CN106542737A - A kind of glaze compositions and its method for cooking - Google Patents
A kind of glaze compositions and its method for cooking Download PDFInfo
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- CN106542737A CN106542737A CN201611256239.0A CN201611256239A CN106542737A CN 106542737 A CN106542737 A CN 106542737A CN 201611256239 A CN201611256239 A CN 201611256239A CN 106542737 A CN106542737 A CN 106542737A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
- C04B41/5023—Glass-ceramics
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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Abstract
The invention provides a kind of glaze compositions and its method for cooking, belong to ceramic product technical field, the glaze compositions include the raw material of following weight portion：0.1～0.2 part of 55～60 parts of glaze fruit, 5～6 parts of dolomite, 5～6 parts of wollastonite, 25～33 parts of Zinc Oxide and sodium carboxymethyl cellulose in precious jade, glaze compositions of the present invention viscosity in sintering process is high, avoid the big defect of glaze temperature flowing, and glaze compositions formula of the present invention is simple, reasonable mixture ratio, so that the firing range width of glaze, advantageously ensure that the qualification rate of product, in addition, it is high that the present invention fires the ceramic glaze glossiness for obtaining, hardness is big, and beautiful appearance, glaze are smooth.
Description
Technical field
The invention belongs to ceramic product technical field, and in particular to a kind of glaze compositions and its method for cooking.
Background technology
Crystalline glaze be by the colourful crystal of self-assembling formation in sintering procedure anchor at beauty that Ceramic glaze obtains,
Novel natural brilliant flower, its outward appearance are varied, riotous with colour, with strong artistic effect.Traditional crystalline glaze is typically used
In the art pottery or the incrustation of ceramic ware for daily use, its production technology is that the raw material needed for various enamel frit makeing is worn into glaze
Slurry, applies on ceramic surface, and Jing high temperature burns till, and makes glaze in high temperature fused state in the presence of Nucleating Agent, around
Nucleus is crystallized and is gradually grown up, and forms the different floral designs of shape size, to reach the effect on decorating ceramic articles surface.
For example, 102515861 A of Chinese patent literature CN discloses a kind of formula of crystalline glaze, the crystalline glaze glaze
Chemical composition is calculated as by weight/mass percentage composition：SiO255.8%th, Al2O322.6%th, TiO22.3%th, Fe2O30.3%th, CaO
7.8%th, MgO 3.5%, Na2O 2.8%, B2O32.5%th, ZnO 2.3% and CMC 0.1%, above-mentioned glaze are applied on biscuit
After glaze, fire into kiln, concrete firing condition is：Room temperature is heated, and is slowly warmed up to 350 DEG C with the speed of 50 DEG C/h, then
With the ramp of 70～80 DEG C/h to 900 DEG C, 30min is incubated, then with the ramp of 150 DEG C/h to 1320 DEG C, is incubated
10min, cools to 1290 DEG C, is incubated 50min, then cools to 1100 insulation 3h, naturally cools to room temperature.What above-mentioned technology was obtained
Brilliant flower flower-shape is of moderate size, and flower-shape is compact, and crystallization is uniform, can keep higher hardness, glossiness, and glaze smooth it is gentle.
But above-mentioned crystalline glaze high-temperature viscosity is low, easily sagging, causes yield rate low, additionally, the speed that heats up in above-mentioned glaze material sintering procedure
Rate is slow, causes the firing time longer.
The content of the invention
The technical problem to be solved be overcome prior art in glaze high temperature viscosity it is low, easily sagging, into
The defect that product rate is low and the firing time is longer, and then provide that a kind of glaze high temperature viscosity is higher, mobility is low, high yield rate and burning
Time processed short glaze compositions and its method for cooking.
The present invention solve the technical scheme that adopts of above-mentioned technical problem for：
The invention provides a kind of glaze compositions, including the raw material of following weight portion, 55～60 parts, white clouds of glaze fruit in precious jade
0.1～0.2 part of 5～6 parts of stone, 5～6 parts of wollastonite, 25～33 parts of Zinc Oxide and sodium carboxymethyl cellulose.
The glaze compositions also include 0.2～0.35 part of cobalt oxide.
In terms of the gross mass of the glaze compositions, including the raw material of following mass percent,
Glaze fruit 58.58%, dolomite 5.85%, wollastonite 5.85%, Zinc Oxide 29.29%, carboxymethyl cellulose in precious jade
Sodium 0.14%, cobalt oxide 0.29%.
