant film layer 3 is evaporated by rifle, the membrane material is sunk in the form of nanoscale molecular under the action of ion source
Product forms uvioresistant film layer 3, the thickness of uvioresistant film layer 3 is 10- in the surface of step A1 moderate resistance shock peenings film layer 2
50 nanometers；The membrane material of the uvioresistant film layer 3 includes the mixture of following weight ratio ingredient：Silica 20%-80%；Zirconium oxide
20%-80%；
A3, plating anti-blue light film layer 4：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3 pas, using electron gun
After the membrane material of anti-blue light film layer 4 is evaporated, the membrane material is deposited in the form of nanoscale molecular under the action of ion source
The surface of step A2 moderate resistance ultraviolet lights film layer 3 forms anti-blue light film layer 4, and the thickness of anti-blue light film layer 4 is 5-20 nanometers；It is described
The membrane material of anti-blue light film layer 4 includes the mixture of following weight ratio ingredient：Tin oxide 30%-60%；Rubidium 10%-40%；Platinum 10%-
40%；
Repeat step A3 at least once more than, form more than the two layers anti-blue light film layer 4 being stacked with；
A4, plating optics regulation and control film layer 5：After using electron gun, the membrane material of optics regulation and control film layer 5 is evaporated, in the work of ion source
The surface of anti-blue light film layer 4 in step A3 is deposited in the form of nanoscale molecular with the lower membrane material, forms optics regulation and control film layer
5, the thickness of optics regulation and control film layer 5 is 20-100 nanometers；The membrane material of the optics regulation and control film layer 5 includes following weight ratio ingredient
Mixture：Aluminium 40%-60%；Silica 40%-60%；
A5, plating oil-stain-preventing film layer 6：After using electron gun, the membrane material of oil-stain-preventing film layer 6 is evaporated, under the action of ion source
The membrane material is deposited on the surface of optics regulation and control film layer 5 in step A4 in the form of nanoscale molecular, forms oil-stain-preventing film layer 6, prevents
The thickness of greasy dirt film layer 6 is 5-20 nanometers；The membrane material of the oil-stain-preventing film layer 6 includes the mixture of following weight ratio ingredient：Fluorine
Change magnesium 60%-80%；Zirconium oxide 20%-40%；
6 plated film of oil-stain-preventing film layer is completed, and after the completion of the outer surface plating membrane system of substrate 1, is transferred to the inner surface plating membrane system of substrate 1；
B, the inner surface plating membrane system of substrate 1 sequentially includes plating shock resistance reinforcing film layer 7, plating uvioresistant film layer 3, plating anti-blue light film
Layer 4, plating oil-stain-preventing film layer 6；
Film layer 7 is strengthened in B1, plating shock resistance：Using electron gun, after the membrane material of shock resistance reinforcing film layer 7 is evaporated, in ion
The membrane material is deposited on 1 inner surface of substrate in the form of nanoscale molecular under the action of source, forms shock resistance and strengthens film layer 7, anti-impact
It hits and strengthens the thickness of film layer 7 as 50-100 nanometers；The membrane material that film layer 7 is strengthened in the shock resistance is silica；
B2, plating uvioresistant film layer 8：After using electron gun, the membrane material of uvioresistant film layer 8 is evaporated, in the work of ion source
The surface of step A1 moderate resistance shock peenings film layer 7 is deposited in the form of nanoscale molecular with the lower membrane material, forms uvioresistant
Film layer 8, the thickness of uvioresistant film layer 8 is 10-50 nanometers；The membrane material of the uvioresistant film layer 8 includes following weight ratio group
The mixture divided：Silica 20%-80%；Zirconium oxide 20-80%；
Repeat step B2 at least once more than, form more than the two layers uvioresistant film layer 8 being stacked with；
B3, plating anti-blue light film layer 9：After using electron gun, the membrane material of anti-blue light film layer 9 is evaporated, under the action of ion source
The membrane material is deposited on the surface of step B2 moderate resistance ultraviolet lights film layer 8 in the form of nanoscale molecular, forms anti-blue light film layer 9, prevents
The thickness of blue light film layer 9 is 5-20 nanometers；The membrane material of the anti-blue light film layer 9 includes the mixture of following weight ratio ingredient：Oxygen
Change tin 30%-60%；Rubidium 10%-40%；Platinum 10%-40%；
Repeat step B3 at least once more than, form more than the two layers anti-blue light film layer 9 being stacked with；
B4, plating oil-stain-preventing film layer 10：After using electron gun, the membrane material of oil-stain-preventing film layer 10 is evaporated, in the effect of ion source
Under the membrane material surface of anti-blue light film layer 9 in step B3 is deposited in the form of nanoscale molecular, form oil-stain-preventing film layer 10, prevent
The thickness of greasy dirt film layer 10 is 20-100 nanometers；The membrane material of the oil-stain-preventing film layer 10 includes the mixing of following weight ratio ingredient
Object：Magnesium fluoride 60%-80%；Zirconium oxide 20%-40%.
