CN107352799B - A kind of crystallite emerald small-size glaze and its application method - Google Patents
A kind of crystallite emerald small-size glaze and its application method Download PDFInfo
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- CN107352799B CN107352799B CN201710626429.5A CN201710626429A CN107352799B CN 107352799 B CN107352799 B CN 107352799B CN 201710626429 A CN201710626429 A CN 201710626429A CN 107352799 B CN107352799 B CN 107352799B
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- 241000579895 Chlorostilbon Species 0.000 title claims abstract description 76
- 239000010976 emerald Substances 0.000 title claims abstract description 76
- 229910052876 emerald Inorganic materials 0.000 title claims abstract description 76
- 238000000034 method Methods 0.000 title claims abstract description 33
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 70
- 239000004575 stone Substances 0.000 claims abstract description 60
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000007873 sieving Methods 0.000 claims abstract description 23
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 241000876852 Scorias Species 0.000 claims abstract description 17
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000454 talc Substances 0.000 claims abstract description 17
- 235000012222 talc Nutrition 0.000 claims abstract description 17
- 229910052623 talc Inorganic materials 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000004615 ingredient Substances 0.000 claims abstract description 15
- 238000000498 ball milling Methods 0.000 claims abstract description 13
- 238000003682 fluorination reaction Methods 0.000 claims abstract description 11
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims abstract description 10
- 239000011013 aquamarine Substances 0.000 claims abstract description 10
- 239000002956 ash Substances 0.000 claims abstract description 10
- 239000013081 microcrystal Substances 0.000 claims abstract description 10
- 238000002834 transmittance Methods 0.000 claims abstract description 10
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 9
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 9
- 239000011787 zinc oxide Substances 0.000 claims abstract description 9
- 238000005034 decoration Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 23
- 230000003647 oxidation Effects 0.000 claims description 18
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- 235000015895 biscuits Nutrition 0.000 claims description 16
- 238000001354 calcination Methods 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 9
- 239000004576 sand Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 8
- 230000000694 effects Effects 0.000 abstract description 10
- 239000010977 jade Substances 0.000 abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 238000004321 preservation Methods 0.000 description 7
- 238000000465 moulding Methods 0.000 description 6
- 238000010304 firing Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 241000218998 Salicaceae Species 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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Abstract
The present invention relates to a kind of crystallite emerald small-size glaze and its application methods, the weight percent of the glaze forms are as follows: fluorination stone 18 ~ 22%, calcite 6 ~ 8%, two ashes 6 ~ 10%, potassium feldspar 16 ~ 22%, Jing Dezhen glaze fruit 22 ~ 34%, aluminium oxide 4 ~ 8%, silication stone 2 ~ 10%, scoria English 6 ~ 12%, burn talcum 6 ~ 12%, zinc oxide 2 ~ 6%, through ingredient, ball milling, sieving obtains crystallite emerald small-size glaze powder, by jade for asking rain glaze powder insert hollow out on green body it is exquisite it is intraocular after through grand feu obtain porcelain body, microcrystal grain is evenly distributed in the small-size glaze of the porcelain body, glaze is in aquamarine, and light transmittance reaches 45%.The present invention has not only restored the decorative effect of Jing Dezhen tradition ling-lung ware, and not only abundance is cheap for natural mineral raw for raw materials used major part, and without any side effects to human body, therefore has a vast market space.
Description
Technical field
The present invention relates to ceramic technology field, especially a kind of crystallite emerald small-size glaze and its application method.
Background technique
Jing Dezhen ancient times ling-lung ware is to chase out many well-regulated " exquisite eyes " by piercing technique on chinaware body
Then uniform crystalloid, and the dark green light transmission of glaze colours is presented in these apertures after being burnt into glaze, very beautiful, is called " edge bird with red feathers
Emerald green porcelain ".However due to the exhaustion of the lost and raw mineral materials of traditional processing technology, after causing current Jing Dezhen ling-lung ware to be burnt into
Glaze body in its hole eye is to lie in less than the technical effect of " emerald " based on milky or all-transparent.Therefore current Jing Dezhen
Ling-lung ware be not able to satisfy the requirement that people live to high-quality.
Summary of the invention
A kind of the technical problem to be solved in the present invention is to provide preparation processes simple, low in cost, health environment-friendly reaches biography
The crystallite emerald small-size glaze and its application method for pierced decoration technical effect of uniting.