The crystalline glaze that above-mentioned glaze compositions are fired.
The present invention also provides the method that above-mentioned glaze compositions fire crystalline glaze, comprises the following steps：
(1) prepare glaze slip
The glaze compositions, high alumina ballstone and water are loaded in ball mill, ball milling, fineness of the particles is more than 10000-hole sieve
0.2%, mixing and stirring makes glaze slip；
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 0.5～2mm, is dried；
(3) fire
Biscuit body by glazing and after drying, is fired using oxidizing flame or neutral flame, from room temperature with 150～200 DEG C/h's
Speed is slowly warmed up to 400 DEG C, is then rapidly heated 900 DEG C with the speed of 300～350 DEG C/h, is incubated 30min, then with 200
DEG C/ramp to 1277 DEG C of h, with 800～850 DEG C/h speed fast cooling to 1145 DEG C after insulation 10min, it is incubated
180min, then cools to 1070 DEG C with 800～850 DEG C/h speed, is incubated 60min, finally naturally cools to room temperature, that is, be obtained
The crystalline glaze.
The mass ratio of the glaze compositions, high alumina ballstone and water is 1:2:0.8；The Ball-milling Time is 30min, rotating speed
For 450r/min.
The above-mentioned technical proposal of the present invention has the advantage that：
(1) glaze compositions of the present invention, including the raw material of following weight portion, 55～60 parts, white clouds of glaze fruit in precious jade
0.1～0.2 part of 5～6 parts of stone, 5～6 parts of wollastonite, 25～33 parts of Zinc Oxide and sodium carboxymethyl cellulose, glaze of the present invention
In compositionss, in precious jade, the main mineral constituent of glaze fruit is sericite, quartz and Anhydrite, and in precious jade, glaze fruit can reduce the melting temperature of glaze
Degree, improves the transparency of glaze；Dolomite can be used as the flux of glaze；Wollastonite can reduce firing temperature, shortening and burn till
Time；Zinc Oxide as the additional nucleating agent of crystalline glaze, and can widen the firing range of glaze, prevent curling；Carboxylic
Sodium carboxymethylcellulose pyce can improve the suspension of glaze, make glaze uniformly body, in the precious jade in the glaze compositions that the present invention is provided
Glaze fruit, dolomite, wollastonite, Zinc Oxide and sodium carboxymethyl cellulose basis of formation glaze together, adjusts the melt temperature of glaze, molten
Melting property, fluxibility, stability, mobility and viscosity etc. so that the glaze of the present invention has high temperature viscosity high, low excellent of mobility
Gesture；Glaze compositions of the present invention also include cobalt oxide, its as colorant, for adjusting background glaze colours.
Glaze compositions of the present invention, formula are simple, reasonable mixture ratio so that the firing range of glaze is broad, effectively
Expand the maturing range of crystalline glaze, cost is burnt till in reduction；The knot fired using the glaze compositions of the present invention
Brilliant glaze, the brilliant flower of its crystallization are uniform compact featheriness, have strong artistic effect；And Low fire ceramic finished product glaze glossiness
Height, hardness are big, and beautiful appearance, glaze are smooth；Importantly, the glaze compositions using the present invention avoid glaze high-temperature stream
The big defect of dynamic property, improves product quality.
(2) method that glaze compositions of the present invention fire glaze, effectively expands the maturing temperature model of crystalline glaze
Enclose, breach that crystalline glaze maturing temperature is narrow, the technical bottleneck that crystalline range is narrow, the interval of temperature change can in sintering procedure
Control, so as to reduce firing cost, and the present invention by the way of warm quick fever is shortened the firing time, is enable crystalline glaze picture
Other glaze equally realize industrialized production, and can improve yield rate.
Specific embodiment
Technical scheme will be clearly and completely described below, it is clear that described embodiment is this
Bright a part of embodiment, rather than the embodiment of whole.Based on the embodiment in the present invention, those of ordinary skill in the art are not having
There is the every other embodiment obtained under the premise of making creative work, belong to the scope of protection of the invention.Additionally, below
Just can be mutual as long as the technical characteristic involved by described different embodiments of the present invention does not constitute conflict each other
With reference to.
