CN103969725B - The anti glare anti static coatings optical mirror slip that a kind of driver is special and manufacture method thereof - Google Patents

The anti glare anti static coatings optical mirror slip that a kind of driver is special and manufacture method thereof Download PDF

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Publication number
CN103969725B
CN103969725B CN201410238673.0A CN201410238673A CN103969725B CN 103969725 B CN103969725 B CN 103969725B CN 201410238673 A CN201410238673 A CN 201410238673A CN 103969725 B CN103969725 B CN 103969725B
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rete
substrate
film material
static coatings
uvioresistant
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CN103969725A (en
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吴晓彤
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Ott Road (zhangzhou) Optical Technology Co Ltd
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Ott Road (zhangzhou) Optical Technology Co Ltd
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Priority to CN201410238673.0A priority Critical patent/CN103969725B/en
Publication of CN103969725A publication Critical patent/CN103969725A/en
Priority to PCT/CN2014/094294 priority patent/WO2015180455A1/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/10Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses

Abstract

The invention discloses the special anti glare anti static coatings optical mirror slip of a kind of driver and manufacture method thereof, this kind of eyeglass is all coated with multilayer film at the outside surface of substrate and inside surface, this anti glare anti static coatings optical mirror slip is all coated with the anti glare anti static coatings film of more than one deck at outside surface and inside surface, strengthen the anti glare anti static coatings effect of eyeglass, manufacture method is that manufacture method comprises the following steps: 1) clean substrate at substrate outside surface and inside surface vapor-deposited film system formation anti glare anti static coatings optical mirror slip respectively; 2) drying after substrate cleaning: the cleaning again 3) before substrate coating in the vacuum chamber of electron beam evaporation plating machine: the 4) plated film of substrate: the plated film of substrate is included in the outside surface plated film system of substrate and the inside surface plated film system at substrate.The special anti glare anti static coatings optical mirror slip of the produced driver of the present invention has and prevents harmful glare and ultraviolet to the injury of human body, make driver safer, the special anti glare anti static coatings optical mirror slip of this driver also has oil-stain-preventing and the function from main optical regulation and control simultaneously.

Description

The anti glare anti static coatings optical mirror slip that a kind of driver is special and manufacture method thereof
Technical field
The present invention relates to the special anti glare anti static coatings optical mirror slip of a kind of driver and manufacture method thereof.
Background technology
Along with the change of modern life form, our every days of the long-time stimulation in the face of high light, as dazzle light, computer, TV, mobile phone, LED, outdoors sunlight etc.Hardly realize that these high light wavelength are short, energy is high, easily cause dry and astringent, early onset cataract, the spontaneous macular diseases such as photophobia, fatigue on ocular vision.High light is present in, and (280-780 nanometer) accounts for 50 ~ 60% of visible ray, and dazzle light light wherein annoyings daily life always, particularly on road surface, run into dazzle light high light when you open vehicle travels evening, this time, your vision can be subject to serious impact, sight line occurs that blind area is easy to cause hidden trouble of traffic like this, particularly highway is subject to the pincer attack of front and back dazzle light high light, be easy to like this cause traffic hazard, the high light sent when the other side's dazzle light shines the eyes of driver, dazzle can be produced, make moment at the moment as dark as a stack of black cats.Found by Qiao Kesile effect study: the impact of dazzle, the reaction time of driver can be made to increase by 1.4 seconds.When automobile travels with hundred kilometers of speed per hours, braking distance can be made to add nearly one times.This, concerning driving night, is breakneck.Driving at night, concerning being not easy, particularly new hand many drivers.Some drivers care only for oneself, and car is front to become clear, abuse high beam.More headachyly be, driver's driving at night of some myopia is responsive especially for light, the high light sent when the other side's dazzle light shines the eyes of driver, can produce dazzle, make to occur blind area instantaneously at the moment, the traffic lights recognition capability at night of crossroad is very poor, the numeral of traffic lights countdown clearly cannot be offered a clear explanation, particularly have myopia to add the driver of astigmatism more serious; This, concerning driving night, is breakneck; But we can select the optical frames eyeglass of one pair of professional driver's anti glare anti static coatings to make visual effect light, clear, and resolution improves, and is the safety many parts insurance of people, many one visions of the high light run in work are protected.The optical mirror slip universal functionality of selling in the market is single, and main is exactly for correcting defects of vision without anti glare anti static coatings and ultraviolet function, is not also applicable to general population's anti glare anti static coatings and ultraviolet plano lens and optical mirror slip.
