CN106966736A - 一种基于陶瓷的3d打印材料 - Google Patents

一种基于陶瓷的3d打印材料 Download PDF

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CN106966736A
CN106966736A CN201710289751.3A CN201710289751A CN106966736A CN 106966736 A CN106966736 A CN 106966736A CN 201710289751 A CN201710289751 A CN 201710289751A CN 106966736 A CN106966736 A CN 106966736A
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Abstract

本发明公开了一种基于陶瓷的3D打印材料,包括以下重量份数的原料:纳米陶瓷材料15‑29份、木寡糖5‑13份、骨粉13‑21份、氧化镧2‑7份、二甲基硅氧烷5‑8份、醇酸树脂12‑28份、纳米银颗粒3‑10份、硅酸铝2‑8份、羧甲基甲壳素2‑7份、太白粉7‑23份、钛酸纤维素5‑12份、烟片胶5‑9份、植物灰烬8‑17份、季戊四醇三丙烯酸酯5‑11份、磷石膏4‑9份、丙二酸二甲酯105‑200份。该基于陶瓷的3D打印材料通过原料复配发挥协同作用,具有耐磨损能力高、抗冲击韧性强、拉伸强度高的优点;成型容易,成型工艺简单,符合3D打印材料的各种要求,可较好的应用于3D打印领域,市场推广价值好。