Embodiment 1
The method for cooking of the uniform compact blue Feather-like Crystal flower crystalline glaze that the present embodiment is provided comprises the steps：
(1) prepare glaze slip
The following glaze raw material of precise：Glaze fruit 58.58g, dolomite 5.85g, wollastonite 5.85g, Zinc Oxide in precious jade
Above-mentioned glaze raw material, high alumina ballstone and water are loaded ball mill by 29.29g, sodium carboxymethyl cellulose 0.14g and cobalt oxide 0.29g
In, the glaze raw material：High alumina ballstone：The mass ratio of water is 1:2:0.8, Ball-milling Time is 30min, rotating speed is 450r/min,
Grain fineness mores than 0.2% for 10000-hole sieve, and mixing and stirring makes glaze slip.
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 1mm, is dried.
(3) fire
Biscuit body by glazing and after drying, is fired using oxidizing flame, is slowly warmed up to the speed of 200 DEG C/h from room temperature
, then 900 DEG C are rapidly heated with the speed of 350 DEG C/h, be incubated 30min, then arrived with the ramp of 200 DEG C/h by 400 DEG C
1277 DEG C, with 800 DEG C/h speed fast cooling to 1145 DEG C after insulation 10min, 180min is incubated, then with 850 DEG C/h speed
1070 DEG C are cooled to, 60min is incubated, is finally naturally cooled to room temperature, that is, the uniform compact blue Feather-like Crystal flower knot is obtained
Brilliant glaze.
Jing flat band methods are determined, and the uniform compact blue Feather-like Crystal that the present embodiment is prepared spends the temperature flowing of crystalline glaze
Spend for 58 millimeters.
Embodiment 2
The method for cooking of the uniform compact blue Feather-like Crystal flower crystalline glaze that the present embodiment is provided comprises the steps：
(1) prepare glaze slip
The following glaze raw material of precise：Glaze fruit 55.55g, dolomite 6g, wollastonite 5g, Zinc Oxide 33g, carboxymethyl in precious jade
Sodium cellulosate 0.1g and cobalt oxide 0.35g, above-mentioned glaze raw material, high alumina ballstone and water is loaded in ball mill, the glaze raw material：It is high
Aluminium ball stone：The mass ratio of water is 1:2:0.8, Ball-milling Time is 30min, rotating speed is 450r/min, and fineness of the particles is more than 10000-hole sieve
0.2%, mixing and stirring makes glaze slip.
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 0.5mm, is dried.
(3) fire
Biscuit body by glazing and after drying, is fired using neutral flame, is slowly warmed up to the speed of 150 DEG C/h from room temperature
, then 900 DEG C are rapidly heated with the speed of 350 DEG C/h, be incubated 30min, then arrived with the ramp of 200 DEG C/h by 400 DEG C
1277 DEG C, with 800 DEG C/h speed fast cooling to 1145 DEG C after insulation 10min, 180min is incubated, then with 850 DEG C/h speed
1070 DEG C are cooled to, 60min is incubated, is finally naturally cooled to room temperature, that is, the uniform compact blue Feather-like Crystal flower knot is obtained
Brilliant glaze.
Jing flat band methods are determined, and the uniform compact blue Feather-like Crystal that the present embodiment is prepared spends the temperature flowing of crystalline glaze
Spend for 59 millimeters.
Embodiment 3
The method for cooking of the uniform compact blue Feather-like Crystal flower crystalline glaze that the present embodiment is provided comprises the steps：
(1) prepare glaze slip
The following glaze raw material of precise：Glaze fruit 60g, dolomite 5g, wollastonite 6g, Zinc Oxide 27g, carboxymethyl cellulose in precious jade
Plain sodium 0.2g and cobalt oxide 0.2g, above-mentioned glaze raw material, high alumina ballstone and water is loaded in ball mill, the glaze raw material：High aluminium ball
Stone：The mass ratio of water is 1:2:0.8, Ball-milling Time is 30min, rotating speed is 450r/min, and fineness of the particles is more than 10000-hole sieve
0.2%, mixing and stirring makes glaze slip.
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 2mm, is dried.
(3) fire
Biscuit body by glazing and after drying, is fired using oxidizing flame, is slowly warmed up to the speed of 200 DEG C/h from room temperature
, then 900 DEG C are rapidly heated with the speed of 300 DEG C/h, be incubated 30min, then arrived with the ramp of 200 DEG C/h by 400 DEG C
1277 DEG C, with 850 DEG C/h speed fast cooling to 1145 DEG C after insulation 10min, 180min is incubated, then with 800 DEG C/h speed
1070 DEG C are cooled to, 60min is incubated, is finally naturally cooled to room temperature, that is, the uniform compact blue Feather-like Crystal flower knot is obtained
Brilliant glaze.