Summary of the invention
The anti glare anti static coatings optical mirror slip that the object of the present invention is to provide a kind of driver special and manufacture method thereof, the special anti glare anti static coatings optical mirror slip of the produced driver of the method has and prevents harmful glare and ultraviolet to the injury of human body, and the special anti glare anti static coatings optical mirror slip of this driver also has oil-stain-preventing and the function from main optical regulation and control simultaneously.
For achieving the above object, the present invention is by the following technical solutions:
The anti glare anti static coatings optical mirror slip that a kind of driver is special, it comprises substrate, the outside surface of described substrate and inside surface are equipped with film system, the film system of described substrate outside surface sequentially comprises shock resistance strengthening rete, uvioresistant rete, anti-blue light rete, anti glare anti static coatings rete, optics regulation and control rete and oil pollution prevention protection film layer from the inside to surface, and the anti glare anti static coatings rete on described substrate outside surface is at least more than one deck; The film system of described substrate interior surface sequentially comprises shock resistance strengthening rete, uvioresistant rete, anti-blue light rete, anti glare anti static coatings rete and oil pollution prevention protection film layer from the inside to surface, and the anti glare anti static coatings rete on described substrate interior surface and uvioresistant rete are all at least more than one deck.
Described substrate is shaping by macromolecule resin.
A manufacture method for the anti glare anti static coatings optical mirror slip that driver as claimed in claim 1 is special, described manufacture method specifically comprises the following steps:
1) substrate is cleaned;
2) drying after substrate cleaning: the substrate after cleaning is de-dry with isopropyl alcohol, de-dry after substrate adopt isopropyl alcohol to draw drying slowly;
3) cleaning again before substrate coating in the vacuum chamber of electron beam evaporation plating machine: drawn by isopropyl alcohol dried substrate to be placed in the vacuum chamber of electron beam evaporation plating machine slowly, the vacuum tightness in vacuum chamber is adjusted to and is less than or equal to 9.5 × 10 -3handkerchief, starts ion gun and cleans substrate;
4) plated film of substrate: the plated film of substrate is included in the outside surface plated film system of substrate and the inside surface plated film system at substrate;
The outside surface plated film A1 of A, substrate, plating shock resistance strengthening rete: the vacuum tightness in vacuum chamber is adjusted to and is less than or equal to 2.0 × 10 -3handkerchief, adopts electron gun, and after film material shock resistance being strengthened rete evaporates, under ionogenic effect, described film material is deposited on substrate outside surface with nanoscale molecular form, forms shock resistance strengthening rete, and the thickness of shock resistance strengthening rete is 0.1-600 nanometer; The film material of described shock resistance strengthening rete is monox;
A2, plating uvioresistant rete: after adopting electron gun to be evaporated by the film material of uvioresistant rete, under ionogenic effect, described film material is deposited on the surface of shock resistance strengthening rete in steps A 1 with nanoscale molecular form, form uvioresistant rete, the thickness of uvioresistant rete is 0.1-600 nanometer; The film material of described uvioresistant rete comprises the potpourri of the component of following percentage by weight: monox 20%-80%; Zirconia 20%-80%;
A3, plating anti-blue light rete: after adopting electron gun to be evaporated by the film material of anti-blue light rete, under ionogenic effect, described film material is deposited on the surface of uvioresistant rete in steps A 2 with nanoscale molecular form, form anti-blue light rete, the thickness of anti-blue light rete is 0.1-600 nanometer; The film material of described anti-blue light rete comprises the potpourri of the component of following percentage by weight: tin oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%.
A4, plating anti glare anti static coatings rete: after adopting electron gun to be evaporated by the film material of anti glare anti static coatings rete, under ionogenic effect, described film material is deposited on the surface of anti-blue light rete in steps A 3 with nanoscale molecular form, form anti glare anti static coatings rete, the thickness of anti glare anti static coatings rete is 0.1-600 nanometer; The film material of described anti glare anti static coatings rete comprises the potpourri of the component of following percentage by weight: tin indium oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%; Dysprosium 10%-20%.