The technical scheme is that a kind of crystallite emerald small-size glaze, it is characterised in that: the weight percent of the glaze
Composition are as follows:
It is fluorinated stone 18 ~ 22%, calcite 6 ~ 8%, two ashes 6 ~ 10%, potassium feldspar 16 ~ 22%, Jing Dezhen glaze fruit 22 ~ 34%, oxidation
Aluminium 4 ~ 8%, scoria English 6 ~ 12%, burns talcum 6 ~ 12%, zinc oxide 2 ~ 6% at silication stone 2 ~ 10%, through ingredient, ball milling, sieving process
Obtain crystallite emerald small-size glaze.
The scoria English, the calcination temperature for burning talcum are 800 ~ 900 DEG C.
Microcrystal grain is evenly distributed in the crystallite emerald small-size glaze, and glaze is in aquamarine, light transmittance reaches 45%.
The sieving process are as follows: sieve with 100 mesh sieve, tailing over is 0.
The application method of above-mentioned crystallite emerald small-size glaze, it is characterised in that according to following steps:
(1) the excellent green body after 900 DEG C of biscuitings is chosen；
(2) the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
(3) crystallite emerald small-size glaze powder and water are uniformly inserted to the tinkling of pieces of jade of hollow out on green body afterwards by weight 90:10 mix
Jade for asking rain is intraocular, after drying grinding homogeneity；
(4) green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, obtains the band tinkling of pieces of jade
The biscuit of jade for asking rain glaze；
(5) enter kiln again after clear frit being applied inside and outside the biscuit with small-size glaze, in 1290 DEG C of grand feus, kiln discharge, acquisitions
The porcelain body of crystallite emerald small-size glaze decoration.
The weight percent of green body described in the step (1) forms are as follows: bright sand kaolin 35%, southern port porcelain stone 15%, willow
Family's gulf porcelain stone 20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain stone 10%, potassium feldspar 5%.
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C be the heat of oxidation, heating rate be 2 degree/min, 1000 DEG C
It is oxidation soak, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C is reduction period, and heating rate is 5 degree/min, when 1290 DEG C
Heat preservation 20 minutes at porcelain.
The porcelain body surface of crystallite emerald small-size glaze decoration is decorated in such a way that Freehandhand-drawing is blue and white or decal paper.
The formulation thinking of the exquisite glaze formula of crystallite emerald of the present invention and technique:
First, largely using the purpose of fluorination stone in material formula: first is that exquisite glaze colours can be made transparent green tinged, reaching emerald
Effect；Second is that the melting temperature of glaze, low energy can be reduced.But it is fluorinated the addition meeting of stone simultaneously so that glaze softening, is easy
Sagging is caused, and the F ion being fluorinated in stone is easy to produce escaping gas and causes glaze bubble excessive, therefore of the invention
Also added suitable aluminium oxide in glaze formula and can react with fluorination stone makes enamel be hardened to avoid sagging, while being added in right amount
Silication stone can improve the melting behaviour of glaze, make glaze that there is good mobility and wider firing model in high temperature firing
It encloses, is easy to be discharged bubble, and can react with fluorination stone and change glaze crystal structure, reaches the effect of stable crystallite.
Second, it does not crack to guarantee to react between porcelain body and small-size glaze, the present invention also especially has adjusted in green body composition
Al2O3、SiO2Content, so that the coefficient of expansion of itself and crystallite emerald small-size glaze is matched；
Third, in order to stablize the crystallite effect in small-size glaze, in control small-size glaze chemical change is not occurring for the present invention
In the case of, by the low temperature biscuiting to small-size glaze, the intermediary water in small-size glaze raw material is discharged, reduces later period glaze firing process
It is middle excessive bubble occur；
4th, in order to generate evenly sized crystallite effect, the present invention is fired by glaze system and is slowly risen using oxidation stage early period
Temperature and oxidation soak, are discharged the constitution water in small-size glaze raw material all, reduce the bubble during glaze firing；Later period
Reduction phase is rapidly heated, and effectively prevents the recrystallization of crystallite in glaze, while can shorten the firing time of hot stage,
Reduce energy consumption.
The present invention is redesigned new glaze formula and technological parameter and is obtained by the production technology of the modern domestic ceramics of improvement
Microcrystal grain is evenly distributed in glaze, glaze is in aquamarine, and light transmittance reaches 45% crystallite emerald small-size glaze, the present invention
The decorative effect of Jing Dezhen tradition ling-lung ware is not only restored, and raw materials used major part is natural mineral raw not only source
It enriches cheap and without any side effects to human body, therefore has a vast market space.