Jing flat band methods are determined, and the uniform compact blue Feather-like Crystal that the present embodiment is prepared spends the temperature flowing of crystalline glaze
Spend for 59 millimeters.
Embodiment 4
The method for cooking of the brilliant flower crystalline glaze of uniform compact white feather shape that the present embodiment is provided comprises the steps：
(1) prepare glaze slip
The following glaze raw material of precise：Glaze fruit 59.1g, dolomite 5.9g, wollastonite 5.6g, Zinc Oxide 29.2g, carboxylic in precious jade
Sodium carboxymethylcellulose pyce 0.2g, above-mentioned glaze raw material, high alumina ballstone and water is loaded in ball mill, the glaze raw material：High alumina ballstone：Water
Mass ratio be 1:2:0.8, it is 450r/min that Ball-milling Time is 30min, rotating speed, and fineness of the particles is that 10000-hole sieve mores than 0.2%, is mixed
Stirs the glaze slip that make.
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 0.8mm, is dried.
(3) fire
Biscuit body by glazing and after drying, is fired using neutral flame, is slowly warmed up to the speed of 180 DEG C/h from room temperature
, then 900 DEG C are rapidly heated with the speed of 330 DEG C/h, be incubated 30min, then arrived with the ramp of 200 DEG C/h by 400 DEG C
1277 DEG C, with 810 DEG C/h speed fast cooling to 1145 DEG C after insulation 10min, 180min is incubated, then with 835 DEG C/h speed
1070 DEG C are cooled to, 60min is incubated, is finally naturally cooled to room temperature, that is, the brilliant flower knot of the uniform compact white feather shape is obtained
Brilliant glaze.
Jing flat band methods are determined, the temperature flowing of the brilliant flower crystalline glaze of the uniform compact white feather shape that the present embodiment is prepared
Spend for 60 millimeters.
Comparative example 1
The method for cooking of the crystalline glaze that this comparative example is provided comprises the steps：
(1) prepare glaze slip
The following glaze raw material of precise：SiO255.8g, Al2O322.6g, TiO22.3g, Fe2O30.3g, CaO
7.8g, MgO 3.5g, Na2O 2.8g, B2O32.5g, ZnO 2.3g, CMC 0.1g, by above-mentioned glaze raw material, high alumina ballstone and water
Load in ball mill, the glaze raw material：High alumina ballstone：The mass ratio of water is 1:2:0.8, Ball-milling Time is 30min, rotating speed is
450r/min, fineness of the particles more than 0.2% for 10000-hole sieve, and mixing and stirring makes glaze slip.
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 1.6mm, is dried.
(3) fire
Biscuit body by glazing and after drying, is fired using oxidizing flame, and room temperature heating is slowly heated up with the speed of 50 DEG C/h
To 350 DEG C, then with the ramp of 70～80 DEG C/h to 900 DEG C, 30min is incubated, then is arrived with the ramp of 150 DEG C/h
1320 DEG C, 10min is incubated, 1290 DEG C are cooled to, be incubated 50min, then cool to 1100 insulation 3h, naturally cool to room temperature.I.e.
The crystalline glaze is obtained.
Jing flat band methods are determined, and the temperature flowing degree of the crystalline glaze that this comparative example is prepared is 65 millimeters.
Comparative example 2
The method for cooking of the brilliant flower crystalline glaze of blueness that this comparative example is provided comprises the steps：
(1) prepare glaze slip
The following glaze raw material of precise：Glaze fruit 55g, wollastonite 5g, Zinc Oxide 33g, sodium carboxymethyl cellulose 0.1g in precious jade
With cobalt oxide 0.35g, above-mentioned glaze raw material, high alumina ballstone and water are loaded in ball mill, the glaze raw material：High alumina ballstone：Water
Mass ratio is 1:2:0.8, it is 450r/min that Ball-milling Time is 30min, rotating speed, and fineness of the particles mores than 0.2% for 10000-hole sieve, and mixing is stirred
Mix and uniformly make glaze slip.
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 0.5mm, is dried.
(3) fire
Biscuit body by glazing and after drying, is fired using oxidizing flame, is slowly warmed up to the speed of 150 DEG C/h from room temperature
, then 900 DEG C are rapidly heated with the speed of 350 DEG C/h, be incubated 30min, then arrived with the ramp of 200 DEG C/h by 400 DEG C
1277 DEG C, with 800 DEG C/h speed fast cooling to 1145 DEG C after insulation 10min, 180min is incubated, then with 850 DEG C/h speed
1070 DEG C are cooled to, 60min is incubated, is finally naturally cooled to room temperature, that is, the uniform compact blue Feather-like Crystal flower knot is obtained
Brilliant glaze.