The step 1）In, the cleaning of substrate 1 is as follows：
A, substrate 1 is cleaned using organic cleaning solvent, and aids in cleaning with ultrasonic wave；
B, the substrate 1 cleaned through step a is cleaned using aqueous cleaning agent, and aids in cleaning with ultrasonic wave；
C, the substrate 1 for handling step b sequentially carries out tap water rinse and distilled water rinsing.
The substrate 1 is molded for macromolecule resin.Macromolecule resin substrate 1 is with resin（A variety of high-molecular compounds
Mixture）The optical mirror slip of synthesis is processed by accurate chemical technology for raw material；Its material advantage has 1, anti-impact force
By force, it is non-friable, anti-impact force be 8-10 kg/cms, 2, translucency it is good, resin lens can be effective by coating film treatment
Injury of the filtering noxious light to human eye；3rd, light weight, weight every square centimeter is at 0.83-1.5 grams；4th, convenient for adding
Work, optical mirror slip and aspherical optical mirror slip such as high index of refraction (1.499-1.74).
In coating process of the present invention, monitored using the full optical spectrum end-point analytical technology of multi-wavelength between 280 nanometers to 760 nanometers
Light wave variation and perspective rate, using quartz crystal monitoring system, utilize the measure of the change of quartz crystal frequency of oscillation, monitoring plating
Membrane material evaporation rate frequency, evaporation rate frequency resolution are 0.01 nanometer per second, 6 rotations of quartz crystal monitoring system
Formula crystal film thickness sensor can improve the precision of coating film thickness, make the trueness error of film thickness between 0.1 nanometer.
The embodiment of the membrane system of 1 outer surface of substrate：
The embodiment of the 3 membrane material component of uvioresistant film layer of 1 outer surface of substrate：
Embodiment 1：Silica 20%, zirconium oxide 80%.
Embodiment 2：Silica 80%, zirconium oxide 20%.
Embodiment 3：Silica 50%, zirconium oxide 50%.
The embodiment of the 4 membrane material component of anti-blue light film layer of 1 outer surface of substrate：
Embodiment 1：Tin oxide 30%；Rubidium 40%；Platinum 40%.
Embodiment 2：Tin oxide 60%, rubidium 10%；Platinum 30%.
Embodiment 3：Tin oxide 55%, rubidium 35%；Platinum 10%.
The embodiment of the optics regulation and control 5 membrane material component of film layer of 1 outer surface of substrate：
Embodiment 1：Aluminium 40%, silica 60%.
Embodiment 2：Aluminium 60%, silica 40%.
Embodiment 3：Aluminium 50%, silica 50%.
The embodiment of the membrane system of 1 inner surface of substrate：
The embodiment of the 8 membrane material component of uvioresistant film layer of 1 inner surface of substrate：
Embodiment 1：Silica 20%, zirconium oxide 80%.
Embodiment 2：Silica 80%, zirconium oxide 20%.
Embodiment 3：Silica 50%, zirconium oxide 50%.
The embodiment of the 9 membrane material component of anti-blue light film layer of 1 inner surface of substrate：
Embodiment 1：Tin oxide 30%；Rubidium 40%；Platinum 40%.
Embodiment 2：Silica 60%, rubidium 10%；Platinum 30%.
Embodiment 3：Silica 55%, rubidium 35%；Platinum 10%.