Repeat steps A 4 at least one times more than, form two-layer above mutually stacking anti glare anti static coatings rete;
A5, light-plated regulation and control rete: after the film material adopting electron gun optics to be regulated and controled rete evaporates, under ionogenic effect, described film material is deposited on the surface of anti glare anti static coatings rete in steps A 4 with nanoscale molecular form, form optics regulation and control rete, the thickness of optics regulation and control rete is 0.1-600 nanometer; The film material of described optics regulation and control rete comprises the potpourri of the component of following percentage by weight: aluminium 40%-60%; Monox 40%-60%;
A6, plating oil-stain-preventing rete: after adopting electron gun to be evaporated by the film material of oil-stain-preventing rete, under ionogenic effect, described film material is deposited on the surface of optics regulation and control rete in steps A 5 with nanoscale molecular form, form oil-stain-preventing rete, the thickness of oil-stain-preventing rete is 0.1-600 nanometer; The film material of described oil-stain-preventing rete comprises the potpourri of the component of following percentage by weight: magnesium fluoride 60%-80%; Zirconia 20%-40%;
Oil-stain-preventing rete plated film completes, and after the outside surface plated film system of substrate completes, proceeds to the inside surface plated film system of substrate;
The inside surface plated film of B, substrate;
B1, plating shock resistance strengthening rete: adopt electron gun, after film material shock resistance being strengthened rete evaporates, under ionogenic effect, described film material is deposited on substrate interior surface surface with nanoscale molecular form, form shock resistance strengthening rete, the thickness of shock resistance strengthening rete is 0.1-600 nanometer; The film material of described shock resistance strengthening rete is monox;
B2, plating uvioresistant rete: after adopting electron gun to be evaporated by the film material of uvioresistant rete, under ionogenic effect, described film material is deposited on the surface of shock resistance strengthening rete in step B1 with nanoscale molecular form, form uvioresistant rete, the thickness of uvioresistant rete is 0.1-600 nanometer; The film material of described uvioresistant rete comprises the potpourri of the component of following percentage by weight: monox 20%-80%; Zirconia 20-80%;
Repeat step B2 at least one times more than, form two-layer above mutually stacking uvioresistant rete;
B3, plating anti-blue light rete: after adopting electron gun to be evaporated by the film material of anti-blue light rete, under ionogenic effect, described film material is deposited on the surface of uvioresistant rete in step B2 with nanoscale molecular form, form anti-blue light rete, the thickness of anti-blue light rete is 0.1-600 nanometer; The film material of described anti-blue light rete comprises the potpourri of the component of following percentage by weight: tin oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%;
B4, plating anti glare anti static coatings rete: after adopting electron gun to be evaporated by the film material of anti glare anti static coatings rete, under ionogenic effect, described film material is deposited on the surface of anti-blue light rete in step B3 with nanoscale molecular form, form anti glare anti static coatings rete, the thickness of anti glare anti static coatings rete is 0.1-600 nanometer; The film material of described anti glare anti static coatings rete comprises the potpourri of the component of following percentage by weight: tin indium oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%; Dysprosium 10%-20%.
Repeat step B4 at least one times more than, form two-layer above mutually stacking anti glare anti static coatings rete;
B5, plating oil-stain-preventing rete: after adopting electron gun to be evaporated by the film material of oil-stain-preventing rete, under ionogenic effect, described film material is deposited on the surface of anti glare anti static coatings rete in step B4 with nanoscale molecular form, form oil-stain-preventing rete, the thickness of oil-stain-preventing rete is 0.1-600 nanometer; The film material of described oil-stain-preventing rete comprises the potpourri of the component of following percentage by weight: magnesium fluoride 60%-80%; Zirconia 20%-40%.
In described step 1), to the cleaning tool body method of substrate be: a, employing organic cleaning solvent clean substrate, and clean with ultrasonic assistant;
B, employing aqueous cleaning agent clean the substrate through step a process, and clean with ultrasonic assistant;
C, sequentially carry out tap water rinse and distilled water rinsing through the substrate of step b process.
Macromolecule resin eyeglass is for raw material carries out processing the optical mirror slip synthesized through accurate chemical technology with resin (potpourri of multiple macromolecular compound); Its material advantage has: 1, anti-impact force is strong, and non-friable, anti-impact force is 8-10 kg/cm; 2, light transmission is good, resin lens through coating film treatment can effective filtering noxious light to the injury of human eye; 3, quality is light, and the weight of every square centimeter is at 0.83-1.5 gram; 4, be convenient to processing, the optical mirror slip of high index of refraction (1.499-1.74) and aspheric optical mirror slip can be processed.
The effect of the shock resistance strengthening rete of substrate outside surface and inside surface: the impact resistance of eyeglass 1, can be made to improve, eyeglass is not easy fragmentation and avoids injuring eyes; 2, improve the adhesion of eyeglass, fine cohesive action can be had to make to be not easy delamination between rete as the medium of the lower skim layer of plating.
The effect of the uvioresistant rete of substrate outside surface and inside surface: corrosion-resistant, anti-oxidant, shielding of ultraviolet.
The effect of the anti-blue light rete of substrate outside surface and inside surface: the blue light absorption rate being 380-500nm for wavelength reaches more than 33%; and various harmful ray; make the visual field more clear bright, and can also available protecting eyes, extenuate visual fatigue.