Specific embodiment
For further illustrate the present invention, to reach the technical means and efficacy that predetermined goal of the invention is taken, tie below
Preferred embodiment is closed, the present invention is described in detail:
The main component of two ashes used in the exquisite glaze formula of crystallite emerald of the present invention is CaCO3。
The chemical composition of part raw mineral materials used in the present invention:
| Material name | SiO2 | Al2O3 | Fe2O3 | CaO | MgO | K2O | Na2O | It burns and loses | It is total |
| Bright sand kaolin | 47.28 | 37.41 | 0.78 | 0.36 | 0.1 | 2.51 | 0.23 | 12.03 | 100.7 |
| Southern port porcelain stone | 76.35 | 15.43 | 0.55 | 0.77 | 0.26 | 3.03 | 0.54 | 3.09 | 100.02 |
| The gulf Liu Jia porcelain stone | 76.32 | 14.46 | 0.5 | 0.27 | 0.23 | 2.92 | 1.9 | 3.47 | 100.21 |
| The fluffy porcelain stone of Triratna | 75.8 | 14.16 | 0.55 | 0.86 | 0.27 | 2.42 | 3.93 | 1.86 | 99.85 |
| Guixi porcelain stone | 75.1 | 16.21 | 0.45 | 0.2 | 0.24 | 3.62 | 0.09 | 3.46 | 99.37 |
Embodiment 1
Step 1: by the weight percentage composition of crystallite emerald small-size glaze: fluorination stone 19%, calcite 7%, two ashes 8%, potassium
Feldspar 18%, aluminium oxide 5%, silication stone 3%, scoria English 7%, burns talcum 7%, zinc oxide 3% at Jing Dezhen glaze fruit 23%, through ingredient, ball
Mill, sieving process obtain crystallite emerald small-size glaze powder, wherein sieving process is to sieve with 100 mesh sieve, tailing over is 0；
Step 2: by the weight percentage composition of green body: bright sand kaolin 35%, southern port porcelain stone 15%, the gulf Liu Jia porcelain stone
20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain stone 10%, potassium feldspar 5%, through ingredient, ball milling, sieving, molding, 900 DEG C of biscuitings, excellent
Process is selected to obtain green body；
Step 3: the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
Step 4: crystallite emerald small-size glaze powder and water are uniformly inserted into hollow out on green body by weight 90:10 mix afterwards
Exquisite intraocular, grinding homogeneity after drying；
Step 5: the green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, acquisitions
Biscuit with small-size glaze；
Step 6: entering kiln after applying clear frit inside and outside the biscuit with small-size glaze again, in 1290 DEG C of grand feus, kiln discharge,
Obtain the porcelain body of crystallite emerald small-size glaze decoration.
The scoria English, the calcination temperature for burning talcum are 820 DEG C；
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C be the heat of oxidation, heating rate be 2 degree/min, 1000 DEG C
It is oxidation soak, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C is reduction period, and heating rate is 5 degree/min, when 1290 DEG C
Heat preservation 20 minutes at porcelain；
Microcrystal grain is evenly distributed in the crystallite emerald small-size glaze of the porcelain body, and glaze is in aquamarine, light transmittance reaches
To 45%；
The porcelain body surface of the crystallite emerald small-size glaze decoration is decorated using Freehandhand-drawing is blue and white.
Embodiment 2
Step 1: by the weight percentage composition of crystallite emerald small-size glaze: fluorination stone 18%, calcite 8%, two ashes 6%, potassium
Feldspar 16%, Jing Dezhen glaze fruit 32%, aluminium oxide 4%, silication stone 2%, scoria English 6%, burn talcum 6%, zinc oxide 2%, through ingredient,
Ball milling, sieving process obtain crystallite emerald small-size glaze powder, wherein sieving process is to sieve with 100 mesh sieve, tailing over is 0；
Step 2: by the weight percentage composition of green body: bright sand kaolin 35%, southern port porcelain stone 15%, the gulf Liu Jia porcelain stone
20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain stone 10%, potassium feldspar 5%, through ingredient, ball milling, sieving, molding, 900 DEG C of biscuitings, excellent
Process is selected to obtain green body；
Step 3: the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
Step 4: crystallite emerald small-size glaze powder and water are uniformly inserted into hollow out on green body by weight 90:10 mix afterwards
Exquisite intraocular, grinding homogeneity after drying；
Step 5: the green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, acquisitions
Biscuit with small-size glaze；
Step 6: entering kiln after applying clear frit inside and outside the biscuit with small-size glaze again, in 1290 DEG C of grand feus, kiln discharge,
Obtain the porcelain body of crystallite emerald small-size glaze decoration.