Jing flat band methods are determined, and the temperature flowing degree of the brilliant flower crystalline glaze of the blueness that this comparative example is prepared is 64 millimeters.
Experimental example
100 ceramics are prepared respectively by method for cooking of embodiment of the present invention 1-4 with comparative example 1-2, are obtained uniform
The ceramic in compact crystallization crystalline substance fancy glaze face is the passing number of the ceramic of certified products, embodiment 1-4 and the firing of comparative example 1-2
As shown in table 1.
The passing number of 100 ceramics that 1 embodiment 1-4 of table is fired with comparative example 1-2
| Passing number | |
| Embodiment 1 | 92 |
| Embodiment 2 | 93 |
| Embodiment 3 | 94 |
| Embodiment 4 | 90 |
| Comparative example 1 | 75 |
| Comparative example 2 | 65 |
As shown in Table 1, the qualification rate of the glaze of embodiment of the present invention 1-4 product in sintering procedure is higher than 1 He of comparative example
Comparative example 2.
To sum up, high temperature viscosity of the glaze of embodiment of the present invention 1-4 in sintering procedure is higher than comparative example 1 and comparative example 2,
Can make crystalline glaze of the present invention that the defect of sagging is avoided in sintering procedure, advantageously ensure that the qualification rate of product；Additionally, of the invention
Glaze firing range is broad, is equally beneficial for ensureing the qualification rate of product, and cost is burnt till in reduction；Additionally, using the glaze of the present invention
The crystalline glaze that feed composition is fired, the brilliant flower of its crystallization are uniform compact featheriness, have strong artistic effect, burn till pottery
Porcelain finished product glaze glossiness is high, and hardness is big, and beautiful appearance, glaze are smooth.
Obviously, above-described embodiment is only intended to clearly illustrate example, and the not restriction to embodiment.It is right
For those of ordinary skill in the art, can also make on the basis of the above description other multi-forms change or
Change.There is no need to be exhaustive to all of embodiment.And thus it is extended obvious change or
Among changing still in the protection domain of the invention.
Claims (6)
1. a kind of glaze compositions, it is characterised in that including the raw material of following weight portion, 55～60 parts, dolomite 5 of glaze fruit in precious jade
0.1～0.2 part of～6 parts, 5～6 parts of wollastonite, 25～33 parts of Zinc Oxide and sodium carboxymethyl cellulose.
2. glaze compositions according to claim 1, it is characterised in that the glaze compositions also include cobalt oxide 0.2
～0.35 part.
3. glaze compositions according to claim 1 and 2, it is characterised in that in terms of the gross mass of the glaze compositions,
Including the raw material of following mass percent,
Glaze fruit 58.58%, dolomite 5.85%, wollastonite 5.85%, Zinc Oxide 29.29%, sodium carboxymethyl cellulose in precious jade
0.14%th, cobalt oxide 0.29%.
4. the crystalline glaze that a kind of glaze compositions by described in any one of claim 1-3 are fired.
5. a kind of method that glaze compositions by described in any one of claim 1-3 fire crystalline glaze, it is characterised in that include
Following steps：
(1) prepare glaze slip
The glaze compositions, high alumina ballstone and water are loaded in ball mill, ball milling, fineness of the particles is that 10000-hole sieve mores than 0.2%, mixed
Conjunction stirs and makes glaze slip；
(2) glazing
Glaze slip is equably coated plain billet surface, glazed thickness is 0.5～2mm, is dried；
(3) fire
Biscuit body by glazing and after drying, is fired using oxidizing flame or neutral flame, from room temperature with the speed of 150～200 DEG C/h
400 DEG C are slowly warmed up to, then 900 DEG C are rapidly heated with the speed of 300～350 DEG C/h, be incubated 30min, then with 200 DEG C/h
Ramp to 1277 DEG C, with 800～850 DEG C/h speed fast cooling to 1145 DEG C after insulation 10min, be incubated 180min,
Then 1070 DEG C are cooled to 800～850 DEG C/h speed, is incubated 60min, finally naturally cools to room temperature, that is, the knot is obtained
Brilliant glaze.