The effect of substrate outside surface optics regulation and control rete: the principle which utilizes zoom camera camera lens, in rather dark or that light is too strong environment, optics regulation and control rete has certain regulating and controlling from main optical, plays the effect of photo-equilibrium, user is conformed sooner; For a long time depending on overtaxing one's nerves, for a long time facing to computer, LCD screen, eyes there will be visual fatigue phenomenons such as aching, dry and astringent, eye is swollen, shed tears, can alleviate visual fatigue by the process of optics regulation and control film.
The effect of the oil-stain-preventing rete of substrate outside surface and inside surface: the rete plating substrate surface covers by oil-stain-preventing rete, and can reduce with the contact area of oil with eyeglass by Jiang Shui, make oil and water droplet not easily adhere to lens surface.
The anti glare anti static coatings rete of substrate outside surface and inside surface is that multiple compound substance coordinates the rete (platinum rete) forming exclusive white clear can unique effective ultraviolet ray filtering; High light between 400-500 nanometer filters and makes vision light, and then alleviates visual fatigue thus can enter desirable visual state.
The present invention adopts the principle of electron beam vacuum evaporation, there is after utilizing charged particle to accelerate in the electric field the feature of certain kinetic energy, ion is guided into the electrode for being made by the substrate of plated film, and by electron gun with high temperature bombardment by high purity metal oxide component, the nano molecular be evaporated makes it move to substrate along certain direction and the final method in deposition on substrate film forming.This invention combine with technique utilizes the trajectory of electron motion in the special distributed controll electric field in magnetic field, improves the technique of plated film with this, make coating film thickness and homogeneity controlled, and good, the cohesive force of rete compactness of preparation is strong and high purity.
The present invention is coated with antiultraviolet and harmful glare to the rete of eye injury on optical mirror slip, therefore people are when use LED lamplight, computer, mobile phone, TV and micro-wave oven etc., use this optical mirror slip to correcting defects of vision and not needing the people corrected defects of vision can play effectively, preventing when using these electrical equipment harmful blue light that produces and ultraviolet to the radiation of people's eye and brain all sidedly, guarantee health and delay eyesight to deepen, and still keep the number of degrees of existing optical mirror slip correct vision and delay the increase of the number of degrees, make visual effect more clear.In addition, the rete (platinum rete) that rete of the present invention and coordinating between rete finally form a kind of white clear on optical mirror slip, the optical mirror slip rete occurred in the market mostly is blue film or partial veil, namely eyeglass background color band blue light and green glow, blue film or partial veil are attached on optical mirror slip because there being the background color of blue light or green glow in the face of screen and light emitting source body, the authenticity of vision can be obscured like this, the same halation that also there will be blueness or green facing to light, rete (platinum rete) optical mirror slip of white clear can make up the weak point of (blue film and partial veil) optical mirror slip visual effect, can the optical mirror slip of filtering noxious high light be blank product in the market again, eyeglass of the present invention effectively can filter the most of harmful glare in light, by effectively visual fatigue can be alleviated to the filtration of harmful glare, and transmittance keeps more than 79%, the sharpness of vision good when can keep driver and authenticity, ensure that security.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is described in further details:
Fig. 1 is exploded view of the present invention.
Embodiment
As shown in Figure 1, the anti glare anti static coatings optical mirror slip that a kind of driver is special, it comprises substrate 1, the outside surface of described substrate and inside surface are equipped with film system, the film system of described substrate 1 outside surface sequentially comprises shock resistance strengthening rete 2, uvioresistant rete 3, anti-blue light rete 4, anti glare anti static coatings rete 5, optics regulation and control rete 6 and oil pollution prevention protection film layer 7 from the inside to surface, and the anti glare anti static coatings rete 5 on described substrate 1 outside surface is at least more than one deck; The film system of described substrate 1 inside surface sequentially comprises shock resistance strengthening rete 8, uvioresistant rete 9, anti-blue light rete 10, anti glare anti static coatings rete 11 and oil pollution prevention protection film layer 12 from the inside to surface, and the anti glare anti static coatings rete 11 on described substrate 1 inside surface and uvioresistant rete 9 are all at least more than one deck.
Described substrate 1 is shaping by macromolecule resin.