The scoria English, the calcination temperature for burning talcum are 830 DEG C；
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C be the heat of oxidation, heating rate be 2 degree/min, 1000 DEG C
It is oxidation soak, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C is reduction period, and heating rate is 5 degree/min, when 1290 DEG C
Heat preservation 20 minutes at porcelain；
Microcrystal grain is evenly distributed in the crystallite emerald small-size glaze of the porcelain body, and glaze is in aquamarine, light transmittance reaches
To 45%；
The porcelain body surface of the crystallite emerald small-size glaze decoration is decorated in such a way that Freehandhand-drawing is blue and white.
Embodiment 3
Step 1: by the weight percentage composition of crystallite emerald small-size glaze: fluorination stone 20%, calcite 6%, two ashes 6%, potassium
Feldspar 16%, Jing Dezhen glaze fruit 27%, aluminium oxide 4%, silication stone 2%, scoria English 6%, burn talcum 11%, zinc oxide 2%, through ingredient,
Ball milling, sieving process obtain crystallite emerald small-size glaze powder, wherein sieving process is to sieve with 100 mesh sieve, tailing over is 0；
Step 2: by the weight percentage composition of green body: bright sand kaolin 35%, southern port porcelain stone 15%, the gulf Liu Jia porcelain stone
20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain stone 10%, potassium feldspar 5%, through ingredient, ball milling, sieving, molding, 900 DEG C of biscuitings, excellent
Process is selected to obtain green body；
Step 3: the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
Step 4: crystallite emerald small-size glaze powder and water are uniformly inserted into hollow out on green body by weight 90:10 mix afterwards
Exquisite intraocular, grinding homogeneity after drying；
Step 5: the green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, acquisitions
Biscuit with small-size glaze；
Step 6: entering kiln after applying clear frit inside and outside the biscuit with small-size glaze again, in 1290 DEG C of grand feus, kiln discharge,
Obtain the porcelain body of crystallite emerald small-size glaze decoration.
The scoria English, the calcination temperature for burning talcum are 840 DEG C；
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C be the heat of oxidation, heating rate be 2 degree/min, 1000 DEG C
It is oxidation soak, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C is reduction period, and heating rate is 5 degree/min, when 1290 DEG C
Heat preservation 20 minutes at porcelain；
Microcrystal grain is evenly distributed in the crystallite emerald small-size glaze of the porcelain body, and glaze is in aquamarine, light transmittance reaches
To 45%；
The porcelain body surface of the crystallite emerald small-size glaze decoration is decorated by the way of decal paper.
Embodiment 4
Step 1: by the weight percentage composition of crystallite emerald small-size glaze: fluorination stone 18%, calcite 6%, two ashes 8%, potassium
Feldspar 20%, aluminium oxide 7%, silication stone 2%, scoria English 6%, burns talcum 6%, zinc oxide 5% at Jing Dezhen glaze fruit 22%, through ingredient, ball
Mill, sieving process obtain crystallite emerald small-size glaze powder, wherein sieving process is to sieve with 100 mesh sieve, tailing over is 0；
Step 2: by the weight percentage composition of green body: bright sand kaolin 35%, southern port porcelain stone 15%, the gulf Liu Jia porcelain stone
20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain stone 10%, potassium feldspar 5%, through ingredient, ball milling, sieving, molding, 900 DEG C of biscuitings, excellent
Process is selected to obtain green body；
Step 3: the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
Step 4: crystallite emerald small-size glaze powder and water are uniformly inserted into hollow out on green body by weight 90:10 mix afterwards
Exquisite intraocular, grinding homogeneity after drying；
Step 5: the green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, acquisitions
Biscuit with small-size glaze；
Step 6: entering kiln after applying clear frit inside and outside the biscuit with small-size glaze again, in 1290 DEG C of grand feus, kiln discharge,
Obtain the porcelain body of crystallite emerald small-size glaze decoration.
The scoria English, the calcination temperature for burning talcum are 850 DEG C；
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C be the heat of oxidation, heating rate be 2 degree/min, 1000 DEG C
It is oxidation soak, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C is reduction period, and heating rate is 5 degree/min, when 1290 DEG C
Heat preservation 20 minutes at porcelain；
Microcrystal grain is evenly distributed in the crystallite emerald small-size glaze of the porcelain body, and glaze is in aquamarine, light transmittance reaches
To 45%；
The porcelain body surface of the crystallite emerald small-size glaze decoration is decorated in such a way that Freehandhand-drawing is blue and white.
