CN107397074A - Improve the microelement pre-mix material for later stage eggshell quality of laying eggs - Google Patents

Improve the microelement pre-mix material for later stage eggshell quality of laying eggs Download PDF

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Publication number
CN107397074A
CN107397074A CN201710739122.6A CN201710739122A CN107397074A CN 107397074 A CN107397074 A CN 107397074A CN 201710739122 A CN201710739122 A CN 201710739122A CN 107397074 A CN107397074 A CN 107397074A
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ultramicro grinding
eggshell
later stage
sulfate
granularity
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Inventor
王苏宁
孙明明
***
田华壮
张恩宽
孟洋
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Albert Anshan Xingda Mineral Science And Technology Co Ltd
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Albert Anshan Xingda Mineral Science And Technology Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K50/00Feeding-stuffs specially adapted for particular animals
    • A23K50/70Feeding-stuffs specially adapted for particular animals for birds
    • A23K50/75Feeding-stuffs specially adapted for particular animals for birds for poultry
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/30Oligoelements

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Birds (AREA)
  • Animal Husbandry (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Fodder In General (AREA)
  • Feed For Specific Animals (AREA)

Abstract

Improve the microelement pre-mix material for later stage eggshell quality of laying eggs, mainly mixed by ultramicro grinding copper sulphate, ultramicro grinding calcium iodate, ultramicro grinding sodium selenite, ferrous sulfate, zinc sulfate, manganese sulfate, sodium acid carbonate and potassium chloride.Ultramicro grinding copper sulphate, ultramicro grinding calcium iodate and ultramicro grinding sodium selenite granularity are 30~40 μm, and other five kinds of granularities are 150~180 μm.Every kind of micro- content is all synergy and antagonism between the element of consideration on the basis of laying hen nutrition needs are fully met, reasonable compatibility.Material containing three kinds of atomic secondary elements carries out ultramicro grinding, and animal use rate is greatly improved, and reduces laying hen later stage rate of broken eggs, improves the economic benefit of breeding layer chicken industry.