Description

一种基于陶瓷的3D打印材料
技术领域
本发明涉及一种打印材料,具体是一种基于陶瓷的3D打印材料。
背景技术
3D打印技术又称增材制造技术,是快速成型领域的一种新兴技术,它是一种以数字模型文件为基础,运用粉末状金属或塑料等可粘合材料,通过逐层打印的方式来构造物体的技术。随着3D打印技术的发展和应用,材料成为限制3D打印技术未来走向的关键因素之一,在某种程度上,材料的发展决定着3D打印能否有更广泛的应用。目前,3D打印材料主要包括工程塑料、光敏树脂、橡胶类材料、金属材料和陶瓷材料等,除此之外,彩色石膏材料、人造骨粉、细胞生物原料、木质材料以及砂糖等食品材料也在3D打印领域得到了应用。纳米陶瓷作为新型的陶瓷材料,以其优异的性能,具有广阔的市场应用前景,但纳米陶瓷材料成型困难,成型工艺复杂,很难满足纳米陶瓷在生产生活中的应用。因此,本发明提供一种基于陶瓷的3D打印材料。
发明内容
本发明的目的在于提供一种基于陶瓷的3D打印材料,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:
一种基于陶瓷的3D打印材料,包括以下重量份数的原料:纳米陶瓷材料15-29份、木寡糖5-13份、骨粉13-21份、氧化镧2-7份、二甲基硅氧烷5-8份、醇酸树脂12-28份、纳米银颗粒3-10份、硅酸铝2-8份、羧甲基甲壳素2-7份、太白粉7-23份、钛酸纤维素5-12份、烟片胶5-9份、植物灰烬8-17份、季戊四醇三丙烯酸酯5-11份、磷石膏4-9份、丙二酸二甲酯105-200份。
作为本发明进一步的方案:包括以下重量份数的原料:纳米陶瓷材料18份、木寡糖8份、骨粉17份、氧化镧5份、二甲基硅氧烷7份、醇酸树脂22份、纳米银颗粒8份、硅酸铝6份、羧甲基甲壳素3份、太白粉11份、钛酸纤维素9份、烟片胶6份、植物灰烬14份、季戊四醇三丙烯酸酯10份、磷石膏5份、丙二酸二甲酯145份。
作为本发明进一步的方案:包括以下重量份数的原料:纳米陶瓷材料24份、木寡糖12份、骨粉15份、氧化镧3份、二甲基硅氧烷6份、醇酸树脂14份、纳米银颗粒5份、硅酸铝4份、羧甲基甲壳素6份、太白粉20份、钛酸纤维素7份、烟片胶8份、植物灰烬11份、季戊四醇三丙烯酸酯8份、磷石膏8份、丙二酸二甲酯178份。
一种基于陶瓷的3D打印材料的制备方法,具体步骤为:
(1)按照上述配方称取各原料,备用;
(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡25-40min;
(3)将上步所得物在80-105℃温度下搅拌混合0.5-1h;
(4)将上步所得物沥干后加入木寡糖、氧化镧、二甲基硅氧烷、硅酸铝、羧甲基甲壳素、钛酸纤维素、烟片胶、季戊四醇三丙烯酸酯,混匀后进行熔融反应;
(5)将上步所得物冷却至65-70℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
作为本发明进一步的方案:所述步骤(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡35min。
作为本发明进一步的方案:所述步骤(3)将上步所得物在95℃温度下搅拌混合0.7h。
作为本发明进一步的方案:所述步骤(5)将上步所得物冷却至65-68℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
与现有技术相比,本发明的有益效果是:
该基于陶瓷的3D打印材料通过原料复配发挥协同作用,具有耐磨损能力高、抗冲击韧性强、拉伸强度高的优点;成型容易,成型工艺简单,符合3D打印材料的各种要求,可较好的应用于3D打印领域,市场推广价值好。
具体实施方式
下面结合具体实施方式对本专利的技术方案作进一步详细地说明。
实施例1
一种基于陶瓷的3D打印材料,包括以下重量份数的原料:纳米陶瓷材料15份、木寡糖5份、骨粉13份、氧化镧2份、二甲基硅氧烷5份、醇酸树脂12份、纳米银颗粒3份、硅酸铝2份、羧甲基甲壳素2份、太白粉7份、钛酸纤维素5份、烟片胶5份、植物灰烬8份、季戊四醇三丙烯酸酯5份、磷石膏4份、丙二酸二甲酯105份。
一种基于陶瓷的3D打印材料的制备方法,具体步骤为:
(1)按照上述配方称取各原料,备用;
(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡25min;
(3)将上步所得物在80-105℃温度下搅拌混合0.5h;
(4)将上步所得物沥干后加入木寡糖、氧化镧、二甲基硅氧烷、硅酸铝、羧甲基甲壳素、钛酸纤维素、烟片胶、季戊四醇三丙烯酸酯,混匀后进行熔融反应;
(5)将上步所得物冷却至65℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
实施例2
一种基于陶瓷的3D打印材料,包括以下重量份数的原料:纳米陶瓷材料29份、木寡糖13份、骨粉21份、氧化镧7份、二甲基硅氧烷8份、醇酸树脂28份、纳米银颗粒10份、硅酸铝8份、羧甲基甲壳素7份、太白粉23份、钛酸纤维素12份、烟片胶9份、植物灰烬17份、季戊四醇三丙烯酸酯11份、磷石膏9份、丙二酸二甲酯200份。
一种基于陶瓷的3D打印材料的制备方法,具体步骤为:
(1)按照上述配方称取各原料,备用;
(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡40min;
(3)将上步所得物在105℃温度下搅拌混合1h;
(4)将上步所得物沥干后加入木寡糖、氧化镧、二甲基硅氧烷、硅酸铝、羧甲基甲壳素、钛酸纤维素、烟片胶、季戊四醇三丙烯酸酯,混匀后进行熔融反应;
(5)将上步所得物冷却至70℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
实施例3
一种基于陶瓷的3D打印材料,作为本发明进一步的方案:包括以下重量份数的原料:纳米陶瓷材料18份、木寡糖8份、骨粉17份、氧化镧5份、二甲基硅氧烷7份、醇酸树脂22份、纳米银颗粒8份、硅酸铝6份、羧甲基甲壳素3份、太白粉11份、钛酸纤维素9份、烟片胶6份、植物灰烬14份、季戊四醇三丙烯酸酯10份、磷石膏5份、丙二酸二甲酯145份。
一种基于陶瓷的3D打印材料的制备方法,具体步骤为:
(1)按照上述配方称取各原料,备用;
(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡35min;
(3)将上步所得物在95℃温度下搅拌混合0.7h;
(4)将上步所得物沥干后加入木寡糖、氧化镧、二甲基硅氧烷、硅酸铝、羧甲基甲壳素、钛酸纤维素、烟片胶、季戊四醇三丙烯酸酯,混匀后进行熔融反应;
(5)将上步所得物冷却至65-68℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
实施例4
一种基于陶瓷的3D打印材料,包括以下重量份数的原料:纳米陶瓷材料24份、木寡糖12份、骨粉15份、氧化镧3份、二甲基硅氧烷6份、醇酸树脂14份、纳米银颗粒5份、硅酸铝4份、羧甲基甲壳素6份、太白粉20份、钛酸纤维素7份、烟片胶8份、植物灰烬11份、季戊四醇三丙烯酸酯8份、磷石膏8份、丙二酸二甲酯178份。
一种基于陶瓷的3D打印材料的制备方法,具体步骤为:
(1)按照上述配方称取各原料,备用;
(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡30min;
(3)将上步所得物在88℃温度下搅拌混合0.9h;
(4)将上步所得物沥干后加入木寡糖、氧化镧、二甲基硅氧烷、硅酸铝、羧甲基甲壳素、钛酸纤维素、烟片胶、季戊四醇三丙烯酸酯,混匀后进行熔融反应;
(5)将上步所得物冷却至68-70℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
经验证,与中国专利“一种用于3D打印的纳米陶瓷材料及其3D打印成型方法”(公开/公告号:CN105130402A)具体实施例相比,本发明实施例1-4所制备的基于陶瓷的3D打印材料的耐磨损能力提高40%以上;抗冲击韧性提高18-25%;拉伸强度提高8%左右。
该基于陶瓷的3D打印材料通过原料复配发挥协同作用,具有耐磨损能力高、抗冲击韧性强、拉伸强度高的优点;成型容易,成型工艺简单,符合3D打印材料的各种要求,可较好的应用于3D打印领域,市场推广价值好。
上面对本专利的较佳实施方式作了详细说明,但是本专利并不限于上述实施方式,在本领域的普通技术人员所具备的知识范围内,还可以在不脱离本专利宗旨的前提下做出各种变化。