A manufacture method for the anti glare anti static coatings optical mirror slip that driver as claimed in claim 1 is special, described manufacture method specifically comprises the following steps:
1) substrate 1 is cleaned;
2) drying after substrate 1 cleaning: the substrate 1 after cleaning is de-dry with isopropyl alcohol, the substrate 1 taken off after doing adopts isopropyl alcohol to draw drying slowly;
3) cleaning again before substrate 1 plated film in the vacuum chamber of electron beam evaporation plating machine: drawn by isopropyl alcohol dried substrate 1 to be placed in the vacuum chamber of electron beam evaporation plating machine slowly, the vacuum tightness in vacuum chamber is adjusted to and is less than or equal to 9.5 × 10 -3handkerchief, starts ion gun and cleans substrate 1;
4) plated film of substrate 1: the plated film of substrate 1 is included in the outside surface plated film system of substrate 1 and the inside surface plated film system at substrate 1;
The outside surface plated film of A, substrate 1
A1, plating shock resistance strengthening rete 2: the vacuum tightness in vacuum chamber is adjusted to and is less than or equal to 2.0 × 10 -3handkerchief, adopt electron gun, after film material shock resistance being strengthened rete 2 evaporates, under ionogenic effect, described film material is deposited on substrate 1 outside surface with nanoscale molecular form, form shock resistance strengthening rete 2, the thickness of shock resistance strengthening rete 2 is 0.1-600 nanometer; The film material of described shock resistance strengthening rete 2 is monox;
A2, plating uvioresistant rete 3: after adopting electron gun to be evaporated by the film material of uvioresistant rete 3, under ionogenic effect, described film material is deposited on the surface of shock resistance strengthening rete 2 in steps A 1 with nanoscale molecular form, form uvioresistant rete 3, the thickness of uvioresistant rete 3 is 0.1-600 nanometer; The film material of described uvioresistant rete 3 comprises the potpourri of the component of following percentage by weight: monox 20%-80%; Zirconia 20%-80%;
A3, plating anti-blue light rete 4: after adopting electron gun to be evaporated by the film material of anti-blue light rete 4, under ionogenic effect, described film material is deposited on the surface of uvioresistant rete 3 in steps A 2 with nanoscale molecular form, form anti-blue light rete 4, the thickness of anti-blue light rete 4 is 0.1-600 nanometer; The film material of described anti-blue light rete 4 comprises the potpourri of the component of following percentage by weight: tin oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%.
A4, plating anti glare anti static coatings rete 5: after adopting electron gun to be evaporated by the film material of anti glare anti static coatings rete 5, under ionogenic effect, described film material is deposited on the surface of anti-blue light rete 4 in steps A 3 with nanoscale molecular form, form anti glare anti static coatings rete 5, the thickness of anti glare anti static coatings rete 5 is 0.1-600 nanometer; The film material of described anti glare anti static coatings rete 5 comprises the potpourri of the component of following percentage by weight: tin indium oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%; Dysprosium 10%-20%.
Repeat steps A 4 at least one times more than, form two-layer above mutually stacking anti glare anti static coatings rete 5;
A5, light-plated regulation and control rete 6: after the film material adopting electron gun optics to be regulated and controled rete 6 evaporates, under ionogenic effect, described film material is deposited on the surface of anti glare anti static coatings rete in steps A 4 with nanoscale molecular form, form optics regulation and control rete 6, the thickness of optics regulation and control rete 6 is 0.1-600 nanometer; The film material of described optics regulation and control rete 6 comprises the potpourri of the component of following percentage by weight: aluminium 40%-60%; Monox 40%-60%;
A6, plating oil-stain-preventing rete 7: after adopting electron gun to be evaporated by the film material of oil-stain-preventing rete 7, under ionogenic effect, described film material is deposited on the surface of optics regulation and control rete 6 in steps A 5 with nanoscale molecular form, form oil-stain-preventing rete 7, the thickness of oil-stain-preventing rete 7 is 0.1-600 nanometer; The film material of described oil-stain-preventing rete 7 comprises the potpourri of the component of following percentage by weight: magnesium fluoride 60%-80%; Zirconia 20%-40%;
Oil-stain-preventing rete 7 plated film completes, and after the outside surface plated film system of substrate 1 completes, proceeds to the inside surface plated film system of substrate 1;
The inside surface plated film of B, substrate 1;
B1, plating shock resistance strengthening rete 8: adopt electron gun, after film material shock resistance being strengthened rete 8 evaporates, under ionogenic effect, described film material is deposited on substrate 1 inside surface surface with nanoscale molecular form, form shock resistance strengthening rete 8, the thickness of shock resistance strengthening rete 8 is 0.1-600 nanometer; The film material of described shock resistance strengthening rete 8 is monox;
B2, plating uvioresistant rete 9: after adopting electron gun to be evaporated by the film material of uvioresistant rete 8, under ionogenic effect, described film material is deposited on the surface of shock resistance strengthening rete 8 in step B1 with nanoscale molecular form, form uvioresistant rete 9, the thickness of uvioresistant rete 9 is 0.1-600 nanometer; The film material of described uvioresistant rete 9 comprises the potpourri of the component of following percentage by weight: monox 20%-80%; Zirconia 20-80%;
Repeat step B2 at least one times more than, form two-layer above mutually stacking uvioresistant rete 9;
B3, plating anti-blue light rete 10: after adopting electron gun to be evaporated by the film material of anti-blue light rete 10, under ionogenic effect, described film material is deposited on the surface of uvioresistant rete 9 in step B2 with nanoscale molecular form, form anti-blue light rete 10, the thickness of anti-blue light rete 10 is 0.1-600 nanometer; The film material of described anti-blue light rete 10 comprises the potpourri of the component of following percentage by weight: tin oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%;
B4, plating anti glare anti static coatings rete 11: after adopting electron gun to be evaporated by the film material of anti glare anti static coatings rete 11, under ionogenic effect, described film material is deposited on the surface of anti-blue light rete 11 in step B3 with nanoscale molecular form, form anti glare anti static coatings rete 11, the thickness of anti glare anti static coatings rete 11 is 0.1-600 nanometer; The film material of described anti glare anti static coatings rete 11 comprises the potpourri of the component of following percentage by weight: tin indium oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%; Dysprosium 10%-20%.