Description

Improve the microelement pre-mix material for later stage eggshell quality of laying eggs
Technical field
The invention belongs to animal feed microelement pre-mix material field, more particularly to improves the micro- of later stage eggshell quality that lay eggs Trace mineral feed.
Background technology
The problem of breakage of egg is one extremely serious in the production of aviculture.With carrying for extensive intensive degree Height, this problem are more prominent.According to foreign countries, the breakage of general egg accounts for the 6~8% of total egg production, it is annual it is Canadian by Laying hen industry is set to suffer 10,000,000 dollars of l loss in broken egg.The annual every laying hen in the U.S. because it is damaged and caused by loss be about 1.38~2.0 dollars.China someone once made to last the sample investigation of half a year, and from egg into consumer's hand, rate of broken eggs is up to LO%, very big economic loss is all brought to consumer and operator.
It is many to influence the factor of eggshell quality, including layer breed, feeding environment, trophic level, age in days of laying eggs etc. are many Aspect.For ovipository cycle, laying hen is optimal in the quality of egg that 33 week old are produced, and is passed with the increase quality at age Subtract.Later stage eggshell quality of laying eggs declines, and eggshell strength declines, and damaged egg increase, causes huge economic loss.
Micro- (Zn, Mn, Cu etc.) has directly influence on eggshell strength, parts of the Mn as enzyme, passes through The glycosyl transferase during mucopolysaccharide is formed is activated, promotes the formation of Aggrecan, and regulates and controls crystal and extends along C axles, is promoted It is correctly grown to regulate and control eggshell crystal structure and eggshell quality.Important components of the Zn as carbonic anhydrase, to providing egg HCO in shell gland3 -Play an important roll.Confactors of the Cu as lysyloxidase, participation lysine metabolism and lysine Conversion, participates in the formation of matrix film, therefore, lacks the distribution that copper can influence eggshell matrix film fiber, so as to cause deformity Egg and abnormal mechanical property.Research shows that Zn, Mn, Cu are adjusted by the formation for influenceing eggshell and the structure for adjusting crystal Save quality of egg.Meanwhile Zn, Cu are added under the conditions of heat stress, internal free radical is can remove, improves the anti-oxidant energy of body Power, so as to improve body health state and improve Egg Quality.Shadow of the present invention according to trace element to later stage eggshell quality of laying eggs Ring, ovipository cycle can be extended by developing one kind, improve the microelement pre-mix material for later stage eggshell quality of laying eggs.
Its technical basis:
Trace element has on eggshell quality directly to be significantly affected.
(1) influence of the manganese (Mn) to eggshell quality.
There is reciprocation between the element such as manganese and calcium, phosphorus, magnesium, zinc, people is particularly subject in terms of eggshell quality is improved Attention.Czech F ri e d in 1985, K. have done experiment of the manganese to eggshell quality, calcic 2.8%, phosphorus 0.46% it is every Add in kg. ration such as 60m g manganese, it will be apparent that improve eggshell quality and egg size, reduce breakage rate.It is many experiment find with The increase eggshell of manganese amount is broken to take the photograph rate decline.High calcium, high phosphorus, using having an impact, have coordinative role to manganese between their threes.Family Fowl nutritionist H o ba r t, R. make overtesting to the manganese compound of different shape, it was demonstrated that the activity of inorganic manganese source is with sulfuric acid Manganese activity is best.
Manganese is that eggshell forms required trace element, and it plays an important role during synthetic protein-mucopolysaccharide (Leach, 1969).Therefore manganese deficiency in feed, egg production and incubation rate reduce, eggshell thinning.Manganese content is down in feed During 7mg/kg, and though in feed calcium, phosphorus content how much, can all cause eggshell quality to decline.NRC (1984) recommends laying hen manganese Requirement is 30mg/kg, and the NRC of version in 1994 is then down to 20mg/kg.When the level of manganese in daily ration brings up to 55~ During 60mg/kg, eggshell quality is optimal.Saly etc. confirms that the laying hen to open the monthly age in postpartum 12 mends manganese, and eggshell is hardened, can significantly carried High eggshell quality, reduce breakage rate.
The acid mucopolysaccharide content of eggshell is largely related to the breaking resistance of eggshell, and manganese is in the conjunction of mucopolysaccharide Played an important role during.When manganese level brings up to 55~60mg/Kg in daily ration, eggshell quality is optimal.Manganese and zinc Be metabolized in vivo it is in close relations, with Gao Meng (100mg/Kg) daily ration feed chicken can prevent egg from rupturing.Poultry is to the requirement of manganese than feeding Newborn animal is high, and this is due to that poultry is relatively low to the utilization rate of manganese, and deposition in vivo is relatively low (being discharged with bile).
(2) influence of the zinc (Zn) to eggshell quality
Zinc is the part of many heavy enzymes, and the activity of kind of enzyme is relevant with zinc at least more than 160.Especially have to metalloenzyme Catalytic, structural and adjusting sexual function, these enzymes mainly include oxidoreducing enzyme (superoxide dismutase), transferase (RNA polymerase), hydrolase (alkaline phosphatase), lyases (carbonic anhydrase) and ligase (tRNA synzyme).Eggshell is in body Carbonic anhydrase is needed in interior calcification process, it is in carbon dioxide and hydrone carbonate synthesis hydrogen radical IONS OF H CO3 -Balanced reaction in Important catalytic action is played, and zinc is one of main component of this enzyme.Laying hen zinc-deficiency, carbonic anhydrase activity reduces, so as to influence Eggshell is formed.Zinc-deficiency is the same with manganese deficiency, eggshell can be made to turn white.When phytic acid or too high calcium content, the absorption of zinc is substantially suppressed, Then eggshell quality is had influence on.It is generally believed that laying hen needs daily ration 50mg/Kg containing zinc just to can guarantee that eggshell quality is normal.Zinc Only it is added to simultaneously in layer dietses just effectively with manganese.