Claims (3)
1. a kind of oil-stain-preventing lens coating method is included in substrate outer surface and inner surface and membrane system formation oil-stain-preventing is deposited respectively
Optical mirror slip, it is characterised in that：The film plating process specifically includes following steps：
1）Substrate is cleaned；
2）Drying after substrate cleaning：Substrate after cleaning is taken off with isopropanol it is dry, it is de- it is dry after substrate drawn slowly using isopropanol
It is dry, then be placed in dustless plated film constant temperature roaster more than when 60 DEG C~75 DEG C bakings 8 are small；
3）Cleaning again before substrate coating in the vacuum chamber of vacuum evaporation plating machine：Slowly dried substrate is drawn to be placed in isopropanol
In the vacuum chamber of vacuum evaporation plating machine, the vacuum degree in vacuum chamber is adjusted to less than or equal to 9.5 × 10-3Pa starts ion source
Icon bombardment cleaning is carried out to substrate, wherein, temperature is 60~68 DEG C in vacuum chamber, and ion bombardment rate is 180~190a/
Sec, time are 2~5min；
4）The plated film of substrate：The plated film of substrate is included in the outer surface plating membrane system of substrate and plates membrane system in the inner surface of substrate；
A, the outer surface plating membrane system of substrate sequentially include plating shock resistance strengthen film layer, plating uvioresistant film layer, plating anti-blue light film layer,
Plate optics regulation and control film layer, plating oil-stain-preventing film layer；
Film layer is strengthened in A1, plating shock resistance：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3Pa, using electronics
Rifle, after the membrane material of shock resistance reinforcing film layer is evaporated, the membrane material is in the form of nanoscale molecular under the action of ion source
Substrate outer surface is deposited on, shock resistance is formed and strengthens film layer, the thickness that film layer is strengthened in shock resistance is 50-100 nanometers；The anti-impact
It hits and strengthens the membrane material of film layer as silica；
A2, plating uvioresistant film layer：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3Pa, using electron gun
After the membrane material of uvioresistant film layer is evaporated, the membrane material is deposited in the form of nanoscale molecular under the action of ion source
The surface of step A1 moderate resistance shock peening film layers forms uvioresistant film layer, and the thickness of uvioresistant film layer is 10-50 nanometers；
The membrane material of the uvioresistant film layer includes the mixture of following weight ratio ingredient：Silica 20%-80%；Zirconium oxide 20%-80%；
A3, plating anti-blue light film layer：Vacuum degree in vacuum chamber is adjusted to less than or equal to 5.0 × 10-3Pa, will using electron gun
After the membrane material of anti-blue light film layer is evaporated, the membrane material is deposited on step in the form of nanoscale molecular under the action of ion source
The surface of A2 moderate resistance ultraviolet light film layers forms anti-blue light film layer, and the thickness of anti-blue light film layer is 5-20 nanometers；The anti-blue light film
The membrane material of layer includes the mixture of following weight ratio ingredient：Tin oxide 30%-60%；Rubidium 10%-40%；Platinum 10%-40%；
Repeat step A3 at least once more than, form more than the two layers anti-blue light film layer being stacked with；
A4, plating optics regulation and control film layer：After using electron gun, the membrane material of optics regulation and control film layer is evaporated, in the effect of ion source
Under the membrane material surface of anti-blue light film layer in step A3 is deposited in the form of nanoscale molecular, form optics regulation and control film layer, light
The thickness for learning regulation and control film layer is 20-100 nanometers；The membrane material of the optics regulation and control film layer includes the mixing of following weight ratio ingredient
Object：Aluminium 40%-60%；Silica 40%-60%；
A5, plating oil-stain-preventing film layer：After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source
The surface that membrane material is deposited on optics regulation and control film layer in step A4 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing
The thickness of film layer is 5-20 nanometers；The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient：Magnesium fluoride
60%-80%；Zirconium oxide 20%-40%；
Oil-stain-preventing film layer plated film is completed, and after the completion of the outer surface plating membrane system of substrate, is transferred to the inner surface plating membrane system of substrate；