Embodiment 5
Step 1: by the weight percentage composition of crystallite emerald small-size glaze: fluorination stone 18%, calcite 6%, two ashes 6%, potassium
Feldspar 16%, Jing Dezhen glaze fruit 22%, aluminium oxide 4%, silication stone 8%, scoria English 11%, burn talcum 7%, zinc oxide 2%, through ingredient,
Ball milling, sieving process obtain crystallite emerald small-size glaze powder, wherein sieving process is to sieve with 100 mesh sieve, tailing over is 0；
Step 2: by the weight percentage composition of green body: bright sand kaolin 35%, southern port porcelain stone 15%, the gulf Liu Jia porcelain stone
20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain stone 10%, potassium feldspar 5%, through ingredient, ball milling, sieving, molding, 900 DEG C of biscuitings, excellent
Process is selected to obtain green body；
Step 3: the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
Step 4: crystallite emerald small-size glaze powder and water are uniformly inserted into hollow out on green body by weight 90:10 mix afterwards
Exquisite intraocular, grinding homogeneity after drying；
Step 5: the green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, acquisitions
Biscuit with small-size glaze；
Step 6: entering kiln after applying clear frit inside and outside the biscuit with small-size glaze again, in 1290 DEG C of grand feus, kiln discharge,
Obtain the porcelain body of crystallite emerald small-size glaze decoration.
The scoria English, the calcination temperature for burning talcum are 860 DEG C；
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C be the heat of oxidation, heating rate be 2 degree/min, 1000 DEG C
It is oxidation soak, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C is reduction period, and heating rate is 5 degree/min, when 1290 DEG C
Heat preservation 20 minutes at porcelain；
Microcrystal grain is evenly distributed in the crystallite emerald small-size glaze of the porcelain body, and glaze is in aquamarine, light transmittance reaches
To 45%；
The porcelain body surface of the crystallite emerald small-size glaze decoration is decorated in such a way that Freehandhand-drawing is blue and white.
Embodiment 6
Step 1: by the weight percentage composition of crystallite emerald small-size glaze: fluorination stone 20%, calcite 6%, two ashes 7%, potassium
Feldspar 16%, Jing Dezhen glaze fruit 23%, aluminium oxide 4%, silication stone 5%, scoria English 7%, burn talcum 10%, zinc oxide 2%, through ingredient,
Ball milling, sieving process obtain crystallite emerald small-size glaze powder, wherein sieving process is to sieve with 100 mesh sieve, tailing over is 0；
Step 2: by the weight percentage composition of green body: bright sand kaolin 35%, southern port porcelain stone 15%, the gulf Liu Jia porcelain stone
20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain stone 10%, potassium feldspar 5%, through ingredient, ball milling, sieving, molding, 900 DEG C of biscuitings, excellent
Process is selected to obtain green body；
Step 3: the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
Step 4: crystallite emerald small-size glaze powder and water are uniformly inserted into hollow out on green body by weight 90:10 mix afterwards
Exquisite intraocular, grinding homogeneity after drying；
Step 5: the green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, acquisitions
Biscuit with small-size glaze；
Step 6: entering kiln after applying clear frit inside and outside the biscuit with small-size glaze again, in 1290 DEG C of grand feus, kiln discharge,
Obtain the porcelain body of crystallite emerald small-size glaze decoration.
The scoria English, the calcination temperature for burning talcum are 880 DEG C；
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C be the heat of oxidation, heating rate be 2 degree/min, 1000 DEG C
It is oxidation soak, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C is reduction period, and heating rate is 5 degree/min, when 1290 DEG C
Heat preservation 20 minutes at porcelain；
Microcrystal grain is evenly distributed in the crystallite emerald small-size glaze of the porcelain body, and glaze is in aquamarine, light transmittance reaches
To 45%；
The porcelain body surface of the crystallite emerald small-size glaze decoration is decorated by the way of decal paper.