6. the method that glaze compositions according to claim 5 fire crystalline glaze, it is characterised in that the glaze combination
The mass ratio of thing, high alumina ballstone and water is 1:2:0.8；The Ball-milling Time is 30min, rotating speed is 450r/min.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110526579A (en) * | 2019-08-02 | 2019-12-03 | 东北大学 | A method of glaze is prepared using gold mine association alterated rocks |
| CN111592381A (en) * | 2020-06-16 | 2020-08-28 | 淄博汉青陶瓷有限公司 | Firing process of high-temperature in-glaze decoration |
| CN112142331A (en) * | 2020-11-19 | 2020-12-29 | 福建省德化县新宇陶瓷有限公司 | High-temperature fast-firing zinc silicate crystal glaze and method for preparing ceramic product |
| CN112608167A (en) * | 2021-01-21 | 2021-04-06 | 福建省德化县伯乐陶瓷有限公司 | Preparation method of crystal stripe ceramic glaze water |
| CN114956560A (en) * | 2022-06-17 | 2022-08-30 | 景德镇欧神诺陶瓷有限公司 | Crystalline glaze, preparation method thereof and crystalline glaze ceramic product |
| CN115650582A (en) * | 2022-09-07 | 2023-01-31 | 福建省德化县哈维陶瓷有限公司 | Sky blue ceramic matt glaze and manufacturing process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040266601A1 (en) * | 2003-06-27 | 2004-12-30 | Jih-Hsin Tsai | Far infrared emitting nano glaze |
| CN103232268A (en) * | 2013-05-13 | 2013-08-07 | 景德镇市宁封窑陶瓷文化发展有限公司 | Five-color exquisite glaze and five-color exquisite porcelain |
| CN104557148A (en) * | 2015-01-29 | 2015-04-29 | 大埔县宝丰陶瓷公共技术研发服务有限公司 | Rice-pattern decorated ceramic glaze with antimicrobial function and preparation method of rice-pattern decorated ceramic glaze |
-
2016
- 2016-12-30 CN CN201611256239.0A patent/CN106542737B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040266601A1 (en) * | 2003-06-27 | 2004-12-30 | Jih-Hsin Tsai | Far infrared emitting nano glaze |
| CN103232268A (en) * | 2013-05-13 | 2013-08-07 | 景德镇市宁封窑陶瓷文化发展有限公司 | Five-color exquisite glaze and five-color exquisite porcelain |
| CN104557148A (en) * | 2015-01-29 | 2015-04-29 | 大埔县宝丰陶瓷公共技术研发服务有限公司 | Rice-pattern decorated ceramic glaze with antimicrobial function and preparation method of rice-pattern decorated ceramic glaze |
Non-Patent Citations (1)
| Title |
|---|
| 贺文奇等: "《窑变神彩用科技解读传统钧瓷工艺》", 31 December 2015, 河南美术出版社 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110526579A (en) * | 2019-08-02 | 2019-12-03 | 东北大学 | A method of glaze is prepared using gold mine association alterated rocks |
| CN110526579B (en) * | 2019-08-02 | 2022-02-11 | 东北大学 | Method for preparing glaze by adopting gold ore associated altered rock |
| CN111592381A (en) * | 2020-06-16 | 2020-08-28 | 淄博汉青陶瓷有限公司 | Firing process of high-temperature in-glaze decoration |
| CN112142331A (en) * | 2020-11-19 | 2020-12-29 | 福建省德化县新宇陶瓷有限公司 | High-temperature fast-firing zinc silicate crystal glaze and method for preparing ceramic product |
| CN112608167A (en) * | 2021-01-21 | 2021-04-06 | 福建省德化县伯乐陶瓷有限公司 | Preparation method of crystal stripe ceramic glaze water |
| CN114956560A (en) * | 2022-06-17 | 2022-08-30 | 景德镇欧神诺陶瓷有限公司 | Crystalline glaze, preparation method thereof and crystalline glaze ceramic product |
| CN114956560B (en) * | 2022-06-17 | 2023-11-03 | 景德镇欧神诺陶瓷有限公司 | Crystal glaze, preparation method thereof and crystal glaze ceramic product |
| CN115650582A (en) * | 2022-09-07 | 2023-01-31 | 福建省德化县哈维陶瓷有限公司 | Sky blue ceramic matt glaze and manufacturing process thereof |
| CN115650582B (en) * | 2022-09-07 | 2023-07-14 | 福建省德化县哈维陶瓷有限公司 | Sky blue ceramic matte glaze and manufacturing process thereof |
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