CN106955600B - 一种片式分子筛膜的制备方法 - Google Patents
一种片式分子筛膜的制备方法 Download PDFInfo
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- CN106955600B CN106955600B CN201710226207.4A CN201710226207A CN106955600B CN 106955600 B CN106955600 B CN 106955600B CN 201710226207 A CN201710226207 A CN 201710226207A CN 106955600 B CN106955600 B CN 106955600B
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- carrier
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- 239000012528 membrane Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 238000002425 crystallisation Methods 0.000 claims abstract description 50
- 230000008025 crystallization Effects 0.000 claims abstract description 50
- 238000010899 nucleation Methods 0.000 claims abstract description 38
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 36
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 36
- 238000005266 casting Methods 0.000 claims abstract description 17
- 239000013078 crystal Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- DKNWSYNQZKUICI-UHFFFAOYSA-N amantadine Chemical compound C1C(C2)CC3CC2CC1(N)C3 DKNWSYNQZKUICI-UHFFFAOYSA-N 0.000 claims description 8
- 229960003805 amantadine Drugs 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 238000002604 ultrasonography Methods 0.000 claims description 4
- 239000005457 ice water Substances 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical compound C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 150000004985 diamines Chemical class 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000010408 film Substances 0.000 description 56
- 238000011160 research Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
- B01D71/027—Silicium oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0051—Inorganic membrane manufacture by controlled crystallisation, e,.g. hydrothermal growth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/06—Flat membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electrochemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Silicon Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Description
Claims (7)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810161064.8A CN108246121B (zh) | 2017-04-08 | 2017-04-08 | 一种片式分子筛膜的制备方法 |
CN201710226207.4A CN106955600B (zh) | 2017-04-08 | 2017-04-08 | 一种片式分子筛膜的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710226207.4A CN106955600B (zh) | 2017-04-08 | 2017-04-08 | 一种片式分子筛膜的制备方法 |
Related Child Applications (1)
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CN201810161064.8A Division CN108246121B (zh) | 2017-04-08 | 2017-04-08 | 一种片式分子筛膜的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN106955600A CN106955600A (zh) | 2017-07-18 |
CN106955600B true CN106955600B (zh) | 2018-09-18 |
Family
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Family Applications (2)
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CN201810161064.8A Expired - Fee Related CN108246121B (zh) | 2017-04-08 | 2017-04-08 | 一种片式分子筛膜的制备方法 |
CN201710226207.4A Active CN106955600B (zh) | 2017-04-08 | 2017-04-08 | 一种片式分子筛膜的制备方法 |
Family Applications Before (1)
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CN201810161064.8A Expired - Fee Related CN108246121B (zh) | 2017-04-08 | 2017-04-08 | 一种片式分子筛膜的制备方法 |
Country Status (1)
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CN (2) | CN108246121B (zh) |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5356016B2 (ja) * | 2006-03-14 | 2013-12-04 | 日本碍子株式会社 | Ddr型ゼオライト膜の製造方法 |
CN101279209A (zh) * | 2008-05-20 | 2008-10-08 | 吉林大学 | 高渗透性a型分子筛膜的制备方法 |
CN101708436B (zh) * | 2009-11-05 | 2012-05-23 | 浙江大学 | 一种分子筛复合膜 |
CN102639441B (zh) * | 2009-12-10 | 2014-10-22 | 日本碍子株式会社 | Ddr型沸石的制造方法 |
CN101920170B (zh) * | 2010-08-10 | 2012-10-10 | 南京工业大学 | 一种高通量的分子筛透醇膜及其制备方法 |
CN101962196B (zh) * | 2010-08-12 | 2012-02-22 | 南京工业大学 | 一种分子筛膜及其制备方法 |
WO2012138418A1 (en) * | 2011-04-04 | 2012-10-11 | Georgia Tech Research Corporation | Zeolite ddr nanocrystals |
CN102600735B (zh) * | 2012-03-29 | 2014-09-03 | 吉林大学 | 一种无机相分离膜及其在油水分离中的应用 |
EP2832694B1 (en) * | 2012-03-30 | 2022-08-17 | NGK Insulators, Ltd. | Method for manufacturing a ddr zeolite type seed crystal |
CN104986783B (zh) * | 2015-07-03 | 2018-09-25 | 中国科学院上海高等研究院 | 一种制备全硅dd3r分子筛的方法 |
CN105129812B (zh) * | 2015-08-21 | 2017-06-06 | 中国科学院上海高等研究院 | 一种快速合成dd3r分子筛的制备方法 |
-
2017
- 2017-04-08 CN CN201810161064.8A patent/CN108246121B/zh not_active Expired - Fee Related
- 2017-04-08 CN CN201710226207.4A patent/CN106955600B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN106955600A (zh) | 2017-07-18 |
CN108246121A (zh) | 2018-07-06 |
CN108246121B (zh) | 2020-11-10 |
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TA01 | Transfer of patent application right |
Effective date of registration: 20180227 Address after: No. 125, No. 125, Ho Lou village, Datian village, Datian Town, Chengwu County, Chengwu, Shandong Applicant after: He Weikang Address before: 262700 Jinhai Road, Shouguang Road, Shouguang City, Weifang, Shandong Province, No. 3101, Shouguang modern middle school, class 39, class 2016 Applicant before: Hao Zhizhen |
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TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20180802 Address after: 318050 No. 65 new avenue, Xinqiao Town, Luqiao District, Taizhou, Zhejiang. Applicant after: Xie Liping Address before: 274300 No. 125, Ho Lou village, Ho Lou administrative village, Datian Town, Chengwu, Heze, Shandong, 2 Applicant before: He Weikang |
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Effective date of registration: 20200107 Address after: No.41-b101, kengziheng Road, Pingshan New District, Shenzhen City, Guangzhou City, Guangdong Province Patentee after: Shenzhen Pristine Polymer Material Co., Ltd. Address before: 318050 No. 65 Xinqiao Street, Luqiao Xinqiao Town, Luqiao District, Taizhou City, Zhejiang Province Patentee before: Xie Liping |
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TR01 | Transfer of patent right |