Repeat step B4 at least one times more than, form two-layer above mutually stacking anti glare anti static coatings rete 11;
B5, plating oil-stain-preventing rete 12: after adopting electron gun to be evaporated by the film material of oil-stain-preventing rete 12, under ionogenic effect, described film material is deposited on the surface of anti glare anti static coatings rete 11 in step B4 with nanoscale molecular form, form oil-stain-preventing rete 12, the thickness of oil-stain-preventing rete 12 is 0.1-600 nanometer; The film material of described oil-stain-preventing rete 12 comprises the potpourri of the component of following percentage by weight: magnesium fluoride 60%-80%; Zirconia 20%-40%.
In described step 1), to the cleaning tool body method of substrate 1 be:
A, employing organic cleaning solvent clean substrate 1, and clean with ultrasonic assistant;
B, employing aqueous cleaning agent clean the substrate 1 through step a process, and clean with ultrasonic assistant;
C, sequentially carry out tap water rinse and distilled water rinsing through the substrate 1 of step b process.
In coating process of the present invention, the light wave adopting the full optical spectrum end-point analytical technology of multi-wavelength to monitor between 280 nanometer to 760 nanometers changes and perspective rate, adopt quartz crystal monitoring system, utilize the measure of the change of quartz crystal oscillation frequency, monitoring Coating Materials velocity of evaporation frequency, velocity of evaporation frequency resolution is 0.01 nanometer per second, the brilliant film thickness sensor of 6 Rotary Water of quartz crystal monitoring system, can improve the precision of coating film thickness, make the trueness error of thickness between 0.1 nanometer.
The embodiment of the film system of substrate 1 outside surface:
The embodiment of uvioresistant rete 3 component of substrate 1 outside surface:
Embodiment 1: monox 20%, zirconia 80%.
Embodiment 2: monox 80%, zirconia 20%.
Embodiment 3: monox 50%, zirconia 50%.
The embodiment of anti-blue light rete 4 component of substrate 1 outside surface:
Embodiment 1: tin oxide 30%; Rubidium 40%; Platinum 40%.
Embodiment 2: tin oxide 60%, rubidium 10%; Platinum 30%.
Embodiment 3: tin oxide 55%, rubidium 35%; Platinum 10%.
The embodiment of anti glare anti static coatings rete 5 component of substrate 1 outside surface:
Embodiment 1: tin indium oxide 30%; Rubidium 40%; Platinum 10%; Dysprosium 20%.
Embodiment 2: tin indium oxide 60%; Rubidium 10%; Platinum 40%; Dysprosium 10%.
Embodiment 3: tin indium oxide 50%; Rubidium 30%; Platinum 25%; Dysprosium 15%.
The embodiment of optics regulation and control rete 6 component of substrate 1 outside surface:
Embodiment 1: aluminium 40%, monox 60%.
Embodiment 2: aluminium 60%, monox 40%.
Embodiment 3: aluminium 50%, monox 50%.
The embodiment of oil-stain-preventing rete 7 component of substrate 1 outside surface:
Embodiment 1: magnesium fluoride 40%, zirconia 60%.
Embodiment 2: magnesium fluoride 60%, zirconia 40%.
Embodiment 3: magnesium fluoride 50%, zirconia 50%.
The embodiment of the film system of substrate 1 inside surface:
The embodiment of uvioresistant rete 9 component of described substrate 1 inside surface:
Embodiment 1: monox 20%, zirconia 80%.
Embodiment 2: monox 80%, zirconia 20%.
Embodiment 3: monox 50%, zirconia 50%.