Claims (7)

1.一种基于陶瓷的3D打印材料,其特征在于,包括以下重量份数的原料:纳米陶瓷材料15-29份、木寡糖5-13份、骨粉13-21份、氧化镧2-7份、二甲基硅氧烷5-8份、醇酸树脂12-28份、纳米银颗粒3-10份、硅酸铝2-8份、羧甲基甲壳素2-7份、太白粉7-23份、钛酸纤维素5-12份、烟片胶5-9份、植物灰烬8-17份、季戊四醇三丙烯酸酯5-11份、磷石膏4-9份、丙二酸二甲酯105-200份。
2.根据权利要求1所述的基于陶瓷的3D打印材料,其特征在于,包括以下重量份数的原料:纳米陶瓷材料18份、木寡糖8份、骨粉17份、氧化镧5份、二甲基硅氧烷7份、醇酸树脂22份、纳米银颗粒8份、硅酸铝6份、羧甲基甲壳素3份、太白粉11份、钛酸纤维素9份、烟片胶6份、植物灰烬14份、季戊四醇三丙烯酸酯10份、磷石膏5份、丙二酸二甲酯145份。
3.根据权利要求1所述的基于陶瓷的3D打印材料,其特征在于,包括以下重量份数的原料:纳米陶瓷材料24份、木寡糖12份、骨粉15份、氧化镧3份、二甲基硅氧烷6份、醇酸树脂14份、纳米银颗粒5份、硅酸铝4份、羧甲基甲壳素6份、太白粉20份、钛酸纤维素7份、烟片胶8份、植物灰烬11份、季戊四醇三丙烯酸酯8份、磷石膏8份、丙二酸二甲酯178份。
4.一种如权利要求1-3任一所述的基于陶瓷的3D打印材料的制备方法,其特征在于,具体步骤为:
(1)按照上述配方称取各原料,备用;
(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡25-40min;
(3)将上步所得物在80-105℃温度下搅拌混合0.5-1h;
(4)将上步所得物沥干后加入木寡糖、氧化镧、二甲基硅氧烷、硅酸铝、羧甲基甲壳素、钛酸纤维素、烟片胶、季戊四醇三丙烯酸酯,混匀后进行熔融反应;
(5)将上步所得物冷却至65-70℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
5.根据权利要求4所述的基于陶瓷的3D打印材料的制备方法,其特征在于,所述步骤(2)将纳米陶瓷材料、醇酸树脂、骨粉、纳米银颗粒、太白粉、磷石膏、植物灰烬浸泡在盛有丙二酸二甲酯的容器中,并将容器放在超声清洗槽中超声,常温下浸泡35min。
6.根据权利要求4所述的基于陶瓷的3D打印材料的制备方法,其特征在于,所述步骤(3)将上步所得物在95℃温度下搅拌混合0.7h。
7.根据权利要求4所述的基于陶瓷的3D打印材料的制备方法,其特征在于,所述步骤(5)将上步所得物冷却至65-68℃,放入挤出机中,加热挤出,真空干燥,即得目标产物。
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