Claims (6)
1. a kind of crystallite emerald small-size glaze, it is characterised in that: the weight percent of crystallite emerald small-size glaze forms are as follows:
Fluorination stone 18 ~ 22%, calcite 6 ~ 8%, two ashes 6 ~ 10%, potassium feldspar 16 ~ 22%, Jing Dezhen glaze fruit 22 ~ 34%, aluminium oxide 4 ~
8%, silication stone 2 ~ 10%, scoria English 6 ~ 12%, burning talcum 6 ~ 12%, zinc oxide 2 ~ 6% are obtained through ingredient, ball milling, sieving process
Crystallite emerald small-size glaze；
The application method of the crystallite emerald small-size glaze, it is characterised in that according to following steps:
(1) the excellent green body after 900 DEG C of biscuitings is chosen；
(2) the mechanical or exquisite eye of pure manual hollow out is carried out on green body by pierced decoration decorative pattern；
(3) crystallite emerald small-size glaze powder and water are uniformly inserted to the exquisite eye of hollow out on green body afterwards by weight 90:10 mix
It is interior, grinding homogeneity after drying；
(4) green body for having inserted crystallite emerald small-size glaze is entered into kiln again, in 850 DEG C of low temperature biscuitings, kiln discharge, obtains band small-size glaze
Biscuit；
(5) enter kiln again after clear frit being applied inside and outside the biscuit with small-size glaze, in 1290 DEG C of grand feus, kiln discharge, obtain crystallite
The porcelain body of emerald small-size glaze decoration；
The calcining system of the grand feu are as follows: room temperature ~ 1000 DEG C are the heat of oxidation, and heating rate is 2 degree/min, and 1000 DEG C of whens are
Soak is aoxidized, keeps the temperature 30 minutes, 1000 ~ 1290 DEG C are reduction period, and heating rate is 5 degree/min, and 1290 DEG C of whens keep the temperature
20 minutes at porcelain.
2. crystallite emerald small-size glaze according to claim 1, it is characterised in that: the scoria English, the calcining temperature for burning talcum
Degree is 800 ~ 900 DEG C.
3. crystallite emerald small-size glaze according to claim 1, it is characterised in that: uniformly divide in the crystallite emerald small-size glaze
It is furnished with microcrystal grain, and glaze is in aquamarine, light transmittance reaches 45%.
4. crystallite emerald small-size glaze according to claim 1, it is characterised in that: the sieving process are as follows: it sieves with 100 mesh sieve,
Tail over is 0.
5. crystallite emerald small-size glaze according to claim 1, it is characterised in that: the weight of green body described in the step (1)
Measure percentage composition are as follows: bright sand kaolin 35%, southern port porcelain stone 15%, the gulf Liu Jia porcelain stone 20%, the fluffy porcelain stone 15% of Triratna, Guixi porcelain
Stone 10%, potassium feldspar 5%.
6. crystallite emerald small-size glaze according to claim 1, it is characterised in that: the porcelain of the crystallite emerald small-size glaze decoration
Body surface face is decorated in such a way that Freehandhand-drawing is blue and white or decal paper.
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| CN114670317A (en) * | 2020-12-24 | 2022-06-28 | 李青春 | Exquisite glaze filling process for manufacturing exquisite porcelain |
| CN115772026A (en) * | 2023-01-07 | 2023-03-10 | 景德镇富玉青花玲珑陶瓷有限公司 | Preparation method of colorful exquisite porcelain |
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| CN101602594A (en) * | 2009-07-06 | 2009-12-16 | 景德镇陶瓷协会 | Process technique for producing blue and white delicate porcelain |
| CN103232268A (en) * | 2013-05-13 | 2013-08-07 | 景德镇市宁封窑陶瓷文化发展有限公司 | Five-color exquisite glaze and five-color exquisite porcelain |
| CN103553717A (en) * | 2013-10-25 | 2014-02-05 | 景德镇市博大精工艺术陶瓷有限公司 | Crystal mirror surface Linglong glaze and application method thereof |
| CN104891809A (en) * | 2015-06-02 | 2015-09-09 | 景德镇市亚星特种陶瓷有限公司 | Flaky exquisite glaze |
| KR101694912B1 (en) * | 2016-05-20 | 2017-01-10 | 주식회사 리빙아이콘 | Crystal glaze pottery and method for manufacturing thereof |
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| CN101602594A (en) * | 2009-07-06 | 2009-12-16 | 景德镇陶瓷协会 | Process technique for producing blue and white delicate porcelain |
| CN103232268A (en) * | 2013-05-13 | 2013-08-07 | 景德镇市宁封窑陶瓷文化发展有限公司 | Five-color exquisite glaze and five-color exquisite porcelain |
| CN103553717A (en) * | 2013-10-25 | 2014-02-05 | 景德镇市博大精工艺术陶瓷有限公司 | Crystal mirror surface Linglong glaze and application method thereof |
| CN104891809A (en) * | 2015-06-02 | 2015-09-09 | 景德镇市亚星特种陶瓷有限公司 | Flaky exquisite glaze |
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