The embodiment of anti-blue light rete 10 component of substrate 1 inside surface:
Embodiment 1: tin oxide 30%; Rubidium 40%; Platinum 40%.
Embodiment 2: monox 60%, rubidium 10%; Platinum 30%.
Embodiment 3: monox 55%, rubidium 35%; Platinum 10%.
The embodiment of anti glare anti static coatings rete 11 component of substrate 1 inside surface:
Embodiment 1: tin indium oxide 30%; Rubidium 40%; Platinum 10%; Dysprosium 20%.
Embodiment 2: tin indium oxide 60%; Rubidium 10%; Platinum 40%; Dysprosium 10%.
Embodiment 3: tin indium oxide 50%; Rubidium 30%; Platinum 25%; Dysprosium 15%.
The embodiment of oil-stain-preventing rete 12 component of substrate 1 inside surface:
Embodiment 1: magnesium fluoride 40%, zirconia 60%.
Embodiment 2: magnesium fluoride 60%, zirconia 40%.
Embodiment 3: magnesium fluoride 50%, zirconia 50%.

Claims (3)

1. the manufacture method of the anti glare anti static coatings optical mirror slip that a driver is special, anti glare anti static coatings optical mirror slip comprises substrate, the outside surface of described substrate and inside surface are equipped with film system, the film system of described substrate outside surface sequentially comprises shock resistance strengthening rete, uvioresistant rete, anti-blue light rete, anti glare anti static coatings rete, optics regulation and control rete and oil pollution prevention protection film layer from the inside to surface, and the anti glare anti static coatings rete on described substrate outside surface is at least more than one deck; The film system of described substrate interior surface sequentially comprises shock resistance strengthening rete, uvioresistant rete, anti-blue light rete, anti glare anti static coatings rete and oil pollution prevention protection film layer from the inside to surface, and the anti glare anti static coatings rete on described substrate interior surface and uvioresistant rete are all at least more than one deck; It is characterized in that: described manufacture method specifically comprises the following steps:
1) substrate is cleaned;
2) drying after substrate cleaning: the substrate after cleaning is de-dry with isopropyl alcohol, de-dry after substrate adopt isopropyl alcohol to draw drying slowly;
3) cleaning again before substrate coating in the vacuum chamber of electron beam evaporation plating machine: drawn by isopropyl alcohol dried substrate to be placed in the vacuum chamber of electron beam evaporation plating machine slowly, the vacuum tightness in vacuum chamber is adjusted to and is less than or equal to 9.5 × 10 -3handkerchief, starts ion gun and cleans substrate;
4) plated film of substrate: the plated film of substrate is included in the outside surface plated film system of substrate and the inside surface plated film system at substrate;
The outside surface plated film A1 of A, substrate, plating shock resistance strengthening rete: the vacuum tightness in vacuum chamber is adjusted to and is less than or equal to 2.0 × 10 -3handkerchief, adopts electron gun, and after film material shock resistance being strengthened rete evaporates, under ionogenic effect, described film material is deposited on substrate outside surface with nanoscale molecular form, forms shock resistance strengthening rete, and the thickness of shock resistance strengthening rete is 0.1-600 nanometer; The film material of described shock resistance strengthening rete is monox;
A2, plating uvioresistant rete: after adopting electron gun to be evaporated by the film material of uvioresistant rete, under ionogenic effect, described film material is deposited on the surface of shock resistance strengthening rete in steps A 1 with nanoscale molecular form, form uvioresistant rete, the thickness of uvioresistant rete is 0.1-600 nanometer; The film material of described uvioresistant rete comprises the potpourri of the component of following percentage by weight: monox 20%-80%; Zirconia 20%-80%;
A3, plating anti-blue light rete: after adopting electron gun to be evaporated by the film material of anti-blue light rete, under ionogenic effect, described film material is deposited on the surface of uvioresistant rete in steps A 2 with nanoscale molecular form, form anti-blue light rete, the thickness of anti-blue light rete is 0.1-600 nanometer; The film material of described anti-blue light rete comprises the potpourri of the component of following percentage by weight: tin oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%;
A4, plating anti glare anti static coatings rete: after adopting electron gun to be evaporated by the film material of anti glare anti static coatings rete, under ionogenic effect, described film material is deposited on the surface of anti-blue light rete in steps A 3 with nanoscale molecular form, form anti glare anti static coatings rete, the thickness of anti glare anti static coatings rete is 0.1-600 nanometer; The film material of described anti glare anti static coatings rete comprises the potpourri of the component of following percentage by weight: tin indium oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%; Dysprosium 10%-20%;
Repeat steps A 4 at least one times more than, form two-layer above mutually stacking anti glare anti static coatings rete;