B, the inner surface plating membrane system of substrate sequentially include plating shock resistance strengthen film layer, plating uvioresistant film layer, plating anti-blue light film layer,
Plate oil-stain-preventing film layer；
Film layer is strengthened in B1, plating shock resistance：Using electron gun, after the membrane material of shock resistance reinforcing film layer is evaporated, in ion source
Under the action of the membrane material be deposited on substrate interior surface in the form of nanoscale molecular, form shock resistance and strengthen film layer, shock resistance is strong
The thickness for changing film layer is 50-100 nanometers；The membrane material that film layer is strengthened in the shock resistance is silica；
B2, plating uvioresistant film layer：After using electron gun, the membrane material of uvioresistant film layer is evaporated, in the effect of ion source
Under the membrane material surfaces of step A1 moderate resistance shock peening film layers is deposited in the form of nanoscale molecular, form uvioresistant film
Layer, the thickness of uvioresistant film layer is 10-50 nanometers；The membrane material of the uvioresistant film layer includes the mixed of following weight ratio ingredient
Close object：Silica 20%-80%；Zirconium oxide 20-80%；
Repeat step B2 at least once more than, form more than the two layers uvioresistant film layer being stacked with；
B3, plating anti-blue light film layer：After using electron gun, the membrane material of anti-blue light film layer is evaporated, the institute under the action of ion source
The surface that membrane material is deposited on step B2 moderate resistance ultraviolet light film layers in the form of nanoscale molecular is stated, forms anti-blue light film layer, anti-blue light
The thickness of film layer is 5-20 nanometers；The membrane material of the anti-blue light film layer includes the mixture of following weight ratio ingredient：Tin oxide
30%-60%；Rubidium 10%-40%；Platinum 10%-40%；
Repeat step B3 at least once more than, form more than the two layers anti-blue light film layer being stacked with；
B4, plating oil-stain-preventing film layer：After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source
The surface that membrane material is deposited on anti-blue light film layer in step B3 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing film
The thickness of layer is 20-100 nanometers；The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient：Magnesium fluoride
60%-80%；Zirconium oxide 20%-40%.
2. a kind of oil-stain-preventing lens coating method according to claim 1, it is characterised in that：The step 1）In, to base
The cleaning of piece is as follows：
A, substrate is cleaned using organic cleaning solvent, and aids in cleaning with ultrasonic wave；
B, the substrate cleaned through step a is cleaned using aqueous cleaning agent, and aids in cleaning with ultrasonic wave；
C, the substrate for handling step b sequentially carries out tap water rinse and distilled water rinsing.
3. a kind of oil-stain-preventing lens coating method according to claim 1, it is characterised in that：The substrate is high score subtree
Fat is molded.
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| CN201711354745.8A CN108048804A (en) | 2017-12-15 | 2017-12-15 | A kind of oil-stain-preventing lens coating method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111929922A (en) * | 2020-07-02 | 2020-11-13 | 滁州优立光学眼镜有限公司 | Manufacturing method of spectacle lens capable of preventing blue light |
| CN114573246A (en) * | 2022-03-05 | 2022-06-03 | 安徽方兴光电新材料科技有限公司 | Double-sided laser-etchable conductive glass and preparation method thereof |
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| CN103969725A (en) * | 2014-05-30 | 2014-08-06 | 奥特路（漳州）光学科技有限公司 | Special antiglare optical lens for driver and production method thereof |
| CN103984120A (en) * | 2014-05-30 | 2014-08-13 | 奥特路（漳州）光学科技有限公司 | Method for manufacturing blue light-resistant optical lens |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103969725A (en) * | 2014-05-30 | 2014-08-06 | 奥特路（漳州）光学科技有限公司 | Special antiglare optical lens for driver and production method thereof |
| CN103984120A (en) * | 2014-05-30 | 2014-08-13 | 奥特路（漳州）光学科技有限公司 | Method for manufacturing blue light-resistant optical lens |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111929922A (en) * | 2020-07-02 | 2020-11-13 | 滁州优立光学眼镜有限公司 | Manufacturing method of spectacle lens capable of preventing blue light |
| CN114573246A (en) * | 2022-03-05 | 2022-06-03 | 安徽方兴光电新材料科技有限公司 | Double-sided laser-etchable conductive glass and preparation method thereof |
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Application publication date: 20180518 |