(3) influence of the copper (Cu) to egg quality.
Appropriate Cu is added in feed, aged laying hen eggshell quality can be improved, reduces Abnormal Eggss and rate of broken eggs.Experiment Show that adding copper sulphate makes laying rate and feedstuff-egg ratio all improve.Copper is to maintaining the normal During Pregnancy of animal and breeding potential and hatching egg Incubation rate have an impact, this may be relevant with the generation of red blood cell and the generation of connective tissue.
Copper is the confactor of lysyloxidase, and lysyloxidase can aoxidize collagen and elasticity in egg shell membrane The special acid residue of albumen, collagen and elastin laminin is set to form covalent bond, copper also participates in the shape of stromatin film Into the metabolism of middle lysine, lack the distribution that copper can influence eggshell stromatin film-based fibre, so as to cause lopsided egg.Copper and its Its trace element cooperation, is significantly improved to eggshell quality.
(4) influence of sodium and chlorine to quality of egg.
One of an important factor for Dietary electrolyte balance is influence eggshell quality.During eggshell formation, by daily ration The influence of many factors such as ionic equilibrium and alcium and phosphor metabolization.Excessive chlorine makes the intensity of eggshell and thickness significantly drop in daily ration It is low.The pure city's report in village difficult to understand, adds 250 milligrams of mineral matter sodium chloride, 40 milligrams of potassium chloride, rupture egg, soft-shelled egg increase in drinking-water Double, in drinking-water add salt 200,400,600 g/l, rate of broken eggs increases to 10.4%, 14.2% and from 6.5% 18.9%, it was reported that for laying hen using eggshell strength and thickness as index, the optimal proportion of sodium and chlorine is 1:0.6 (quality).Blood NaHCO3Concentration be proportionate with eggshell quality.NaHCO is added in layer dietses3Improve eggshell quality, main cause is NaHCO3Cause in blood alkali storage to be increased reduces with the concentration of phosphate radical, and the reduction of serium inorganic phosphorus concentration is advantageous to improve eggshell quality. Experiment is confirmed, 0.1~0.5% (quality) NaHCO is added in feed3Salt is substituted, eggshell loss 1%~2% can be reduced.This Outside, Dietary electrolyte balance value can also significantly affect eggshell quality, Vogt etc. (1983) discovery, DEB too low (68mEq/kg) or When too high (296mEq/kg), eggshell thinning.When DEB is in more than 150mEq/kg, shell thickness rises and increased with DEB.Carry High diet potassium content (bringing up to 0.88% (quality) by 0.66%), can improve quality of egg.General laying hen is in suitable for producing In the range of Dietary electrolyte balance value, the normal quality of eggshell can be ensured.
Keep electrolyte balance:For chlorine in acidity in chicken body, high-caliber chlorine is harmful to eggshell.Because high chlorine produces Metabolic acid can suppress carbonic anhydrase, hinder bicarbonate to be changed into carbonate;Suppress the 1- hydroxylases in kidney, harm simultaneously Hinder 25- hydroxyls-vitamine D3 to be changed into active metabolite 1,25-2 hydroxyls-vitamine D3, influence alcium and phosphor metabolization in chicken body.And sodium With potassium in chicken body in alkalescence, can be substituted mutually with 1: 1 mass ratio, with resist sodium containing normal amount, potassium daily ration in excess Influence of the chlorine to eggshell.Research shows, in the normal daily ration of calcium phosphorus content, the equivalent of sodium+potassium-chlorine should at least meet 180mg/ kilograms of electrolyte balance, the salt of 0.1%~0.5% (quality) can be replaced with sodium bicarbonate, it is internal effectively to adjust Acid-base balance, eggshell crack rate is reduced, add sodium bicarbonate, eggshell hardness can be improved.These mineral additives improve eggshell Structure, so as to improve eggshell strength.
In summary, copper sulphate is the cupric feed addictive being widely used at present, and what this area used adds containing copper feed It is cupric sulfate pentahydrate to add agent copper sulphate, and biological value is high, while also has the function that similar antibiotic, and feeding effect is good, easily Absorb, cost is low, is widely used.Zinc sulfate is tested in laying hen and proved, in terms of eggshell strength is improved, is better than other including organic Zinc source including zinc.Diet electrolyte balance can influence zwitterion ratio in blood, so as to influence the egg laying performance of egg fowl.Raise Grain is chloride excessively seriously to reduce chicken feed intake and egg laying performance, be unfavorable for eggshell calcification.
The content of the invention
It is a kind of animal feed it is an object of the invention to provide the microelement pre-mix material for improving later stage eggshell quality of laying eggs Microelement pre-mix material agent.
Experiment proves that the present invention improves the microelement pre-mix material for later stage eggshell quality of laying eggs, and greatly improves micro member The intestinal absorption of element, improves utilization rate, improves performance in layers, especially pole and significantly reduces laying hen later stage broken egg Rate, pole significantly improve the eggshell strength in later stage of laying eggs, and extend the layer breeding cycle, bring tremendous economic to imitate for aquaculture Benefit.
The technical scheme of use is:
Improve the microelement pre-mix material for later stage eggshell quality of laying eggs, mainly by manganese sulfate, ultramicro grinding copper sulphate, sulphur What sour zinc, ferrous sulfate, ultramicro grinding calcium iodate, ultramicro grinding sodium selenite, sodium acid carbonate and potassium chloride mixed.
The formula of the present invention:
The described calcium iodate containing iodine 1% and the sodium selenite containing selenium 1% is the commercially available known product of field of fodder.Institute The part stated is mass parts.
Ultramicro grinding copper sulphate, ultramicro grinding calcium iodate (contain iodine 1%), and ultramicro grinding sodium selenite (containing selenium 1%) can divide Not Cai Yong ball mill be milled to 30-40 μm of granularity.
It the advantage is that:
1, formula is unique.Every kind of micro- content is all on the basis of laying hen nutrition needs are fully met, is considered To the synergy and antagonism between element, reasonable compatibility.Wherein three kinds of materials carry out ultramicro grinding, and animal is greatly improved Utilization rate.
2, elemental copper, iodine, the selenium of denier, ultramicro grinding are made, good fluidity, good dispersion, are well mixed, and feeding is equal It is even.
3, the element utilization rate of laying hen is improved, improves eggshell strength positive effect.The ovipository cycle of laying hen can be extended, dropped Low laying hen later stage rate of broken eggs, improve the economic benefit of breeding layer chicken industry.
4, using inorganic microelement, calculated meticulously according to the nutritional need of laying hen, reasonable compatibility, copper sulphate, calcium iodate, The raw materials such as sodium selenite carry out ultramicro grinding, nutrient balance, so as to stimulate the hormone secretion of laying hen, strengthen enzyme activity, promote Eggshell is formed.
5, the present invention uniformly mixes this microelement pre-mix material with other feedstuffs using simply, you can.
Embodiment
In following examples:
Control group fed original microelement pre-mix material daily ration.
Test group feeding, which substitutes former microelement pre-mix material in former microelement pre-mix material Diet Formula mean quality, to be added Add as improving in corresponding embodiment the microelement pre-mix material of eggshell quality, new daily ration is made.
Microelement pre-mix material in daily ration accounts for 0.4% (quality).
Embodiment 1
Improve the microelement pre-mix material for later stage eggshell quality of laying eggs, mainly by ultramicro grinding copper sulphate 0.06kg, surpass Calcium iodate 0.08kg of the Crushing of Ultrafine containing iodine 1%, sodium selenite 0.02kg of the ultramicro grinding containing selenium 1%, ferrous sulfate 0.10kg, sulphur Sour zinc 0.14kg, manganese sulfate 0.25kg, sodium acid carbonate 1.0kg and potassium chloride 1.0kg are mixed.
Ultramicro grinding copper sulphate granularity is 30~40 μm, and calcium iodate granularity of the ultramicro grinding containing iodine 1% is 30~40 μm, is surpassed Sodium selenite granularity of the Crushing of Ultrafine containing selenium 1% is 30~40 μm, and ferrous sulfate granularity is 150~180 μm, and zinc sulfate granularity is 150~180 μm, manganese sulfate granularity be 150~180 μm, sodium acid carbonate granularity be 150~180 μm, potassium chloride granularity be 150~ 180μm。
Improve the preparation method of the microelement pre-mix material for later stage eggshell quality of laying eggs:By ultramicro grinding copper sulphate The calcium iodate 0.08kg of 0.06kg, ultramicro grinding containing iodine 1%, sodium selenite 0.02kg, ferrous sulfate of the ultramicro grinding containing selenium 1% 0.10kg, zinc sulfate 0.14kg, manganese sulfate 0.25kg, sodium acid carbonate 1.0kg and potassium chloride 1.0kg mixing, obtain premix.
To prove the feeding effect of the present invention, feeding experiment has been carried out in breeding layer chicken field.The laying hen normally raised is chosen, It is divided into control group and test group, control group fed original microelement pre-mix material daily ration, test group feeds new daily ration, experimental period 37 My god.
The statistical result of animal experiment is shown in Table 1.
Table 1
Embodiment 1 Control group Test group A
Laying hen quantity 1845 1888
Average value (Kg/cm2) 3.883429 4.085962
Statistical number 105 104
Standard deviation 0.8776683 0.9154886
Variance 0.77 0.838
Interpretation of result 100 105.2153136
Animal test results show, feed new daily ration, and test group eggshell strength increases by 5.21% than control group,
Reach the pole level of signifiance.
Embodiment 2
Embodiment 2 is substantially the same manner as Example 1, and its difference is that element formula does following adjustment:
Ultramicro-powder copper sulphate 0.08kg, calcium iodate 0.10kg, ultramicro grinding Asia containing selenium 1% of the ultramicro grinding containing iodine 1% Sodium selenate 0.03kg, ferrous sulfate 0.13kg, zinc sulfate 0.23kg, manganese sulfate 0.30kg, sodium acid carbonate 1.1kg and potassium chloride 1.1kg mix.
Animal experiment:The statistical result of animal experiment is shown in Table 2.
Table 2
Animal test results show that test group eggshell strength reaches the pole level of signifiance than control group increase by 6.31%.
Embodiment 3
Improve the microelement pre-mix material for later stage eggshell quality of laying eggs, mainly by ultramicro grinding copper sulphate 0.13kg, surpass Calcium iodate 0.15kg of the Crushing of Ultrafine containing iodine 1%, sodium selenite 0.03kg of the ultramicro grinding containing selenium 1%, ferrous sulfate 0.15kg, sulphur Sour zinc 0.26kg, manganese sulfate 0.35kg, sodium acid carbonate 1.5kg and potassium chloride 1.20kg are mixed.
Animal experiment
The statistical result of animal experiment is shown in Table 3.
Table 3
Animal test results show that the feeding result of inventive formulation, test group eggshell strength increases than control group
Add 6.61%, reach the pole level of signifiance.