A5, light-plated regulation and control rete: after the film material adopting electron gun optics to be regulated and controled rete evaporates, under ionogenic effect, described film material is deposited on the surface of anti glare anti static coatings rete in steps A 4 with nanoscale molecular form, form optics regulation and control rete, the thickness of optics regulation and control rete is 0.1-600 nanometer; The film material of described optics regulation and control rete comprises the potpourri of the component of following percentage by weight: aluminium 40%-60%; Monox 40%-60%;
A6, plating oil-stain-preventing rete: after adopting electron gun to be evaporated by the film material of oil-stain-preventing rete, under ionogenic effect, described film material is deposited on the surface of optics regulation and control rete in steps A 5 with nanoscale molecular form, form oil-stain-preventing rete, the thickness of oil-stain-preventing rete is 0.1-600 nanometer; The film material of described oil-stain-preventing rete comprises the potpourri of the component of following percentage by weight: magnesium fluoride 60%-80%; Zirconia 20%-40%;
Oil-stain-preventing rete plated film completes, and after the outside surface plated film system of substrate completes, proceeds to the inside surface plated film system of substrate;
The inside surface plated film of B, substrate;
B1, plating shock resistance strengthening rete: adopt electron gun, after film material shock resistance being strengthened rete evaporates, under ionogenic effect, described film material is deposited on substrate interior surface surface with nanoscale molecular form, form shock resistance strengthening rete, the thickness of shock resistance strengthening rete is 0.1-600 nanometer; The film material of described shock resistance strengthening rete is monox;
B2, plating uvioresistant rete: after adopting electron gun to be evaporated by the film material of uvioresistant rete, under ionogenic effect, described film material is deposited on the surface of shock resistance strengthening rete in step B1 with nanoscale molecular form, form uvioresistant rete, the thickness of uvioresistant rete is 0.1-600 nanometer; The film material of described uvioresistant rete comprises the potpourri of the component of following percentage by weight: monox 20%-80%; Zirconia 20-80%;
Repeat step B2 at least one times more than, form two-layer above mutually stacking uvioresistant rete;
B3, plating anti-blue light rete: after adopting electron gun to be evaporated by the film material of anti-blue light rete, under ionogenic effect, described film material is deposited on the surface of uvioresistant rete in step B2 with nanoscale molecular form, form anti-blue light rete, the thickness of anti-blue light rete is 0.1-600 nanometer; The film material of described anti-blue light rete comprises the potpourri of the component of following percentage by weight: tin oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%;
B4, plating anti glare anti static coatings rete: after adopting electron gun to be evaporated by the film material of anti glare anti static coatings rete, under ionogenic effect, described film material is deposited on the surface of anti-blue light rete in step B3 with nanoscale molecular form, form anti glare anti static coatings rete, the thickness of anti glare anti static coatings rete is 0.1-600 nanometer; The film material of described anti glare anti static coatings rete comprises the potpourri of the component of following percentage by weight: tin indium oxide 30%-60%; Rubidium 10%-40%; Platinum 10%-40%; Dysprosium 10%-20%;
Repeat step B4 at least one times more than, form two-layer above mutually stacking anti glare anti static coatings rete;
B5, plating oil-stain-preventing rete: after adopting electron gun to be evaporated by the film material of oil-stain-preventing rete, under ionogenic effect, described film material is deposited on the surface of anti glare anti static coatings rete in step B4 with nanoscale molecular form, form oil-stain-preventing rete, the thickness of oil-stain-preventing rete is 0.1-600 nanometer; The film material of described oil-stain-preventing rete comprises the potpourri of the component of following percentage by weight: magnesium fluoride 60%-80%; Zirconia 20%-40%.
2. the manufacture method of the anti glare anti static coatings optical mirror slip that a kind of driver according to claim 1 is special, is characterized in that: described substrate is shaping by macromolecule resin.
3. the manufacture method of the anti glare anti static coatings optical mirror slip that a kind of driver according to claim 1 is special, is characterized in that: in described step 1), to the cleaning tool body method of substrate is:
A, employing organic cleaning solvent clean substrate, and clean with ultrasonic assistant;
B, employing aqueous cleaning agent clean the substrate through step a process, and clean with ultrasonic assistant;
C, sequentially carry out tap water rinse and distilled water rinsing through the substrate of step b process.
CN201410238673.0A 2014-05-30 2014-05-30 The anti glare anti static coatings optical mirror slip that a kind of driver is special and manufacture method thereof Active CN103969725B (en)

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PCT/CN2014/094294 WO2015180455A1 (en) 2014-05-30 2014-12-19 Anti-glare optical lens dedicated for driver and manufacturing method therefor

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