Claims (4)

1. improve the microelement pre-mix material for later stage eggshell quality of laying eggs, mainly by ultramicro grinding copper sulphate 0.06~0.13 Part, 0.08~0.15 part of calcium iodate of the ultramicro grinding containing iodine 1%, 0.02~0.03 part of sodium selenite of the ultramicro grinding containing selenium 1%, 0.10~0.15 part of ferrous sulfate, 0.14~0.26 part of zinc sulfate, 0.25~0.35 part of manganese sulfate, sodium acid carbonate 1.00~1.50 What 1.00~1.20 parts of part and potassium chloride mixed;
Ultramicro grinding copper sulphate granularity is 30~40 μm, and calcium iodate granularity of the ultramicro grinding containing iodine 1% is 30~40 μm, Ultramicro-powder The broken sodium selenite granularity containing selenium 1% be 30~40 μm, ferrous sulfate granularity be 150~180 μm, zinc sulfate granularity be 150~ 180 μm, manganese sulfate granularity is 150~180 μm, and sodium acid carbonate granularity is 150~180 μm, and potassium chloride granularity is 150~180 μm.
The microelement pre-mix material of later stage eggshell quality 2. improvement according to claim 1 is laid eggs, it is characterised in that:Ultra micro Crush 0.06 part of copper sulphate, 0.08 part of calcium iodate of the ultramicro grinding containing iodine 1%, sodium selenite 0.02 of the ultramicro grinding containing selenium 1% Part, 0.10 part of ferrous sulfate, 0.14 part of zinc sulfate, 0.25 part of manganese sulfate, 1.0 parts of sodium acid carbonate and the mixing of 1.0 parts of potassium chloride and Into.
The microelement pre-mix material of later stage eggshell quality 3. improvement according to claim 1 is laid eggs, it is characterised in that:Ultra micro 0.08 part of powder copper sulphate, 0.10 part of calcium iodate of the ultramicro grinding containing iodine 1%, 0.03 part of sodium selenite of the ultramicro grinding containing selenium 1%, 1.1 parts of 0.13 part of ferrous sulfate, 0.23 part of zinc sulfate, 0.30 part of manganese sulfate, 1.1 parts of sodium acid carbonate and potassium chloride mix.
The microelement pre-mix material of later stage eggshell quality 4. improvement according to claim 1 is laid eggs, it is characterised in that:Ultra micro Crush 0.13 part of copper sulphate, 0.15 part of calcium iodate of the ultramicro grinding containing iodine 1%, sodium selenite 0.03 of the ultramicro grinding containing selenium 1% Part, 0.15 part of ferrous sulfate, 0.26 part of zinc sulfate, 0.35 part of manganese sulfate, 1.5 parts of sodium acid carbonate and the mixing of 1.20 parts of potassium chloride and Into.
CN201710739122.6A 2017-08-25 2017-08-25 Improve the microelement pre-mix material for later stage eggshell quality of laying eggs Pending CN107397074A (en)

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CN114052141A (en) * 2021-11-06 2022-02-18 江苏蜀星饲料科技有限公司 Formula of organic composite trace elements for improving egg quality of laying hens

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Publication number Priority date Publication date Assignee Title
CN110679746A (en) * 2019-08-21 2020-01-14 中国农业大学 Microelement premix for improving eggshell quality of old laying hens and application thereof
CN114052141A (en) * 2021-11-06 2022-02-18 江苏蜀星饲料科技有限公司 Formula of organic composite trace elements for improving egg quality of laying hens

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Application publication date: 20171128